ATE168588T1 - Verfahren zur verbesserung der physikalischen und katalytischen eigenschaften von fluidisierten krackkatalysatoren - Google Patents

Verfahren zur verbesserung der physikalischen und katalytischen eigenschaften von fluidisierten krackkatalysatoren

Info

Publication number
ATE168588T1
ATE168588T1 AT91915205T AT91915205T ATE168588T1 AT E168588 T1 ATE168588 T1 AT E168588T1 AT 91915205 T AT91915205 T AT 91915205T AT 91915205 T AT91915205 T AT 91915205T AT E168588 T1 ATE168588 T1 AT E168588T1
Authority
AT
Austria
Prior art keywords
physical
particles
catalytic properties
improving
cracking catalysts
Prior art date
Application number
AT91915205T
Other languages
English (en)
Inventor
Joseph C S Shi
Edwin W Dr Albers
Geoffrey R Wilson
Original Assignee
Thiele Kaolin Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Thiele Kaolin Co filed Critical Thiele Kaolin Co
Application granted granted Critical
Publication of ATE168588T1 publication Critical patent/ATE168588T1/de

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C10G11/02—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils characterised by the catalyst used
    • C10G11/04—Oxides
    • C10G11/05—Crystalline alumino-silicates, e.g. molecular sieves
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/06—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/12—Silica and alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/16—Clays or other mineral silicates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B01J29/084—Y-type faujasite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0027—Powdering
    • B01J37/0045—Drying a slurry, e.g. spray drying
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0236—Drying, e.g. preparing a suspension, adding a soluble salt and drying
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B21/00—Nitrogen; Compounds thereof
    • C01B21/06—Binary compounds of nitrogen with metals, with silicon, or with boron, or with carbon, i.e. nitrides; Compounds of nitrogen with more than one metal, silicon or boron
    • C01B21/068—Binary compounds of nitrogen with metals, with silicon, or with boron, or with carbon, i.e. nitrides; Compounds of nitrogen with more than one metal, silicon or boron with silicon
    • C01B21/0687—After-treatment, e.g. grinding, purification
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
    • C01F5/00—Compounds of magnesium
    • C01F5/02—Magnesia
    • C01F5/06—Magnesia by thermal decomposition of magnesium compounds
    • C01F5/08—Magnesia by thermal decomposition of magnesium compounds by calcining magnesium hydroxide
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
    • C01F7/00—Compounds of aluminium
    • C01F7/02—Aluminium oxide; Aluminium hydroxide; Aluminates
    • C01F7/04—Preparation of alkali metal aluminates; Aluminium oxide or hydroxide therefrom
    • C01F7/14—Aluminium oxide or hydroxide from alkali metal aluminates
    • C01F7/141—Aluminium oxide or hydroxide from alkali metal aluminates from aqueous aluminate solutions by neutralisation with an acidic agent
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
    • C01F7/00—Compounds of aluminium
    • C01F7/02—Aluminium oxide; Aluminium hydroxide; Aluminates
    • C01F7/34—Preparation of aluminium hydroxide by precipitation from solutions containing aluminium salts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/42—Addition of matrix or binder particles
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/01—Particle morphology depicted by an image
    • C01P2004/03—Particle morphology depicted by an image obtained by SEM
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/30—Particle morphology extending in three dimensions
    • C01P2004/32—Spheres
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/50—Agglomerated particles
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/60—Particles characterised by their size
    • C01P2004/61—Micrometer sized, i.e. from 1-100 micrometer
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/12—Surface area
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/21—Attrition-index or crushing strength of granulates

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Analytical Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Thermal Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Dispersion Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
AT91915205T 1990-08-06 1991-08-05 Verfahren zur verbesserung der physikalischen und katalytischen eigenschaften von fluidisierten krackkatalysatoren ATE168588T1 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US07/562,905 US5135756A (en) 1989-03-10 1990-08-06 Process for improving the physical and catalytic properties of a fluid cracking catalyst

Publications (1)

Publication Number Publication Date
ATE168588T1 true ATE168588T1 (de) 1998-08-15

Family

ID=24248289

Family Applications (1)

Application Number Title Priority Date Filing Date
AT91915205T ATE168588T1 (de) 1990-08-06 1991-08-05 Verfahren zur verbesserung der physikalischen und katalytischen eigenschaften von fluidisierten krackkatalysatoren

Country Status (10)

Country Link
US (1) US5135756A (de)
EP (1) EP0542871B1 (de)
JP (1) JP2918335B2 (de)
AT (1) ATE168588T1 (de)
AU (1) AU658367B2 (de)
BR (1) BR9103379A (de)
DE (1) DE69129854T2 (de)
FI (1) FI930517L (de)
NZ (1) NZ239272A (de)
WO (1) WO1992002299A1 (de)

Families Citing this family (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5330943A (en) * 1989-03-10 1994-07-19 Thiele Kaolin Company Process for improving the physical and catalytic properties of a fluid cracking catalyst
US5866496A (en) * 1989-03-10 1999-02-02 Thiele Kaolin Company Cracking catalyst and process for preparing same
US5711930A (en) * 1989-03-10 1998-01-27 Thiele Kaolin Company Process for improving the phyiscal properties of formed particles
US4946814A (en) * 1989-03-10 1990-08-07 Thiele-Kaolin Company Process for improving the physical and catalytic properties of fluid cracking catalysts
US5114895A (en) * 1990-02-22 1992-05-19 Uop Alumina clay compositions
AU3595095A (en) * 1994-09-26 1996-04-19 Thiele Kaolin Company Cracking catalyst and process for preparing same
US5714431A (en) * 1994-10-19 1998-02-03 Research Triangle Institute Zinc titanate sorbents
US5972835A (en) * 1995-09-13 1999-10-26 Research Triangle Institute Fluidizable particulate materials and methods of making same
US6680271B1 (en) 1997-12-17 2004-01-20 Grace Gmbh & Co. Kg Solid zeolite granulates having improved abrasion resistance, and methods of making them
CN1096296C (zh) 1998-11-13 2002-12-18 中国石油化工集团公司 一种生产中间馏分油的加氢裂化催化剂及其制备
EP1421044B1 (de) 2001-07-02 2007-03-07 Exxonmobil Chemical Patents Inc. Inhibierung der katalysatorverkokung bei der herstellung eines olefins
US7271123B2 (en) 2002-03-20 2007-09-18 Exxonmobil Chemical Patents Inc. Molecular sieve catalyst composition, its making and use in conversion process
US6872680B2 (en) * 2002-03-20 2005-03-29 Exxonmobil Chemical Patents Inc. Molecular sieve catalyst composition, its making and use in conversion processes
EP1623965A1 (de) * 2004-07-21 2006-02-08 Walsin Lihwa Corporation Tonmischung und Verfahren zu deren Herstellung
US7309679B2 (en) * 2005-08-08 2007-12-18 Uop Llc Attrition resistant MTO catalyst
US20100264066A1 (en) * 2006-07-06 2010-10-21 Ranjit Kumar Aluminum sulfate bound catalysts
WO2009085189A2 (en) * 2007-12-20 2009-07-09 W. R. Grace & Co. - Conn. Process for preparing high attrition resistant inorganic compositions and compositions prepared therefrom
JP5628027B2 (ja) * 2008-05-30 2014-11-19 日揮触媒化成株式会社 炭化水素油の流動接触分解触媒及びそれを用いた炭化水素油の流動接触分解方法
CN101733141B (zh) * 2008-11-20 2012-07-04 中国石油化工股份有限公司 一种催化裂化催化剂及其制备方法
EP2221285A1 (de) * 2009-02-24 2010-08-25 Ecotech Polka Sp. z.o.o. Zusammensetzung und Verfahren zur Stabilisierung von umweltschädlichen Substanzen, Verwendung von eisenfreien Metallsalzen und -oxiden zur Stabilisierung von umweltschädlichen Substanzen mit kaustischem Magnesiumoxid
US9725335B2 (en) * 2013-03-12 2017-08-08 The Frazer And Cruickshank Living Trust Dated 3/24/1982 Removal of copper from aqueous streams using an iron promoted activated alumina
CA2925010A1 (en) * 2013-10-15 2015-04-23 Basf Corporation Mesoporous fcc catalysts with excellent attrition resistance
KR102351691B1 (ko) * 2017-10-24 2022-01-14 사우디 아라비안 오일 컴퍼니 스프레이-건조된 복분해(metathesis) 촉매의 제조 방법 및 이의 사용 방법
CN114433173B (zh) * 2020-10-16 2023-09-05 中国石油化工股份有限公司 一种制备低表观松密度fcc催化剂的方法
WO2023239560A1 (en) 2022-06-09 2023-12-14 Formosa Plastics Corporaton, U.S.A. Clay composite support-activators and catalyst compositions

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JP2546734B2 (ja) * 1990-05-07 1996-10-23 株式会社ジャパンエナジー 触媒用アルミナの製造方法

Also Published As

Publication number Publication date
US5135756A (en) 1992-08-04
NZ239272A (en) 1994-11-25
FI930517A7 (fi) 1993-04-05
JPH06501876A (ja) 1994-03-03
DE69129854T2 (de) 1999-03-04
WO1992002299A1 (en) 1992-02-20
DE69129854D1 (de) 1998-08-27
AU8418191A (en) 1992-03-02
AU658367B2 (en) 1995-04-13
EP0542871A1 (de) 1993-05-26
FI930517A0 (fi) 1993-02-05
BR9103379A (pt) 1992-05-12
EP0542871B1 (de) 1998-07-22
FI930517L (fi) 1993-04-05
JP2918335B2 (ja) 1999-07-12
EP0542871A4 (en) 1993-07-28

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