ATE252605T1 - Mehrstufiges verfahren zur (co)polymersation von olefinen - Google Patents

Mehrstufiges verfahren zur (co)polymersation von olefinen

Info

Publication number
ATE252605T1
ATE252605T1 AT00918760T AT00918760T ATE252605T1 AT E252605 T1 ATE252605 T1 AT E252605T1 AT 00918760 T AT00918760 T AT 00918760T AT 00918760 T AT00918760 T AT 00918760T AT E252605 T1 ATE252605 T1 AT E252605T1
Authority
AT
Austria
Prior art keywords
sub
stage
sup
polymerization
olefins
Prior art date
Application number
AT00918760T
Other languages
English (en)
Inventor
Gianni Collina
Edward Bryan Coughlin
Giuliano Cecchin
Giovanni Baruzzi
Anna Fait
Original Assignee
Basell Polyolefine Gmbh
Du Pont
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basell Polyolefine Gmbh, Du Pont filed Critical Basell Polyolefine Gmbh
Application granted granted Critical
Publication of ATE252605T1 publication Critical patent/ATE252605T1/de

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/08—Copolymers of ethene
    • C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms
    • C08L23/0815—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms with aliphatic 1-olefins containing one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/642—Component covered by group C08F4/64 with an organo-aluminium compound
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/24—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/34—Polymerisation in gaseous state
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/06—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/06—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type
    • C08F297/08—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins
    • C08F297/083—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins the monomers being ethylene or propylene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/64003—Titanium, zirconium, hafnium or compounds thereof the metallic compound containing a multidentate ligand, i.e. a ligand capable of donating two or more pairs of electrons to form a coordinate or ionic bond
    • C08F4/64006—Bidentate ligand
    • C08F4/6401—Neutral ligand
    • C08F4/64013—NN
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/646—Catalysts comprising at least two different metals, in metallic form or as compounds thereof, in addition to the component covered by group C08F4/64
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652—Pretreating with metals or metal-containing compounds
    • C08F4/654—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof
    • C08F4/6543—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof halides of magnesium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C08L23/14—Copolymers of propene
    • C08L23/142—Copolymers of propene at least partially crystalline copolymers of propene with other olefins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/05—Transitioning, i.e. transition from one catalyst to another with use of a deactivating agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2308/00—Chemical blending or stepwise polymerisation process with the same catalyst
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2314/00—Polymer mixtures characterised by way of preparation
    • C08L2314/08—Polymer mixtures characterised by way of preparation prepared by late transition metal, i.e. Ni, Pd, Pt, Co, Rh, Ir, Fe, Ru or Os, single site catalyst

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)
  • Graft Or Block Polymers (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
AT00918760T 1999-03-09 2000-03-06 Mehrstufiges verfahren zur (co)polymersation von olefinen ATE252605T1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP99200698 1999-03-09
PCT/EP2000/001924 WO2000053646A1 (en) 1999-03-09 2000-03-06 Multi-stage process for the (co)polymerization of olefins

Publications (1)

Publication Number Publication Date
ATE252605T1 true ATE252605T1 (de) 2003-11-15

Family

ID=8239965

Family Applications (1)

Application Number Title Priority Date Filing Date
AT00918760T ATE252605T1 (de) 1999-03-09 2000-03-06 Mehrstufiges verfahren zur (co)polymersation von olefinen

Country Status (12)

Country Link
US (1) US6992153B1 (de)
EP (1) EP1161465B1 (de)
JP (1) JP2002539283A (de)
KR (1) KR20010102542A (de)
CN (1) CN1350552A (de)
AT (1) ATE252605T1 (de)
AU (1) AU3960500A (de)
BR (1) BR0010376A (de)
DE (1) DE60006082T2 (de)
ES (1) ES2208301T3 (de)
MY (1) MY133191A (de)
WO (1) WO2000053646A1 (de)

Families Citing this family (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6521724B2 (en) 2000-03-10 2003-02-18 E. I. Du Pont De Nemours And Company Polymerization process
WO2002051887A2 (en) * 2000-12-22 2002-07-04 Basell Poliolefine Italia S.P.A. Process for the preparation of porous polymers and polymers obtainable thereof
JP2004535505A (ja) * 2001-07-17 2004-11-25 バセル ポリオレフィン ジーエムビーエイチ オレフィン(共)重合のための多工程方法
EP1518866A1 (de) * 2003-09-29 2005-03-30 Basell Poliolefine Italia S.P.A. Verfahren zur Herstellung von porösen Ethylenpolymeren
FR2860238B1 (fr) * 2003-09-29 2006-07-21 Atofina Res Polyethylene bimodal
US9403956B2 (en) 2013-02-06 2016-08-02 Exxonmobil Chemical Patents Inc. Incipient wetness method to enhance productivity of supported Ziegler-Natta catalysts
CZ305857B6 (cs) 2013-08-12 2016-04-13 Polymer Institute Brno, Spol. S R.O. Použití činidla pro nukleaci polyolefinů pro eliminaci tvorby úsad polyolefinového prášku v plynofázních polymeračních reaktorech
CN105985490A (zh) * 2015-02-16 2016-10-05 中国石油天然气股份有限公司 耐热聚乙烯共聚物的制备方法及耐热聚乙烯共聚物、管材
US10294316B2 (en) 2015-06-05 2019-05-21 Exxonmobil Chemical Patents Inc. Silica supports with high aluminoxane loading capability
US9725569B2 (en) 2015-06-05 2017-08-08 Exxonmobil Chemical Patents Inc. Porous propylene polymers
US10077325B2 (en) 2015-06-05 2018-09-18 Exxonmobil Chemical Patents Inc. Silica supports with high aluminoxane loading capability
US9809664B2 (en) 2015-06-05 2017-11-07 Exxonmobil Chemical Patents Inc. Bimodal propylene polymers and sequential polymerization
US9738779B2 (en) 2015-06-05 2017-08-22 Exxonmobil Chemical Patents Inc. Heterophasic copolymers and sequential polymerization
US10280233B2 (en) 2015-06-05 2019-05-07 Exxonmobil Chemical Patents Inc. Catalyst systems and methods of making and using the same
EP3303423A1 (de) 2015-06-05 2018-04-11 ExxonMobil Chemical Patents Inc. Einzelreaktor-herstellung von polymeren in der gas- oder suspensionsphase
US9725537B2 (en) 2015-06-05 2017-08-08 Exxonmobil Chemical Patents Inc. High activity catalyst supportation
US10723821B2 (en) 2015-06-05 2020-07-28 Exxonmobil Chemical Patents Inc. Supported metallocene catalyst systems for polymerization
WO2016197014A1 (en) * 2015-06-05 2016-12-08 Exxonmobil Chemical Patents Inc. Catalyst system containing high surface area supports and sequential polymerization to produce heterophasic polymers
US10280235B2 (en) 2015-06-05 2019-05-07 Exxonmobil Chemical Patents Inc. Catalyst system containing high surface area supports and sequential polymerization to produce heterophasic polymers
US9920176B2 (en) 2015-06-05 2018-03-20 Exxonmobil Chemical Patents Inc. Single site catalyst supportation
EP3303422B1 (de) 2015-06-05 2021-03-17 ExxonMobil Chemical Patents Inc. Herstellung von heterophasischen polymeren in gas- oder schlämmephase
US10329360B2 (en) 2015-06-05 2019-06-25 Exxonmobil Chemical Patents Inc. Catalyst system comprising supported alumoxane and unsupported alumoxane particles
EP3464390A1 (de) 2016-05-27 2019-04-10 ExxonMobil Chemical Patents Inc. Metallocenkatalysatorzusammensetzungen und und polymerisationsverfahren damit
KR20190038812A (ko) * 2016-06-30 2019-04-09 다우 글로벌 테크놀로지스 엘엘씨 낮은 공 단량체 도입용 전촉매 조성물 및 이의 제조 공정
CN114478865B (zh) * 2020-10-27 2023-04-11 中国石油化工股份有限公司 用于烯烃聚合的后过渡金属催化剂及其制备方法和应用
CN114478869B (zh) * 2020-10-27 2023-04-11 中国石油化工股份有限公司 用于烯烃聚合的后过渡金属催化剂及其制备方法和应用
CN114478868B (zh) * 2020-10-27 2023-04-11 中国石油化工股份有限公司 一种用于烯烃聚合的后过渡金属催化剂及其制备方法和应用
CN114478867B (zh) * 2020-10-27 2023-03-14 中国石油化工股份有限公司 一种用于烯烃聚合的后过渡金属催化剂及其制备方法和应用

Family Cites Families (38)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL162661B (nl) 1968-11-21 1980-01-15 Montedison Spa Werkwijze om een katalysator te bereiden voor de poly- merisatie van alkenen-1.
YU35844B (en) 1968-11-25 1981-08-31 Montedison Spa Process for obtaining catalysts for the polymerization of olefines
IT1140221B (it) 1981-10-14 1986-09-24 Montedison Spa Composizioni polipropileniche aventi migliorate caratteristiche di resistenza all'urto alle basse temperature e procedimento di preparazione
IT1227259B (it) 1988-09-30 1991-03-28 Himont Inc Catalizzatori per la polimerizzazione di olefine.
IT1227258B (it) 1988-09-30 1991-03-28 Himont Inc Componenti e catalizzatori per la polimerizzazione di olefine
IT1227260B (it) 1988-09-30 1991-03-28 Himont Inc Dieteri utilizzabili nella preparazione di catalizzatori ziegler-natta
IT1230134B (it) * 1989-04-28 1991-10-14 Himont Inc Componenti e catalizzatori per la polimerizzazione di olefine.
IT1241093B (it) 1990-03-30 1993-12-29 Himont Inc Componenti e catalizzatori per la polimerizzazione di olefine
JP2917412B2 (ja) * 1990-05-22 1999-07-12 三菱化学株式会社 プロピレン系共重合体の製造法
IT1262934B (it) 1992-01-31 1996-07-22 Montecatini Tecnologie Srl Componenti e catalizzatori per la polimerizzazione di olefine
IT1262935B (it) 1992-01-31 1996-07-22 Montecatini Tecnologie Srl Componenti e catalizzatori per la polimerizzazione di olefine
AU660808B2 (en) 1992-06-18 1995-07-06 Montell Technology Company B.V. Catalysts for the polymerization of olefins
US5442019A (en) * 1994-03-25 1995-08-15 Exxon Chemical Company Process for transitioning between incompatible polymerization catalysts
IT1269931B (it) * 1994-03-29 1997-04-16 Spherilene Srl Componenti e catalizzatori per la polimerizzazione di olefine
IT1273660B (it) 1994-07-20 1997-07-09 Spherilene Srl Procedimento per la preparazione di polimeri amorfi del propilene
IT1273661B (it) 1994-07-20 1997-07-09 Spherilene Srl Catalizzatori per la polimerizzazione delle olefine
IT1270125B (it) * 1994-10-05 1997-04-28 Spherilene Srl Processo per la ( co) polimerizzazione di olefine
DE4437057C2 (de) * 1994-10-17 1999-04-01 Agie Ag Ind Elektronik Verfahren und Vorrichtung zur Steuerung von Funkenerosionsmaschinen
JP3847783B2 (ja) 1995-01-24 2006-11-22 イー・アイ・デュポン・ドゥ・ヌムール・アンド・カンパニー オレフィンの重合方法
IL117114A (en) 1995-02-21 2000-02-17 Montell North America Inc Components and catalysts for the polymerization ofolefins
US5714556A (en) 1995-06-30 1998-02-03 E. I. Dupont De Nemours And Company Olefin polymerization process
JPH09278821A (ja) 1996-04-08 1997-10-28 Mitsui Petrochem Ind Ltd オレフィン重合用触媒およびオレフィンの重合方法
JPH09278822A (ja) 1996-04-08 1997-10-28 Mitsui Petrochem Ind Ltd オレフィン重合用触媒およびオレフィンの重合方法
CN1105730C (zh) * 1996-04-09 2003-04-16 三井化学株式会社 烯烃聚合催化剂及烯烃聚合方法,以及烯烃聚合物组合物和热模塑产品
HU223533B1 (hu) * 1996-06-17 2004-08-30 Exxonmobil Chemical Patents Inc. Vegyes átmenetifém katalizátor-rendszer olefinek polimerizálására
WO1997048736A1 (en) 1996-06-17 1997-12-24 Exxon Chemical Patents Inc. Supported late transition metal catalyst systems
IL129929A0 (en) 1996-12-17 2000-02-29 Du Pont Polymerization of ethylene with specific iron or cobalt complexes novel pyridinebis (imines) and novel complexes of pyridinebis(imines) with iron and cobalt
EP0951489B1 (de) 1997-01-13 2004-10-06 E.I. Du Pont De Nemours And Company Propylenpolymerisationsverfahren
KR100517852B1 (ko) 1997-01-14 2005-09-30 이 아이 듀폰 디 네모아 앤드 캄파니 올레핀 중합반응
JP2002514252A (ja) 1997-03-10 2002-05-14 イーストマン ケミカル カンパニー 第8〜10族遷移金属を含むオレフィン重合触媒、二座配位子、このような触媒の使用方法及びそれから得られるポリマー
US6573345B1 (en) 1997-03-24 2003-06-03 Cryovac, Inc. Catalyst compositions and processes for olefin oligomerization and polymerization
US6410664B1 (en) 1997-03-24 2002-06-25 Cryovac, Inc. Catalyst compositions and processes for olefin polymers and copolymers
IL127230A (en) 1997-03-29 2004-07-25 Montell Technology Company Bv Magnesium dichloride-alcohol adducts, process for their preparation and catalyst components obtained therefrom
GB9708487D0 (en) 1997-04-25 1997-06-18 Bp Chem Int Ltd Novel catalysts for olefin polymerisation
US6559252B1 (en) 1997-10-29 2003-05-06 Basell Technology Company Bv Catalysts and processes for the polymerization of olefins
IT1302029B1 (it) 1998-08-19 2000-07-20 Montech Usa Inc Processo per produrre composizioni polimeriche eterofasiche ecomposizioni cosi' ottenute
WO2000022007A1 (en) 1998-10-14 2000-04-20 E.I. Du Pont De Nemours And Company Polymerization of olefins
EP1214364B1 (de) 1999-09-22 2003-07-16 Basell Polyolefine GmbH Katalysatorsystem unf verfahren zur polymerisierung von olefine

Also Published As

Publication number Publication date
AU3960500A (en) 2000-09-28
KR20010102542A (ko) 2001-11-15
US6992153B1 (en) 2006-01-31
DE60006082D1 (de) 2003-11-27
EP1161465A1 (de) 2001-12-12
EP1161465B1 (de) 2003-10-22
BR0010376A (pt) 2001-12-26
ES2208301T3 (es) 2004-06-16
WO2000053646A1 (en) 2000-09-14
JP2002539283A (ja) 2002-11-19
CN1350552A (zh) 2002-05-22
MY133191A (en) 2007-10-31
DE60006082T2 (de) 2004-07-22

Similar Documents

Publication Publication Date Title
DE60006082D1 (de) Mehrstufiges verfahren zur (co)polymersation von olefinen
ATE179724T1 (de) Mehrstufenverfahren zur (co)-polymerisierung von olefinen
ATE432949T1 (de) Verfahren zur herstellung eines ziegler-natta- katalysators
DK0742801T3 (da) Fremgangsmåde til (co)polymerisation af olefiner
KR950005853A (ko) 올래핀 중합용촉매 및 올레핀중합방법
BR9305093A (pt) Sistema catalítico, processo de preparação e utilização do mesmo, precursor de sistema catalítico e processo de co-polimerização de, pelomenos, uma olefina
WO2003014166A1 (fr) Procede de fabrication de polymeres
ATE166077T1 (de) Metallocen(co)polymere, verfahren zu ihrer herstellung und ihre verwendung als katalysatoren; metallocene hierfür.
ATE419283T1 (de) Katalysatorsystem zur polymerisation von olefinen
KR970027113A (ko) 올레핀중합용 촉매
RU94023246A (ru) Катализатор и способ (со)полимеризации этилена
ATE22452T1 (de) Verfahren zur herstellung von polymeren von olefinen.
ATE461224T1 (de) Katalysatorzusammensetzung für olefinpolymerisation, verfahren zur herstellung von polyolefinen damit
ATE263193T1 (de) Alfa-olefin polymerisarionskatalysatorsytem und seine verwendung zur polymerisation von alfa- olefinen
EP0240254A3 (de) Polymerisationskatalysator, Herstellung und Anwendung
ATE382641T1 (de) Verfahren zur polymerisation von olefinen
ATE297417T1 (de) Geträgerte katalysatorzusammensetzung für die olefinpolymerisation : verfahren zu deren herstellung und polymerisationsverfahren unter deren verwendung
MY112158A (en) Multistage process for the (co) polymerization of olefins
DE50201397D1 (de) Verfahren zur Herstellung von auf inerten Trägermaterialien immobilisierten Teilhydrolysaten metallorganischer Verbindungen oder Übergangsmetallkatalysatoren
DE69904418D1 (de) Verfahren zur herstellung von ep(d)m copolymere mit enger molekulargewichtsverteilung

Legal Events

Date Code Title Description
RER Ceased as to paragraph 5 lit. 3 law introducing patent treaties