ATE271099T1 - Verfahren zur herstellung von vernetzten mischungen amorpher und kristalliner polymere - Google Patents
Verfahren zur herstellung von vernetzten mischungen amorpher und kristalliner polymereInfo
- Publication number
- ATE271099T1 ATE271099T1 AT00989220T AT00989220T ATE271099T1 AT E271099 T1 ATE271099 T1 AT E271099T1 AT 00989220 T AT00989220 T AT 00989220T AT 00989220 T AT00989220 T AT 00989220T AT E271099 T1 ATE271099 T1 AT E271099T1
- Authority
- AT
- Austria
- Prior art keywords
- amorphic
- crystalline polymers
- producing cross
- linked mixtures
- mixtures
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title abstract 3
- 229920000642 polymer Polymers 0.000 title abstract 3
- 238000004519 manufacturing process Methods 0.000 title 1
- 239000012968 metallocene catalyst Substances 0.000 abstract 2
- 230000000707 stereoselective effect Effects 0.000 abstract 2
- 238000004132 cross linking Methods 0.000 abstract 1
- 238000010348 incorporation Methods 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 239000000178 monomer Substances 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
- 239000004711 α-olefin Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/04—Monomers containing three or four carbon atoms
- C08F210/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/14—Copolymers of propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/04—Monomers containing three or four carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/14—Copolymers of propene
- C08L23/142—Copolymers of propene at least partially crystalline copolymers of propene with other olefins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/18—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms
- C08L23/20—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms having four to nine carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2314/00—Polymer mixtures characterised by way of preparation
- C08L2314/02—Ziegler natta catalyst
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2314/00—Polymer mixtures characterised by way of preparation
- C08L2314/06—Metallocene or single site catalysts
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/458,755 US6323284B1 (en) | 1999-12-10 | 1999-12-10 | Method of preparation of crosslinked blends of amorphous and crystalline polymers |
| PCT/US2000/033100 WO2001042351A1 (en) | 1999-12-10 | 2000-12-06 | Method of preparation of crosslinked blends of amorphous and crystalline polymers |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ATE271099T1 true ATE271099T1 (de) | 2004-07-15 |
Family
ID=23821970
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AT00989220T ATE271099T1 (de) | 1999-12-10 | 2000-12-06 | Verfahren zur herstellung von vernetzten mischungen amorpher und kristalliner polymere |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US6323284B1 (de) |
| EP (1) | EP1268657B1 (de) |
| JP (1) | JP2003516452A (de) |
| KR (1) | KR20020061634A (de) |
| CN (1) | CN1181129C (de) |
| AT (1) | ATE271099T1 (de) |
| BR (1) | BR0016272A (de) |
| CA (1) | CA2393698A1 (de) |
| DE (1) | DE60012232T2 (de) |
| ES (1) | ES2220584T3 (de) |
| MX (1) | MXPA02005714A (de) |
| WO (1) | WO2001042351A1 (de) |
Families Citing this family (38)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7919561B2 (en) * | 1996-09-04 | 2011-04-05 | Exxonmobil Chemical Patents Inc. | Process of producing thermoplastic polymer blends |
| US7223822B2 (en) | 2002-10-15 | 2007-05-29 | Exxonmobil Chemical Patents Inc. | Multiple catalyst and reactor system for olefin polymerization and polymers produced therefrom |
| US8618219B2 (en) * | 2002-10-15 | 2013-12-31 | Exxonmobil Chemical Patents Inc. | Propylene copolymers for adhesive applications |
| US7541402B2 (en) | 2002-10-15 | 2009-06-02 | Exxonmobil Chemical Patents Inc. | Blend functionalized polyolefin adhesive |
| US7550528B2 (en) * | 2002-10-15 | 2009-06-23 | Exxonmobil Chemical Patents Inc. | Functionalized olefin polymers |
| US7700707B2 (en) | 2002-10-15 | 2010-04-20 | Exxonmobil Chemical Patents Inc. | Polyolefin adhesive compositions and articles made therefrom |
| ES2394304T3 (es) * | 2002-10-15 | 2013-01-30 | Exxonmobil Chemical Patents, Inc. | Sistema de múltiples catalizadores para la polimerización de olefinas y polímeros producidos a partir de éstos |
| US8653169B2 (en) | 2002-10-15 | 2014-02-18 | Exxonmobil Chemical Patents Inc. | Propylene copolymers for adhesive applications |
| WO2004037872A2 (en) * | 2002-10-24 | 2004-05-06 | Exxonmobil Chemical Patents Inc. | Branched crystalline polypropylene |
| WO2004037871A1 (en) * | 2002-10-24 | 2004-05-06 | Exxonmobil Chemical Patents Inc. | Branched crystalline polypropylene |
| US7504347B2 (en) * | 2004-03-17 | 2009-03-17 | Dow Global Technologies Inc. | Fibers made from copolymers of propylene/α-olefins |
| NZ549262A (en) * | 2004-03-17 | 2010-08-27 | Dow Global Technologies Inc | Catalyst composition comprising shuttling agent for higher olefin multi-block copolymer formation |
| RU2375381C2 (ru) * | 2004-03-17 | 2009-12-10 | Дау Глобал Текнолоджиз Инк. | Состав катализатора, содержащий челночный агент, для формирования мульти-блок-сополимера высшего олефина |
| US7803728B2 (en) * | 2004-03-17 | 2010-09-28 | Dow Global Technologies Inc. | Fibers made from copolymers of ethylene/α-olefins |
| AU2005224259B2 (en) * | 2004-03-17 | 2010-09-09 | Dow Global Technologies Inc. | Catalyst composition comprising shuttling agent for ethylene multi-block copolymer formation |
| GB2420348B (en) * | 2004-10-28 | 2009-11-18 | Exxonmobil Chem Patents Inc | Syndiotactic rich polyolefins |
| CA2601376A1 (en) * | 2005-03-17 | 2006-09-28 | Dow Global Technologies Inc. | Fibers made from copolymers of ethylene/alpha-olefins |
| BRPI0609818A2 (pt) * | 2005-03-17 | 2010-04-27 | Dow Global Technologies Inc | fibra obtenìvel de ou compreendendo um interpolìmero de propileno/(alfa)-olefina, fibra obtenìvel de ou compreendendo pelo menos um interpolìmero de propileno e uma (alfa)-olefina de c2 ou c4-c20, pano, fio e método para fabricar uma fibra |
| US9745461B2 (en) | 2005-06-22 | 2017-08-29 | Exxonmobil Chemical Patents Inc. | Vulcanized polymer blends |
| US8022142B2 (en) * | 2008-12-15 | 2011-09-20 | Exxonmobil Chemical Patents Inc. | Thermoplastic olefin compositions |
| US7928164B2 (en) * | 2005-06-22 | 2011-04-19 | Exxonmobil Chemical Patents Inc. | Homogeneous polymer blend and process of making the same |
| US9644092B2 (en) | 2005-06-22 | 2017-05-09 | Exxonmobil Chemical Patents Inc. | Heterogeneous in-situ polymer blend |
| US20060293462A1 (en) * | 2005-06-22 | 2006-12-28 | Sunny Jacob | Heterogeneous polymer blend and process of making the same |
| US7951872B2 (en) | 2005-06-22 | 2011-05-31 | Exxonmobil Chemical Patents Inc. | Heterogeneous polymer blend with continuous elastomeric phase and process of making the same |
| US8143353B2 (en) * | 2008-01-18 | 2012-03-27 | Exxonmobil Chemical Patents Inc. | Polymerization process and adhesives therefrom |
| US8283428B2 (en) | 2008-06-20 | 2012-10-09 | Exxonmobil Chemical Patents Inc. | Polymacromonomer and process for production thereof |
| US8399725B2 (en) | 2008-06-20 | 2013-03-19 | Exxonmobil Chemical Patents Inc. | Functionalized high vinyl terminated propylene based oligomers |
| US8283419B2 (en) | 2008-06-20 | 2012-10-09 | Exxonmobil Chemical Patents Inc. | Olefin functionalization by metathesis reaction |
| US8802797B2 (en) | 2008-06-20 | 2014-08-12 | Exxonmobil Chemical Patents Inc. | Vinyl-terminated macromonomer oligomerization |
| US8372930B2 (en) | 2008-06-20 | 2013-02-12 | Exxonmobil Chemical Patents Inc. | High vinyl terminated propylene based oligomers |
| US8106127B2 (en) * | 2008-12-15 | 2012-01-31 | Exxonmobil Chemical Patents Inc. | Heterogeneous in-reactor polymer blends |
| US8410217B2 (en) * | 2008-12-15 | 2013-04-02 | Exxonmobil Chemical Patents Inc. | Thermoplastic polyolefin blends |
| US8497325B2 (en) | 2008-12-15 | 2013-07-30 | Exxonmobil Chemical Patents Inc. | Thermoplastic polyolefin blends and films therefrom |
| US8101685B2 (en) | 2008-12-15 | 2012-01-24 | Exxonmobil Chemical Patents Inc. | Thermoplastic elastomer polyolefin in-reactor blends and molded articles therefrom |
| US8093335B2 (en) * | 2008-12-15 | 2012-01-10 | Exxonmobil Chemical Patents Inc. | Thermoplastic polyolefin in-reactor blends and molded articles therefrom |
| US20110054117A1 (en) * | 2009-08-27 | 2011-03-03 | Hall Gregory K | Polyolefin Adhesive Compositions and Method of Making Thereof |
| CN103273614B (zh) * | 2013-05-23 | 2015-11-18 | 四川大学 | 一种以无规聚丙烯作为弹性体增韧等规聚丙烯iPP制品的方法 |
| US8859638B1 (en) * | 2013-05-31 | 2014-10-14 | Lion Copolymer Geismar, Llc | Method for making a high solids cross-linked ethylene propylene diene terpolymer latex |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5153157A (en) | 1987-01-30 | 1992-10-06 | Exxon Chemical Patents Inc. | Catalyst system of enhanced productivity |
| EP0366411A3 (de) | 1988-10-28 | 1991-04-24 | Exxon Chemical Patents Inc. | Pfropfpolymere von Ethylen-Propylen-Dien mit Propylen, Verfahren zu deren Herstellung und ihre Anwendung in Polypropylenzusammensetzungen |
| JPH051185A (ja) | 1990-11-16 | 1993-01-08 | Mitsubishi Petrochem Co Ltd | 強度に優れた熱可塑性樹脂組成物及びその製造法 |
| DE69225749T2 (de) | 1991-08-08 | 1998-10-01 | Rexene Corp | Harzzusammensetzung aus amorphem Polyolefin und crystallinem Polypropylen |
| US6121383A (en) | 1993-01-19 | 2000-09-19 | Advanced Elastomer Systems, L.P. | Thermosplastic vulcanizates from blends of a polypropylene and elastic α-olefin/cyclic olefin copolymers |
| US5516848A (en) * | 1995-01-31 | 1996-05-14 | Exxon Chemical Patents Inc. | Process to produce thermoplastic elastomers |
| US5539056A (en) | 1995-01-31 | 1996-07-23 | Exxon Chemical Patents Inc. | Thermoplastic elastomers |
| US5986009A (en) | 1997-12-03 | 1999-11-16 | The Dow Chemical Company | Blends of polypropylenes |
| US6177527B1 (en) * | 1998-09-08 | 2001-01-23 | Union Carbide Chemical & Plastics Technology Corporation | Process for the preparation of polyethylene or polypropylene |
-
1999
- 1999-12-10 US US09/458,755 patent/US6323284B1/en not_active Expired - Lifetime
-
2000
- 2000-12-06 EP EP00989220A patent/EP1268657B1/de not_active Expired - Lifetime
- 2000-12-06 JP JP2001543642A patent/JP2003516452A/ja not_active Withdrawn
- 2000-12-06 BR BR0016272-8A patent/BR0016272A/pt not_active IP Right Cessation
- 2000-12-06 CN CNB008168636A patent/CN1181129C/zh not_active Expired - Fee Related
- 2000-12-06 MX MXPA02005714A patent/MXPA02005714A/es active IP Right Grant
- 2000-12-06 ES ES00989220T patent/ES2220584T3/es not_active Expired - Lifetime
- 2000-12-06 WO PCT/US2000/033100 patent/WO2001042351A1/en not_active Ceased
- 2000-12-06 DE DE60012232T patent/DE60012232T2/de not_active Expired - Fee Related
- 2000-12-06 AT AT00989220T patent/ATE271099T1/de not_active IP Right Cessation
- 2000-12-06 KR KR1020027007317A patent/KR20020061634A/ko not_active Ceased
- 2000-12-06 CA CA002393698A patent/CA2393698A1/en not_active Abandoned
Also Published As
| Publication number | Publication date |
|---|---|
| ES2220584T3 (es) | 2004-12-16 |
| WO2001042351A1 (en) | 2001-06-14 |
| CN1408011A (zh) | 2003-04-02 |
| CN1181129C (zh) | 2004-12-22 |
| EP1268657A1 (de) | 2003-01-02 |
| US6323284B1 (en) | 2001-11-27 |
| JP2003516452A (ja) | 2003-05-13 |
| DE60012232T2 (de) | 2005-07-28 |
| MXPA02005714A (es) | 2002-09-18 |
| CA2393698A1 (en) | 2001-06-14 |
| BR0016272A (pt) | 2002-10-22 |
| DE60012232D1 (de) | 2004-08-19 |
| KR20020061634A (ko) | 2002-07-24 |
| EP1268657B1 (de) | 2004-07-14 |
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