ATE238359T1 - Liganden und katalysatoren um elastomerische propylenpolymere herzustellen - Google Patents

Liganden und katalysatoren um elastomerische propylenpolymere herzustellen

Info

Publication number
ATE238359T1
ATE238359T1 AT99967306T AT99967306T ATE238359T1 AT E238359 T1 ATE238359 T1 AT E238359T1 AT 99967306 T AT99967306 T AT 99967306T AT 99967306 T AT99967306 T AT 99967306T AT E238359 T1 ATE238359 T1 AT E238359T1
Authority
AT
Austria
Prior art keywords
ligands
catalysts
propylene polymers
elastomeric propylene
producing elastomeric
Prior art date
Application number
AT99967306T
Other languages
English (en)
Inventor
Andreas P Ernst
Eric J Moore
Charles L Myers
Roger W Quan
Original Assignee
Bp Corp North America Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bp Corp North America Inc filed Critical Bp Corp North America Inc
Application granted granted Critical
Publication of ATE238359T1 publication Critical patent/ATE238359T1/de

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2282—Unsaturated compounds used as ligands
    • B01J31/2295—Cyclic compounds, e.g. cyclopentadienyls
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C13/00—Cyclic hydrocarbons containing rings other than, or in addition to, six-membered aromatic rings
    • C07C13/28—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof
    • C07C13/32—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings
    • C07C13/45—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings with a bicyclo ring system containing nine carbon atoms
    • C07C13/465—Indenes; Completely or partially hydrogenated indenes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C—Si linkages
    • C07F7/0803—Compounds with Si-C or Si-Si linkages
    • C07F7/0805—Compounds with Si-C or Si-Si linkages comprising only Si, C or H atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/06—Propene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/48—Zirconium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/49—Hafnium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2602/00—Systems containing two condensed rings
    • C07C2602/02—Systems containing two condensed rings the rings having only two atoms in common
    • C07C2602/04—One of the condensed rings being a six-membered aromatic ring
    • C07C2602/08—One of the condensed rings being a six-membered aromatic ring the other ring being five-membered, e.g. indane
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Inorganic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
AT99967306T 1998-12-14 1999-12-14 Liganden und katalysatoren um elastomerische propylenpolymere herzustellen ATE238359T1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US11238398P 1998-12-14 1998-12-14
PCT/US1999/029616 WO2000035975A1 (en) 1998-12-14 1999-12-14 Ligands and catalysts for producing elastomeric propylene polymers

Publications (1)

Publication Number Publication Date
ATE238359T1 true ATE238359T1 (de) 2003-05-15

Family

ID=22343610

Family Applications (1)

Application Number Title Priority Date Filing Date
AT99967306T ATE238359T1 (de) 1998-12-14 1999-12-14 Liganden und katalysatoren um elastomerische propylenpolymere herzustellen

Country Status (7)

Country Link
US (1) US6479424B1 (de)
EP (1) EP1157047B1 (de)
AT (1) ATE238359T1 (de)
AU (1) AU2360900A (de)
CA (1) CA2355236A1 (de)
DE (1) DE69907279T2 (de)
WO (1) WO2000035975A1 (de)

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2292538A1 (en) * 1997-06-14 1998-12-23 Charles L. Myers Ethylene enhancement of processes for synthesis of high melting thermoplastic elastomeric .alpha.-olefin polymers (pre/epe effects)
US7459511B2 (en) * 2001-06-12 2008-12-02 Basell Polyolefine Gmbh Process for the polymerization of 1-butene
US8008412B2 (en) 2002-09-20 2011-08-30 Exxonmobil Chemical Patents Inc. Polymer production at supersolution conditions
DE60329523D1 (de) * 2002-12-04 2009-11-12 Basell Polyolefine Gmbh 1-Buten-Copolymere und Herstellungsverfahren dafür
US7589160B2 (en) * 2002-12-04 2009-09-15 Basell Polyolefine Gmbh Process for preparing 1-butene polymers
DE60318616T2 (de) * 2002-12-04 2009-01-08 Basell Polyolefine Gmbh Verfahren zur herstellung von1-buten-polymeren
CN101124235B (zh) * 2004-07-08 2010-12-15 埃克森美孚化学专利公司 烯烃聚合催化剂体系及其使用方法
US8242237B2 (en) 2006-12-20 2012-08-14 Exxonmobil Chemical Patents Inc. Phase separator and monomer recycle for supercritical polymerization process
WO2008150572A1 (en) 2007-06-04 2008-12-11 Exxonmobil Chemical Patents Inc. Super-solution homogeneous propylene polymerization
US8318875B2 (en) 2008-01-18 2012-11-27 Exxonmobil Chemical Patents Inc. Super-solution homogeneous propylene polymerization and polypropylenes made therefrom
KR102372974B1 (ko) * 2019-04-05 2022-03-10 한화솔루션 주식회사 혼성 촉매 조성물, 이를 포함하는 촉매 및 이들의 제조방법
EP4716709A1 (de) 2023-05-23 2026-04-01 ExxonMobil Technology and Engineering Company Polyethylene, katalysatoren für ihre polymerisation und daraus hergestellte filme
WO2024242929A1 (en) 2023-05-23 2024-11-28 ExxonMobil Technology and Engineering Company Low density polethylenes, films thereof, and methods and catalysts for production thereof
CN121420002A (zh) 2023-05-23 2026-01-27 埃克森美孚技术与工程公司 用于改进的聚烯烃的催化剂和聚合
CN121420003A (zh) 2023-05-23 2026-01-27 埃克森美孚技术与工程公司 催化剂、聚乙烯、其聚合及其膜
WO2024242933A1 (en) 2023-05-23 2024-11-28 ExxonMobil Technology and Engineering Company Catalysts and polymerizations for improved polyolefins
EP4716704A1 (de) 2023-05-23 2026-04-01 ExxonMobil Technology and Engineering Company Polyethylene mit verbesserter verarbeitbarkeit und daraus hergestellte folien

Family Cites Families (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2024830A1 (en) 1989-09-29 1991-03-30 Richard E. Campbell, Jr. Process for preparation of syndiotactic vinyl aromatic polymers
US5247020A (en) 1990-01-30 1993-09-21 Idemitsu Kosan Co., Ltd. Process for producing a styrene polymer composition
JP2888648B2 (ja) 1990-12-28 1999-05-10 出光興産株式会社 スチレン系重合体の製造方法及びその触媒
JP2840462B2 (ja) 1990-12-28 1998-12-24 出光興産株式会社 スチレン系重合体の製造方法及びその触媒
US5206197A (en) 1991-03-04 1993-04-27 The Dow Chemical Company Catalyst composition for preparation of syndiotactic vinyl aromatic polymers
JP2939354B2 (ja) 1991-03-26 1999-08-25 出光興産株式会社 スチレン系重合体の製造方法及びその触媒
US5886117A (en) 1991-08-05 1999-03-23 The Dow Chemical Company Process using borane derived catalysts for preparation of syndiotactic vinyl aromatic polymers
JP3194438B2 (ja) 1992-01-08 2001-07-30 出光興産株式会社 スチレン系重合体の製造方法及びその触媒
JP3121116B2 (ja) 1992-05-21 2000-12-25 出光興産株式会社 スチレン系ブロック共重合体及びその製造方法
CA2180558A1 (en) 1994-01-18 1995-07-20 Thomas H. Newman Process for preparation of reduced metal titanium complexes
US5594080A (en) 1994-03-24 1997-01-14 Leland Stanford, Jr. University Thermoplastic elastomeric olefin polymers, method of production and catalysts therefor
US5616664A (en) 1994-08-02 1997-04-01 The Dow Chemical Company Polymerization process with biscyclopentadienyl diene complex containing catalysts
CN1147822A (zh) 1994-12-20 1997-04-16 蒙特尔技术有限公司 反应器掺混聚丙烯,其制备方法和金属茂配位体的制备方法
US5491246A (en) 1995-04-24 1996-02-13 The Dow Chemical Company Synthesis of group 4 metal diene complexes
NL1001237C2 (nl) 1995-09-19 1997-03-20 Dsm Nv Copolymeer van een olefinisch monomeer en 1,2-polybutadieen.
IT1284105B1 (it) 1996-07-04 1998-05-08 Enichem Elastomers Procedimento per la preparazione di un catalizzatore utile per la idrogenazione di copolimeri stirene-butadiene
CA2292538A1 (en) 1997-06-14 1998-12-23 Charles L. Myers Ethylene enhancement of processes for synthesis of high melting thermoplastic elastomeric .alpha.-olefin polymers (pre/epe effects)
DE69902638T2 (de) 1998-03-11 2003-04-24 The Dow Chemical Co., Midland Integriertes verfahren zur herstellung von dien-komplexen

Also Published As

Publication number Publication date
EP1157047B1 (de) 2003-04-23
US6479424B1 (en) 2002-11-12
WO2000035975A1 (en) 2000-06-22
DE69907279T2 (de) 2004-03-11
DE69907279D1 (de) 2003-05-28
EP1157047A1 (de) 2001-11-28
AU2360900A (en) 2000-07-03
CA2355236A1 (en) 2000-06-22

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