ATE267218T1 - Sulfonierte ionenleitende perfluorocyclobutan- membranen - Google Patents

Sulfonierte ionenleitende perfluorocyclobutan- membranen

Info

Publication number
ATE267218T1
ATE267218T1 AT00972045T AT00972045T ATE267218T1 AT E267218 T1 ATE267218 T1 AT E267218T1 AT 00972045 T AT00972045 T AT 00972045T AT 00972045 T AT00972045 T AT 00972045T AT E267218 T1 ATE267218 T1 AT E267218T1
Authority
AT
Austria
Prior art keywords
unsubstituted
substituted
polymer
ion conducting
perfluorocyclobutane
Prior art date
Application number
AT00972045T
Other languages
English (en)
Inventor
Shane S Mao
Krzysztof A Lewinski
David A Ylitalo
Original Assignee
3M Innovative Properties Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 3M Innovative Properties Co filed Critical 3M Innovative Properties Co
Application granted granted Critical
Publication of ATE267218T1 publication Critical patent/ATE267218T1/de

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/34—Introducing sulfur atoms or sulfur-containing groups
    • C08F8/36—Sulfonation; Sulfation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18—Manufacture of films or sheets
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2800/00—Copolymer characterised by the proportions of the comonomers expressed
    • C08F2800/20—Copolymer characterised by the proportions of the comonomers expressed as weight or mass percentages
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Manufacturing & Machinery (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Conductive Materials (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
  • Fuel Cell (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Polyethers (AREA)
  • Other Resins Obtained By Reactions Not Involving Carbon-To-Carbon Unsaturated Bonds (AREA)
  • Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
AT00972045T 2000-06-05 2000-10-10 Sulfonierte ionenleitende perfluorocyclobutan- membranen ATE267218T1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US09/587,522 US6559237B1 (en) 2000-06-05 2000-06-05 Sulfonated perfluorocyclobutane ion-conducting membranes
PCT/US2000/027939 WO2001094427A1 (en) 2000-06-05 2000-10-10 Sulfonated perfluorocyclobutane ion-conducting membranes

Publications (1)

Publication Number Publication Date
ATE267218T1 true ATE267218T1 (de) 2004-06-15

Family

ID=24350141

Family Applications (1)

Application Number Title Priority Date Filing Date
AT00972045T ATE267218T1 (de) 2000-06-05 2000-10-10 Sulfonierte ionenleitende perfluorocyclobutan- membranen

Country Status (9)

Country Link
US (1) US6559237B1 (de)
EP (1) EP1290041B1 (de)
JP (1) JP2003535929A (de)
KR (1) KR100650483B1 (de)
AT (1) ATE267218T1 (de)
AU (1) AU2001210762A1 (de)
CA (1) CA2407665A1 (de)
DE (1) DE60010937T2 (de)
WO (1) WO2001094427A1 (de)

Families Citing this family (54)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4106983B2 (ja) 2002-03-25 2008-06-25 住友化学株式会社 芳香族系高分子、その製造方法およびその用途
CA2485971A1 (en) * 2002-05-13 2004-05-21 Polyfuel, Inc. Ion conductive block copolymers
JP2005526365A (ja) * 2002-05-17 2005-09-02 グリーンライト パワー テクノロジーズ、インコーポレイテッド 燃料電池及び燃料電池構成要素における障害状況を指示する方法及び装置
JP3868419B2 (ja) * 2002-12-27 2007-01-17 日本特殊陶業株式会社 ガスセンサ
US7022810B1 (en) 2003-05-09 2006-04-04 Sandia Corporation Proton exchange membrane materials for the advancement of direct methanol fuel-cell technology
US7207732B2 (en) * 2003-06-04 2007-04-24 Corning Incorporated Coated optical fiber and curable compositions suitable for coating optical fiber
CA2554160A1 (en) * 2004-01-23 2005-09-22 The University Of North Carolina At Chapel Hill Liquid materials for use in electrochemical cells
JP2008522350A (ja) * 2004-11-29 2008-06-26 ハイドロジェニクス コーポレイション 電気化学電池の故障状態を検出し表示するためのシステムおよび方法
JP4237156B2 (ja) * 2005-03-28 2009-03-11 富士通株式会社 電解質組成物、固体電解質膜、固体高分子型燃料電池および固体電解質膜の製造方法
US7538160B2 (en) * 2005-07-01 2009-05-26 Bausch & Lomb Incorporated Trifluorovinyl aromatic containing poly(alkyl ether) prepolymers
US7425600B2 (en) * 2005-07-01 2008-09-16 Bausch & Lomb Incorporated Polymerization products and biomedical devices containing same
US7402634B2 (en) * 2005-07-01 2008-07-22 Bausch And Lamb Incorporated Perfluorocyclobutane copolymers
US7582704B2 (en) * 2005-07-01 2009-09-01 Bausch & Lomb Incorporated Biomedical devices
US7534836B2 (en) * 2005-07-01 2009-05-19 Bausch & Lomb Incorporated Biomedical devices
US20070099054A1 (en) * 2005-11-01 2007-05-03 Fuller Timothy J Sulfonated-perfluorocyclobutane polyelectrolyte membranes for fuel cells
WO2007052954A1 (en) 2005-11-01 2007-05-10 Lg Chem, Ltd. Block copolymers containing perfluorocyclobutane rings and electrolyte membranes using the same
US7635744B2 (en) * 2006-04-05 2009-12-22 General Electric Company Trifluorovinyloxy monomers and polymers
US8492460B2 (en) * 2006-07-28 2013-07-23 GM Global Technology Operations LLC Fluorinated polymer blocks for PEM applications
US20090137925A1 (en) * 2007-11-23 2009-05-28 Divya Cantor Impedance Spectroscopy Cervix Scanning Apparatus and Method
EP2270818B1 (de) * 2008-03-19 2020-03-04 Asahi Kasei Kabushiki Kaisha Polyelektrolyt und prozess zur herstellung des polyelektrolyts
US7888433B2 (en) * 2008-05-09 2011-02-15 Gm Global Technology Operations, Inc. Sulfonated-polyperfluoro-cyclobutane-polyphenylene polymers for PEM fuel cell applications
US7897692B2 (en) * 2008-05-09 2011-03-01 Gm Global Technology Operations, Inc. Sulfonated perfluorocyclobutane block copolymers and proton conductive polymer membranes
US7897691B2 (en) 2008-05-09 2011-03-01 Gm Global Technology Operations, Inc. Proton exchange membranes for fuel cell applications
US8030405B2 (en) * 2008-05-09 2011-10-04 GM Global Technology Operations LLC Blended PEM's with elastomers for improved mechanical durability
US7897693B2 (en) * 2008-05-09 2011-03-01 Gm Global Technology Operations, Inc. Proton conductive polymer electrolytes and fuel cells
US8008404B2 (en) 2008-05-09 2011-08-30 GM Global Technology Operations LLC Composite membrane
US7985805B2 (en) * 2008-05-09 2011-07-26 GM Global Technology Operations LLC Polyelectrolyte membranes comprised of blends of PFSA and sulfonated PFCB polymers
US8003732B2 (en) * 2008-08-25 2011-08-23 GM Global Technology Operations LLC Gradient reinforced proton exchange membrane
US7976730B2 (en) * 2008-08-25 2011-07-12 GM Global Technology Operations LLC Blends of low equivalent molecular weight PFSA ionomers with Kynar 2751
KR101012124B1 (ko) 2008-12-17 2011-02-07 한국화학연구원 퍼플루오로싸이클로부탄기를 포함하는 술폰화 공중합체, 이의 제조방법 및 이의 용도
KR101017649B1 (ko) * 2008-12-30 2011-02-25 한국화학연구원 퍼플루오로싸이클로부탄기를 포함하는 후술폰화된 공중합체, 이의 제조방법 및 이의 용도
US20110045381A1 (en) * 2009-08-18 2011-02-24 Gm Global Technology Operations, Inc. Hydrocarbon PEM Membranes with Perfluorosulfonic Acid Groups for Automotive Fuel Cells
US8053530B2 (en) * 2009-08-26 2011-11-08 GM Global Technology Operations LLC Polyelectrolyte membranes made of poly(perfluorocyclobutanes) with pendant perfluorosulfonic acid groups and blends with poly(vinylidene fluoride)
US8852823B2 (en) * 2009-08-26 2014-10-07 GM Global Technology Operations LLC Sodium stannate additive to improve the durability of PEMS for H2/air fuel cells
US7972732B2 (en) * 2009-08-28 2011-07-05 GM Global Technology Operations LLC Perfluorocyclobutane based water vapor transfer membranes with side chain perfluorosulfonic acid moieties
US8058352B2 (en) * 2009-08-28 2011-11-15 GM Global Technology Operations LLC Perfluorocyclobutane based water vapor transfer membranes
US20110053008A1 (en) * 2009-08-28 2011-03-03 Gm Global Technology Operations, Inc. Water vapor transfer membrane and paper integrated assembly
US8354201B2 (en) * 2009-08-28 2013-01-15 GM Global Technology Operations LLC Fuel cell with spatially non-homogeneous ionic membrane
US20110053009A1 (en) * 2009-08-28 2011-03-03 Gm Global Technology Operations, Inc. Customized water vapor transfer membrane layered structure
US8409765B2 (en) * 2009-08-31 2013-04-02 GM Global Technology Operations LLC Co(II)tetramethoxyphenylporphyrin additive to PFSA PEMS for improved fuel cell durability
US8048963B2 (en) * 2009-08-31 2011-11-01 GM Global Technology Operations LLC Ion exchange membrane having lamellar morphology and process of making the same
US9133316B2 (en) * 2009-09-18 2015-09-15 Asahi Kasei E-Materials Corporation Electrolyte emulsion and process for producing same
US8252712B2 (en) * 2009-11-13 2012-08-28 GM Global Technology Operations LLC Polymer dispersant addition to fuel cell electrode inks for improved manufacturability
US8735023B2 (en) 2009-12-14 2014-05-27 GM Global Technology Operations LLC Fuel cell with layered electrode
US20110159404A1 (en) * 2009-12-29 2011-06-30 Gm Global Technology Operations, Inc. Polyolefin Support to Prevent Dielectric Breakdown in PEMS
US20110159405A1 (en) * 2009-12-30 2011-06-30 Gm Global Technology Operations, Inc. Hydrophilic Polyelectrolyte Membranes Containing Poly(Vinyl Acetate) and Poly(Vinyl Alcohol)
US20110165497A1 (en) * 2010-01-06 2011-07-07 Gm Global Technology Operations, Inc. Method for Mitigating Fuel Cell Chemical Degradation
US7989512B1 (en) 2010-03-17 2011-08-02 GM Global Technology Operations LLC Polyelectrolyte membranes derived from soluble perfluorocyclobutane polymers with sulfonyl chloride groups
US8735021B2 (en) 2010-04-16 2014-05-27 GM Global Technology Operations LLC Cobalt(II) tetramethoxyphenylporphyrin (CoTMPP) ionomer stabilization to prevent electrode degradation
US8044146B1 (en) 2010-04-16 2011-10-25 GM Global Technology Operations LLC Combination of main-chain and side-chain sulfonation of PFCB-6F high-temperature fuel cell membranes
US8609739B2 (en) * 2011-02-17 2013-12-17 GM Global Technology Operations LLC Poly(perfluorocyclobutane) ionomer with phosphonic acid groups for high temperature fuel cells
US20130084516A1 (en) * 2011-09-30 2013-04-04 GM Global Technology Operations LLC Poly(Methyl Methacrylate) Additive to Polyelectrolyte Membrane
US9163337B2 (en) 2012-10-24 2015-10-20 GM Global Technology Operations LLC PFCB nanometer scale fibers
JP7103830B2 (ja) * 2018-04-16 2022-07-20 旭化成株式会社 高分子電解質

Family Cites Families (35)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4337211A (en) 1980-06-11 1982-06-29 The Dow Chemical Company Fluorocarbon ethers having substituted halogen site(s) and process to prepare
US4358412A (en) 1980-06-11 1982-11-09 The Dow Chemical Company Preparation of vinyl ethers
JPS5794006A (en) 1980-12-03 1982-06-11 Toyo Soda Mfg Co Ltd Perfluorocarbon polymer
EP0188486B1 (de) 1984-07-13 1989-02-01 Elf Atochem S.A. Molekül, das wenigstens eine peptidische sequenz mit einem epitop enthält
JPS6223401A (ja) 1985-07-22 1987-01-31 Nok Corp 限外ロ過膜
JP2609524B2 (ja) 1987-06-15 1997-05-14 旭化成工業株式会社 フッ素系イオン交換樹脂膜の加水分解方法
US5039561A (en) 1986-08-25 1991-08-13 Minnesota Mining And Manufacturing Company Method for preparing an article having surface layer of uniformly oriented, crystalline, organic microstructures
US4812352A (en) 1986-08-25 1989-03-14 Minnesota Mining And Manufacturing Company Article having surface layer of uniformly oriented, crystalline, organic microstructures
US5246782A (en) 1990-12-10 1993-09-21 The Dow Chemical Company Laminates of polymers having perfluorocyclobutane rings and polymers containing perfluorocyclobutane rings
US5198513A (en) 1989-06-09 1993-03-30 The Dow Chemical Company Reactive compounds containing perfluorovinyl groups
US5037918A (en) 1989-12-15 1991-08-06 The Dow Chemical Company Perfluorocyclobutane ring-containing polymers with crosslinking
US5162468A (en) 1989-06-09 1992-11-10 The Dow Chemical Company Perfluorovinyl compounds
US5066746A (en) 1989-06-09 1991-11-19 The Dow Chemical Company Perfluorocyclobutane ring-containing polymers
US5210265A (en) 1989-06-09 1993-05-11 The Dow Chemical Company Reactive compounds containing perfluorocyclobutane rings
US5037919A (en) 1989-06-09 1991-08-06 The Dow Chemical Company Reactive compounds containing perfluorovinyl groups
US5021602A (en) 1989-06-09 1991-06-04 The Dow Chemical Company Reactive compounds containing perfluorocyclobutane rings
US5364917A (en) 1989-06-09 1994-11-15 The Dow Chemical Company Perfluorocyclobutane ring-containing polymers
US5159038A (en) 1989-06-09 1992-10-27 Dow Chemical Company Perfluorocyclobutane ring-containing polymers
US5023380A (en) 1989-06-09 1991-06-11 The Dow Chemical Company Perfluorovinyl compounds
US5037917A (en) 1989-06-09 1991-08-06 The Dow Chemical Company Perfluorocyclobutane ring-containing polymers
US5364547A (en) 1989-06-09 1994-11-15 The Dow Chemical Company Lubricants containing perfluorocyclobutane rings
US5159037A (en) 1989-06-09 1992-10-27 The Dow Chemical Company Perfluorocyclobutane ring-containing polymers
US5159036A (en) 1989-12-15 1992-10-27 The Dow Chemical Company Perfluorocyclobutane ring-containing polymers with crosslinking
US5449825A (en) 1992-06-25 1995-09-12 The Dow Chemical Company Preparation of haloperfluoro and perfluoro ethers
US5264508A (en) 1992-06-25 1993-11-23 The Dow Chemical Company Polymers of haloperfluoro and perfluoro ethers
US5338430A (en) 1992-12-23 1994-08-16 Minnesota Mining And Manufacturing Company Nanostructured electrode membranes
US5426164A (en) 1992-12-24 1995-06-20 The Dow Chemical Company Photodefinable polymers containing perfluorocyclobutane groups
US5834523A (en) 1993-09-21 1998-11-10 Ballard Power Systems, Inc. Substituted α,β,β-trifluorostyrene-based composite membranes
US5525436A (en) 1994-11-01 1996-06-11 Case Western Reserve University Proton conducting polymers used as membranes
US5620807A (en) 1995-08-31 1997-04-15 The Dow Chemical Company Flow field assembly for electrochemical fuel cells
AU1831397A (en) 1996-01-16 1997-08-11 Memtec America Corporation Method for gas phase sulfonation of polymer membranes
WO1999005126A1 (fr) 1997-07-25 1999-02-04 Acep Inc. Composes ioniques perfluorovinyliques et leur utilisation dans des materiaux conducteurs
US5879828A (en) 1997-10-10 1999-03-09 Minnesota Mining And Manufacturing Company Membrane electrode assembly
US5910378A (en) 1997-10-10 1999-06-08 Minnesota Mining And Manufacturing Company Membrane electrode assemblies
DE69908499T2 (de) 1998-01-30 2004-05-13 Hydro-Québec, Montréal Polymerisierbare bis-sulfonylderivate und ihre verwendung in der herstellung von ionenaustauschermembranen

Also Published As

Publication number Publication date
EP1290041B1 (de) 2004-05-19
KR100650483B1 (ko) 2006-11-30
US6559237B1 (en) 2003-05-06
WO2001094427A1 (en) 2001-12-13
KR20030007864A (ko) 2003-01-23
DE60010937T2 (de) 2005-06-16
EP1290041A1 (de) 2003-03-12
CA2407665A1 (en) 2001-12-13
JP2003535929A (ja) 2003-12-02
AU2001210762A1 (en) 2001-12-17
DE60010937D1 (de) 2004-06-24

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