ATE243717T1 - Verwendung von metallocenkatalysatoren zur herstellung von regiospezifischen, isotaktischen polyolefinen - Google Patents
Verwendung von metallocenkatalysatoren zur herstellung von regiospezifischen, isotaktischen polyolefinenInfo
- Publication number
- ATE243717T1 ATE243717T1 AT98930732T AT98930732T ATE243717T1 AT E243717 T1 ATE243717 T1 AT E243717T1 AT 98930732 T AT98930732 T AT 98930732T AT 98930732 T AT98930732 T AT 98930732T AT E243717 T1 ATE243717 T1 AT E243717T1
- Authority
- AT
- Austria
- Prior art keywords
- hydrocarbyl
- chosen
- carbon atoms
- substituent
- different
- Prior art date
Links
- 229920000098 polyolefin Polymers 0.000 title abstract 2
- 239000003054 catalyst Substances 0.000 title 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 4
- 125000001183 hydrocarbyl group Chemical group 0.000 abstract 4
- 125000001424 substituent group Chemical group 0.000 abstract 4
- 125000000058 cyclopentadienyl group Chemical group C1(=CC=CC1)* 0.000 abstract 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 2
- 229910052739 hydrogen Inorganic materials 0.000 abstract 2
- 239000001257 hydrogen Substances 0.000 abstract 2
- 125000003983 fluorenyl group Chemical group C1(=CC=CC=2C3=CC=CC=C3CC12)* 0.000 abstract 1
- 229910052736 halogen Inorganic materials 0.000 abstract 1
- 125000005843 halogen group Chemical group 0.000 abstract 1
- 239000012968 metallocene catalyst Substances 0.000 abstract 1
- 229910052723 transition metal Inorganic materials 0.000 abstract 1
- 150000003624 transition metals Chemical class 0.000 abstract 1
- 229910052720 vanadium Inorganic materials 0.000 abstract 1
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65904—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with another component of C08F4/64
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP97108467A EP0881236A1 (de) | 1997-05-26 | 1997-05-26 | Mettallocen-Katalysatorkomponente zur Herstellung von isotaktischen Polyolefinen |
| PCT/EP1998/003099 WO1998054230A1 (en) | 1997-05-26 | 1998-05-26 | Metallocene catalyst component for use in producing isotactic polyolefins |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ATE243717T1 true ATE243717T1 (de) | 2003-07-15 |
Family
ID=8226830
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AT02078802T ATE391734T1 (de) | 1997-05-26 | 1998-05-26 | Verwendung einer mischung aus zwei regioisomeren eines metallocens als katalysatorbestandteil für die herstellung bimodaler isotaktischen polyolefine |
| AT98930732T ATE243717T1 (de) | 1997-05-26 | 1998-05-26 | Verwendung von metallocenkatalysatoren zur herstellung von regiospezifischen, isotaktischen polyolefinen |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AT02078802T ATE391734T1 (de) | 1997-05-26 | 1998-05-26 | Verwendung einer mischung aus zwei regioisomeren eines metallocens als katalysatorbestandteil für die herstellung bimodaler isotaktischen polyolefine |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US6559089B1 (de) |
| EP (3) | EP0881236A1 (de) |
| JP (1) | JP4208097B2 (de) |
| AT (2) | ATE391734T1 (de) |
| DE (2) | DE69815846T2 (de) |
| DK (1) | DK0984989T3 (de) |
| ES (2) | ES2202875T3 (de) |
| PT (2) | PT984989E (de) |
| WO (1) | WO1998054230A1 (de) |
Families Citing this family (32)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6469188B1 (en) * | 1999-01-20 | 2002-10-22 | California Institute Of Technology | Catalyst system for the polymerization of alkenes to polyolefins |
| US6515086B1 (en) | 1999-02-19 | 2003-02-04 | Fina Research, S.A. | Polyolefin production |
| WO2000049029A1 (en) * | 1999-02-19 | 2000-08-24 | Fina Research S.A. | Polyolefin production |
| EP1031582A1 (de) * | 1999-02-26 | 2000-08-30 | Fina Research S.A. | Verwendung und Herstellung von Polypropylen |
| US6939928B1 (en) * | 1999-10-08 | 2005-09-06 | Mitsui Chemicals, Inc. | Metallocene compound, process for producing metallocene compound, olefin polymerization catalyst, process for producing polyolefin, and polyolefin |
| US7475098B2 (en) * | 2002-03-19 | 2009-01-06 | Network Appliance, Inc. | System and method for managing a plurality of snapshots |
| JP4202320B2 (ja) | 2002-08-29 | 2008-12-24 | エルジー・ケム・リミテッド | フルベン、メタロセン触媒とその製造方法、及びこれを用いたポリオレフィン共重合体の製造方法 |
| EP1985637B1 (de) | 2003-03-28 | 2010-03-03 | Mitsui Chemicals, Inc. | Propylen-Copolymer, Polypropylen-Zusammensetzung, Verwendung davon, Übergangsmetallverbindungen und Katalysatoren zur Olefin-Polymerisation |
| US6855783B2 (en) * | 2003-04-11 | 2005-02-15 | Fina Technology, Inc. | Supported metallocene catalysts |
| US6878787B2 (en) | 2003-08-26 | 2005-04-12 | Fina Technology, Inc. | Polyamide supported metallocene catalysts |
| US20050234198A1 (en) * | 2004-04-20 | 2005-10-20 | Fina Technology, Inc. | Heterophasic copolymer and metallocene catalyst system and method of producing the heterophasic copolymer using the metallocene catalyst system |
| US7879960B2 (en) | 2004-08-30 | 2011-02-01 | Mitsui Chemicals, Inc. | Process for producing propylene polymer |
| US7795194B2 (en) | 2004-11-26 | 2010-09-14 | Mitsui Chemicals, Inc. | Synthetic lubricating oil and lubricating oil composition |
| KR101064037B1 (ko) | 2005-05-18 | 2011-09-08 | 미쓰이 가가쿠 가부시키가이샤 | 올레핀 중합용 촉매, 올레핀 중합체의 제조방법, 프로필렌계 공중합체의 제조방법, 프로필렌 중합체, 프로필렌계 중합체 조성물 및 이들의 용도 |
| JPWO2006126610A1 (ja) * | 2005-05-25 | 2008-12-25 | 三井化学株式会社 | 遷移金属化合物、オレフィン重合用触媒およびオレフィン系重合体の製造方法 |
| US7834204B2 (en) * | 2005-05-25 | 2010-11-16 | Mitsui Chemicals, Inc. | Fluorene derivative, transition metal compound, catalyst for olefin polymerization, and process for producing olefin polymer |
| US7226886B2 (en) * | 2005-09-15 | 2007-06-05 | Chevron Phillips Chemical Company, L.P. | Polymerization catalysts and process for producing bimodal polymers in a single reactor |
| EP1762577A1 (de) * | 2005-09-02 | 2007-03-14 | Total Petrochemicals Research Feluy | Schlagfeste propylen-copolymere vorbereitet in einem reactor |
| US7619047B2 (en) | 2006-02-22 | 2009-11-17 | Chevron Phillips Chemical Company, Lp | Dual metallocene catalysts for polymerization of bimodal polymers |
| US7514510B2 (en) * | 2006-07-25 | 2009-04-07 | Fina Technology, Inc. | Fluorenyl catalyst compositions and olefin polymerization process |
| EP2204375A1 (de) | 2008-12-12 | 2010-07-07 | Total Petrochemicals Research Feluy | Herstellung von monoarylsubstituierten, methylenverbrückten substituierten Cyclopentadienyl-Fluorenyl-Liganden und davon abgeleitete Zirkoniumkomplexe |
| US8114946B2 (en) | 2008-12-18 | 2012-02-14 | Chevron Phillips Chemical Company Lp | Process for producing broader molecular weight distribution polymers with a reverse comonomer distribution and low levels of long chain branches |
| SG181837A1 (en) | 2009-12-21 | 2012-08-30 | Mitsui Chemicals Inc | Process for production of syndiotactic a-olefin polymer |
| US20120135903A1 (en) | 2010-05-11 | 2012-05-31 | Mitsui Chemicals, Inc. | Lubricating oil composition |
| WO2013140991A1 (ja) | 2012-03-21 | 2013-09-26 | 三井化学株式会社 | オレフィン重合体の製造方法 |
| WO2014050816A1 (ja) | 2012-09-25 | 2014-04-03 | 三井化学株式会社 | 遷移金属化合物、オレフィン重合用触媒およびオレフィン重合体の製造方法 |
| US9458257B2 (en) | 2012-09-25 | 2016-10-04 | Mitsui Chemicals, Inc. | Process for producing olefin polymer and olefin polymer |
| US8937139B2 (en) | 2012-10-25 | 2015-01-20 | Chevron Phillips Chemical Company Lp | Catalyst compositions and methods of making and using same |
| US8895679B2 (en) | 2012-10-25 | 2014-11-25 | Chevron Phillips Chemical Company Lp | Catalyst compositions and methods of making and using same |
| US8877672B2 (en) | 2013-01-29 | 2014-11-04 | Chevron Phillips Chemical Company Lp | Catalyst compositions and methods of making and using same |
| US9034991B2 (en) | 2013-01-29 | 2015-05-19 | Chevron Phillips Chemical Company Lp | Polymer compositions and methods of making and using same |
| US11028192B2 (en) | 2017-03-27 | 2021-06-08 | Exxonmobil Chemical Patents Inc. | Solution process to make ethylene copolymers |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5416228A (en) * | 1991-10-07 | 1995-05-16 | Fina Technology, Inc. | Process and catalyst for producing isotactic polyolefins |
| US6245870B1 (en) * | 1992-03-20 | 2001-06-12 | Fina Technology, Inc. | Process for producing syndiotactic/isotactic block polyolefins |
| US5459117A (en) * | 1993-08-27 | 1995-10-17 | Ewen; John A. | Doubly-conformationally locked, stereorigid catalysts for the preparation of tactiospecific polymers |
| US5631202A (en) * | 1993-09-24 | 1997-05-20 | Montell Technology Company B.V. | Stereospecific metallocene catalysts with stereolocking α-CP substituents |
| DE4431643C2 (de) * | 1994-07-22 | 2002-08-08 | Borealis Polymere Holding Ag | Verfahren zur Herstellung von Silizium-verbrückten unsymmetrischen Cyclopentadienyl-, Indenyl- und Fluorenyl-Ligandsystemen |
-
1997
- 1997-05-26 EP EP97108467A patent/EP0881236A1/de not_active Withdrawn
-
1998
- 1998-05-26 DE DE69815846T patent/DE69815846T2/de not_active Expired - Lifetime
- 1998-05-26 ES ES98930732T patent/ES2202875T3/es not_active Expired - Lifetime
- 1998-05-26 EP EP02078802A patent/EP1283223B1/de not_active Expired - Lifetime
- 1998-05-26 DK DK98930732T patent/DK0984989T3/da active
- 1998-05-26 AT AT02078802T patent/ATE391734T1/de not_active IP Right Cessation
- 1998-05-26 AT AT98930732T patent/ATE243717T1/de not_active IP Right Cessation
- 1998-05-26 US US09/424,416 patent/US6559089B1/en not_active Expired - Lifetime
- 1998-05-26 PT PT98930732T patent/PT984989E/pt unknown
- 1998-05-26 PT PT02078802T patent/PT1283223E/pt unknown
- 1998-05-26 JP JP50022899A patent/JP4208097B2/ja not_active Expired - Lifetime
- 1998-05-26 EP EP98930732A patent/EP0984989B1/de not_active Expired - Lifetime
- 1998-05-26 WO PCT/EP1998/003099 patent/WO1998054230A1/en not_active Ceased
- 1998-05-26 ES ES02078802T patent/ES2302782T3/es not_active Expired - Lifetime
- 1998-05-26 DE DE69839354T patent/DE69839354T2/de not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| EP1283223A2 (de) | 2003-02-12 |
| DE69815846T2 (de) | 2004-05-13 |
| JP4208097B2 (ja) | 2009-01-14 |
| DE69815846D1 (de) | 2003-07-31 |
| WO1998054230A1 (en) | 1998-12-03 |
| EP0984989A1 (de) | 2000-03-15 |
| DK0984989T3 (da) | 2003-10-06 |
| ES2202875T3 (es) | 2004-04-01 |
| DE69839354T2 (de) | 2009-05-28 |
| PT984989E (pt) | 2003-09-30 |
| EP0881236A1 (de) | 1998-12-02 |
| ES2302782T3 (es) | 2008-08-01 |
| PT1283223E (pt) | 2008-09-17 |
| JP2001526730A (ja) | 2001-12-18 |
| EP1283223A3 (de) | 2004-12-22 |
| ATE391734T1 (de) | 2008-04-15 |
| US6559089B1 (en) | 2003-05-06 |
| EP0984989B1 (de) | 2003-06-25 |
| EP1283223B1 (de) | 2008-04-09 |
| DE69839354D1 (de) | 2008-05-21 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| UEP | Publication of translation of european patent specification |
Ref document number: 0984989 Country of ref document: EP |
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| REN | Ceased due to non-payment of the annual fee |