ATE234152T1 - Hochwirksame doppelmetallcyanidkatalysatorenkomplex - Google Patents
Hochwirksame doppelmetallcyanidkatalysatorenkomplexInfo
- Publication number
- ATE234152T1 ATE234152T1 AT96305409T AT96305409T ATE234152T1 AT E234152 T1 ATE234152 T1 AT E234152T1 AT 96305409 T AT96305409 T AT 96305409T AT 96305409 T AT96305409 T AT 96305409T AT E234152 T1 ATE234152 T1 AT E234152T1
- Authority
- AT
- Austria
- Prior art keywords
- highly effective
- metal cyanide
- double metal
- catalyst complex
- cyanide catalyst
- Prior art date
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
- C08G65/2642—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the catalyst used
- C08G65/2645—Metals or compounds thereof, e.g. salts
- C08G65/2663—Metal cyanide catalysts, i.e. DMC's
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/24—Nitrogen compounds
- B01J27/26—Cyanides
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Toxicology (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Medicinal Chemistry (AREA)
- General Health & Medical Sciences (AREA)
- Polymers & Plastics (AREA)
- Inorganic Chemistry (AREA)
- Polyethers (AREA)
- Catalysts (AREA)
- Epoxy Resins (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Polyurethanes Or Polyureas (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US08/505,938 US5627122A (en) | 1995-07-24 | 1995-07-24 | Highly active double metal cyanide complex catalysts |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ATE234152T1 true ATE234152T1 (de) | 2003-03-15 |
Family
ID=24012498
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AT96305409T ATE234152T1 (de) | 1995-07-24 | 1996-07-23 | Hochwirksame doppelmetallcyanidkatalysatorenkomplex |
Country Status (19)
| Country | Link |
|---|---|
| US (2) | US5627122A (de) |
| EP (1) | EP0755716B1 (de) |
| JP (2) | JPH0931185A (de) |
| KR (1) | KR100422792B1 (de) |
| CN (1) | CN1082833C (de) |
| AR (1) | AR003016A1 (de) |
| AT (1) | ATE234152T1 (de) |
| AU (1) | AU702299B2 (de) |
| BR (1) | BR9603146A (de) |
| CA (1) | CA2179946A1 (de) |
| DE (1) | DE69626581T2 (de) |
| DK (1) | DK0755716T3 (de) |
| ES (1) | ES2194081T3 (de) |
| HU (1) | HU220836B1 (de) |
| MX (1) | MX9602959A (de) |
| RO (1) | RO118120B1 (de) |
| SG (1) | SG77118A1 (de) |
| TW (1) | TW374737B (de) |
| ZA (1) | ZA965773B (de) |
Families Citing this family (73)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5767323A (en) * | 1995-12-22 | 1998-06-16 | Arco Chemical Technology, L.P. | Process for preparing polyoxyalkylene polyether polyols having low levels of transition metals through double metal cyanide complex polyoxyalkylation |
| US6103850A (en) * | 1995-12-29 | 2000-08-15 | Basf Corporation | Sealants made using low unsaturation polyoxyalkylene polyether polyols |
| DE19709031A1 (de) | 1997-03-06 | 1998-09-10 | Basf Ag | Verfahren zur Herstellung von Doppelmetallcyanidkatalysatoren |
| US5783513A (en) * | 1997-03-13 | 1998-07-21 | Arco Chemical Technology, L.P. | Process for making double metal cyanide catalysts |
| DE19730467A1 (de) * | 1997-07-16 | 1999-01-21 | Bayer Ag | Neue Zink/Metall-Hexacyanocobaltat-Katalysatoren für die Herstellung von Polyetherpolyolen |
| DE19742978A1 (de) | 1997-09-29 | 1999-04-01 | Basf Ag | Multimetallcyanidkomplexe als Katalysatoren |
| AU9542598A (en) * | 1997-10-13 | 1999-05-03 | Bayer Aktiengesellschaft | Crystalline double metal cyanide catalysts for producing polyether polyols |
| DE19745120A1 (de) * | 1997-10-13 | 1999-04-15 | Bayer Ag | Verbesserte Doppelmetallcyanid-Katalysatoren für die Herstellung von Polyetherpolyolen |
| US6624286B2 (en) | 1997-10-13 | 2003-09-23 | Bayer Aktiengesellschaft | Double-metal cyanide catalysts containing polyester for preparing polyether polyols |
| DE19809538A1 (de) * | 1998-03-05 | 1999-09-09 | Basf Ag | Verfahren zur Herstellung von Doppelmetallcyanidkatalysatoren |
| US5952261A (en) * | 1998-03-20 | 1999-09-14 | Arco Chemical Technology, L.P. | Double metal cyanide complex catalysts modified with Group IIA compounds |
| CN1080589C (zh) * | 1998-04-29 | 2002-03-13 | 中国科学院山西煤炭化学研究所 | 双金属氰化物催化剂及其制备方法 |
| CN1080590C (zh) * | 1998-04-29 | 2002-03-13 | 中国科学院山西煤炭化学研究所 | 一种双金属氰化物催化剂及其制备方法 |
| US6063897A (en) * | 1998-05-05 | 2000-05-16 | Arco Chemical Technology, L.P. | Acid-treated double metal cyanide complex catalysts |
| US6028230A (en) * | 1998-06-05 | 2000-02-22 | Arco Chemical Technology, L.P. | Epoxide polymerization process |
| US6051680A (en) * | 1998-06-08 | 2000-04-18 | Arco Chemical Technology, L.P. | Silylated double metal cyanide complex catalysts |
| CN1080588C (zh) * | 1998-06-19 | 2002-03-13 | 中国科学院山西煤炭化学研究所 | 一种双金属氰化物催化剂的简易制备方法 |
| DE19840585A1 (de) † | 1998-09-05 | 2000-03-09 | Basf Ag | Verfahren zur Herstellung von Polyetherolen durch ringöffnende Polymerisation von Alkylenoxiden |
| US6051622A (en) * | 1998-09-17 | 2000-04-18 | Arco Chemical Technology, L.P. | Low resilience, low frequency molded polyurethane foam |
| DE19903274A1 (de) | 1999-01-28 | 2000-08-03 | Basf Ag | Verfahren zur Herstellung von Polyetherpolyolen |
| US6613714B2 (en) | 1999-06-02 | 2003-09-02 | Basf Aktiengesellschaft | Multimetal cyanide compounds, their preparation and their use |
| AU5069100A (en) * | 1999-06-02 | 2000-12-28 | Basf Aktiengesellschaft | Multi-metal cyanide catalysts |
| US6800583B2 (en) * | 1999-06-02 | 2004-10-05 | Basf Aktiengesellschaft | Suspension of multimetal cyanide compounds, their preparation and their use |
| US6423662B1 (en) | 1999-07-09 | 2002-07-23 | Dow Global Technologies Inc. | Incipient wetness method for making metal-containing cyanide catalysts |
| US20040266982A1 (en) * | 1999-07-09 | 2004-12-30 | Clement Katherine S | Polymerization of alkylene oxides onto functionalized initiators |
| DE50103101D1 (de) * | 2000-02-29 | 2004-09-09 | Basf Ag | Verfahren zur herstellung von multimetallcyanidverbindungen |
| CA2404652A1 (en) | 2000-03-30 | 2001-10-04 | Shell Internationale Research Maatschappij B.V. | Dmc complex catalyst and process for its preparation |
| WO2001083107A2 (en) | 2000-04-28 | 2001-11-08 | Synuthane International, Inc. | Double metal cyanide catalysts containing polyglycol ether complexing agents |
| US6436867B1 (en) * | 2000-08-01 | 2002-08-20 | Basf Corporation | One-step synthesis of double metal cyanides |
| CN1109058C (zh) * | 2000-08-16 | 2003-05-21 | 中国科学院山西煤炭化学研究所 | 双金属氰化物复合催化剂及其制备方法和应用 |
| DE10129287A1 (de) * | 2001-06-18 | 2002-12-19 | Basf Ag | Verfahren zur Herstellung von Alkylpolyakylenglykolcarbonsäureestern |
| DE10143195A1 (de) * | 2001-09-04 | 2003-03-20 | Basf Ag | Integriertes Verfahren zur Herstellung von Polyurethan-Schäumen |
| DE10205086A1 (de) | 2002-02-07 | 2003-08-21 | Basf Ag | Verfahren zur Aktivierung von Doppelmetallcyanid-Verbindungen |
| KR20040108674A (ko) * | 2002-03-21 | 2004-12-24 | 다우 글로벌 테크놀로지스 인크. | 0가 금속을 사용하는 금속 시아나이드 촉매의 제조 방법 |
| DE10243366A1 (de) | 2002-09-18 | 2004-04-01 | Basf Ag | Herstellung von Alkoxylaten bei optimierten Reaktionsdrücken |
| US6696383B1 (en) | 2002-09-20 | 2004-02-24 | Bayer Polymers Llc | Double-metal cyanide catalysts which can be used to prepare polyols and the processes related thereto |
| BR0315469A (pt) * | 2002-11-07 | 2005-08-23 | Dow Global Technologies Inc | Complexo catalisador, polìmero, método para produzir um catalisador de polimerização e método para produzir um poliéter |
| US7001634B2 (en) * | 2002-11-07 | 2006-02-21 | Bayer Materialscience Llc | Process for suppressing the foaming of an aqueous system |
| EP1632517B1 (de) * | 2003-06-04 | 2009-07-22 | Asahi Glass Company Ltd. | Mischmetallcyanidkomplexkatalysator, herstellungsverfahren dafür und verwendung davon |
| US6855658B1 (en) | 2003-08-26 | 2005-02-15 | Bayer Antwerp, N.V. | Hydroxide containing double metal cyanide (DMC) catalysts |
| ATE454435T1 (de) | 2003-10-06 | 2010-01-15 | Kaneka Corp | Haftklebemittel |
| WO2005040248A1 (en) * | 2003-10-10 | 2005-05-06 | Shell Internationale Research Maatschappij B.V. | Process for the preparation of a polyether polyol |
| US7223890B2 (en) * | 2003-10-10 | 2007-05-29 | Bayer Materialscience Llc | Isocyanate reactive mixture and process for preparing same |
| US20060058182A1 (en) * | 2004-09-13 | 2006-03-16 | Combs George G | Processes for the preparation of double metal cyanide (DMC) catalysts |
| CA2580569C (en) * | 2004-10-26 | 2013-11-19 | Dow Global Technologies Inc. | Improved method for alkoxylating active hydrogen containing compounds and the alkoxylated compounds made therefrom |
| US7609773B2 (en) * | 2005-04-18 | 2009-10-27 | Qualcomm Incorporated | Method of determining the location of the FFT window and the delay spread for the platinum broadcast channel estimator |
| US20080090921A1 (en) * | 2006-10-12 | 2008-04-17 | Hayes John E | DMC-catalyzed polyol containing polyurethane pultrusion formulations and processes |
| KR100941637B1 (ko) | 2008-05-21 | 2010-02-11 | 에스케이씨 주식회사 | 반응성이 제어된, 폴리올 제조용 복금속 시안계 촉매 및이의 제조방법 |
| KR101404702B1 (ko) | 2011-03-08 | 2014-06-17 | 에스케이이노베이션 주식회사 | 에테르 결합 단위체를 함유한 이산화탄소/에폭사이드 공중합체의 제조 방법 |
| EP2691440B1 (de) * | 2011-03-31 | 2015-05-27 | Dow Global Technologies LLC | Verfahren zur herstellung von kurzkettigen polyfunktionellen polyetherpolyolen mit supersaurer und doppelmetallcyanid-katalyse |
| BR112014003972B1 (pt) | 2011-08-25 | 2020-05-19 | Dow Global Technologies Llc | processo para preparar um poliéter contendo unidades de etilenóxi ligadas por éter |
| US9562134B2 (en) | 2013-03-12 | 2017-02-07 | Covestro Llc | Catalyst for the production of polyols having lower amounts of high molecular weight tail |
| DE102013206175A1 (de) | 2013-04-09 | 2014-10-09 | Evonik Industries Ag | Polysiloxan-Polyether-Copolymere mit Amino- und/oder quaternären Ammoniumgruppen im Polyetherteil und Verfahren zu deren Herstellung |
| ES2809675T3 (es) | 2015-07-02 | 2021-03-05 | Shell Int Research | Mejoras relacionadas con los poliuretanos |
| GB201515350D0 (en) | 2015-08-28 | 2015-10-14 | Econic Technologies Ltd | Method for preparing polyols |
| GB201703324D0 (en) | 2017-03-01 | 2017-04-12 | Econic Tech Ltd | Method for preparing polyether carbonates |
| GB201717441D0 (en) | 2017-10-24 | 2017-12-06 | Econic Tech Ltd | A polymerisation process |
| EP3608018A1 (de) * | 2018-08-08 | 2020-02-12 | Covestro Deutschland AG | Verfahren zur herstellung von doppelmetallcyanid-katalysatoren |
| GB201814526D0 (en) | 2018-09-06 | 2018-10-24 | Econic Tech Ltd | Methods for forming polycarbonate ether polyols and high molecular weight polyether carbonates |
| GB201906214D0 (en) | 2019-05-02 | 2019-06-19 | Econic Tech Ltd | A polyol block copolymer, compositions and processes therefor |
| GB201906210D0 (en) | 2019-05-02 | 2019-06-19 | Econic Tech Limited | A polyol block copolymer, compositions and processes therefor |
| GB202003002D0 (en) | 2020-03-02 | 2020-04-15 | Crane Ltd | Method of preparation of a polyol block copolymer |
| GB202003003D0 (en) | 2020-03-02 | 2020-04-15 | Econic Tech Ltd | A polyol block copolymer |
| CN112111056A (zh) * | 2020-09-22 | 2020-12-22 | 河北工业大学 | 一种高活性制备聚醚多元醇或聚醚酯多元醇的双组分催化体系及应用 |
| GB202017531D0 (en) | 2020-11-05 | 2020-12-23 | Econic Tech Limited | (poly)ol block copolymer |
| MX2024001871A (es) | 2021-08-11 | 2024-03-04 | Econic Tech Ltd | Metodo para preparar tensoactivos mediante copolimerizacion de epoxidos y co2 utilizando una mezcla de un catalizador bimetalico macrociclico y un catalizador de cianuro bimetalico. |
| GB202115335D0 (en) | 2021-10-25 | 2021-12-08 | Econic Tech Ltd | Surface-active agent |
| GB2626546A (en) | 2023-01-25 | 2024-07-31 | Econic Tech Ltd | Surface-active agent |
| GB2626989A (en) | 2023-02-10 | 2024-08-14 | Econic Tech Ltd | Surface-active agent |
| GB2629367A (en) | 2023-04-25 | 2024-10-30 | Econic Tech Ltd | Surface-active agent |
| EP4702078A1 (de) | 2023-04-25 | 2026-03-04 | Unilever IP Holdings B.V. | Zusammensetzungen |
| JP7473059B1 (ja) | 2023-06-01 | 2024-04-23 | Agc株式会社 | 複合金属シアン化物錯体触媒及びその製造方法、複合金属シアン化物錯体スラリー触媒及びその製造方法、並びに重合体の製造方法 |
| CN120733801B (zh) * | 2025-08-25 | 2025-11-21 | 中化东大(淄博)有限公司 | 基于机械化学法的失活dmc催化剂再生方法、再生dmc催化剂及应用 |
Family Cites Families (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1063525A (en) * | 1963-02-14 | 1967-03-30 | Gen Tire & Rubber Co | Organic cyclic oxide polymers, their preparation and tires prepared therefrom |
| US3427335A (en) * | 1963-02-14 | 1969-02-11 | Gen Tire & Rubber Co | Double metal cyanides complexed with an acyclic aliphatic saturated monoether,an ester and a cyclic ether and methods for making the same |
| US3278457A (en) * | 1963-02-14 | 1966-10-11 | Gen Tire & Rubber Co | Method of making a polyether using a double metal cyanide complex compound |
| US3427334A (en) * | 1963-02-14 | 1969-02-11 | Gen Tire & Rubber Co | Double metal cyanides complexed with an alcohol aldehyde or ketone to increase catalytic activity |
| US3278458A (en) * | 1963-02-14 | 1966-10-11 | Gen Tire & Rubber Co | Method of making a polyether using a double metal cyanide complex compound |
| US3427256A (en) * | 1963-02-14 | 1969-02-11 | Gen Tire & Rubber Co | Double metal cyanide complex compounds |
| GB1225803A (de) * | 1967-06-02 | 1971-03-24 | ||
| US3900518A (en) * | 1967-10-20 | 1975-08-19 | Gen Tire & Rubber Co | Hydroxyl or thiol terminated telomeric ethers |
| US3941849A (en) * | 1972-07-07 | 1976-03-02 | The General Tire & Rubber Company | Polyethers and method for making the same |
| AU552988B2 (en) * | 1982-03-31 | 1986-06-26 | Shell Internationale Research Maatschappij B.V. | Polymerizing epoxides and catalyst suspensions for this |
| AU551979B2 (en) * | 1982-03-31 | 1986-05-15 | Shell Internationale Research Maatschappij B.V. | Epoxy polymerisation catalysts |
| GB8528071D0 (en) * | 1985-11-14 | 1985-12-18 | Shell Int Research | Polycarbonates |
| US4843054A (en) * | 1987-02-26 | 1989-06-27 | Arco Chemical Technology, Inc. | Preparation of filterable double metal cyanide complex catalyst for propylene oxide polymerization |
| DE3855974T2 (de) * | 1987-02-26 | 1997-12-04 | Arco Chem Tech | Herstellung eines filtrierbaren, für die Alkylenoxidpolymerisation verwendbaren Doppelmetallcyanidkomplex-Katalysators |
| JP2995568B2 (ja) * | 1989-05-09 | 1999-12-27 | 旭硝子株式会社 | ポリアルキレンオキシド誘導体の製造法 |
| JP3097854B2 (ja) * | 1989-05-12 | 2000-10-10 | 旭硝子株式会社 | ポリウレタン類の製造方法 |
| WO1991018909A1 (en) * | 1990-03-30 | 1991-12-12 | Olin Corporation | Process for removing double metal cyanide complex catalyst residues from catalyst-residue containing polyols |
| JP2653236B2 (ja) * | 1990-10-05 | 1997-09-17 | 旭硝子株式会社 | ポリエーテル化合物の製造方法 |
| US5158922A (en) * | 1992-02-04 | 1992-10-27 | Arco Chemical Technology, L.P. | Process for preparing metal cyanide complex catalyst |
| US5470813A (en) | 1993-11-23 | 1995-11-28 | Arco Chemical Technology, L.P. | Double metal cyanide complex catalysts |
| US5426081A (en) * | 1993-12-23 | 1995-06-20 | Arco Chemical Technology, L.P. | Polyurethane foam-supported double metal cyanide catalysts for polyol synthesis |
| CA2138063C (en) * | 1993-12-23 | 2007-02-20 | Bi Le-Khac | Polyurethane foam-supported double metal cyanide catalysts for polyol synthesis |
| US5482908A (en) * | 1994-09-08 | 1996-01-09 | Arco Chemical Technology, L.P. | Highly active double metal cyanide catalysts |
-
1995
- 1995-07-24 US US08/505,938 patent/US5627122A/en not_active Expired - Lifetime
-
1996
- 1996-06-26 CA CA002179946A patent/CA2179946A1/en not_active Abandoned
- 1996-07-03 TW TW085108039A patent/TW374737B/zh active
- 1996-07-08 ZA ZA9605773A patent/ZA965773B/xx unknown
- 1996-07-15 JP JP8202766A patent/JPH0931185A/ja active Pending
- 1996-07-23 AU AU60652/96A patent/AU702299B2/en not_active Ceased
- 1996-07-23 AT AT96305409T patent/ATE234152T1/de not_active IP Right Cessation
- 1996-07-23 DE DE69626581T patent/DE69626581T2/de not_active Expired - Lifetime
- 1996-07-23 SG SG1996010313A patent/SG77118A1/en unknown
- 1996-07-23 EP EP96305409A patent/EP0755716B1/de not_active Expired - Lifetime
- 1996-07-23 ES ES96305409T patent/ES2194081T3/es not_active Expired - Lifetime
- 1996-07-23 RO RO96-01501A patent/RO118120B1/ro unknown
- 1996-07-23 DK DK96305409T patent/DK0755716T3/da active
- 1996-07-23 BR BR9603146A patent/BR9603146A/pt not_active IP Right Cessation
- 1996-07-24 MX MX9602959A patent/MX9602959A/es not_active IP Right Cessation
- 1996-07-24 AR ARP960103714A patent/AR003016A1/es unknown
- 1996-07-24 KR KR1019960029922A patent/KR100422792B1/ko not_active Expired - Fee Related
- 1996-07-24 HU HU9602014A patent/HU220836B1/hu not_active IP Right Cessation
- 1996-07-24 CN CN96108898A patent/CN1082833C/zh not_active Expired - Fee Related
-
1997
- 1997-01-07 US US08/780,659 patent/US5780584A/en not_active Expired - Lifetime
-
2002
- 2002-01-25 JP JP2002017233A patent/JP2002282699A/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| ES2194081T3 (es) | 2003-11-16 |
| CA2179946A1 (en) | 1997-01-25 |
| DE69626581T2 (de) | 2003-12-11 |
| CN1147423A (zh) | 1997-04-16 |
| HUP9602014A3 (en) | 1998-12-28 |
| KR100422792B1 (ko) | 2004-06-24 |
| HU9602014D0 (en) | 1996-09-30 |
| EP0755716B1 (de) | 2003-03-12 |
| AU6065296A (en) | 1997-01-30 |
| CN1082833C (zh) | 2002-04-17 |
| ZA965773B (en) | 1997-01-27 |
| BR9603146A (pt) | 1998-05-05 |
| US5780584A (en) | 1998-07-14 |
| HU220836B1 (en) | 2002-06-29 |
| RO118120B1 (ro) | 2003-02-28 |
| EP0755716A1 (de) | 1997-01-29 |
| JP2002282699A (ja) | 2002-10-02 |
| KR970005391A (ko) | 1997-02-19 |
| AU702299B2 (en) | 1999-02-18 |
| JPH0931185A (ja) | 1997-02-04 |
| US5627122A (en) | 1997-05-06 |
| TW374737B (en) | 1999-11-21 |
| DK0755716T3 (da) | 2003-06-16 |
| HUP9602014A2 (en) | 1997-06-30 |
| AR003016A1 (es) | 1998-05-27 |
| SG77118A1 (en) | 2000-12-19 |
| MX9602959A (es) | 1998-04-30 |
| DE69626581D1 (de) | 2003-04-17 |
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