ATE286920T1 - Verfahren zum herstellen von stereospezifischen polymeren - Google Patents
Verfahren zum herstellen von stereospezifischen polymerenInfo
- Publication number
- ATE286920T1 ATE286920T1 AT00200779T AT00200779T ATE286920T1 AT E286920 T1 ATE286920 T1 AT E286920T1 AT 00200779 T AT00200779 T AT 00200779T AT 00200779 T AT00200779 T AT 00200779T AT E286920 T1 ATE286920 T1 AT E286920T1
- Authority
- AT
- Austria
- Prior art keywords
- supported
- catalyst component
- stereospecific
- silica support
- metallocene catalyst
- Prior art date
Links
- 230000000707 stereoselective effect Effects 0.000 title abstract 4
- 229920000642 polymer Polymers 0.000 title abstract 2
- 238000004519 manufacturing process Methods 0.000 title 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 7
- 239000012968 metallocene catalyst Substances 0.000 abstract 3
- 239000000377 silicon dioxide Substances 0.000 abstract 3
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 2
- 125000000058 cyclopentadienyl group Chemical group C1(=CC=CC1)* 0.000 abstract 2
- 239000011148 porous material Substances 0.000 abstract 2
- 150000003624 transition metals Chemical group 0.000 abstract 2
- 239000004743 Polypropylene Substances 0.000 abstract 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 abstract 1
- 125000005234 alkyl aluminium group Chemical group 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 239000003426 co-catalyst Substances 0.000 abstract 1
- 239000003446 ligand Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 239000000178 monomer Substances 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
- -1 polypropylene Polymers 0.000 abstract 1
- 229920001155 polypropylene Polymers 0.000 abstract 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 abstract 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 abstract 1
- 125000001424 substituent group Chemical group 0.000 abstract 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 abstract 1
- 239000004711 α-olefin Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/04—Monomers containing three or four carbon atoms
- C08F10/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F12/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
- C08F12/02—Monomers containing only one unsaturated aliphatic radical
- C08F12/04—Monomers containing only one unsaturated aliphatic radical containing one ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/02—Carriers therefor
- C08F4/025—Metal oxides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
- C08F2500/15—Isotactic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Crystallography & Structural Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Steroid Compounds (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/273,819 US6432860B1 (en) | 1999-03-22 | 1999-03-22 | Supported metallocene catalysts |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ATE286920T1 true ATE286920T1 (de) | 2005-01-15 |
Family
ID=23045532
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AT00200779T ATE286920T1 (de) | 1999-03-22 | 2000-03-06 | Verfahren zum herstellen von stereospezifischen polymeren |
Country Status (8)
| Country | Link |
|---|---|
| US (2) | US6432860B1 (de) |
| EP (1) | EP1038885B1 (de) |
| JP (1) | JP2000273112A (de) |
| KR (1) | KR100586358B1 (de) |
| AT (1) | ATE286920T1 (de) |
| DE (1) | DE60017306T2 (de) |
| ES (1) | ES2234509T3 (de) |
| TW (1) | TWI252236B (de) |
Families Citing this family (50)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6777366B2 (en) * | 2001-02-13 | 2004-08-17 | Fina Technology, Inc. | Method for the preparation of metallocene catalysts |
| US6777367B2 (en) * | 2001-02-13 | 2004-08-17 | Fina Technology, Inc. | Method for the preparation of metallocene catalysts |
| US20030236365A1 (en) * | 2002-06-24 | 2003-12-25 | Fina Technology, Inc. | Polyolefin production with a high performance support for a metallocene catalyst system |
| EP1403293A1 (de) * | 2002-09-27 | 2004-03-31 | ATOFINA Research Société Anonyme | Metallocenkatalysatorbestandteil, der ein Silyl Gruppe-enthaltender Cyclopentadienylring enthält |
| US6992034B2 (en) * | 2003-07-10 | 2006-01-31 | Formosa Plastics Corporation, U.S.A. | Catalyst component for olefin polymerization |
| US6878787B2 (en) * | 2003-08-26 | 2005-04-12 | Fina Technology, Inc. | Polyamide supported metallocene catalysts |
| US7368411B2 (en) * | 2004-01-20 | 2008-05-06 | Fina Technology, Inc | Supported metallocene catalysts and their use in producing stereospecific polymers |
| US7211536B2 (en) * | 2004-10-22 | 2007-05-01 | Fina Technology, Inc. | Supported metallocene catalysts and their use in producing stereospecific polymers |
| US20060279026A1 (en) * | 2005-06-09 | 2006-12-14 | Fina Technology, Inc. | Polypropylene composition for injection stretch blow molding |
| US20070040292A1 (en) * | 2005-08-22 | 2007-02-22 | Fina Technology, Inc. | Polypropylene composition for high gloss retention |
| EP1785435A1 (de) * | 2005-11-09 | 2007-05-16 | Borealis Technology Oy | Methode zur Ueberpruefung der Homogenität des Katalysators |
| US20070110997A1 (en) * | 2005-11-17 | 2007-05-17 | Fina Technology, Inc. | Polymeric film structures and compositions for high surface treatment retention |
| US20070116911A1 (en) * | 2005-11-21 | 2007-05-24 | Fina Technology, Inc. | Hot seal resins |
| US20070235896A1 (en) * | 2006-04-06 | 2007-10-11 | Fina Technology, Inc. | High shrink high modulus biaxially oriented films |
| US7446167B2 (en) * | 2006-04-13 | 2008-11-04 | Fina Technology, Inc. | Catalyst deactivation agents and methods for use of same |
| US20080061468A1 (en) * | 2006-09-07 | 2008-03-13 | Frank Li | Fiber processing of high ethylene level propylene-ethylene random copolymers by use of nucleators |
| US7589138B2 (en) * | 2006-12-05 | 2009-09-15 | Fina Technology, Inc. | Injection molding process |
| US20090202770A1 (en) * | 2008-02-08 | 2009-08-13 | Fengkui Li | Polypropylene/polyisobutylene blends and films prepared from same |
| US8759446B2 (en) | 2008-06-30 | 2014-06-24 | Fina Technology, Inc. | Compatibilized polypropylene and polylactic acid blends and methods of making and using same |
| US8268913B2 (en) | 2008-06-30 | 2012-09-18 | Fina Technology, Inc. | Polymeric blends and methods of using same |
| US8545971B2 (en) | 2008-06-30 | 2013-10-01 | Fina Technology, Inc. | Polymeric compositions comprising polylactic acid and methods of making and using same |
| US20100015331A1 (en) * | 2008-07-16 | 2010-01-21 | Fina Technology, Inc. | Hot melt adhesive compositions and methods of making and using same |
| US20100087602A1 (en) * | 2008-10-08 | 2010-04-08 | Fina Technology, Inc. | Long chain branched polypropylene for cast film applications |
| EP2385080B1 (de) * | 2009-01-27 | 2021-01-06 | Kaneka Corporation | Vorgeschäumte polypropylenharzpartikel und verfahren zu ihrer herstellung sowie schaumstoffgeformter polypropylenharzartikel |
| US9174384B2 (en) * | 2009-09-01 | 2015-11-03 | Fina Technology, Inc. | Multilayer polypropylene films and methods of making and using same |
| EP2923756B1 (de) | 2012-11-26 | 2018-05-30 | Braskem S.A. | Durch hybridstütze geträgerter metallocenkatalysator, verfahren zur herstellung davon, polymerisationsverfahren zur herstellung eines ethylenhomopolymers oder copolymers mit breiter oder bimodaler molmassenverteilung, verwednung des geträgerter metallocenkatalysators und ethylenpolymer mit breiter oder bimodaler molmassenverteilung |
| EP3046543A1 (de) * | 2013-09-18 | 2016-07-27 | Stc.Unm | Ringförmige mesoporöse silicananoteilchen (tmsnps) und verwandte protozellen |
| US10329360B2 (en) | 2015-06-05 | 2019-06-25 | Exxonmobil Chemical Patents Inc. | Catalyst system comprising supported alumoxane and unsupported alumoxane particles |
| US9738779B2 (en) | 2015-06-05 | 2017-08-22 | Exxonmobil Chemical Patents Inc. | Heterophasic copolymers and sequential polymerization |
| US10280233B2 (en) | 2015-06-05 | 2019-05-07 | Exxonmobil Chemical Patents Inc. | Catalyst systems and methods of making and using the same |
| US9725537B2 (en) | 2015-06-05 | 2017-08-08 | Exxonmobil Chemical Patents Inc. | High activity catalyst supportation |
| EP3303422B1 (de) | 2015-06-05 | 2021-03-17 | ExxonMobil Chemical Patents Inc. | Herstellung von heterophasischen polymeren in gas- oder schlämmephase |
| US9725569B2 (en) | 2015-06-05 | 2017-08-08 | Exxonmobil Chemical Patents Inc. | Porous propylene polymers |
| WO2016195875A1 (en) * | 2015-06-05 | 2016-12-08 | Exxonmobil Chemical Patents Inc. | Silica supports with high aluminoxane loading capability |
| US10759886B2 (en) | 2015-06-05 | 2020-09-01 | Exxonmobil Chemical Patents Inc. | Single reactor production of polymers in gas or slurry phase |
| WO2016195876A1 (en) * | 2015-06-05 | 2016-12-08 | Exxonmobil Chemical Patents Inc. | Silica supports with high aluminoxane loading capability |
| US9809664B2 (en) | 2015-06-05 | 2017-11-07 | Exxonmobil Chemical Patents Inc. | Bimodal propylene polymers and sequential polymerization |
| US10280235B2 (en) | 2015-06-05 | 2019-05-07 | Exxonmobil Chemical Patents Inc. | Catalyst system containing high surface area supports and sequential polymerization to produce heterophasic polymers |
| US9920176B2 (en) | 2015-06-05 | 2018-03-20 | Exxonmobil Chemical Patents Inc. | Single site catalyst supportation |
| US10077325B2 (en) | 2015-06-05 | 2018-09-18 | Exxonmobil Chemical Patents Inc. | Silica supports with high aluminoxane loading capability |
| US10294316B2 (en) | 2015-06-05 | 2019-05-21 | Exxonmobil Chemical Patents Inc. | Silica supports with high aluminoxane loading capability |
| WO2016196331A1 (en) | 2015-06-05 | 2016-12-08 | Exxonmobil Chemical Patents Inc. | Supported metallocene catalyst systems for polymerization |
| WO2017120504A1 (en) | 2016-01-08 | 2017-07-13 | Durfee Paul N | Osteotropic nanoparticles for prevention or treatment of bone metastases |
| US11059918B2 (en) | 2016-05-27 | 2021-07-13 | Exxonmobil Chemical Patents Inc. | Metallocene catalyst compositions and polymerization process therewith |
| KR102411877B1 (ko) | 2016-10-28 | 2022-06-22 | 피나 테크놀러지, 인코포레이티드 | Bopp 적용을 위한 폴리프로필렌 속의 결정화도를 감소시키기 위한 제제의 용도 |
| WO2018160865A1 (en) | 2017-03-01 | 2018-09-07 | Charles Jeffrey Brinker | Active targeting of cells by monosized protocells |
| WO2020068798A1 (en) | 2018-09-24 | 2020-04-02 | Guo Jimin | Living mammalian cells modified with functional modular nanoparticles |
| US12208164B2 (en) | 2019-02-28 | 2025-01-28 | Unm Rainforest Innovations | Modular metal-organic polyhedra superassembly compositions |
| KR102547232B1 (ko) | 2019-10-24 | 2023-06-26 | 한화솔루션 주식회사 | 올레핀 중합용 촉매의 제조방법 |
| US20250243354A1 (en) | 2024-01-29 | 2025-07-31 | Fina Technology, Inc. | Polypropylene compositions with improved weld strength |
Family Cites Families (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4808561A (en) | 1985-06-21 | 1989-02-28 | Exxon Chemical Patents Inc. | Supported polymerization catalyst |
| US4701432A (en) | 1985-11-15 | 1987-10-20 | Exxon Chemical Patents Inc. | Supported polymerization catalyst |
| US4794096A (en) * | 1987-04-03 | 1988-12-27 | Fina Technology, Inc. | Hafnium metallocene catalyst for the polymerization of olefins |
| US4975403A (en) * | 1987-09-11 | 1990-12-04 | Fina Technology, Inc. | Catalyst systems for producing polyolefins having a broad molecular weight distribution |
| US5008228A (en) * | 1988-03-29 | 1991-04-16 | Exxon Chemical Patents Inc. | Method for preparing a silica gel supported metallocene-alumoxane catalyst |
| US4876229A (en) * | 1988-05-31 | 1989-10-24 | Mobil Oil Corporation | Catalyst composition for polymerizing olefins of narrow molecular weight distribution and polymerization therewith |
| US4892851A (en) * | 1988-07-15 | 1990-01-09 | Fina Technology, Inc. | Process and catalyst for producing syndiotactic polyolefins |
| US5243002A (en) * | 1988-07-15 | 1993-09-07 | Fina Technology, Inc. | Process and catalyst for producing syndiotactic polymers |
| US5118648A (en) * | 1988-10-05 | 1992-06-02 | Mobil Oil Corporation | Particulate polymer-supported olefin polymerization catalyst |
| JP2768479B2 (ja) * | 1988-12-27 | 1998-06-25 | 三井化学株式会社 | オレフィン重合用触媒成分およびオレフィンの重合方法 |
| US5036034A (en) * | 1989-10-10 | 1991-07-30 | Fina Technology, Inc. | Catalyst for producing hemiisotactic polypropylene |
| TW218884B (de) | 1991-05-01 | 1994-01-11 | Mitsubishi Kakoki Kk | |
| US5399636A (en) | 1993-06-11 | 1995-03-21 | Phillips Petroleum Company | Metallocenes and processes therefor and therewith |
| EP0522581B1 (de) | 1991-07-11 | 1997-10-15 | Idemitsu Kosan Company Limited | Verfahren zur Herstellung von Polymeren auf Olefinbasis und Olefin-Polymerisationskatalysatoren |
| US5281679A (en) | 1991-11-07 | 1994-01-25 | Exxon Chemical Patents Inc. | Catalyst and method of broadening polymer molecular weight distribution and increasing polymer tensile impact strength and products made thereof |
| US5238892A (en) | 1992-06-15 | 1993-08-24 | Exxon Chemical Patents Inc. | Supported catalyst for 1-olefin(s) (co)polymerization |
| DE69326561T2 (de) * | 1992-12-28 | 2000-01-05 | Mobil Oil Corp., Fairfax | Verfahren zur herstellung eines trägermaterials |
| JPH06345817A (ja) * | 1993-06-14 | 1994-12-20 | Mitsui Toatsu Chem Inc | 固体触媒成分およびこれを用いたオレフィンの重合方法 |
| CZ293261B6 (cs) | 1994-11-17 | 2004-03-17 | The Dow Chemical Company | Nanesená katalytická komponenta, nanesený katalyzátor, způsob jejich přípravy a jejich použití |
| SG64939A1 (en) * | 1995-07-17 | 2002-02-19 | Mitsui Chemicals Inc | Olefin polymerization catalyst, process for preparing olefin polymer, and olefin polymer |
| EP0837068A3 (de) * | 1996-10-15 | 2002-04-17 | Basell Polyolefine GmbH | Stereorigide Metallocenverbindung |
| US5968864A (en) * | 1996-12-20 | 1999-10-19 | Fina Technology, Inc. | Catalyst efficiency for supported metallocene catalyst |
| US5807800A (en) | 1997-02-11 | 1998-09-15 | Fina Technology, Inc. | Process for producing stereospecific polymers |
| DE19710761A1 (de) * | 1997-03-14 | 1998-09-17 | Basf Ag | Hochkristalline Propylenhomopolymerisate |
-
1999
- 1999-03-22 US US09/273,819 patent/US6432860B1/en not_active Expired - Lifetime
-
2000
- 2000-03-01 TW TW089103611A patent/TWI252236B/zh not_active IP Right Cessation
- 2000-03-06 EP EP00200779A patent/EP1038885B1/de not_active Expired - Lifetime
- 2000-03-06 DE DE60017306T patent/DE60017306T2/de not_active Expired - Lifetime
- 2000-03-06 AT AT00200779T patent/ATE286920T1/de not_active IP Right Cessation
- 2000-03-06 ES ES00200779T patent/ES2234509T3/es not_active Expired - Lifetime
- 2000-03-17 JP JP2000076295A patent/JP2000273112A/ja active Pending
- 2000-03-21 KR KR1020000014359A patent/KR100586358B1/ko not_active Expired - Fee Related
-
2002
- 2002-04-02 US US10/114,185 patent/US6855782B2/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| EP1038885A2 (de) | 2000-09-27 |
| DE60017306T2 (de) | 2006-01-05 |
| EP1038885A3 (de) | 2000-11-02 |
| ES2234509T3 (es) | 2005-07-01 |
| US6432860B1 (en) | 2002-08-13 |
| US6855782B2 (en) | 2005-02-15 |
| JP2000273112A (ja) | 2000-10-03 |
| EP1038885B1 (de) | 2005-01-12 |
| DE60017306D1 (de) | 2005-02-17 |
| KR20000062971A (ko) | 2000-10-25 |
| KR100586358B1 (ko) | 2006-06-08 |
| US20020147105A1 (en) | 2002-10-10 |
| TWI252236B (en) | 2006-04-01 |
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