ATE243717T1 - USE OF METALLOCE CATALYSTS FOR THE PRODUCTION OF REGIOSPECIFIC ISOTACTIC POLYOLEFINS - Google Patents

USE OF METALLOCE CATALYSTS FOR THE PRODUCTION OF REGIOSPECIFIC ISOTACTIC POLYOLEFINS

Info

Publication number
ATE243717T1
ATE243717T1 AT98930732T AT98930732T ATE243717T1 AT E243717 T1 ATE243717 T1 AT E243717T1 AT 98930732 T AT98930732 T AT 98930732T AT 98930732 T AT98930732 T AT 98930732T AT E243717 T1 ATE243717 T1 AT E243717T1
Authority
AT
Austria
Prior art keywords
hydrocarbyl
chosen
carbon atoms
substituent
different
Prior art date
Application number
AT98930732T
Other languages
German (de)
Inventor
Abbas Razavi
Vincenzo Bellia
Original Assignee
Atofina Res
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Atofina Res filed Critical Atofina Res
Application granted granted Critical
Publication of ATE243717T1 publication Critical patent/ATE243717T1/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65904—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with another component of C08F4/64
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

Use for preparing isotactic polyolefins of a metallocene catalyst component, which has the general formula: R" (CpR1R2) (Cp'Rn') MQ2 wherein Cp is a substituted cyclopentadienyl ring; Cp' is a substituted or unsubstituted fluorenyl ring; R" is a structural bridge imparting stereorigidity to the component; R1 is a substituent on the cyclopentadienyl ring which is distal to the bridge, which distal substituent comprises a bulky group of the formula XR*3 in which X is chosen from Group IVA, and each R* is the same or different and chosen from hydrogen or hydrocarbyl of from 1 to 20 carbon atoms, R2 is a substituent on the cyclopentadienyl ring which is proximal to the bridge and positioned non-vicinal to the distal substituent and is of the formula YR#3 in which Y is chosen from group IVA, and each R# is the same or different and chosen from hydrogen or hydrocarbyl of 1 to 7 carbon atoms, each R'n is the same or different and is hydrocarbyl having 1 to 20 carbon atoms in whrch o≤n≤8; M is a Group IVB transition metal or vanadium; and each Q is hydrocarbyl having 1 to 20 carbon atoms or is a halogen.
AT98930732T 1997-05-26 1998-05-26 USE OF METALLOCE CATALYSTS FOR THE PRODUCTION OF REGIOSPECIFIC ISOTACTIC POLYOLEFINS ATE243717T1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP97108467A EP0881236A1 (en) 1997-05-26 1997-05-26 Metallocene catalyst component for use in producing isotactic polyolefins
PCT/EP1998/003099 WO1998054230A1 (en) 1997-05-26 1998-05-26 Metallocene catalyst component for use in producing isotactic polyolefins

Publications (1)

Publication Number Publication Date
ATE243717T1 true ATE243717T1 (en) 2003-07-15

Family

ID=8226830

Family Applications (2)

Application Number Title Priority Date Filing Date
AT98930732T ATE243717T1 (en) 1997-05-26 1998-05-26 USE OF METALLOCE CATALYSTS FOR THE PRODUCTION OF REGIOSPECIFIC ISOTACTIC POLYOLEFINS
AT02078802T ATE391734T1 (en) 1997-05-26 1998-05-26 USE OF A MIXTURE OF TWO REGIOISOMERS OF A METALLOCENE AS A CATALYST COMPONENT FOR THE PRODUCTION OF BIMODAL ISOTACTIC POLYOLEFINS

Family Applications After (1)

Application Number Title Priority Date Filing Date
AT02078802T ATE391734T1 (en) 1997-05-26 1998-05-26 USE OF A MIXTURE OF TWO REGIOISOMERS OF A METALLOCENE AS A CATALYST COMPONENT FOR THE PRODUCTION OF BIMODAL ISOTACTIC POLYOLEFINS

Country Status (9)

Country Link
US (1) US6559089B1 (en)
EP (3) EP0881236A1 (en)
JP (1) JP4208097B2 (en)
AT (2) ATE243717T1 (en)
DE (2) DE69839354T2 (en)
DK (1) DK0984989T3 (en)
ES (2) ES2202875T3 (en)
PT (2) PT1283223E (en)
WO (1) WO1998054230A1 (en)

Families Citing this family (32)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6469188B1 (en) 1999-01-20 2002-10-22 California Institute Of Technology Catalyst system for the polymerization of alkenes to polyolefins
US6515086B1 (en) 1999-02-19 2003-02-04 Fina Research, S.A. Polyolefin production
JP4864176B2 (en) * 1999-02-19 2012-02-01 トータル・ペトロケミカルズ・リサーチ・フエリユイ Polyolefin production
EP1031582A1 (en) * 1999-02-26 2000-08-30 Fina Research S.A. Use and production of polypropylene
DE60034308T2 (en) * 1999-10-08 2007-12-20 Mitsui Chemicals, Inc. Metallocenes, a process for their preparation, olefin polymerization catalyst, and a process for the preparation of polyolefins
US7475098B2 (en) * 2002-03-19 2009-01-06 Network Appliance, Inc. System and method for managing a plurality of snapshots
TWI296270B (en) * 2002-07-19 2008-05-01 Mitsui Chemicals Inc Propylene copolymer, polypropylene composition and its usage, and transition metal compound, catalyst for olefinic polymerization
AU2003261617A1 (en) 2002-08-29 2004-03-19 Lg Chem, Ltd. Fulvene, metallocene catalysts and preparation method thereof, and preparation of polyolefines copolymer using the same
US6855783B2 (en) 2003-04-11 2005-02-15 Fina Technology, Inc. Supported metallocene catalysts
US6878787B2 (en) 2003-08-26 2005-04-12 Fina Technology, Inc. Polyamide supported metallocene catalysts
US20050234198A1 (en) * 2004-04-20 2005-10-20 Fina Technology, Inc. Heterophasic copolymer and metallocene catalyst system and method of producing the heterophasic copolymer using the metallocene catalyst system
US7879960B2 (en) 2004-08-30 2011-02-01 Mitsui Chemicals, Inc. Process for producing propylene polymer
CN100390256C (en) 2004-11-26 2008-05-28 三井化学株式会社 Synthetic lubricating oils and lubricating oil compositions
KR101044134B1 (en) 2005-05-18 2011-06-28 미쓰이 가가쿠 가부시키가이샤 Catalyst for olefin polymerization, method for preparing olefin polymer, method for preparing propylene copolymer, propylene polymer, propylene polymer composition and uses thereof
EP1900744A4 (en) * 2005-05-25 2010-10-20 Mitsui Chemicals Inc Transition metal compound, olefin polymerization catalyst, and process for producing olefin polymer
KR100948728B1 (en) * 2005-05-25 2010-03-22 미쓰이 가가쿠 가부시키가이샤 Fluorene Derivatives, Transition Metal Compounds, Catalysts for Olefin Polymerization and Processes for Preparing Olefin Polymers
US7226886B2 (en) 2005-09-15 2007-06-05 Chevron Phillips Chemical Company, L.P. Polymerization catalysts and process for producing bimodal polymers in a single reactor
EP1762577A1 (en) * 2005-09-02 2007-03-14 Total Petrochemicals Research Feluy Impact copolymer of propylene prepared in single reactor
US7619047B2 (en) 2006-02-22 2009-11-17 Chevron Phillips Chemical Company, Lp Dual metallocene catalysts for polymerization of bimodal polymers
US7514510B2 (en) * 2006-07-25 2009-04-07 Fina Technology, Inc. Fluorenyl catalyst compositions and olefin polymerization process
EP2204375A1 (en) 2008-12-12 2010-07-07 Total Petrochemicals Research Feluy Preparation of mono-aryl-substituted methylene-bridged substituted cyclopentadienyl-fluorenyl ligands and zirconium complexes derived thereof
US8114946B2 (en) 2008-12-18 2012-02-14 Chevron Phillips Chemical Company Lp Process for producing broader molecular weight distribution polymers with a reverse comonomer distribution and low levels of long chain branches
WO2011078054A1 (en) 2009-12-21 2011-06-30 三井化学株式会社 PROCESS FOR PRODUCTION OF SYNDIOTACTIC α-OLEFIN POLYMER
US20120135903A1 (en) 2010-05-11 2012-05-31 Mitsui Chemicals, Inc. Lubricating oil composition
CN104203993B (en) 2012-03-21 2016-06-15 三井化学株式会社 Process for producing olefin polymers
SG11201502288TA (en) 2012-09-25 2015-05-28 Mitsui Chemicals Inc Process for producing olefin polymer and olefin polymer
JP6033322B2 (en) 2012-09-25 2016-11-30 三井化学株式会社 Transition metal compound, catalyst for olefin polymerization, and method for producing olefin polymer
US8895679B2 (en) 2012-10-25 2014-11-25 Chevron Phillips Chemical Company Lp Catalyst compositions and methods of making and using same
US8937139B2 (en) 2012-10-25 2015-01-20 Chevron Phillips Chemical Company Lp Catalyst compositions and methods of making and using same
US9034991B2 (en) 2013-01-29 2015-05-19 Chevron Phillips Chemical Company Lp Polymer compositions and methods of making and using same
US8877672B2 (en) 2013-01-29 2014-11-04 Chevron Phillips Chemical Company Lp Catalyst compositions and methods of making and using same
US11028192B2 (en) 2017-03-27 2021-06-08 Exxonmobil Chemical Patents Inc. Solution process to make ethylene copolymers

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5416228A (en) * 1991-10-07 1995-05-16 Fina Technology, Inc. Process and catalyst for producing isotactic polyolefins
US6245870B1 (en) * 1992-03-20 2001-06-12 Fina Technology, Inc. Process for producing syndiotactic/isotactic block polyolefins
US5459117A (en) * 1993-08-27 1995-10-17 Ewen; John A. Doubly-conformationally locked, stereorigid catalysts for the preparation of tactiospecific polymers
US5631202A (en) * 1993-09-24 1997-05-20 Montell Technology Company B.V. Stereospecific metallocene catalysts with stereolocking α-CP substituents
DE4431643C2 (en) * 1994-07-22 2002-08-08 Borealis Polymere Holding Ag Process for the preparation of silicon-bridged asymmetric cyclopentadienyl, indenyl and fluorenyl ligand systems

Also Published As

Publication number Publication date
DE69815846D1 (en) 2003-07-31
EP1283223B1 (en) 2008-04-09
ES2202875T3 (en) 2004-04-01
US6559089B1 (en) 2003-05-06
ES2302782T3 (en) 2008-08-01
PT1283223E (en) 2008-09-17
DE69839354T2 (en) 2009-05-28
JP2001526730A (en) 2001-12-18
EP0984989B1 (en) 2003-06-25
EP0984989A1 (en) 2000-03-15
DK0984989T3 (en) 2003-10-06
WO1998054230A1 (en) 1998-12-03
DE69839354D1 (en) 2008-05-21
PT984989E (en) 2003-09-30
EP1283223A2 (en) 2003-02-12
EP1283223A3 (en) 2004-12-22
JP4208097B2 (en) 2009-01-14
ATE391734T1 (en) 2008-04-15
DE69815846T2 (en) 2004-05-13
EP0881236A1 (en) 1998-12-02

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