ATE252645T1 - Verfahren und anlage zur herstellung von organischen säuren - Google Patents
Verfahren und anlage zur herstellung von organischen säurenInfo
- Publication number
- ATE252645T1 ATE252645T1 AT97935196T AT97935196T ATE252645T1 AT E252645 T1 ATE252645 T1 AT E252645T1 AT 97935196 T AT97935196 T AT 97935196T AT 97935196 T AT97935196 T AT 97935196T AT E252645 T1 ATE252645 T1 AT E252645T1
- Authority
- AT
- Austria
- Prior art keywords
- biomass
- reactors
- acid
- organic acids
- present
- Prior art date
Links
- 150000007524 organic acids Chemical class 0.000 title abstract 3
- 235000005985 organic acids Nutrition 0.000 title abstract 3
- 238000000034 method Methods 0.000 title abstract 2
- 239000002028 Biomass Substances 0.000 abstract 5
- 239000002253 acid Substances 0.000 abstract 5
- 150000003839 salts Chemical class 0.000 abstract 5
- 238000000855 fermentation Methods 0.000 abstract 3
- 230000004151 fermentation Effects 0.000 abstract 3
- BCZXFFBUYPCTSJ-UHFFFAOYSA-L Calcium propionate Chemical compound [Ca+2].CCC([O-])=O.CCC([O-])=O BCZXFFBUYPCTSJ-UHFFFAOYSA-L 0.000 abstract 1
- -1 acetic Chemical class 0.000 abstract 1
- VSGNNIFQASZAOI-UHFFFAOYSA-L calcium acetate Chemical compound [Ca+2].CC([O-])=O.CC([O-])=O VSGNNIFQASZAOI-UHFFFAOYSA-L 0.000 abstract 1
- 235000011092 calcium acetate Nutrition 0.000 abstract 1
- 239000001639 calcium acetate Substances 0.000 abstract 1
- 229960005147 calcium acetate Drugs 0.000 abstract 1
- 235000010331 calcium propionate Nutrition 0.000 abstract 1
- 239000004330 calcium propionate Substances 0.000 abstract 1
- FYPVXEILSNEKOO-UHFFFAOYSA-L calcium;butanoate Chemical compound [Ca+2].CCCC([O-])=O.CCCC([O-])=O FYPVXEILSNEKOO-UHFFFAOYSA-L 0.000 abstract 1
- 238000010924 continuous production Methods 0.000 abstract 1
- 235000014113 dietary fatty acids Nutrition 0.000 abstract 1
- 229930195729 fatty acid Natural products 0.000 abstract 1
- 239000000194 fatty acid Substances 0.000 abstract 1
- 150000004665 fatty acids Chemical class 0.000 abstract 1
- 150000004672 propanoic acids Chemical class 0.000 abstract 1
- 235000019260 propionic acid Nutrition 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
- C12P7/00—Preparation of oxygen-containing organic compounds
- C12P7/40—Preparation of oxygen-containing organic compounds containing a carboxyl group including Peroxycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12M—APPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
- C12M21/00—Bioreactors or fermenters specially adapted for specific uses
- C12M21/04—Bioreactors or fermenters specially adapted for specific uses for producing gas, e.g. biogas
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12M—APPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
- C12M23/00—Constructional details, e.g. recesses, hinges
- C12M23/58—Reaction vessels connected in series or in parallel
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12M—APPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
- C12M29/00—Means for introduction, extraction or recirculation of materials, e.g. pumps
- C12M29/18—External loop; Means for reintroduction of fermented biomass or liquid percolate
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12M—APPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
- C12M41/00—Means for regulation, monitoring, measurement or control, e.g. flow regulation
- C12M41/30—Means for regulation, monitoring, measurement or control, e.g. flow regulation of concentration
- C12M41/32—Means for regulation, monitoring, measurement or control, e.g. flow regulation of concentration of substances in solution
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12M—APPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
- C12M47/00—Means for after-treatment of the produced biomass or of the fermentation or metabolic products, e.g. storage of biomass
- C12M47/10—Separation or concentration of fermentation products
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/30—Fuel from waste, e.g. synthetic alcohol or diesel
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S435/00—Chemistry: molecular biology and microbiology
- Y10S435/813—Continuous fermentation
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S435/00—Chemistry: molecular biology and microbiology
- Y10S435/819—Fermentation vessels in series
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Bioinformatics & Cheminformatics (AREA)
- Biotechnology (AREA)
- Genetics & Genomics (AREA)
- General Engineering & Computer Science (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Microbiology (AREA)
- Sustainable Development (AREA)
- Biomedical Technology (AREA)
- General Chemical & Material Sciences (AREA)
- Molecular Biology (AREA)
- Analytical Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Clinical Laboratory Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Processing Of Solid Wastes (AREA)
- Preparation Of Compounds By Using Micro-Organisms (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US08/688,051 US5874263A (en) | 1996-07-31 | 1996-07-31 | Method and apparatus for producing organic acids |
| PCT/US1997/013356 WO1998004729A2 (en) | 1996-07-31 | 1997-07-30 | Method and apparatus for producing organic acids |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ATE252645T1 true ATE252645T1 (de) | 2003-11-15 |
Family
ID=24762917
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AT97935196T ATE252645T1 (de) | 1996-07-31 | 1997-07-30 | Verfahren und anlage zur herstellung von organischen säuren |
Country Status (8)
| Country | Link |
|---|---|
| US (2) | US5874263A (de) |
| EP (1) | EP0918876B1 (de) |
| AT (1) | ATE252645T1 (de) |
| AU (1) | AU3819397A (de) |
| DE (1) | DE69725730T2 (de) |
| ES (1) | ES2210550T3 (de) |
| PT (1) | PT918876E (de) |
| WO (1) | WO1998004729A2 (de) |
Families Citing this family (40)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5986133A (en) | 1997-06-30 | 1999-11-16 | The Texas A&M University System | Recovery of fermentation salts from dilute aqueous solutions |
| US6043392A (en) | 1997-06-30 | 2000-03-28 | Texas A&M University System | Method for conversion of biomass to chemicals and fuels |
| DE19804007A1 (de) * | 1998-02-02 | 1999-08-05 | Nordenskjoeld Reinhart Von | Verfahren und Vorrichtung zur biologischen Behandlung eines organisch belasteten Fluids unter Biogasgenerierung |
| US7074603B2 (en) * | 1999-03-11 | 2006-07-11 | Zeachem, Inc. | Process for producing ethanol from corn dry milling |
| CN100575331C (zh) | 1999-03-11 | 2009-12-30 | 齐凯姆公司 | 一种生产乙醇的方法 |
| US7537826B2 (en) * | 1999-06-22 | 2009-05-26 | Xyleco, Inc. | Cellulosic and lignocellulosic materials and compositions and composites made therefrom |
| US7318374B2 (en) * | 2003-01-21 | 2008-01-15 | Victor Guerrero | Wire cloth coffee filtering systems |
| US7461587B2 (en) * | 2004-01-21 | 2008-12-09 | Victor Guerrero | Beverage container with wire cloth filter |
| JP5013879B2 (ja) * | 2004-01-29 | 2012-08-29 | ズィーケム インコーポレイテッド | 有機酸の回収 |
| CA2569822A1 (en) | 2004-06-16 | 2006-01-19 | The Texas A&M University System | Methods and systems for biomass conversion to carboxylic acids and alcohols |
| CA2589225A1 (en) * | 2004-12-10 | 2006-06-15 | The Texas A & M University System | System and method for processing biomass |
| US20150328347A1 (en) | 2005-03-24 | 2015-11-19 | Xyleco, Inc. | Fibrous materials and composites |
| US7708214B2 (en) * | 2005-08-24 | 2010-05-04 | Xyleco, Inc. | Fibrous materials and composites |
| US8634940B2 (en) * | 2006-10-31 | 2014-01-21 | Rockwell Automation Technologies, Inc. | Model predictive control of a fermentation feed in biofuel production |
| MX2009005806A (es) * | 2006-12-01 | 2009-06-08 | Texas A & M Univ Sys | Procesamiento de hidrogeno, y metodos de remocion y limpieza de impurezas en un proceso de conversion de biomasa. |
| BRPI0806417A2 (pt) | 2007-02-09 | 2011-09-06 | Zeachem Inc | métodos de energia eficiente para produzir produtos |
| NZ553786A (en) * | 2007-03-09 | 2009-07-31 | Waikatolink Ltd | Treatment method for organic material |
| US8153850B2 (en) | 2007-05-11 | 2012-04-10 | The Texas A&M University System | Integrated biofuel production system |
| US8252567B2 (en) * | 2008-02-07 | 2012-08-28 | Zeachem, Inc. | Method for the indirect production of butanol and hexanol |
| US20090275098A1 (en) * | 2008-05-01 | 2009-11-05 | Christopher Beatty | Systems and processes for enhanced yield from fermentations that contain xylose |
| NZ588804A (en) * | 2008-05-07 | 2012-03-30 | Zeachem Inc | Recovery of organic acids |
| US20100003741A1 (en) * | 2008-07-01 | 2010-01-07 | Fromson Howard A | Integrated power plant, sewage treatment, and aquatic biomass fuel production system |
| AU2009322457B2 (en) | 2008-12-02 | 2014-08-07 | Ee-Terrabon Biofuels Llc | Alternative paths to alcohols and hydrocarbons from biomass |
| US8518680B2 (en) * | 2009-04-17 | 2013-08-27 | The United States Of America, As Represented By The Secretary Of Agriculture | Biological/electrolytic conversion of biomass to hydrocarbons |
| MY162616A (en) | 2010-03-19 | 2017-06-30 | Sk Innovation Co Ltd | Preparation method of transportation fuel or lubricating base oil using biomass |
| WO2011119826A2 (en) * | 2010-03-24 | 2011-09-29 | The Texas A&M University System | Multi-stage fermenter nutrient feeding |
| EP2718447B1 (de) | 2011-06-09 | 2017-08-23 | Integrated BioChem, LLC | Managed ecosystem fermentation (mef) mit pansen und einer stickstoffquelle |
| BR112015014895A2 (pt) * | 2012-12-21 | 2017-07-11 | Ee Terrabon Biofuels Llc | processo para produção de produtos de biomassa |
| NZ707073A (en) * | 2012-12-31 | 2019-11-29 | Shell Int Research | Process for converting a biomass material |
| FR3024044B1 (fr) * | 2014-07-25 | 2018-03-23 | Afyren | Procede d'extraction de molecules produites par fermentation anaerobie a partir de biomasse fermentescible |
| FI126781B (en) | 2015-05-25 | 2017-05-31 | Neste Corp | Methods for the continuous production of products from microorganisms |
| DE102015210871A1 (de) | 2015-06-15 | 2016-12-15 | Verbio Vereinigte Bioenergie Ag | Verfahren zur stofflichen Nutzung organischen Substrats |
| US10837605B2 (en) * | 2016-11-10 | 2020-11-17 | Mitigation And Resilience Strategies, Llc | Pipeline environmental barrier system |
| CN107723054A (zh) * | 2017-09-06 | 2018-02-23 | 吴江华威特种油有限公司 | 一种环保生物基润滑油制备方法 |
| CA3091187A1 (en) * | 2018-02-13 | 2019-08-22 | The Texas A&M University System | Processes for converting biomass into high-value products |
| CN111647496A (zh) * | 2020-04-28 | 2020-09-11 | 河北首朗新能源科技有限公司 | 一种连续发酵菌体循环分离耦合系统 |
| US12234496B1 (en) * | 2020-07-22 | 2025-02-25 | Bioveritas, Llc | Systems and processes for obtaining natural preservatives and nutritional supplements |
| IT202100014993A1 (it) * | 2021-06-09 | 2022-12-09 | Alvus S R L | Sistema di estrazione di biomassa per digestori |
| WO2023086496A1 (en) * | 2021-11-10 | 2023-05-19 | The Penn State Research Foundation | Systems and methods for the production of biogases from a lignocellulosic feedstock |
| CN119391531A (zh) * | 2024-12-16 | 2025-02-07 | 山东雨田食品科技股份有限公司 | 一种丙酸钙原料发酵装置 |
Family Cites Families (30)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2458431A (en) * | 1944-04-20 | 1949-01-04 | Pacific Flush Tank Co | Apparatus for and method of digesting garbage |
| US3067107A (en) * | 1959-05-11 | 1962-12-04 | Columbia Cellulose Company Ltd | Propionic acid fermentation |
| GB1028822A (en) * | 1962-01-08 | 1966-05-11 | Lucius John Fry | Apparatus for and a method of generating methane gas from animal manure |
| US3241943A (en) * | 1962-04-13 | 1966-03-22 | Bystrom Sven Gustav | Method for the production of a fertilizer or soil improvement agent from sulfite waste liquor while recovering acids and combustible gases formed in the process |
| US3933628A (en) * | 1974-07-10 | 1976-01-20 | Bio-Gas Of Colorado, Inc. | Method and apparatus for the anaerobic digestion of decomposable organic materials |
| US4318993A (en) * | 1974-12-09 | 1982-03-09 | Institute Of Gas Technology | Two phase anaerobic digester system |
| US4022665A (en) * | 1974-12-09 | 1977-05-10 | Institute Of Gas Technology | Two phase anaerobic digestion |
| US4057401A (en) * | 1976-09-03 | 1977-11-08 | Bio-Gas Corporation | Methane gas process and apparatus |
| US4100023A (en) * | 1977-04-08 | 1978-07-11 | Mcdonald Byron A | Digester and process for converting organic matter to methane and fertilizer |
| IE772633L (en) * | 1977-12-29 | 1979-06-29 | Sweeney J J Newell P J | Treating waste products |
| US4267049A (en) * | 1978-02-13 | 1981-05-12 | Erickson Lennart G | Biological sludge-energy recycling method |
| US4252901A (en) * | 1979-07-11 | 1981-02-24 | Universal Research And Development Corp. | System and process for anaerobic digestion |
| CA1173380A (en) * | 1980-02-19 | 1984-08-28 | Michael I. Sherman | Acid hydrolysis of biomass for ethanol production |
| US4444881A (en) * | 1981-10-26 | 1984-04-24 | Cpc International Inc. | Recovery of organic acids from a fermentation broth |
| US4405717A (en) * | 1981-10-26 | 1983-09-20 | Cpc International Inc. | Recovery of acetic acid from a fermentation broth |
| GB2125064B (en) * | 1982-08-11 | 1985-09-11 | Univ Manchester | Multiple-stage continuous fermentation for the products of growth-inhibitory fermentation products |
| US4536584A (en) * | 1983-10-03 | 1985-08-20 | The Standard Oil Company (Ohio) | Process for the thermochemical conversion of biomass |
| US4665027A (en) * | 1983-11-03 | 1987-05-12 | Bio-Process Innovation, Inc. | Immobilized cell reactor-separator with simultaneous product separation and methods for design and use thereof |
| JPS60102998A (ja) * | 1983-11-11 | 1985-06-07 | Toshiba Corp | 返送汚泥制御装置 |
| LU85141A1 (fr) * | 1983-12-15 | 1985-09-12 | Belge Etat | Procede de production de methane par digestion anaerobie de matieres organiques |
| US4636467A (en) * | 1985-02-01 | 1987-01-13 | Institute Of Gas Technology | Mixed microbial fermentation of carbonaceous matter to road de-icer |
| US4814273A (en) * | 1985-03-20 | 1989-03-21 | Michigan Biotechnology Institute | Production of organic acids by an improved fermentation process |
| DE3618076A1 (de) * | 1986-06-02 | 1987-12-03 | Kernforschungsanlage Juelich | Verfahren zur mikrobiellen anaeroben gewinnung von essigsaeure |
| DK71987D0 (da) * | 1987-02-13 | 1987-02-13 | Nordiske Kabel Traad | Fremgangsmaade til rensning af olie- og kemikalieforurenet jord |
| US5254465A (en) * | 1989-06-20 | 1993-10-19 | Northeastern University | Process for manufacture of alkaline earth acetates |
| US5464760A (en) * | 1990-04-04 | 1995-11-07 | University Of Chicago | Fermentation and recovery process for lactic acid production |
| US5125977A (en) * | 1991-04-08 | 1992-06-30 | The United States Of America As Represented By The United States Department Of Energy | Two-stage dilute acid prehydrolysis of biomass |
| US5412126A (en) * | 1991-04-17 | 1995-05-02 | The Regents Of The University Of California | Carboxylic acid sorption regeneration process |
| US5510526A (en) * | 1993-06-29 | 1996-04-23 | Cargill, Incorporated | Lactic acid production, separation and/or recovery process |
| UA43879C2 (uk) * | 1994-12-07 | 2002-01-15 | Кентроулд Інвайєронментал Сістемз Корпорейшн | Спосіб одержання молочної кислоти з міських твердих відходів (варіанти) та спосіб одержання молочної кислоти з целюлозного компонента міських твердих відходів |
-
1996
- 1996-07-31 US US08/688,051 patent/US5874263A/en not_active Expired - Lifetime
-
1997
- 1997-07-30 AU AU38193/97A patent/AU3819397A/en not_active Abandoned
- 1997-07-30 PT PT97935196T patent/PT918876E/pt unknown
- 1997-07-30 AT AT97935196T patent/ATE252645T1/de not_active IP Right Cessation
- 1997-07-30 ES ES97935196T patent/ES2210550T3/es not_active Expired - Lifetime
- 1997-07-30 EP EP97935196A patent/EP0918876B1/de not_active Expired - Lifetime
- 1997-07-30 WO PCT/US1997/013356 patent/WO1998004729A2/en not_active Ceased
- 1997-07-30 DE DE69725730T patent/DE69725730T2/de not_active Expired - Lifetime
- 1997-10-23 US US08/956,469 patent/US5962307A/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| ES2210550T3 (es) | 2004-07-01 |
| EP0918876B1 (de) | 2003-10-22 |
| AU3819397A (en) | 1998-02-20 |
| US5874263A (en) | 1999-02-23 |
| DE69725730T2 (de) | 2004-08-19 |
| DE69725730D1 (de) | 2003-11-27 |
| PT918876E (pt) | 2004-03-31 |
| EP0918876A2 (de) | 1999-06-02 |
| US5962307A (en) | 1999-10-05 |
| WO1998004729A2 (en) | 1998-02-05 |
| WO1998004729A3 (en) | 1998-03-19 |
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