ATE267844T1 - Verfahren zur (co)polymerisation von olefinen - Google Patents

Verfahren zur (co)polymerisation von olefinen

Info

Publication number: ATE267844T1
Authority: AT; Austria
Prior art keywords: mixture; derivative; ionizing agent; olefin; halogen
Prior art date: 1992-12-17

Application number

AT98124378T

Other languages

English (en)

Inventor

Nicola Zandona

Original Assignee

Solvay

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1992-12-17

Filing date

1993-12-08

Publication date

2004-06-15

1993-12-08 Application filed by Solvay filed Critical Solvay

2004-06-15 Application granted granted Critical

2004-06-15 Publication of ATE267844T1 publication Critical patent/ATE267844T1/de

Links

150000001336 alkenes Chemical class 0.000 title abstract 5
238000000034 method Methods 0.000 title abstract 4
230000000379 polymerizing effect Effects 0.000 title abstract 2
AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 abstract 3
230000003197 catalytic effect Effects 0.000 abstract 3
239000003795 chemical substances by application Substances 0.000 abstract 3
239000000203 mixture Substances 0.000 abstract 3
239000004215 Carbon black (E152) Substances 0.000 abstract 2
150000001875 compounds Chemical class 0.000 abstract 2
229910052736 halogen Inorganic materials 0.000 abstract 2
229930195733 hydrocarbon Natural products 0.000 abstract 2
150000002430 hydrocarbons Chemical group 0.000 abstract 2
230000007935 neutral effect Effects 0.000 abstract 2
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 abstract 2
239000007787 solid Substances 0.000 abstract 2
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract 1
239000005977 Ethylene Substances 0.000 abstract 1
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 abstract 1
239000003054 catalyst Substances 0.000 abstract 1
239000003085 diluting agent Substances 0.000 abstract 1
125000005843 halogen group Chemical group 0.000 abstract 1
150000002367 halogens Chemical class 0.000 abstract 1
229910052749 magnesium Inorganic materials 0.000 abstract 1
239000011777 magnesium Substances 0.000 abstract 1
238000006116 polymerization reaction Methods 0.000 abstract 1
QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 abstract 1
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 abstract 1
229910052723 transition metal Inorganic materials 0.000 abstract 1
150000003624 transition metals Chemical class 0.000 abstract 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
- C08F4/61904—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with another component of C08F4/60
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
- C08F4/61908—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
- C08F4/61912—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an organoaluminium compound
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
- C08F4/6192—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65904—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with another component of C08F4/64
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Crystallography & Structural Chemistry (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

AT98124378T 1992-12-17 1993-12-08 Verfahren zur (co)polymerisation von olefinen ATE267844T1 (de)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
BE9201105A BE1006438A3 (fr)	1992-12-17	1992-12-17	Systeme catalytique, utilisation de ce systeme catalytique pour la (co)polymerisation d'olefines, procede de preparation de ce systeme catalytique et procede de (co)polymerisation d'olefines.

Publications (1)

Publication Number	Publication Date
ATE267844T1 true ATE267844T1 (de)	2004-06-15

Family

ID=3886590

Family Applications (2)

Application Number	Title	Priority Date	Filing Date
AT93203437T ATE187744T1 (de)	1992-12-17	1993-12-08	Katalysatorsystem, verfahren zur dessen herstellung und seine verwendung in der olefinpolymerisation
AT98124378T ATE267844T1 (de)	1992-12-17	1993-12-08	Verfahren zur (co)polymerisation von olefinen

Family Applications Before (1)

Application Number	Title	Priority Date	Filing Date
AT93203437T ATE187744T1 (de)	1992-12-17	1993-12-08	Katalysatorsystem, verfahren zur dessen herstellung und seine verwendung in der olefinpolymerisation

Country Status (13)

Country	Link
US (2)	US5496782A (de)
EP (2)	EP0602716B1 (de)
JP (1)	JP3466681B2 (de)
KR (1)	KR100291249B1 (de)
AT (2)	ATE187744T1 (de)
BE (1)	BE1006438A3 (de)
BR (1)	BR9305093A (de)
CA (1)	CA2111369A1 (de)
DE (2)	DE69327303T2 (de)
ES (2)	ES2142330T3 (de)
PT (2)	PT602716E (de)
RU (1)	RU2145612C1 (de)
TW (1)	TW332821B (de)

Families Citing this family (29)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US5466766A (en) *	1991-05-09	1995-11-14	Phillips Petroleum Company	Metallocenes and processes therefor and therewith
BE1006880A3 (fr)	1993-03-01	1995-01-17	Solvay	Precurseur solide d'un systeme catalytique pour la polymerisation d'olefines, procede pour sa preparation, systeme catalytique comprenant ce precurseur solide et procede de polymerisation d'olefines en presence de ce systeme catalytique.
EP0683180B1 (de) *	1994-05-18	2002-03-06	Mitsubishi Chemical Corporation	Katalysator zur Polymerisation eines Olefins und Verfahren zum Polymerisieren des Olefins
DE19622207A1 (de) *	1996-06-03	1997-12-04	Hoechst Ag	Chemische Verbindung
GB9712663D0 (en) *	1997-06-16	1997-08-20	Borealis As	Process
BR9917674B1 (pt) *	1998-05-18	2012-06-12		processo para produzir uma composiÇço de catalisador para polimerizar monâmeros.
US6300271B1 (en) *	1998-05-18	2001-10-09	Phillips Petroleum Company	Compositions that can produce polymers
US6165929A (en)	1998-05-18	2000-12-26	Phillips Petroleum Company	Compositions that can produce polymers
US6107230A (en) *	1998-05-18	2000-08-22	Phillips Petroleum Company	Compositions that can produce polymers
US6391816B1 (en)	1999-10-27	2002-05-21	Phillips Petroleum	Organometal compound catalyst
US6548441B1 (en) *	1999-10-27	2003-04-15	Phillips Petroleum Company	Organometal catalyst compositions
EP1101777A1 (de)	1999-11-22	2001-05-23	UNION CARBIDE CHEMICALS & PLASTICS TECHNOLOGY CORPORATION (a Delaware corporation)	Metallmischkatalysatoren
US6750302B1 (en)	1999-12-16	2004-06-15	Phillips Petroleum Company	Organometal catalyst compositions
US20020037979A1 (en) *	1999-12-28	2002-03-28	Robert Charles Job	Mixed ziegler/metallocene catalysts for the production of bimodal polyolefins
MY136330A (en) *	2001-12-12	2008-09-30	Basell Poliolefine Spa	Process for the polymerization of olefins
US7541402B2 (en)	2002-10-15	2009-06-02	Exxonmobil Chemical Patents Inc.	Blend functionalized polyolefin adhesive
US7550528B2 (en)	2002-10-15	2009-06-23	Exxonmobil Chemical Patents Inc.	Functionalized olefin polymers
US7223822B2 (en)	2002-10-15	2007-05-29	Exxonmobil Chemical Patents Inc.	Multiple catalyst and reactor system for olefin polymerization and polymers produced therefrom
US7700707B2 (en)	2002-10-15	2010-04-20	Exxonmobil Chemical Patents Inc.	Polyolefin adhesive compositions and articles made therefrom
WO2004046214A2 (en)	2002-10-15	2004-06-03	Exxonmobil Chemical Patents Inc.	Multiple catalyst system for olefin polymerization and polymers produced therefrom
US7754834B2 (en)	2007-04-12	2010-07-13	Univation Technologies, Llc	Bulk density promoting agents in a gas-phase polymerization process to achieve a bulk particle density
RU2500691C2 (ru) *	2009-08-07	2013-12-10	Бриджстоун Корпорейшн	Способ получения сополимера
US8937139B2 (en)	2012-10-25	2015-01-20	Chevron Phillips Chemical Company Lp	Catalyst compositions and methods of making and using same
US8895679B2 (en)	2012-10-25	2014-11-25	Chevron Phillips Chemical Company Lp	Catalyst compositions and methods of making and using same
US8877672B2 (en)	2013-01-29	2014-11-04	Chevron Phillips Chemical Company Lp	Catalyst compositions and methods of making and using same
US9034991B2 (en)	2013-01-29	2015-05-19	Chevron Phillips Chemical Company Lp	Polymer compositions and methods of making and using same
EP3148937B1 (de) *	2014-05-30	2019-09-18	Bridgestone Corporation	Metallkomplexkatalysator und polymerisationsverfahren damit
EP3738927A1 (de) *	2014-05-31	2020-11-18	Bridgestone Corporation	Metallkomplexkatalysator polymerisationsverfahren damit und polymerprodukte dafür
US9303106B1 (en) *	2014-10-17	2016-04-05	Chevron Phillips Chemical Company Lp	Processes for preparing solid metallocene-based catalyst systems

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Publication number	Priority date	Publication date	Assignee	Title
NL137056C (de) *	1966-10-21
NL137364C (de) *	1968-03-22
BE791676A (fr) *	1971-12-08	1973-05-21	Solvay	Procédé pour la polymérisation des oléfines
US4659685A (en) *	1986-03-17	1987-04-21	The Dow Chemical Company	Heterogeneous organometallic catalysts containing a supported titanium compound and at least one other supported organometallic compound
PL276385A1 (en) *	1987-01-30	1989-07-24	Exxon Chemical Patents Inc	Method for polymerization of olefines,diolefins and acetylene unsaturated compounds
EP0376145B1 (de) *	1988-12-26	1994-03-23	Tosoh Corporation	Verfahren zur Herstellung von stereoregularem Polyolefin
DE69026907T2 (de) *	1989-10-10	1996-10-10	Fina Technology	Metallocenkatalysator mit Lewissäure und Alkylaluminium
ATE120768T1 (de) *	1989-10-30	1995-04-15	Fina Technology	Herstellung von metallocenkatalysatoren für olefinpolymerisation.
ATE137247T1 (de) *	1989-10-30	1996-05-15	Fina Technology	Addition von alkylaluminium zum verbessern eines metallocenkatalysators
KR910011910A (ko) *	1989-12-13	1991-08-07	사와무라 하루오	α-올레핀의 중합방법
US5032562A (en) *	1989-12-27	1991-07-16	Mobil Oil Corporation	Catalyst composition and process for polymerizing polymers having multimodal molecular weight distribution
US5145818A (en) *	1989-12-29	1992-09-08	Mitsui Petrochemical Industries, Ltd.	Olefin polymerization catalyst and process for the polymerization of olefins
TW198726B (de) *	1989-12-29	1993-01-21	Mitsui Petroleum Chemicals Ind
JP3115595B2 (ja) *	1990-07-24	2000-12-11	三井化学株式会社	α―オレフィンの重合触媒及びそれを用いたポリ―α―オレフィンの製造方法
JP3383998B2 (ja) *	1992-08-06	2003-03-10	東ソー株式会社	ポリオレフィンの製造方法

1992
- 1992-12-17 BE BE9201105A patent/BE1006438A3/fr not_active IP Right Cessation
1993
- 1993-12-06 TW TW082110300A patent/TW332821B/zh active
- 1993-12-08 AT AT93203437T patent/ATE187744T1/de not_active IP Right Cessation
- 1993-12-08 ES ES93203437T patent/ES2142330T3/es not_active Expired - Lifetime
- 1993-12-08 DE DE69327303T patent/DE69327303T2/de not_active Expired - Fee Related
- 1993-12-08 EP EP93203437A patent/EP0602716B1/de not_active Expired - Lifetime
- 1993-12-08 AT AT98124378T patent/ATE267844T1/de not_active IP Right Cessation
- 1993-12-08 US US08/162,940 patent/US5496782A/en not_active Expired - Fee Related
- 1993-12-08 EP EP98124378A patent/EP0908468B1/de not_active Expired - Lifetime
- 1993-12-08 PT PT93203437T patent/PT602716E/pt unknown
- 1993-12-08 DE DE69333535T patent/DE69333535T2/de not_active Expired - Fee Related
- 1993-12-08 PT PT98124378T patent/PT908468E/pt unknown
- 1993-12-08 ES ES98124378T patent/ES2217490T3/es not_active Expired - Lifetime
- 1993-12-14 CA CA002111369A patent/CA2111369A1/fr not_active Abandoned
- 1993-12-16 KR KR1019930028040A patent/KR100291249B1/ko not_active Expired - Fee Related
- 1993-12-16 JP JP31663393A patent/JP3466681B2/ja not_active Expired - Fee Related
- 1993-12-16 BR BR9305093A patent/BR9305093A/pt not_active IP Right Cessation
- 1993-12-16 RU RU93055873A patent/RU2145612C1/ru active
1995
- 1995-11-16 US US08/558,485 patent/US5719235A/en not_active Expired - Fee Related

Also Published As

Publication number	Publication date
US5719235A (en)	1998-02-17
EP0908468A2 (de)	1999-04-14
US5496782A (en)	1996-03-05
TW332821B (en)	1998-06-01
KR100291249B1 (ko)	2001-10-24
DE69333535D1 (de)	2004-07-01
ES2217490T3 (es)	2004-11-01
ATE187744T1 (de)	2000-01-15
BR9305093A (pt)	1994-07-05
EP0602716A1 (de)	1994-06-22
KR940014452A (ko)	1994-07-18
DE69333535T2 (de)	2004-12-02
BE1006438A3 (fr)	1994-08-30
DE69327303D1 (de)	2000-01-20
EP0908468A3 (de)	2000-05-17
JP3466681B2 (ja)	2003-11-17
EP0602716B1 (de)	1999-12-15
EP0908468B1 (de)	2004-05-26
PT908468E (pt)	2004-08-31
JPH0710917A (ja)	1995-01-13
ES2142330T3 (es)	2000-04-16
CA2111369A1 (fr)	1994-06-18
PT602716E (pt)	2000-06-30
RU2145612C1 (ru)	2000-02-20
DE69327303T2 (de)	2000-07-20

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