ATE236864T1 - Verfahren zur alkylierung von aromatischen verbindungen - Google Patents
Verfahren zur alkylierung von aromatischen verbindungenInfo
- Publication number
- ATE236864T1 ATE236864T1 AT99103541T AT99103541T ATE236864T1 AT E236864 T1 ATE236864 T1 AT E236864T1 AT 99103541 T AT99103541 T AT 99103541T AT 99103541 T AT99103541 T AT 99103541T AT E236864 T1 ATE236864 T1 AT E236864T1
- Authority
- AT
- Austria
- Prior art keywords
- benzene
- reaction zone
- intergrowth
- rtm
- zsm
- Prior art date
Links
- 230000002152 alkylating effect Effects 0.000 title 1
- 150000001491 aromatic compounds Chemical class 0.000 title 1
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 abstract 12
- YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 abstract 6
- 238000006243 chemical reaction Methods 0.000 abstract 4
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical class O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 abstract 4
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 abstract 3
- 239000003054 catalyst Substances 0.000 abstract 3
- 229910021536 Zeolite Inorganic materials 0.000 abstract 2
- 230000029936 alkylation Effects 0.000 abstract 2
- 238000005804 alkylation reaction Methods 0.000 abstract 2
- 125000003118 aryl group Chemical group 0.000 abstract 2
- 239000007791 liquid phase Substances 0.000 abstract 2
- 239000000758 substrate Substances 0.000 abstract 2
- 239000010457 zeolite Substances 0.000 abstract 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract 1
- 239000005977 Ethylene Substances 0.000 abstract 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 abstract 1
- 239000002168 alkylating agent Substances 0.000 abstract 1
- 229940100198 alkylating agent Drugs 0.000 abstract 1
- 239000012021 ethylating agents Substances 0.000 abstract 1
- 230000006203 ethylation Effects 0.000 abstract 1
- 238000006200 ethylation reaction Methods 0.000 abstract 1
- 239000002808 molecular sieve Substances 0.000 abstract 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 abstract 1
- 239000008096 xylene Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
- C07C2/64—Addition to a carbon atom of a six-membered aromatic ring
- C07C2/66—Catalytic processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
- B01J29/7049—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing rare earth elements, titanium, zirconium, hafnium, zinc, cadmium, mercury, gallium, indium, thallium, tin or lead
- B01J29/7057—Zeolite Beta
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/030,285 US5907073A (en) | 1998-02-24 | 1998-02-24 | Aromatic alkylation process |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ATE236864T1 true ATE236864T1 (de) | 2003-04-15 |
Family
ID=21853463
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AT99103541T ATE236864T1 (de) | 1998-02-24 | 1999-02-24 | Verfahren zur alkylierung von aromatischen verbindungen |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US5907073A (de) |
| EP (1) | EP0943594B1 (de) |
| JP (1) | JPH11286460A (de) |
| KR (1) | KR100597077B1 (de) |
| CN (1) | CN1160281C (de) |
| AT (1) | ATE236864T1 (de) |
| DE (1) | DE69906615T2 (de) |
| ES (1) | ES2193612T3 (de) |
| TW (1) | TW524792B (de) |
Families Citing this family (43)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7371911B2 (en) | 2005-02-25 | 2008-05-13 | Fina Technology, Inc. | Critical phase alkylation and transalkylation process in the presence of a beta zeolite |
| TW572784B (en) * | 2000-10-18 | 2004-01-21 | Fina Technology | Silica-supported alkylation catalyst |
| US6878327B2 (en) * | 2002-04-19 | 2005-04-12 | Fina Technology, Inc. | Process of making polypropylene fibers |
| US7268264B2 (en) * | 2002-10-04 | 2007-09-11 | Fina Technology, Inc. | Critical phase alkylation process |
| US20040138511A1 (en) * | 2003-01-10 | 2004-07-15 | James Butler | Aromatic alkylation process with direct recycle |
| WO2004085062A1 (en) * | 2003-03-21 | 2004-10-07 | Stone & Webster, Inc. | Production of alkyl aromatic compounds with catalyst reactivation |
| US7084318B2 (en) * | 2003-08-01 | 2006-08-01 | Saudi Basic Industries Corporation | Toluene methylation process |
| US7060864B2 (en) * | 2003-09-30 | 2006-06-13 | Saudi Basic Industries Corporation | Toluene methylation process |
| US6987078B2 (en) * | 2003-10-03 | 2006-01-17 | Fina Technology, Inc. | Alkylation and catalyst regenerative process |
| US6943131B1 (en) * | 2004-03-02 | 2005-09-13 | Saudi Basic Industries Corporation | Selective zeolite catalyst modification |
| US7285511B2 (en) * | 2004-04-23 | 2007-10-23 | Saudi Basic Industries Corporation | Method of modifying zeolite catalyst |
| US7399727B2 (en) * | 2004-04-23 | 2008-07-15 | Saudi Basic Industries Corporation | Zeolite catalyst and method |
| JP4655039B2 (ja) * | 2004-06-07 | 2011-03-23 | 株式会社ニコン | ステージ装置、露光装置及び露光方法 |
| US7525002B2 (en) * | 2005-02-28 | 2009-04-28 | Exxonmobil Research And Engineering Company | Gasoline production by olefin polymerization with aromatics alkylation |
| US7498474B2 (en) * | 2005-02-28 | 2009-03-03 | Exxonmobil Research And Engineering Company | Vapor phase aromatics alkylation process |
| US20060194998A1 (en) * | 2005-02-28 | 2006-08-31 | Umansky Benjamin S | Process for making high octane gasoline with reduced benzene content |
| US7476774B2 (en) * | 2005-02-28 | 2009-01-13 | Exxonmobil Research And Engineering Company | Liquid phase aromatics alkylation process |
| US7368410B2 (en) * | 2005-08-03 | 2008-05-06 | Saudi Basic Industries Corporation | Zeolite catalyst and method of preparing and use of zeolite catalyst |
| US7662737B2 (en) * | 2005-12-22 | 2010-02-16 | Saudi Basic Industries Corporation | Bound phosphorus-modified zeolite catalyst, method of preparing and method of using thereof |
| US7834227B2 (en) * | 2006-12-29 | 2010-11-16 | Uop Llc | Aromatics co-production in a methanol-to-propylene unit |
| US8134036B2 (en) * | 2008-03-13 | 2012-03-13 | Fina Technology Inc | Process for liquid phase alkylation |
| EP2110368A1 (de) | 2008-04-18 | 2009-10-21 | Total Petrochemicals France | Alkylierung aromatischer Substrate und Transalkylierungsverfahren |
| US8865958B2 (en) * | 2008-09-30 | 2014-10-21 | Fina Technology, Inc. | Process for ethylbenzene production |
| US8420877B2 (en) * | 2008-09-30 | 2013-04-16 | Fina Technology, Inc. | Process for ethylbenzene production |
| US8846559B2 (en) * | 2008-11-03 | 2014-09-30 | Saudi Basic Industries Corporation | Stable shape-selective catalyst for aromatic alkylation and methods of using and preparing |
| US8105969B2 (en) * | 2008-12-29 | 2012-01-31 | Fina Technology Inc. | Catalyst with an ion-modified binder |
| US8395006B2 (en) * | 2009-03-13 | 2013-03-12 | Exxonmobil Research And Engineering Company | Process for making high octane gasoline with reduced benzene content by benzene alkylation at high benzene conversion |
| US8865121B2 (en) * | 2009-06-18 | 2014-10-21 | Basf Se | Organotemplate-free synthetic process for the production of a zeolitic material |
| US8455383B2 (en) * | 2009-09-28 | 2013-06-04 | Fina Technology, Inc. | Process for catalyst regeneration and extended use |
| US8062987B2 (en) * | 2009-10-05 | 2011-11-22 | Saudi Basic Industries Corporation | Phosphorus-containing zeolite catalysts and their method of preparation |
| RU2499631C1 (ru) * | 2010-03-31 | 2013-11-27 | Юоп Ллк | Алюмосиликатный цеолит uzm-37 |
| US7985886B1 (en) * | 2010-03-31 | 2011-07-26 | Uop Llc | Aromatic alkylation process using UZM-37 aluminosilicate zeolite |
| CN102892732B (zh) * | 2010-05-20 | 2015-06-03 | 埃克森美孚化学专利公司 | 改进的烷基化方法 |
| CN101954294A (zh) * | 2010-09-26 | 2011-01-26 | 同济大学 | 甲苯和丙烯合成对甲基异丙苯的烷基化催化剂及其制备方法 |
| SG194154A1 (en) * | 2011-05-02 | 2013-11-29 | Fina Technology | Process for ethylbenzene production |
| US20130131415A1 (en) * | 2011-11-22 | 2013-05-23 | Fina Technology, Inc. | Process for Ethylbenzene Production From Ethanol |
| US8759597B2 (en) * | 2012-04-18 | 2014-06-24 | Uop Llc | Methods for producing zeolite catalysts and methods for producing alkylated aromatic compounds using the zeolite catalysts |
| US9278342B2 (en) | 2012-07-02 | 2016-03-08 | Saudi Basic Industries Corporation | Method of modifying a phosphorus-containing zeolite catalyst |
| CN103663485B (zh) * | 2012-09-24 | 2016-12-21 | 中国石油化工股份有限公司 | 一种P-Si-IM-5分子筛及其催化剂的制备与应用 |
| CN103920527B (zh) * | 2014-04-24 | 2016-01-13 | 南开大学 | 环氧化合物水合制备1,2-二醇的催化剂及制备方法和应用 |
| CN114471685B (zh) * | 2020-10-26 | 2023-08-29 | 中国石油化工股份有限公司 | 一种无粘结剂Beta分子筛催化剂及其制备方法和应用 |
| CN114471673B (zh) * | 2020-10-26 | 2023-08-29 | 中国石油化工股份有限公司 | 一种含磷无粘结剂zsm-5分子筛催化剂及其制备方法和应用 |
| US11873453B2 (en) * | 2021-05-28 | 2024-01-16 | ExxonMobil Technology and Engineering Company | Adsorptive process for separation of isoparaffinic lube base stock from lower quality oils |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3308069A (en) * | 1964-05-01 | 1967-03-07 | Mobil Oil Corp | Catalytic composition of a crystalline zeolite |
| US3832449A (en) * | 1971-03-18 | 1974-08-27 | Mobil Oil Corp | Crystalline zeolite zsm{14 12 |
| US4107224A (en) * | 1977-02-11 | 1978-08-15 | Mobil Oil Corporation | Manufacture of ethyl benzene |
| US4185040A (en) * | 1977-12-16 | 1980-01-22 | Union Oil Company Of California | Alkylation of aromatic hydrocarbons |
| US4387259A (en) * | 1981-07-16 | 1983-06-07 | Mobil Oil Corporation | Selective alkylation of aromatic hydrocarbons using a mixed ethylene/propylene alkylation agent |
| US4642226A (en) * | 1984-04-16 | 1987-02-10 | Mobil Oil Corporation | Process for the preparation of zeolite Beta using dibenzyldimethylammonium ions and the product produced |
| DE3571598D1 (en) * | 1984-04-16 | 1989-08-24 | Mobil Oil Corp | Preparation of zeolite beta |
| AU575451B2 (en) * | 1984-12-27 | 1988-07-28 | Mobil Oil Corporation | Catalytic cracking of paraffinic feedstocks with zeolite beta |
| US4774377A (en) * | 1987-09-11 | 1988-09-27 | Uop Inc. | Alkylation/transalkylation process |
| US4891458A (en) * | 1987-12-17 | 1990-01-02 | Innes Robert A | Liquid phase alkylation or transalkylation process using zeolite beta |
| DE69026613T2 (de) * | 1990-07-18 | 1996-10-24 | Fina Technology | Transalkylierungsverfahren |
| DE69033689T2 (de) * | 1990-11-13 | 2001-05-17 | Fina Technology, Inc. | Herstellung alkylierter Aromaten |
| KR920009746A (ko) * | 1990-11-15 | 1992-06-25 | 피나 테크놀로지, 인코포레이티드 | 방향족 전환 방법 및 이에 유용한 촉매 |
| US5600048A (en) * | 1994-12-27 | 1997-02-04 | Mobil Oil Corporation | Continuous process for preparing ethylbenzene using liquid phase alkylation and vapor phase transalkylation |
-
1998
- 1998-02-24 US US09/030,285 patent/US5907073A/en not_active Expired - Fee Related
-
1999
- 1999-01-04 TW TW088100034A patent/TW524792B/zh not_active IP Right Cessation
- 1999-02-19 JP JP11041770A patent/JPH11286460A/ja not_active Withdrawn
- 1999-02-24 AT AT99103541T patent/ATE236864T1/de active
- 1999-02-24 ES ES99103541T patent/ES2193612T3/es not_active Expired - Lifetime
- 1999-02-24 KR KR1019990007006A patent/KR100597077B1/ko not_active Expired - Fee Related
- 1999-02-24 EP EP99103541A patent/EP0943594B1/de not_active Expired - Lifetime
- 1999-02-24 DE DE69906615T patent/DE69906615T2/de not_active Expired - Lifetime
- 1999-02-24 CN CNB991025717A patent/CN1160281C/zh not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| JPH11286460A (ja) | 1999-10-19 |
| CN1160281C (zh) | 2004-08-04 |
| TW524792B (en) | 2003-03-21 |
| KR100597077B1 (ko) | 2006-07-04 |
| KR19990087866A (ko) | 1999-12-27 |
| US5907073A (en) | 1999-05-25 |
| EP0943594B1 (de) | 2003-04-09 |
| ES2193612T3 (es) | 2003-11-01 |
| EP0943594A1 (de) | 1999-09-22 |
| DE69906615T2 (de) | 2004-02-12 |
| CN1228401A (zh) | 1999-09-15 |
| DE69906615D1 (de) | 2003-05-15 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| UEP | Publication of translation of european patent specification |
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