ATE274534T1 - Metallocen trägerkatalysator und olefinpolymerisation unter verwendung desselben - Google Patents
Metallocen trägerkatalysator und olefinpolymerisation unter verwendung desselbenInfo
- Publication number
- ATE274534T1 ATE274534T1 AT00911437T AT00911437T ATE274534T1 AT E274534 T1 ATE274534 T1 AT E274534T1 AT 00911437 T AT00911437 T AT 00911437T AT 00911437 T AT00911437 T AT 00911437T AT E274534 T1 ATE274534 T1 AT E274534T1
- Authority
- AT
- Austria
- Prior art keywords
- olefin polymerization
- metallocene
- catalyst
- supported
- ligand
- Prior art date
Links
- 150000001336 alkenes Chemical class 0.000 title abstract 4
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 title abstract 4
- 238000006116 polymerization reaction Methods 0.000 title abstract 4
- 239000003054 catalyst Substances 0.000 title abstract 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 4
- 150000001875 compounds Chemical class 0.000 abstract 3
- 125000006515 benzyloxy alkyl group Chemical group 0.000 abstract 2
- 125000000524 functional group Chemical group 0.000 abstract 2
- 239000003446 ligand Substances 0.000 abstract 2
- 239000000377 silicon dioxide Substances 0.000 abstract 2
- DHKHKXVYLBGOIT-UHFFFAOYSA-N acetaldehyde Diethyl Acetal Natural products CCOC(C)OCC DHKHKXVYLBGOIT-UHFFFAOYSA-N 0.000 abstract 1
- 150000001241 acetals Chemical class 0.000 abstract 1
- 238000001994 activation Methods 0.000 abstract 1
- 125000004183 alkoxy alkyl group Chemical group 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 238000007796 conventional method Methods 0.000 abstract 1
- 238000002386 leaching Methods 0.000 abstract 1
- 239000012968 metallocene catalyst Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 150000004250 monothioacetals Chemical class 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- 238000002360 preparation method Methods 0.000 abstract 1
- 239000002002 slurry Substances 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1019990023575A KR100354290B1 (ko) | 1999-06-22 | 1999-06-22 | 담지 메탈로센 촉매 및 이를 이용한 올레핀 중합 |
| PCT/KR2000/000189 WO2000078827A1 (en) | 1999-06-22 | 2000-03-09 | Supported metallocene catalyst and olefin polymerization using the same |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ATE274534T1 true ATE274534T1 (de) | 2004-09-15 |
Family
ID=19594332
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AT00911437T ATE274534T1 (de) | 1999-06-22 | 2000-03-09 | Metallocen trägerkatalysator und olefinpolymerisation unter verwendung desselben |
Country Status (10)
| Country | Link |
|---|---|
| EP (1) | EP1196459B1 (de) |
| JP (1) | JP3592672B2 (de) |
| KR (1) | KR100354290B1 (de) |
| CN (1) | CN100503658C (de) |
| AT (1) | ATE274534T1 (de) |
| AU (1) | AU767633B2 (de) |
| CA (1) | CA2340713C (de) |
| DE (1) | DE60013297T2 (de) |
| ES (1) | ES2223476T3 (de) |
| WO (1) | WO2000078827A1 (de) |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100536181B1 (ko) * | 2001-05-25 | 2005-12-14 | 주식회사 엘지화학 | 표면 개질 담체와 작용기를 가진 촉매 전구체를 사용한중합 담지 촉매 및 이를 이용한 올레핀 중합 |
| KR100440482B1 (ko) | 2001-07-11 | 2004-07-14 | 주식회사 엘지화학 | 새로운 다중핵 반쪽 메탈로센 촉매 |
| KR100497172B1 (ko) * | 2002-11-11 | 2005-06-28 | 주식회사 엘지화학 | 양쪽 메탈로센 유도체 화합물을 리간드로 가진 다중핵반쪽 메탈로센 촉매 및 이를 이용한 스티렌 중합체의제조방법 |
| KR100579843B1 (ko) * | 2003-04-01 | 2006-05-12 | 주식회사 엘지화학 | 혼성 담지 메탈로센 촉매 및 그의 제조방법과 이를 이용한폴리올레핀의 제조방법 |
| KR100646249B1 (ko) | 2004-04-08 | 2006-11-23 | 주식회사 엘지화학 | 혼성 담지 메탈로센 촉매를 이용한 가공성 및 내압 특성이뛰어난 급수관 파이프용 폴리에틸렌 및 그의 제조방법 |
| KR100690345B1 (ko) | 2004-09-03 | 2007-03-09 | 주식회사 엘지화학 | 담지 메탈로센 촉매, 그 제조방법 및 이를 이용한폴리올레핀의 제조방법 |
| CN1944473B (zh) * | 2005-09-30 | 2010-12-08 | 住友化学株式会社 | 制备预聚催化剂组分的方法、预聚催化剂组分及用该预聚催化剂组分制备烯烃聚合物的方法 |
| WO2007078134A1 (en) * | 2005-12-30 | 2007-07-12 | Lg Chem. Ltd. | Transition metal complexes and preparation methods thereof |
| KR101271055B1 (ko) | 2008-03-28 | 2013-06-04 | 에스케이종합화학 주식회사 | 메탈로센 담지촉매 조성물 및 이를 이용한 폴리올레핀의제조방법 |
| EP2559710B1 (de) | 2010-04-12 | 2016-07-13 | Lotte Chemical Corporation | Katalysatorzusammensetzung zur polymerisierung von olefinen und verfahren zur herstellung von olefinen damit |
| WO2011129594A2 (ko) | 2010-04-12 | 2011-10-20 | 호남석유화학 주식회사 | 티오펜-축합고리 사이클로펜타디에닐 리간드를 포함하는 전이금속 화합물을 사용한 올레핀-디엔 공중합체의 제조방법 |
| CN102858808B (zh) | 2010-04-12 | 2015-04-01 | 乐天化学株式会社 | 用于烯烃聚合的负载型催化剂以及利用该催化剂的聚烯烃的制备方法 |
| KR100986301B1 (ko) | 2010-04-12 | 2010-10-07 | 아주대학교산학협력단 | 테트라하이드로퀴놀린 유도체로부터 유래한 티오펜-축합고리 싸이클로펜타디에닐 4족 금속 화합물 및 이를 이용한 올레핀 중합 |
| KR101384450B1 (ko) | 2010-04-12 | 2014-04-25 | 롯데케미칼 주식회사 | 티오펜-축합고리 사이클로펜타디에닐 리간드를 포함하는 전이금속 화합물을 사용한 올레핀-디엔 공중합체의 제조방법 |
| KR101703274B1 (ko) * | 2014-08-12 | 2017-02-22 | 주식회사 엘지화학 | 메탈로센 화합물, 이를 포함하는 촉매 조성물 및 이를 이용한 올레핀 중합체의 제조방법 |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3718888A1 (de) * | 1987-06-05 | 1988-12-22 | Hoechst Ag | Verfahren zur herstellung eines 1-olefinpolymers |
| GB9300934D0 (en) * | 1993-01-19 | 1993-03-10 | Bp Chem Int Ltd | Metallocene complexes |
| BR9611188A (pt) * | 1995-10-27 | 1999-03-30 | Dow Chemical Co | Complexo metálico sistema catalisador e processo para polimerizar uma alpha-olefina |
| US20030195109A1 (en) * | 1996-10-31 | 2003-10-16 | Jose Sancho Royo | Catalytic systems for the polimerisation and copolimerisation of alpha-olefins |
| GB9722447D0 (en) * | 1997-10-23 | 1997-12-24 | Borealis As | Process |
| KR100380018B1 (ko) * | 1998-04-09 | 2003-10-04 | 주식회사 엘지화학 | 메탈로센담지촉매및이를이용한올레핀중합방법 |
-
1999
- 1999-06-22 KR KR1019990023575A patent/KR100354290B1/ko not_active Expired - Lifetime
-
2000
- 2000-03-09 AU AU33311/00A patent/AU767633B2/en not_active Expired
- 2000-03-09 AT AT00911437T patent/ATE274534T1/de not_active IP Right Cessation
- 2000-03-09 ES ES00911437T patent/ES2223476T3/es not_active Expired - Lifetime
- 2000-03-09 CN CNB008011591A patent/CN100503658C/zh not_active Expired - Lifetime
- 2000-03-09 EP EP00911437A patent/EP1196459B1/de not_active Expired - Lifetime
- 2000-03-09 WO PCT/KR2000/000189 patent/WO2000078827A1/en not_active Ceased
- 2000-03-09 DE DE60013297T patent/DE60013297T2/de not_active Expired - Lifetime
- 2000-03-09 CA CA002340713A patent/CA2340713C/en not_active Expired - Lifetime
- 2000-03-09 JP JP2001505584A patent/JP3592672B2/ja not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| JP3592672B2 (ja) | 2004-11-24 |
| CA2340713A1 (en) | 2000-12-28 |
| AU767633B2 (en) | 2003-11-20 |
| CN1314920A (zh) | 2001-09-26 |
| ES2223476T3 (es) | 2005-03-01 |
| EP1196459A1 (de) | 2002-04-17 |
| WO2000078827A1 (en) | 2000-12-28 |
| EP1196459B1 (de) | 2004-08-25 |
| DE60013297T2 (de) | 2005-09-08 |
| KR100354290B1 (ko) | 2002-09-28 |
| CN100503658C (zh) | 2009-06-24 |
| JP2003502492A (ja) | 2003-01-21 |
| DE60013297D1 (de) | 2004-09-30 |
| KR20010003325A (ko) | 2001-01-15 |
| CA2340713C (en) | 2009-09-08 |
| AU3331100A (en) | 2001-01-09 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| RER | Ceased as to paragraph 5 lit. 3 law introducing patent treaties |