ATE238359T1 - Liganden und katalysatoren um elastomerische propylenpolymere herzustellen - Google Patents

Liganden und katalysatoren um elastomerische propylenpolymere herzustellen

Info

Publication number
ATE238359T1
ATE238359T1 AT99967306T AT99967306T ATE238359T1 AT E238359 T1 ATE238359 T1 AT E238359T1 AT 99967306 T AT99967306 T AT 99967306T AT 99967306 T AT99967306 T AT 99967306T AT E238359 T1 ATE238359 T1 AT E238359T1
Authority
AT
Austria
Prior art keywords
ligands
catalysts
propylene polymers
elastomeric propylene
producing elastomeric
Prior art date
Application number
AT99967306T
Other languages
English (en)
Inventor
Andreas P Ernst
Eric J Moore
Charles L Myers
Roger W Quan
Original Assignee
Bp Corp North America Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bp Corp North America Inc filed Critical Bp Corp North America Inc
Application granted granted Critical
Publication of ATE238359T1 publication Critical patent/ATE238359T1/de

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/14Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • B01J31/143Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22Organic complexes
    • B01J31/2282Unsaturated compounds used as ligands
    • B01J31/2295Cyclic compounds, e.g. cyclopentadienyls
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C13/00Cyclic hydrocarbons containing rings other than, or in addition to, six-membered aromatic rings
    • C07C13/28Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof
    • C07C13/32Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings
    • C07C13/45Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings with a bicyclo ring system containing nine carbon atoms
    • C07C13/465Indenes; Completely or partially hydrogenated indenes
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00Metallocenes
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02Silicon compounds
    • C07F7/08Compounds having one or more C—Si linkages
    • C07F7/0803Compounds with Si-C or Si-Si linkages
    • C07F7/0805Compounds with Si-C or Si-Si linkages comprising only Si, C or H atoms
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04Monomers containing three or four carbon atoms
    • C08F10/06Propene
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/48Zirconium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/49Hafnium
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2602/00Systems containing two condensed rings
    • C07C2602/02Systems containing two condensed rings the rings having only two atoms in common
    • C07C2602/04One of the condensed rings being a six-membered aromatic ring
    • C07C2602/08One of the condensed rings being a six-membered aromatic ring the other ring being five-membered, e.g. indane
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04Monomers containing three or four carbon atoms
    • C08F110/06Propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
AT99967306T 1998-12-14 1999-12-14 Liganden und katalysatoren um elastomerische propylenpolymere herzustellen ATE238359T1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US11238398P 1998-12-14 1998-12-14
PCT/US1999/029616 WO2000035975A1 (en) 1998-12-14 1999-12-14 Ligands and catalysts for producing elastomeric propylene polymers

Publications (1)

Publication Number Publication Date
ATE238359T1 true ATE238359T1 (de) 2003-05-15

Family

ID=22343610

Family Applications (1)

Application Number Title Priority Date Filing Date
AT99967306T ATE238359T1 (de) 1998-12-14 1999-12-14 Liganden und katalysatoren um elastomerische propylenpolymere herzustellen

Country Status (7)

Country Link
US (1) US6479424B1 (de)
EP (1) EP1157047B1 (de)
AT (1) ATE238359T1 (de)
AU (1) AU2360900A (de)
CA (1) CA2355236A1 (de)
DE (1) DE69907279T2 (de)
WO (1) WO2000035975A1 (de)

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1998057996A1 (en) * 1997-06-14 1998-12-23 The Board Of Trustees Of The Leland Stanford, Jr. University ETHYLENE ENHANCEMENT OF PROCESSES FOR SYNTHESIS OF HIGH MELTING THERMOPLASTIC ELASTOMERIC α-OLEFIN POLYMERS (PRE/EPE EFFECTS)
US7459511B2 (en) * 2001-06-12 2008-12-02 Basell Polyolefine Gmbh Process for the polymerization of 1-butene
US8008412B2 (en) 2002-09-20 2011-08-30 Exxonmobil Chemical Patents Inc. Polymer production at supersolution conditions
DE60329523D1 (de) * 2002-12-04 2009-11-12 Basell Polyolefine Gmbh 1-Buten-Copolymere und Herstellungsverfahren dafür
DE60318616T2 (de) * 2002-12-04 2009-01-08 Basell Polyolefine Gmbh Verfahren zur herstellung von1-buten-polymeren
US7589160B2 (en) * 2002-12-04 2009-09-15 Basell Polyolefine Gmbh Process for preparing 1-butene polymers
KR20070039930A (ko) * 2004-07-08 2007-04-13 엑손모빌 케미칼 패턴츠 인코포레이티드 초임계 조건에서 중합체의 제조방법
US8242237B2 (en) 2006-12-20 2012-08-14 Exxonmobil Chemical Patents Inc. Phase separator and monomer recycle for supercritical polymerization process
ES2446294T3 (es) 2007-06-04 2014-03-07 Exxonmobil Chemical Patents Inc. Polimerización de propileno en un sistema homogéneo en condiciones de superdisolución
US8318875B2 (en) 2008-01-18 2012-11-27 Exxonmobil Chemical Patents Inc. Super-solution homogeneous propylene polymerization and polypropylenes made therefrom
KR102372974B1 (ko) * 2019-04-05 2022-03-10 한화솔루션 주식회사 혼성 촉매 조성물, 이를 포함하는 촉매 및 이들의 제조방법
EP4716705A1 (de) 2023-05-23 2026-04-01 ExxonMobil Technology and Engineering Company Polyethylene niedriger dichte, folien daraus und verfahren und katalysatoren zur herstellung davon
WO2024242933A1 (en) 2023-05-23 2024-11-28 ExxonMobil Technology and Engineering Company Catalysts and polymerizations for improved polyolefins
EP4716704A1 (de) 2023-05-23 2026-04-01 ExxonMobil Technology and Engineering Company Polyethylene mit verbesserter verarbeitbarkeit und daraus hergestellte folien
CN121420001A (zh) 2023-05-23 2026-01-27 埃克森美孚技术与工程公司 聚乙烯、用于它们的聚合的催化剂及其膜
EP4716706A1 (de) 2023-05-23 2026-04-01 ExxonMobil Technology and Engineering Company Katalysatoren, polyethylene, polymerisationen davon und folien daraus
EP4716708A1 (de) 2023-05-23 2026-04-01 ExxonMobil Technology and Engineering Company Katalysatoren und polymerisationen für verbesserte polyolefine

Family Cites Families (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2024830A1 (en) 1989-09-29 1991-03-30 Richard E. Campbell, Jr. Process for preparation of syndiotactic vinyl aromatic polymers
US5247020A (en) 1990-01-30 1993-09-21 Idemitsu Kosan Co., Ltd. Process for producing a styrene polymer composition
JP2840462B2 (ja) 1990-12-28 1998-12-24 出光興産株式会社 スチレン系重合体の製造方法及びその触媒
JP2888648B2 (ja) 1990-12-28 1999-05-10 出光興産株式会社 スチレン系重合体の製造方法及びその触媒
US5206197A (en) 1991-03-04 1993-04-27 The Dow Chemical Company Catalyst composition for preparation of syndiotactic vinyl aromatic polymers
JP2939354B2 (ja) 1991-03-26 1999-08-25 出光興産株式会社 スチレン系重合体の製造方法及びその触媒
US5886117A (en) 1991-08-05 1999-03-23 The Dow Chemical Company Process using borane derived catalysts for preparation of syndiotactic vinyl aromatic polymers
JP3194438B2 (ja) 1992-01-08 2001-07-30 出光興産株式会社 スチレン系重合体の製造方法及びその触媒
JP3121116B2 (ja) 1992-05-21 2000-12-25 出光興産株式会社 スチレン系ブロック共重合体及びその製造方法
ATE174029T1 (de) 1994-01-18 1998-12-15 Dow Chemical Co Verfahren zur herstellung von reduzierten metal- titankomplexen
US5594080A (en) 1994-03-24 1997-01-14 Leland Stanford, Jr. University Thermoplastic elastomeric olefin polymers, method of production and catalysts therefor
WO1996020225A2 (en) * 1994-12-20 1996-07-04 Montell Technology Company B.V. Reactor blend polypropylene, process for the preparation thereof and process for preparing metallocene ligands
US5527929A (en) 1994-08-02 1996-06-18 The Dow Chemical Company Zwitterionic biscyclopentadienyl complexes
US5491246A (en) 1995-04-24 1996-02-13 The Dow Chemical Company Synthesis of group 4 metal diene complexes
NL1001237C2 (nl) 1995-09-19 1997-03-20 Dsm Nv Copolymeer van een olefinisch monomeer en 1,2-polybutadieen.
IT1284105B1 (it) 1996-07-04 1998-05-08 Enichem Elastomers Procedimento per la preparazione di un catalizzatore utile per la idrogenazione di copolimeri stirene-butadiene
WO1998057996A1 (en) 1997-06-14 1998-12-23 The Board Of Trustees Of The Leland Stanford, Jr. University ETHYLENE ENHANCEMENT OF PROCESSES FOR SYNTHESIS OF HIGH MELTING THERMOPLASTIC ELASTOMERIC α-OLEFIN POLYMERS (PRE/EPE EFFECTS)
ES2182494T3 (es) 1998-03-11 2003-03-01 Dow Chemical Co Procedimiento integrado para la preparacion de complejos de dienos.

Also Published As

Publication number Publication date
EP1157047B1 (de) 2003-04-23
WO2000035975A1 (en) 2000-06-22
AU2360900A (en) 2000-07-03
CA2355236A1 (en) 2000-06-22
US6479424B1 (en) 2002-11-12
DE69907279T2 (de) 2004-03-11
EP1157047A1 (de) 2001-11-28
DE69907279D1 (de) 2003-05-28

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