ATE293493T1 - Saure aktivierung von ruthenium-metathese- katalysatoren und lebende romp in wasser - Google Patents

Saure aktivierung von ruthenium-metathese- katalysatoren und lebende romp in wasser

Info

Publication number
ATE293493T1
ATE293493T1 AT98956491T AT98956491T ATE293493T1 AT E293493 T1 ATE293493 T1 AT E293493T1 AT 98956491 T AT98956491 T AT 98956491T AT 98956491 T AT98956491 T AT 98956491T AT E293493 T1 ATE293493 T1 AT E293493T1
Authority
AT
Austria
Prior art keywords
water
romp
acid
reactions
ruthenium
Prior art date
Application number
AT98956491T
Other languages
English (en)
Inventor
David M Lynn
Eric L Dias
Robert H Grubbs
Bernhard Mohr
Original Assignee
California Inst Of Techn
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by California Inst Of Techn filed Critical California Inst Of Techn
Application granted granted Critical
Publication of ATE293493T1 publication Critical patent/ATE293493T1/de

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/04—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing carboxylic acids or their salts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
    • B01J31/223—At least two oxygen atoms present in one at least bidentate or bridging ligand
    • B01J31/2234—Beta-dicarbonyl ligands, e.g. acetylacetonates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
    • B01J31/2243—At least one oxygen and one nitrogen atom present as complexing atoms in an at least bidentate or bridging ligand
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2265—Carbenes or carbynes, i.e.(image)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C6/00—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
    • C07C6/02—Metathesis reactions at an unsaturated carbon-to-carbon bond
    • C07C6/04—Metathesis reactions at an unsaturated carbon-to-carbon bond at a carbon-to-carbon double bond
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/10—Polymerisation reactions involving at least dual use catalysts, e.g. for both oligomerisation and polymerisation
    • B01J2231/14—Other (co) polymerisation, e.g. of lactides or epoxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/50—Redistribution or isomerisation reactions of C-C, C=C or C-C triple bonds
    • B01J2231/54—Metathesis reactions, e.g. olefin metathesis
    • B01J2231/543—Metathesis reactions, e.g. olefin metathesis alkene metathesis
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/821—Ruthenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/90—Catalytic systems characterized by the solvent or solvent system used
    • B01J2531/96—Water
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2540/00—Compositional aspects of coordination complexes or ligands in catalyst systems
    • B01J2540/40—Non-coordinating groups comprising nitrogen
    • B01J2540/42—Quaternary ammonium groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • C07C2531/22—Organic complexes
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S585/00—Chemistry of hydrocarbon compounds
    • Y10S585/929—Special chemical considerations
    • Y10S585/94—Opening of hydrocarbon ring

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Catalysts (AREA)
  • Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Graft Or Block Polymers (AREA)
  • Saccharide Compounds (AREA)
AT98956491T 1997-10-30 1998-10-30 Saure aktivierung von ruthenium-metathese- katalysatoren und lebende romp in wasser ATE293493T1 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US6440597P 1997-10-30 1997-10-30
US09/183,025 US6284852B1 (en) 1997-10-30 1998-10-29 Acid activation of ruthenium metathesis catalysts and living ROMP metathesis polymerization in water
PCT/US1998/023343 WO1999022865A1 (en) 1997-10-30 1998-10-30 Acid activation of ruthenium metathesis catalysts and living romp metathesis polymerization in water

Publications (1)

Publication Number Publication Date
ATE293493T1 true ATE293493T1 (de) 2005-05-15

Family

ID=26744483

Family Applications (1)

Application Number Title Priority Date Filing Date
AT98956491T ATE293493T1 (de) 1997-10-30 1998-10-30 Saure aktivierung von ruthenium-metathese- katalysatoren und lebende romp in wasser

Country Status (7)

Country Link
US (2) US6284852B1 (de)
EP (1) EP1056538B1 (de)
JP (2) JP4554072B2 (de)
AT (1) ATE293493T1 (de)
AU (1) AU1300699A (de)
DE (1) DE69829882T2 (de)
WO (1) WO1999022865A1 (de)

Families Citing this family (84)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6284852B1 (en) * 1997-10-30 2001-09-04 California Institute Of Technology Acid activation of ruthenium metathesis catalysts and living ROMP metathesis polymerization in water
EP1070091B1 (de) * 1998-03-31 2004-04-28 Ciba Specialty Chemicals Holding Inc. Ruthenium und osmium carben-carbonyl-katalysatoren
AU3535599A (en) * 1998-04-23 1999-11-08 Hitachi Chemical Company, Ltd. Curable molding material and method for producing molded article
KR100372985B1 (ko) * 1998-05-14 2003-02-25 히다치 가세고교 가부시끼가이샤 수지 조성물 및 이를 사용한 경화물의 제조법
EP2000803A1 (de) 1998-11-30 2008-12-10 Nanosphere, Inc. Nanoteilchen mit Polymerschalen
US8133421B2 (en) * 1999-02-23 2012-03-13 Warsaw Orthopedic, Inc. Methods of making shaped load-bearing osteoimplant
US20030135080A1 (en) * 1999-12-21 2003-07-17 Botha Jan Mattheus Metathesis process for converting short chain olefins to longer chain olefins
US6884859B2 (en) * 2001-08-29 2005-04-26 California Institute Of Technology Ring-opening metathesis polymerization of bridged bicyclic and polycyclic olefins containing two or more heteroatoms
ATE348835T1 (de) * 2002-01-22 2007-01-15 Univ Gent Metallkomplexe für die metathese
CA2512815A1 (en) * 2003-01-13 2004-07-29 Cargill, Incorporated Method for making industrial chemicals
EP1855861A4 (de) * 2003-07-18 2010-12-01 Univ Northwestern Oberflächen- und ortsspezifische polymerisierung durch direktschreibe-lithographie
US7250523B2 (en) * 2003-10-22 2007-07-31 Board Of Trustees Of Michigan State University Imido-tethered carbenes of molybdenum for ring-opening metathesis polymerization and ring-closing metathesis
US7132565B2 (en) * 2004-02-13 2006-11-07 National Taiwan University Of Science & Technology Norbornene compounds with cross-linkable groups and their derivatives
PL1577282T3 (pl) * 2004-02-26 2011-11-30 Rimtec Corp Kompleksy metali do stosowania w metatezie olefin i reakcjach przeniesienia atomu lub grupy
US20070185343A1 (en) * 2004-02-26 2007-08-09 Universiteit Gent Metal complexes for use in olefin metathesis and atom group transfer reactions
US8461223B2 (en) * 2005-04-07 2013-06-11 Aspen Aerogels, Inc. Microporous polycyclopentadiene-based aerogels
ATE496057T1 (de) * 2005-08-22 2011-02-15 Telene Sas Vielfachkoordinierte metal-komplexe zur verwendung in metathese-reaktionen
GB0517137D0 (en) 2005-08-22 2005-09-28 Viacatt N V Multicoordinated metal complexes for use in metalthesis reactions
ES2288370B1 (es) * 2005-09-21 2009-04-01 Universidad De Almeria Nuevos catalizadores para la metatesis de olefinas en medio acuoso.
WO2007081987A2 (en) * 2006-01-10 2007-07-19 Elevance Renewable Sciences, Inc. Method of making hydrogenated metathesis products
EP2046719B1 (de) * 2006-07-12 2013-09-04 Elevance Renewable Sciences, Inc. Ringöffnungs-kreuzmetathese zyklischer olefine mit samenölen und dergleichen
WO2008010961A2 (en) 2006-07-13 2008-01-24 Elevance Renewable Sciences, Inc. Synthesis of terminal alkenes from internal alkenes and ethylene via olefin metathesis
CN101558027B (zh) * 2006-10-13 2013-10-16 埃莱文斯可更新科学公司 通过复分解反应制备α，ω-二羧酸烯烃衍生物的方法
WO2008048520A2 (en) 2006-10-13 2008-04-24 Elevance Renewable Sciences, Inc. Methods of making organic compounds by metathesis and hydrocyanation
CN102123979A (zh) 2006-10-13 2011-07-13 埃莱文斯可更新科学公司 通过烯烃复分解由内烯烃合成末端烯烃的方法
US20080306230A1 (en) * 2007-06-07 2008-12-11 General Electric Company Composition and Associated Method
US8188823B2 (en) * 2007-09-21 2012-05-29 Abb Technology Ag Dry-type transformer with a polymer shield case and a method of manufacturing the same
US7915318B2 (en) * 2008-09-09 2011-03-29 General Electric Company Aqueous ROMP-based monolith materials and methods for making
MY156576A (en) 2008-11-26 2016-03-15 Elevance Renewable Sciences Methods of producing jet fuel from natural oil feedstocks through metathesis reactions
US8889932B2 (en) 2008-11-26 2014-11-18 Elevance Renewable Sciences, Inc. Methods of producing jet fuel from natural oil feedstocks through oxygen-cleaved reactions
EP2280017B1 (de) 2009-07-21 2013-01-02 Rimtec Corporation Katalytischer Komplex für Olefin-Metathesenreaktionen, Herstellungsverfahren und Verwendung davon
US9222056B2 (en) 2009-10-12 2015-12-29 Elevance Renewable Sciences, Inc. Methods of refining natural oils, and methods of producing fuel compositions
US9382502B2 (en) 2009-10-12 2016-07-05 Elevance Renewable Sciences, Inc. Methods of refining and producing isomerized fatty acid esters and fatty acids from natural oil feedstocks
PL2488474T3 (pl) 2009-10-12 2017-07-31 Elevance Renewable Sciences, Inc. Sposoby rafinacji i wytwarzania paliw z surowców na bazie olejów naturalnych
US9051519B2 (en) 2009-10-12 2015-06-09 Elevance Renewable Sciences, Inc. Diene-selective hydrogenation of metathesis derived olefins and unsaturated esters
US9175231B2 (en) 2009-10-12 2015-11-03 Elevance Renewable Sciences, Inc. Methods of refining natural oils and methods of producing fuel compositions
US9169447B2 (en) 2009-10-12 2015-10-27 Elevance Renewable Sciences, Inc. Methods of refining natural oils, and methods of producing fuel compositions
US8735640B2 (en) 2009-10-12 2014-05-27 Elevance Renewable Sciences, Inc. Methods of refining and producing fuel and specialty chemicals from natural oil feedstocks
US9000246B2 (en) 2009-10-12 2015-04-07 Elevance Renewable Sciences, Inc. Methods of refining and producing dibasic esters and acids from natural oil feedstocks
US9365487B2 (en) 2009-10-12 2016-06-14 Elevance Renewable Sciences, Inc. Methods of refining and producing dibasic esters and acids from natural oil feedstocks
WO2011051374A1 (de) 2009-11-02 2011-05-05 Basf Se Verfahren zur herstellung einer wässrigen polymerisatdispersion
WO2012076426A1 (de) * 2010-12-08 2012-06-14 Basf Se Verfahren zur herstellung einer wässrigen polymerisatdispersion
US20120149840A1 (en) * 2010-12-08 2012-06-14 Univ. of Southern Mississippi Res. Foundation Process for producing an aqueous polymer dispersion
US9597674B2 (en) * 2011-01-14 2017-03-21 California Institute Of Technology Z-selective olefin metathesis catalysts and their synthetic procedure
IN2014DN00290A (de) 2011-06-17 2015-06-05 Materia Inc
US9169174B2 (en) 2011-12-22 2015-10-27 Elevance Renewable Sciences, Inc. Methods for suppressing isomerization of olefin metathesis products
US9133416B2 (en) 2011-12-22 2015-09-15 Elevance Renewable Sciences, Inc. Methods for suppressing isomerization of olefin metathesis products
US9139493B2 (en) 2011-12-22 2015-09-22 Elevance Renewable Sciences, Inc. Methods for suppressing isomerization of olefin metathesis products
KR20130073822A (ko) * 2011-12-23 2013-07-03 가부시키가이샤 한도오따이 에네루기 켄큐쇼 이온 액체, 비수 전해질 및 축전 장치
PL230302B1 (pl) * 2012-02-27 2018-10-31 Apeiron Synthesis Spolka Z Ograniczona Odpowiedzialnoscia Katalizatory metatezy zawierające grupy oniowe
US9234985B2 (en) 2012-08-01 2016-01-12 California Institute Of Technology Birefringent polymer brush structures formed by surface initiated ring-opening metathesis polymerization
WO2014022482A1 (en) 2012-08-01 2014-02-06 California Institute Of Technology Solvent-free enyne metathesis polymerization
US9207532B2 (en) 2012-10-05 2015-12-08 California Institute Of Technology Photoinitiated olefin methathesis polymerization
US9388098B2 (en) 2012-10-09 2016-07-12 Elevance Renewable Sciences, Inc. Methods of making high-weight esters, acids, and derivatives thereof
US9527982B2 (en) 2012-12-19 2016-12-27 Materia, Inc. Storage stable adhesion promoter compositions for cyclic olefin resin compositions
US9598531B2 (en) * 2013-02-27 2017-03-21 Materia, Inc. Olefin metathesis catalyst compositions comprising at least two metal carbene olefin metathesis catalysts
CN105229040B (zh) 2013-02-27 2017-05-31 马特里亚公司 金属卡宾烯烃易位双催化剂组合物
US9803046B2 (en) 2013-03-15 2017-10-31 Materia, Inc. In-mold coating of ROMP polymers
BR112015025850B1 (pt) 2013-04-09 2021-11-03 Materia, Inc Método para produzir pelo menos um produto de metátese cruzada
CA2915486C (en) 2013-06-24 2023-01-03 Materia, Inc. Thermal insulation
CN105492489B (zh) 2013-07-03 2017-06-13 马特里亚公司 液体模制组合物
WO2015035097A1 (en) 2013-09-04 2015-03-12 California Institute Of Technology Functionalized linear and cyclic polyolefins
JP6273749B2 (ja) * 2013-10-04 2018-02-07 国立大学法人山口大学 ネットワークポリマー及びポリマーゲル電解質
EP3063592B1 (de) 2013-10-30 2021-04-07 California Institute of Technology Direkte fotostrukturierung von robusten und unterschiedlichen materialien
US10633484B2 (en) 2014-01-10 2020-04-28 Materia, Inc. Method and composition for improving adhesion of metathesis compositions to substrates
WO2015130802A1 (en) 2014-02-27 2015-09-03 Materia, Inc. Adhesion promoter compositions for cyclic olefin resin compositions
CN104003926B (zh) * 2014-05-30 2016-06-15 天津大学 基于烷基铵盐的侧链型磁性单体、聚合物及其制备方法和应用
RU2674471C2 (ru) 2014-07-03 2018-12-11 Гуан Мин Инновейшн Компани (Ухань) Катализаторы на основе переходного металла 8 группы, способ их получения и способ их применения в реакции метатезиса
JP6633070B2 (ja) 2014-10-21 2020-01-22 ストラタシス リミテッド 開環メタセシス重合を用いた三次元インクジェット印刷
CN107207679A (zh) 2015-02-12 2017-09-26 马特里亚公司 包含官能弹性体的环烯烃树脂组合物
US10344118B2 (en) 2015-02-14 2019-07-09 Materia, Inc. Romp polymers having improved resistance to hydrocarbon fluids
WO2017134674A1 (en) 2016-02-05 2017-08-10 Stratasys Ltd. Three-dimensional inkjet printing using ring-opening metathesis polymerization
WO2017134672A2 (en) 2016-02-05 2017-08-10 Stratasys Ltd. Three-dimensional inkjet printing using polyamide-forming materials
EP3411218B1 (de) 2016-02-07 2025-04-30 Stratasys Ltd. Dreidimensionales drucken mit kombination aus ringöffnungsmetathese-polymerisation und radikalischer polymerisation
US11118004B2 (en) 2016-04-26 2021-09-14 Stratasys Ltd. Three-dimensional inkjet printing using ring-opening metathesis polymerization
CN109982995B (zh) 2016-09-23 2022-09-30 优美科股份公司及两合公司 氨基酸和氨基酸衍生物的制备
TWI758525B (zh) * 2017-08-10 2022-03-21 日商住友電木股份有限公司 作為光學材料之聚環烯烴聚合物組成物
TWI777027B (zh) * 2018-01-26 2022-09-11 日商住友電木股份有限公司 聚環烯烴單體及由能夠產生光酸作為光學材料的化合物活化之催化劑
PL429476A1 (pl) 2019-04-02 2020-10-05 Apeiron Synthesis Spółka Akcyjna Nowe zastosowanie kompleksów metali posiadających ligandy organiczne do aktywacji rutenowych (pre)katalizatorów metatezy olefin
WO2021074734A1 (en) 2019-10-14 2021-04-22 3M Innovative Properties Company Compositions comprising cyclic olefins and thermally conductive filler
KR102915528B1 (ko) 2019-12-20 2026-01-21 쓰리엠 이노베이티브 프로퍼티즈 캄파니 중합체 및 중합성 환형 올레핀을 포함하는 접착제 물품, 접착제 조성물 및 방법
WO2021124156A1 (en) * 2019-12-20 2021-06-24 3M Innovative Properties Company Method of pattern coating adhesive composition comprising unpolymerized cyclic olefin and latent catalyst, adhesive compositions and articles
JP2024522319A (ja) * 2021-05-19 2024-06-17 ビーエーエスエフ ソシエタス・ヨーロピア Ｌ－イジトールの合成方法、及び触媒のリサイクル
US11667731B2 (en) 2021-06-30 2023-06-06 Promerus, Llc Stabilized UV active organopalladium compounds as vinyl addition catalysts

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1253156A3 (de) * 1992-04-03 2004-01-07 California Institute Of Technology Hochwirksame Ruthenium- oder Osmium- Metall-Carben-Komplexe für Olefinmetathesereaktionen, und deren Herstellung und Verwendung
US5710298A (en) 1992-04-03 1998-01-20 California Institute Of Technology Method of preparing ruthenium and osmium carbene complexes
US5312940A (en) * 1992-04-03 1994-05-17 California Institute Of Technology Ruthenium and osmium metal carbene complexes for olefin metathesis polymerization
JPH10508892A (ja) * 1994-11-17 1998-09-02 チバ スペシャルティ ケミカルズ ホールディング インコーポレーテッド 重合可能な組成物および環状オレフィンを重合させる方法
US6235856B1 (en) * 1994-12-23 2001-05-22 Ciba Specialty Chemicals Corporation Polymerization of dicyclopentadiene
US5831108A (en) 1995-08-03 1998-11-03 California Institute Of Technology High metathesis activity ruthenium and osmium metal carbene complexes
JPH09183832A (ja) * 1995-12-28 1997-07-15 Nippon Zeon Co Ltd 成形材料
US6020443A (en) * 1996-02-08 2000-02-01 Advanced Polymer Technologies, Inc. Polymerization of low grade DCPD monomers using an olefin metathesis catalyst
US6284852B1 (en) * 1997-10-30 2001-09-04 California Institute Of Technology Acid activation of ruthenium metathesis catalysts and living ROMP metathesis polymerization in water

Also Published As

Publication number Publication date
AU1300699A (en) 1999-05-24
EP1056538B1 (de) 2005-04-20
DE69829882D1 (de) 2005-05-25
WO1999022865A1 (en) 1999-05-14
JP4554072B2 (ja) 2010-09-29
EP1056538A1 (de) 2000-12-06
EP1056538A4 (de) 2002-12-04
JP2002516911A (ja) 2002-06-11
DE69829882T2 (de) 2006-03-09
JP2010138413A (ja) 2010-06-24
US6486279B2 (en) 2002-11-26
US6284852B1 (en) 2001-09-04
US20020055598A1 (en) 2002-05-09

Similar Documents

Publication Publication Date Title
DE69829882D1 (de) Saure aktivierung von ruthenium-metathese-katalysatoren und lebende romp in wasser
Buchmeiser Recent advances in the synthesis of supported metathesis catalysts
Lozano-Vila et al. Ruthenium-based olefin metathesis catalysts derived from alkynes
Bruneau et al. Metal Vinylidenes and Allenylidenes in Catalysis: Applications in Anti‐Markovnikov Additions to Terminal Alkynes and Alkene Metathesis
Severin Ruthenium catalysts for the Kharasch reaction
CA2455893C (en) Hexacoordinated ruthenium or osmium metal carbene metathesis catalysts
ATE260938T1 (de) Ruthenium und osmium metallcarben-komplexe mit hoher metathese-aktivitat
Çetinkaya et al. Synthesis and catalytic properties of N-functionalized carbene complexes of rhodium (I) and ruthenium (II)
US7205424B2 (en) Preparation of ruthenium-based olefin metathesis catalysts
Wan et al. Ruthenium (II)-sulfonated BINAP: A novel water-soluble asymmetric hydrogenation catalyst.
ATE398133T1 (de) Mit triazolydin-liganden koordinierte rutheniummetall-alkyliden-komplexe die hohe olefin-metathese-aktivität aufweisen
Picquet et al. Room temperature operating allenylidene precatalyst [L n RuξCξCξCR 2]+ X-for olefin metathesis: dramatic influence of the counter anion X
EP2943499B1 (de) Katalysatorkomplexe mit carbenligand und verfahren zur herstellung davon und verwendung in metathesereaktion
DE69824314D1 (de) Derivate schiff'scher basen von ruthenium und osmium katalysatoren zur olefinmetathese
DE69806053D1 (de) Hochwirksame kationische ruthenium und osmiumkomplexe für die metathesereaktionen
KR20080103961A (ko) 유기금속 루테늄 착물, 및 사치환 및 기타 입체장애된올레핀의 제조를 위한 관련 방법
Smoleń et al. Ruthenium Complexes Bearing Thiophene‐Based Unsymmetrical N‐Heterocyclic Carbene Ligands as Selective Catalysts for Olefin Metathesis in Toluene and Environmentally Friendly 2‐Methyltetrahydrofuran
Endo et al. Investigations into ruthenium metathesis catalysts with six-membered chelating NHC ligands: Relationship between catalyst structure and stereoselectivity
Dragutan et al. Metathesis catalysed by the platinum group metals
EP1300410A3 (de) Neue Übergangsmetall-Komplexe mit Diamino-Carbenliganden und deren Einsatz in Übergangsmetallkatalysierten Reaktionen
Dragutan et al. Practical New Strategies for Immobilising Ruthenium Alkylidene Complexes: Part I
Lehtonen et al. New practical tungsten (VI) based catalyst systems for ring opening metathesis polymerisation
George Synthetic Routes to Metal Alkylidene Complexes that Catalyze Olefin Metathesis and the Utilization of [1.1. 1] Propellane as a Carbene Precursor
CA2352377A1 (en) Method of producing ruthenium complexes
Dixneuf et al. Ruthenium indenylidene catalysts for alkene metathesis

Legal Events

Date Code Title Description
RER Ceased as to paragraph 5 lit. 3 law introducing patent treaties