ATE217891T1 - Metallocen-alumoxan-trägerkatalysator für die herstellung von polyethylen mit breiter monomodaler molekulargewichtsverteilung - Google Patents
Metallocen-alumoxan-trägerkatalysator für die herstellung von polyethylen mit breiter monomodaler molekulargewichtsverteilungInfo
- Publication number
- ATE217891T1 ATE217891T1 AT97102116T AT97102116T ATE217891T1 AT E217891 T1 ATE217891 T1 AT E217891T1 AT 97102116 T AT97102116 T AT 97102116T AT 97102116 T AT97102116 T AT 97102116T AT E217891 T1 ATE217891 T1 AT E217891T1
- Authority
- AT
- Austria
- Prior art keywords
- metallocene
- production
- molecular weight
- weight distribution
- polyethylene
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title abstract 2
- 238000004519 manufacturing process Methods 0.000 title abstract 2
- -1 POLYETHYLENE Polymers 0.000 title 1
- 239000004698 Polyethylene Substances 0.000 title 1
- 229920000573 polyethylene Polymers 0.000 title 1
- 229920001577 copolymer Polymers 0.000 abstract 1
- 125000003983 fluorenyl group Chemical group C1(=CC=CC=2C3=CC=CC=C3CC12)* 0.000 abstract 1
- 229920001903 high density polyethylene Polymers 0.000 abstract 1
- 239000004700 high-density polyethylene Substances 0.000 abstract 1
- 229920001519 homopolymer Polymers 0.000 abstract 1
- 125000003454 indenyl group Chemical group C1(C=CC2=CC=CC=C12)* 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/934—Electrodeposit, e.g. electrophoretic, xerographic
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP96200422 | 1996-02-19 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ATE217891T1 true ATE217891T1 (de) | 2002-06-15 |
Family
ID=8223694
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AT97102116T ATE217891T1 (de) | 1996-02-19 | 1997-02-11 | Metallocen-alumoxan-trägerkatalysator für die herstellung von polyethylen mit breiter monomodaler molekulargewichtsverteilung |
Country Status (9)
| Country | Link |
|---|---|
| US (2) | US5914289A (de) |
| EP (1) | EP0790259B1 (de) |
| JP (1) | JPH09227613A (de) |
| AT (1) | ATE217891T1 (de) |
| CA (1) | CA2197848C (de) |
| DE (1) | DE69712652T2 (de) |
| DK (1) | DK0790259T3 (de) |
| ES (1) | ES2176536T3 (de) |
| PT (1) | PT790259E (de) |
Families Citing this family (83)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5968864A (en) * | 1996-12-20 | 1999-10-19 | Fina Technology, Inc. | Catalyst efficiency for supported metallocene catalyst |
| EP0953582A1 (de) * | 1998-04-27 | 1999-11-03 | Fina Research S.A. | Herstellung von Polyolefin |
| EP0989141A1 (de) * | 1998-09-25 | 2000-03-29 | Fina Research S.A. | Herstellung von multimodalem Polyäthylen |
| US6346586B1 (en) * | 1999-10-22 | 2002-02-12 | Univation Technologies, Llc | Method for preparing a supported catalyst system and its use in a polymerization process |
| JP4542664B2 (ja) * | 2000-04-13 | 2010-09-15 | 日本ポリプロ株式会社 | プロピレン系重合体の製造方法 |
| ES2427626T3 (es) | 2003-02-21 | 2013-10-31 | Styron Europe Gmbh | Procedimiento para homo- o copolimerización de olefinas conjugadas |
| ATE361323T1 (de) * | 2004-03-12 | 2007-05-15 | Saudi Basic Ind Corp | Katalysatorzusammensetzung für die polymerisation von olefinen und polymerisationsverfahren unter dessen verwendung |
| KR100753478B1 (ko) | 2005-02-15 | 2007-08-31 | 주식회사 엘지화학 | 혼성 담지 메탈로센 촉매 및 이를 이용한 폴리에틸렌 공중합체의 제조방법 |
| US20100137532A1 (en) * | 2006-10-19 | 2010-06-03 | Odilia Perez-Camacho | Catalyst to polymerize olefins and conjugated dienes in heterogeneous phase, process for obtaining and using the same |
| KR101249995B1 (ko) | 2008-12-11 | 2013-04-03 | 주식회사 엘지화학 | 혼성 담지 메탈로센 촉매, 이의 제조방법 및 이를 이용한 올레핀계 중합체의 제조방법 |
| WO2015056975A1 (ko) | 2013-10-18 | 2015-04-23 | 주식회사 엘지화학 | 혼성 담지 메탈로센 촉매 |
| KR101644113B1 (ko) | 2013-10-18 | 2016-07-29 | 주식회사 엘지화학 | 혼성 담지 메탈로센 촉매 |
| WO2015056974A1 (ko) | 2013-10-18 | 2015-04-23 | 주식회사 엘지화학 | 혼성 담지 메탈로센 촉매의 제조방법 |
| KR101631700B1 (ko) | 2013-10-18 | 2016-06-17 | 주식회사 엘지화학 | 혼성 담지 메탈로센 촉매의 제조방법 |
| WO2015072658A1 (ko) | 2013-11-18 | 2015-05-21 | 주식회사 엘지화학 | 가공성이 우수한 올레핀계 중합체 |
| KR101549209B1 (ko) | 2013-11-18 | 2015-09-02 | 주식회사 엘지화학 | 가공성이 우수한 올레핀계 중합체 |
| EP3031831B1 (de) | 2014-09-05 | 2019-06-19 | LG Chem, Ltd. | Hybrider geträgerter katalysator und verfahren zur herstellung eines olefinbasierten polymers damit |
| KR101617870B1 (ko) | 2014-09-05 | 2016-05-03 | 주식회사 엘지화학 | 가공성이 우수한 올레핀계 중합체 |
| WO2016060445A1 (ko) | 2014-10-13 | 2016-04-21 | 주식회사 엘지화학 | 가공성 및 환경 응력 균열 저항성이 우수한 에틸렌 /1-헥센 또는 에틸렌 /1-부텐 공중합체 |
| EP3056524B1 (de) | 2014-10-13 | 2021-09-22 | LG Chem, Ltd. | Ethylen/1-butencopolymer mit hervorragender bearbeitbarkeit und spannungsrissbeständigkeit |
| KR101725351B1 (ko) | 2014-12-04 | 2017-04-10 | 주식회사 엘지화학 | 혼성 담지 메탈로센 촉매의 제조방법 및 이를 이용하여 제조된 혼성 담지 메탈로센 촉매 |
| KR101747401B1 (ko) | 2014-12-08 | 2017-06-14 | 주식회사 엘지화학 | 가공성이 우수한 에틸렌/알파-올레핀 공중합체 |
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| JP6499280B2 (ja) | 2014-12-12 | 2019-04-10 | エルジー・ケム・リミテッド | メタロセン担持触媒およびこれを用いるポリオレフィンの製造方法 |
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| CN108026199B (zh) | 2015-12-04 | 2020-08-11 | Lg化学株式会社 | 制备负载型混杂茂金属催化剂的方法以及使用该方法制备的负载型混杂茂金属催化剂 |
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| KR102019467B1 (ko) | 2015-12-23 | 2019-11-04 | 주식회사 엘지화학 | 메탈로센 담지 촉매 및 이를 이용하는 폴리올레핀의 제조방법 |
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| KR102064990B1 (ko) | 2016-03-11 | 2020-03-02 | 주식회사 엘지화학 | 에틸렌 슬러리 중합용 혼성 담지 촉매 시스템 및 이를 이용한 에틸렌 중합체의 제조 방법 |
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| KR102209393B1 (ko) | 2016-12-02 | 2021-01-28 | 주식회사 엘지화학 | 혼성 담지 촉매 |
| KR102073252B1 (ko) | 2016-12-05 | 2020-02-04 | 주식회사 엘지화학 | 올레핀 공중합체 합성용 촉매 조성물 및 올레핀 공중합체의 제조 방법 |
| KR102065715B1 (ko) | 2016-12-05 | 2020-01-13 | 주식회사 엘지화학 | 혼성 담지 촉매 |
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| KR102073253B1 (ko) | 2016-12-19 | 2020-02-04 | 주식회사 엘지화학 | 혼성 담지 메탈로센 촉매 및 이를 이용한 폴리올레핀의 제조 방법 |
| KR102227351B1 (ko) | 2016-12-23 | 2021-03-11 | 주식회사 엘지화학 | 전이 금속 화합물, 이를 포함하는 촉매 조성물 및 이를 이용하는 올레핀 중합체의 제조 방법 |
| WO2018139874A1 (ko) | 2017-01-25 | 2018-08-02 | 주식회사 엘지화학 | 혼성 담지 촉매 |
| KR102065719B1 (ko) | 2017-01-25 | 2020-01-13 | 주식회사 엘지화학 | 혼성 담지 촉매 |
| KR102293208B1 (ko) | 2017-09-01 | 2021-08-23 | 주식회사 엘지화학 | 에틸렌/알파-올레핀 공중합체 및 이의 제조방법 |
| KR102294874B1 (ko) | 2017-09-11 | 2021-08-26 | 주식회사 엘지화학 | 에틸렌/알파-올레핀 공중합체 |
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| US10889663B2 (en) | 2017-11-29 | 2021-01-12 | Exxonmobil Chemical Patents Inc. | Asymmetric ANSA-metallocene catalyst compounds for producing polyolefins having a broad molecular weight distribution |
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| KR102343937B1 (ko) | 2017-12-26 | 2021-12-27 | 주식회사 엘지화학 | 메탈로센 담지 촉매 및 이를 이용한 폴리프로필렌의 제조 방법 |
| KR102363189B1 (ko) | 2018-01-11 | 2022-02-15 | 주식회사 엘지화학 | 혼성 담지 메탈로센 촉매를 이용한 폴리올레핀의 제조 방법 |
| WO2019139355A1 (ko) | 2018-01-11 | 2019-07-18 | 주식회사 엘지화학 | 혼성 담지 메탈로센 촉매를 이용한 폴리올레핀의 제조방법 |
| WO2019212309A1 (ko) | 2018-05-04 | 2019-11-07 | 주식회사 엘지화학 | 에틸렌/알파-올레핀 공중합체를 포함하는 접착제 조성물 |
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| KR102427755B1 (ko) | 2018-12-10 | 2022-08-01 | 주식회사 엘지화학 | 폴리에틸렌 및 이의 염소화 폴리에틸렌 |
| WO2021060907A1 (ko) | 2019-09-27 | 2021-04-01 | 주식회사 엘지화학 | 폴리에틸렌 및 이의 염소화 폴리에틸렌 |
| EP3865522A4 (de) | 2019-09-27 | 2022-05-18 | LG Chem, Ltd. | Polyethylen und chloriertes polyethylen davon |
| WO2021060908A1 (ko) | 2019-09-27 | 2021-04-01 | 주식회사 엘지화학 | 혼성 담지 촉매 및 이용한 폴리올레핀의 제조 방법 |
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| KR102616697B1 (ko) | 2019-10-11 | 2023-12-21 | 주식회사 엘지화학 | 폴리에틸렌 및 이의 제조방법 |
| EP4043519A4 (de) | 2020-09-29 | 2023-01-11 | LG Chem, Ltd. | Polyethylenzusammensetzung und verfahren zur herstellung davon |
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| US5017714A (en) * | 1988-03-21 | 1991-05-21 | Exxon Chemical Patents Inc. | Silicon-bridged transition metal compounds |
| US4871705A (en) * | 1988-06-16 | 1989-10-03 | Exxon Chemical Patents Inc. | Process for production of a high molecular weight ethylene a-olefin elastomer with a metallocene alumoxane catalyst |
| CA1327673C (en) * | 1988-06-16 | 1994-03-08 | Sigmund Floyd | Process for production of high molecular weight epdm elastomers using a metallocene-alumoxane catalyst system |
| US5036034A (en) * | 1989-10-10 | 1991-07-30 | Fina Technology, Inc. | Catalyst for producing hemiisotactic polypropylene |
| JP2826362B2 (ja) * | 1990-02-13 | 1998-11-18 | 三井化学株式会社 | オレフィン重合用固体触媒の製造方法、オレフィン重合用固体触媒およびオレフィンの重合方法 |
| DE59107926D1 (de) * | 1990-11-12 | 1996-07-18 | Hoechst Ag | Metallocene mit Liganden aus 2-substituierten Indenylderivaten, Verfahren zu ihrer Herstellung und ihre Verwendung als Katalysatoren |
| US5240894A (en) * | 1992-05-18 | 1993-08-31 | Exxon Chemical Patents Inc. | Method for making and using a supported metallocene catalyst system |
| DE69313354T3 (de) * | 1992-06-04 | 2001-01-18 | Mitsui Chemicals, Inc. | Verfahren zur Herstellung von einem Ethylencopolymeren |
| DE69307472T2 (de) * | 1992-11-10 | 1997-05-15 | Mitsubishi Chem Corp | Verfahren zur Herstellung von Alpha-Olefinpolymeren |
| IT1264680B1 (it) * | 1993-07-07 | 1996-10-04 | Spherilene Srl | Catalizzatori supportati per la polimerizzazione delle olefine |
| CA2180180C (en) * | 1994-01-11 | 2006-03-14 | Jeffrey Harold Butler | Alumoxanes and catalysts comprising alumoxanes |
| ATE304025T1 (de) * | 1994-04-07 | 2005-09-15 | Innovene Europ Ltd | Copolymere |
| EP0693502B1 (de) * | 1994-07-22 | 1997-11-05 | Mitsubishi Chemical Corporation | Katalysatorbestandteil für alpha-Olefinpolymerisation und Verfahren zur Herstellung von alpha-Olefinpolymeren unter Anwendung desselben |
-
1997
- 1997-02-07 US US08/797,800 patent/US5914289A/en not_active Expired - Fee Related
- 1997-02-11 DE DE69712652T patent/DE69712652T2/de not_active Revoked
- 1997-02-11 ES ES97102116T patent/ES2176536T3/es not_active Expired - Lifetime
- 1997-02-11 DK DK97102116T patent/DK0790259T3/da active
- 1997-02-11 EP EP97102116A patent/EP0790259B1/de not_active Revoked
- 1997-02-11 PT PT97102116T patent/PT790259E/pt unknown
- 1997-02-11 AT AT97102116T patent/ATE217891T1/de not_active IP Right Cessation
- 1997-02-14 JP JP9044964A patent/JPH09227613A/ja active Pending
- 1997-02-18 CA CA002197848A patent/CA2197848C/en not_active Expired - Fee Related
-
1999
- 1999-06-18 US US09/336,011 patent/US6225428B1/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| ES2176536T3 (es) | 2002-12-01 |
| CA2197848A1 (en) | 1997-08-20 |
| DE69712652D1 (de) | 2002-06-27 |
| EP0790259A1 (de) | 1997-08-20 |
| US6225428B1 (en) | 2001-05-01 |
| EP0790259B1 (de) | 2002-05-22 |
| CA2197848C (en) | 2007-04-17 |
| US5914289A (en) | 1999-06-22 |
| DE69712652T2 (de) | 2002-12-12 |
| JPH09227613A (ja) | 1997-09-02 |
| DK0790259T3 (da) | 2002-09-09 |
| PT790259E (pt) | 2002-09-30 |
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| Date | Code | Title | Description |
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| RZN | Patent revoked |