ATE217877T1 - Unverbrückte substituierte indenyl-metallocene - Google Patents

Unverbrückte substituierte indenyl-metallocene

Info

Publication number
ATE217877T1
ATE217877T1 AT97105257T AT97105257T ATE217877T1 AT E217877 T1 ATE217877 T1 AT E217877T1 AT 97105257 T AT97105257 T AT 97105257T AT 97105257 T AT97105257 T AT 97105257T AT E217877 T1 ATE217877 T1 AT E217877T1
Authority
AT
Austria
Prior art keywords
substituted indenyl
indenyl metallocenes
unbridged
unbridged substituted
metallocenes
Prior art date
Application number
AT97105257T
Other languages
English (en)
Inventor
Claudia Schmid
Helmut G Alt
Melvin Bruce Welch
Original Assignee
Phillips Petroleum Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Phillips Petroleum Co filed Critical Phillips Petroleum Co
Application granted granted Critical
Publication of ATE217877T1 publication Critical patent/ATE217877T1/de

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65925—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually non-bridged
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
AT97105257T 1996-03-29 1997-03-27 Unverbrückte substituierte indenyl-metallocene ATE217877T1 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US08/622,907 US5780659A (en) 1996-03-29 1996-03-29 Substituted indenyl unbridged metallocenes

Publications (1)

Publication Number Publication Date
ATE217877T1 true ATE217877T1 (de) 2002-06-15

Family

ID=24495992

Family Applications (1)

Application Number Title Priority Date Filing Date
AT97105257T ATE217877T1 (de) 1996-03-29 1997-03-27 Unverbrückte substituierte indenyl-metallocene

Country Status (13)

Country Link
US (2) US5780659A (de)
EP (1) EP0798306B1 (de)
JP (1) JPH107692A (de)
KR (1) KR970065549A (de)
CN (1) CN1065868C (de)
AT (1) ATE217877T1 (de)
AU (1) AU701588B2 (de)
CA (1) CA2198954C (de)
DE (1) DE69712667T2 (de)
ES (1) ES2173350T3 (de)
HU (1) HU218358B (de)
NO (1) NO971461L (de)
SG (1) SG96172A1 (de)

Families Citing this family (47)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2067525C (en) * 1991-05-09 1998-09-15 Helmut G. Alt Organometallic fluorenyl compounds, preparation and use
US5780659A (en) * 1996-03-29 1998-07-14 Phillips Petroleum Company Substituted indenyl unbridged metallocenes
DE19637669A1 (de) 1996-09-16 1998-03-19 Hoechst Ag Verfahren zur Herstellung einer methylenverbrückten Biscyclopentadienylverbindung
DE69705186T2 (de) 1996-10-30 2002-03-14 Repsol Quimica S.A., Madrid Katalysatorsysteme für die (Co)Polymerisation von Alpha-Olefinen
EP0839836B1 (de) * 1996-10-31 2000-12-20 Repsol Quimica S.A. Katalysatorsysteme für die Polymerisation und Copolymerisation von Alpha-Olefinen
US6180736B1 (en) * 1996-12-20 2001-01-30 Exxon Chemical Patents Inc High activity metallocene polymerization process
US5886202A (en) * 1997-01-08 1999-03-23 Jung; Michael Bridged fluorenyl/indenyl metallocenes and the use thereof
CA2292538A1 (en) * 1997-06-14 1998-12-23 Charles L. Myers Ethylene enhancement of processes for synthesis of high melting thermoplastic elastomeric .alpha.-olefin polymers (pre/epe effects)
DE69737776T2 (de) 1997-07-09 2008-01-31 Maruzen Petrochemical Co., Ltd. Katalysatorbestandteil zur Olefinpolymerisation
US6486278B1 (en) * 1998-02-17 2002-11-26 Exxonmobil Chemical Patents Inc. Ethylene copolymerization process
PT953581E (pt) 1998-04-27 2004-07-30 Repsol Quimica Sa Sistemas cataliticos para a polimerizacao e a copolimerizacao de alfa-olefinas
PT953580E (pt) * 1998-04-29 2004-09-30 Repsol Quimica Sa Preparacao e uso de componentes catalisadores heterogeneos para polimerizacao de olefinas
US6262201B1 (en) 1998-06-19 2001-07-17 Phillips Petroleum Company Aryl substituted metallocene catalysts and their use
US6482905B1 (en) * 1999-08-16 2002-11-19 Phillips Petroleum Company Unsymmetric unbridged bis-indenyl metallocenes and their use
IT1314261B1 (it) * 1999-12-03 2002-12-06 Enichem Spa Composti metallocenici pontati, processo per la loro preparazione eloro uso come catalizzatori per la polimerizzazione di olefine.
KR100404780B1 (ko) 2000-02-18 2003-11-07 대림산업 주식회사 메탈로센 화합물과 이로부터 제조되는 메탈로센 촉매 및이를 이용한 올레핀의 중합 방법
KR100447799B1 (ko) * 2001-01-03 2004-09-08 대림산업 주식회사 메탈로센 화합물 및 이를 포함하는 촉매 조성물
KR100677869B1 (ko) * 2004-07-01 2007-02-02 대림산업 주식회사 다중핵 금속 화합물, 이를 포함하는 촉매 시스템 및 이를이용한 올레핀의 중합 방법
US7226886B2 (en) 2005-09-15 2007-06-05 Chevron Phillips Chemical Company, L.P. Polymerization catalysts and process for producing bimodal polymers in a single reactor
US7312283B2 (en) * 2005-08-22 2007-12-25 Chevron Phillips Chemical Company Lp Polymerization catalysts and process for producing bimodal polymers in a single reactor
US7598329B2 (en) 2005-11-04 2009-10-06 Ticona Gmbh Process for manufacturing ultra high molecular weight polymers using novel bridged metallocene catalysts
US8034886B2 (en) 2005-11-04 2011-10-11 Ticona Gmbh Process for manufacturing high to ultra high molecular weight polymers using novel bridged metallocene catalysts
US7619047B2 (en) * 2006-02-22 2009-11-17 Chevron Phillips Chemical Company, Lp Dual metallocene catalysts for polymerization of bimodal polymers
EP2591017B1 (de) 2010-07-06 2015-09-09 Ticona GmbH Verfahren zur herstellung von polyethylen mit ultrahohem molekulargewicht
BR112012032745A2 (pt) 2010-07-06 2016-11-08 Ticona Gmbh processo para produção de polietileno de alto peso molecular
CN102959144A (zh) 2010-07-06 2013-03-06 提克纳有限公司 高分子量聚乙烯纤维和膜、它们的生产和用途
WO2012004680A2 (en) 2010-07-06 2012-01-12 Ticona Gmbh Process for producing high molecular weight polyethylene
JP2013529718A (ja) 2010-07-06 2013-07-22 ティコナ ゲゼルシャフト ミット ベシュレンクテル ハフツング 高分子量ポリエチレンの製造方法
WO2013093540A1 (en) 2011-12-19 2013-06-27 Ticona Gmbh Process for producing high molecular weight polyethylene
EP2679594A1 (de) 2012-06-25 2014-01-01 Daelim Industrial Co., Ltd. Metallocenverbindung, Katalysatorzusammensetzung damit und Olefinpolymerisierungsverfahren damit
RU2529020C2 (ru) * 2012-10-17 2014-09-27 ЭлДжи КЕМ, ЛТД. Новое металлоценовое соединение, содержащая его каталитическая композиция и способ получения полимеров на основе олефинов с ее применением
US8895679B2 (en) 2012-10-25 2014-11-25 Chevron Phillips Chemical Company Lp Catalyst compositions and methods of making and using same
US8937139B2 (en) 2012-10-25 2015-01-20 Chevron Phillips Chemical Company Lp Catalyst compositions and methods of making and using same
US9034991B2 (en) 2013-01-29 2015-05-19 Chevron Phillips Chemical Company Lp Polymer compositions and methods of making and using same
US8877672B2 (en) 2013-01-29 2014-11-04 Chevron Phillips Chemical Company Lp Catalyst compositions and methods of making and using same
US9266910B2 (en) 2013-10-29 2016-02-23 Exxonmobil Chemical Patents Inc. Asymmetric polypropylene catalysts
US9376559B2 (en) 2013-11-22 2016-06-28 Exxonmobil Chemical Patents Inc. Reverse staged impact copolymers
SG11201606592VA (en) * 2014-02-11 2016-09-29 Univation Tech Llc Producing polyethylene products with improved stiffness, toughness, and processability
KR101566328B1 (ko) * 2014-06-03 2015-11-05 주식회사 엘지화학 메탈로센 화합물 및 그 제조방법
KR101973191B1 (ko) 2015-06-05 2019-04-26 주식회사 엘지화학 메탈로센 담지 촉매 및 이를 이용하는 폴리올레핀의 제조 방법
KR101926833B1 (ko) 2015-06-05 2019-03-07 주식회사 엘지화학 메탈로센 화합물
ES2923003T3 (es) 2016-09-30 2022-09-22 Univation Tech Llc Catalizadores de polimerización
CN113748140B (zh) * 2019-04-30 2025-03-11 陶氏环球技术有限责任公司 金属-配体络合物
US11186665B2 (en) 2019-10-04 2021-11-30 Chevron Phillips Chemical Company Lp Catalyst composition and method for preparing polyethylene
US11667777B2 (en) 2019-10-04 2023-06-06 Chevron Phillips Chemical Company Lp Bimodal polyethylene copolymers
KR102687445B1 (ko) * 2020-03-17 2024-07-23 한화솔루션 주식회사 전이금속 화합물의 제조방법
WO2023150480A1 (en) 2022-02-07 2023-08-10 Exxonmobil Chemical Patents Inc. C1 symmetric 5-ome-6-alkyl substituted metallocenes

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5084534A (en) * 1987-06-04 1992-01-28 Exxon Chemical Patents, Inc. High pressure, high temperature polymerization of ethylene
US5223467A (en) * 1988-07-15 1993-06-29 Fina Technology, Inc. Process and catalyst for producing syndiotactic polymers
IT8919252A0 (it) * 1989-01-31 1989-01-31 Ilano Catalizzatori per la polimerizzazione di olefine.
IT1237398B (it) * 1989-01-31 1993-06-01 Ausimont Srl Catalizzatori per la polimerizzazione di olefine.
US5225092A (en) * 1990-02-01 1993-07-06 Exxon Chemical Patents Inc. Ethylene alpha-olefin polymer substituted amine dispersant additives
EP0538749B1 (de) * 1991-10-21 1995-01-11 Mitsubishi Petrochemical Co., Ltd. Propylencopolymerzusammensetzung
DE69221283T2 (de) * 1992-01-08 1998-01-02 Nippon Oil Co Ltd Verfahren zur Herstellung von Polysilanen
NL9201970A (nl) * 1992-11-11 1994-06-01 Dsm Nv Indenylverbindingen en katalysatorcomponenten voor de polymerisatie van olefinen.
DE4344688A1 (de) * 1993-12-27 1995-06-29 Hoechst Ag Metallocenverbindung
US5594080A (en) * 1994-03-24 1997-01-14 Leland Stanford, Jr. University Thermoplastic elastomeric olefin polymers, method of production and catalysts therefor
US5498581A (en) * 1994-06-01 1996-03-12 Phillips Petroleum Company Method for making and using a supported metallocene catalyst system
US5541272A (en) * 1994-06-03 1996-07-30 Phillips Petroleum Company High activity ethylene selective metallocenes
US5780659A (en) * 1996-03-29 1998-07-14 Phillips Petroleum Company Substituted indenyl unbridged metallocenes

Also Published As

Publication number Publication date
AU1638997A (en) 1997-10-02
NO971461D0 (no) 1997-03-26
CA2198954A1 (en) 1997-09-29
ES2173350T3 (es) 2002-10-16
AU701588B2 (en) 1999-02-04
JPH107692A (ja) 1998-01-13
DE69712667D1 (de) 2002-06-27
EP0798306B1 (de) 2002-05-22
CN1065868C (zh) 2001-05-16
HUP9700674A3 (en) 2000-03-28
HUP9700674A2 (en) 1997-12-29
EP0798306A1 (de) 1997-10-01
MX9702083A (es) 1998-03-31
SG96172A1 (en) 2003-05-23
NO971461L (no) 1997-09-30
DE69712667T2 (de) 2002-10-17
HU218358B (hu) 2000-08-28
US5780659A (en) 1998-07-14
KR970065549A (ko) 1997-10-13
CN1164535A (zh) 1997-11-12
CA2198954C (en) 2000-09-05
US6037427A (en) 2000-03-14

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