ATE260304T1 - Verfahren zur herstellung und verwendung von meso-racemisch bis(indenyl)ethan-zirconium- dichloridverbindungen - Google Patents
Verfahren zur herstellung und verwendung von meso-racemisch bis(indenyl)ethan-zirconium- dichloridverbindungenInfo
- Publication number
- ATE260304T1 ATE260304T1 AT96116159T AT96116159T ATE260304T1 AT E260304 T1 ATE260304 T1 AT E260304T1 AT 96116159 T AT96116159 T AT 96116159T AT 96116159 T AT96116159 T AT 96116159T AT E260304 T1 ATE260304 T1 AT E260304T1
- Authority
- AT
- Austria
- Prior art keywords
- indenyl
- meso
- ethane
- zirconium dichloride
- production
- Prior art date
Links
- 238000000034 method Methods 0.000 title abstract 2
- RYMHWULWPBJOFE-UHFFFAOYSA-L 1-[1-(1h-inden-1-yl)ethyl]-1h-indene;zirconium(2+);dichloride Chemical class [Cl-].[Cl-].[Zr+2].C1=CC2=CC=CC=C2C1C(C)C1C2=CC=CC=C2C=C1 RYMHWULWPBJOFE-UHFFFAOYSA-L 0.000 title 1
- YBYIRNPNPLQARY-UHFFFAOYSA-N 1H-indene Natural products C1=CC=C2CC=CC2=C1 YBYIRNPNPLQARY-UHFFFAOYSA-N 0.000 abstract 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract 2
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 abstract 2
- KWGKDLIKAYFUFQ-UHFFFAOYSA-M lithium chloride Chemical compound [Li+].[Cl-] KWGKDLIKAYFUFQ-UHFFFAOYSA-M 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- 239000012429 reaction media Substances 0.000 abstract 2
- 239000002904 solvent Substances 0.000 abstract 2
- WAADRLKGQPOVGL-UHFFFAOYSA-N 1-[1-(1h-inden-1-yl)ethyl]-1h-indene Chemical compound C1=CC2=CC=CC=C2C1C(C)C1C2=CC=CC=C2C=C1 WAADRLKGQPOVGL-UHFFFAOYSA-N 0.000 abstract 1
- 239000007795 chemical reaction product Substances 0.000 abstract 1
- 239000003446 ligand Substances 0.000 abstract 1
- 239000007787 solid Substances 0.000 abstract 1
- 239000008247 solid mixture Substances 0.000 abstract 1
- -1 zirconium dichloride compound Chemical class 0.000 abstract 1
- DUNKXUFBGCUVQW-UHFFFAOYSA-J zirconium tetrachloride Chemical compound Cl[Zr](Cl)(Cl)Cl DUNKXUFBGCUVQW-UHFFFAOYSA-J 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Polymerization Catalysts (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP96116159A EP0835886B1 (de) | 1996-10-09 | 1996-10-09 | Verfahren zur Herstellung und Verwendung von meso-racemisch Bis(Indenyl)Ethan-Zirconium-Dichloridverbindungen |
| US08/948,224 US6103656A (en) | 1996-10-09 | 1997-10-09 | Process for preparing and using meso/racemic-[bis (indenyl) ethane]zirconium dichloride compounds |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ATE260304T1 true ATE260304T1 (de) | 2004-03-15 |
Family
ID=26142231
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AT96116159T ATE260304T1 (de) | 1996-10-09 | 1996-10-09 | Verfahren zur herstellung und verwendung von meso-racemisch bis(indenyl)ethan-zirconium- dichloridverbindungen |
Country Status (8)
| Country | Link |
|---|---|
| US (2) | US6103656A (de) |
| EP (1) | EP0835886B1 (de) |
| JP (1) | JP4115563B2 (de) |
| AT (1) | ATE260304T1 (de) |
| DE (1) | DE69631659T2 (de) |
| DK (1) | DK0835886T3 (de) |
| ES (1) | ES2213761T3 (de) |
| PT (1) | PT835886E (de) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0953582A1 (de) * | 1998-04-27 | 1999-11-03 | Fina Research S.A. | Herstellung von Polyolefin |
| KR100709557B1 (ko) * | 2007-01-02 | 2007-04-20 | 한국과학기술연구원 | 입상 지르코늄 나노 메조구조체의 제조방법 |
| US9376518B2 (en) | 2013-08-28 | 2016-06-28 | Exxonmobil Chemical Patents Inc. | Racemo selective metallation process |
| WO2015030996A1 (en) * | 2013-08-28 | 2015-03-05 | Exxonmobil Chemical Patents Inc. | Racemo selective metallation process |
| BR122020005071B1 (pt) * | 2014-02-11 | 2021-06-08 | Univation Technologies, Llc | composição de catalisador |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3742934A1 (de) * | 1987-12-18 | 1989-06-29 | Hoechst Ag | Verfahren zur herstellung einer chiralen, stereorigiden metallocen-verbindung |
| US5017714A (en) * | 1988-03-21 | 1991-05-21 | Exxon Chemical Patents Inc. | Silicon-bridged transition metal compounds |
| EP0426643B1 (de) * | 1989-10-30 | 1995-12-27 | Fina Research S.A. | Verfahren zur Herstellung von Metallocenen |
| US5117020A (en) * | 1989-10-30 | 1992-05-26 | Fina Research, S.A. | Process for the preparation of metallocenes |
| NL9101502A (nl) * | 1991-09-06 | 1993-04-01 | Dsm Nv | Werkwijze voor het bereiden van een gebrugde metalloceenverbinding alsmede een katalysatorcomponent en een werkwijze voor de polymerisatie van een olefinen. |
| EP0574597B2 (de) * | 1992-06-13 | 2002-06-26 | Basell Polyolefine GmbH | Verfahren zur Herstellung von verbrückten, chiralen Metallocenkatalysatoren des Types Bisindenyl |
| FI945873L (fi) * | 1992-06-18 | 1994-12-14 | Spherilene Srl | Menetelmä etyleenisen polymeerin valmistamiseksi |
| TW294669B (de) * | 1992-06-27 | 1997-01-01 | Hoechst Ag | |
| IT1273661B (it) * | 1994-07-20 | 1997-07-09 | Spherilene Srl | Catalizzatori per la polimerizzazione delle olefine |
| WO1996019488A1 (en) * | 1994-12-21 | 1996-06-27 | Exxon Chemical Patents Inc. | A method of preparing high purity racemic metallocene alkyls and use thereof |
| US5556997A (en) * | 1995-04-24 | 1996-09-17 | Albemarle Corporation | Enhanced synthesis of racemic metallocenes |
-
1996
- 1996-10-09 AT AT96116159T patent/ATE260304T1/de not_active IP Right Cessation
- 1996-10-09 DE DE69631659T patent/DE69631659T2/de not_active Expired - Lifetime
- 1996-10-09 ES ES96116159T patent/ES2213761T3/es not_active Expired - Lifetime
- 1996-10-09 EP EP96116159A patent/EP0835886B1/de not_active Expired - Lifetime
- 1996-10-09 PT PT96116159T patent/PT835886E/pt unknown
- 1996-10-09 DK DK96116159T patent/DK0835886T3/da active
-
1997
- 1997-10-03 JP JP28626497A patent/JP4115563B2/ja not_active Expired - Fee Related
- 1997-10-09 US US08/948,224 patent/US6103656A/en not_active Expired - Lifetime
-
2002
- 2002-04-22 US US10/127,090 patent/US20020115801A1/en not_active Abandoned
Also Published As
| Publication number | Publication date |
|---|---|
| DE69631659D1 (de) | 2004-04-01 |
| ES2213761T3 (es) | 2004-09-01 |
| JPH10130322A (ja) | 1998-05-19 |
| DE69631659T2 (de) | 2004-12-23 |
| EP0835886A1 (de) | 1998-04-15 |
| JP4115563B2 (ja) | 2008-07-09 |
| PT835886E (pt) | 2004-05-31 |
| DK0835886T3 (da) | 2004-05-17 |
| US6103656A (en) | 2000-08-15 |
| EP0835886B1 (de) | 2004-02-25 |
| US20020115801A1 (en) | 2002-08-22 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| UEP | Publication of translation of european patent specification |
Ref document number: 0835886 Country of ref document: EP |
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| REN | Ceased due to non-payment of the annual fee |