ATE294260T1 - Korrosionsschutzüberzüge für aluminium und aluminiumlegierungen - Google Patents
Korrosionsschutzüberzüge für aluminium und aluminiumlegierungenInfo
- Publication number
- ATE294260T1 ATE294260T1 AT01993197T AT01993197T ATE294260T1 AT E294260 T1 ATE294260 T1 AT E294260T1 AT 01993197 T AT01993197 T AT 01993197T AT 01993197 T AT01993197 T AT 01993197T AT E294260 T1 ATE294260 T1 AT E294260T1
- Authority
- AT
- Austria
- Prior art keywords
- aluminum
- water soluble
- aluminum substrates
- effective amounts
- trivalent chromium
- Prior art date
Links
- 229910052782 aluminium Inorganic materials 0.000 title abstract 5
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 title abstract 5
- 238000005260 corrosion Methods 0.000 title abstract 3
- 229910000838 Al alloy Inorganic materials 0.000 title abstract 2
- 239000000758 substrate Substances 0.000 abstract 3
- 230000007797 corrosion Effects 0.000 abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 2
- VVXLFFIFNVKFBD-UHFFFAOYSA-N 4,4,4-trifluoro-1-phenylbutane-1,3-dione Chemical compound FC(F)(F)C(=O)CC(=O)C1=CC=CC=C1 VVXLFFIFNVKFBD-UHFFFAOYSA-N 0.000 abstract 1
- 230000002378 acidificating effect Effects 0.000 abstract 1
- 229910052783 alkali metal Inorganic materials 0.000 abstract 1
- 150000001340 alkali metals Chemical class 0.000 abstract 1
- 239000007864 aqueous solution Substances 0.000 abstract 1
- 239000001913 cellulose Substances 0.000 abstract 1
- 229920002678 cellulose Polymers 0.000 abstract 1
- 150000001844 chromium Chemical class 0.000 abstract 1
- GRWVQDDAKZFPFI-UHFFFAOYSA-H chromium(III) sulfate Chemical compound [Cr+3].[Cr+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O GRWVQDDAKZFPFI-UHFFFAOYSA-H 0.000 abstract 1
- 238000000576 coating method Methods 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 239000003973 paint Substances 0.000 abstract 1
- 238000004381 surface treatment Methods 0.000 abstract 1
- 239000004094 surface-active agent Substances 0.000 abstract 1
- 239000002562 thickening agent Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/82—After-treatment
- C23C22/83—Chemical after-treatment
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
- C09D5/082—Anti-corrosive paints characterised by the anti-corrosive pigment
- C09D5/084—Inorganic compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
- C09D5/12—Wash primers
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/34—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing fluorides or complex fluorides
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2222/00—Aspects relating to chemical surface treatment of metallic material by reaction of the surface with a reactive medium
- C23C2222/10—Use of solutions containing trivalent chromium but free of hexavalent chromium
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Wood Science & Technology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Inorganic Chemistry (AREA)
- Chemical Treatment Of Metals (AREA)
- Paints Or Removers (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Laminated Bodies (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/702,225 US6375726B1 (en) | 2000-10-31 | 2000-10-31 | Corrosion resistant coatings for aluminum and aluminum alloys |
| PCT/US2001/045434 WO2002055758A2 (en) | 2000-10-31 | 2001-10-31 | Corrosion resistant coatings for aluminum and aluminum alloys |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ATE294260T1 true ATE294260T1 (de) | 2005-05-15 |
Family
ID=24820331
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AT01993197T ATE294260T1 (de) | 2000-10-31 | 2001-10-31 | Korrosionsschutzüberzüge für aluminium und aluminiumlegierungen |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US6375726B1 (de) |
| EP (1) | EP1404894B1 (de) |
| JP (1) | JP4391085B2 (de) |
| CN (1) | CN1252314C (de) |
| AT (1) | ATE294260T1 (de) |
| CA (1) | CA2425661C (de) |
| DE (1) | DE60110470T2 (de) |
| ES (1) | ES2241898T3 (de) |
| WO (1) | WO2002055758A2 (de) |
Families Citing this family (54)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7314671B1 (en) | 1996-04-19 | 2008-01-01 | Surtec International Gmbh | Chromium(VI)-free conversion layer and method for producing it |
| DE19615664A1 (de) | 1996-04-19 | 1997-10-23 | Surtec Produkte Und Systeme Fu | Chrom(VI)freie Chromatschicht sowie Verfahren zu ihrer Herstellung |
| US6669764B1 (en) * | 2000-10-31 | 2003-12-30 | The United States Of America As Represented By The Secretary Of The Navy | Pretreatment for aluminum and aluminum alloys |
| US6511532B2 (en) * | 2000-10-31 | 2003-01-28 | The United States Of America As Represented By The Secretary Of The Navy | Post-treatment for anodized aluminum |
| US6521029B1 (en) * | 2000-10-31 | 2003-02-18 | The United States Of America As Represented By The Secretary Of The Navy | Pretreatment for aluminum and aluminum alloys |
| US6663700B1 (en) * | 2000-10-31 | 2003-12-16 | The United States Of America As Represented By The Secretary Of The Navy | Post-treatment for metal coated substrates |
| US6527841B2 (en) * | 2000-10-31 | 2003-03-04 | The United States Of America As Represented By The Secretary Of The Navy | Post-treatment for metal coated substrates |
| US6887321B2 (en) * | 2002-05-22 | 2005-05-03 | United Technologies Corporation | Corrosion resistant surface treatment for structural adhesive bonding to metal |
| US8142841B2 (en) * | 2003-12-18 | 2012-03-27 | Henkel Kgaa | Apparatus and methods for deoxidizing metal surfaces |
| US20050213493A1 (en) * | 2004-03-09 | 2005-09-29 | Nelson Westin W | Drive mounting system |
| US7452427B2 (en) * | 2004-12-01 | 2008-11-18 | Deft, Inc. | Corrosion resistant conversion coatings |
| US8277688B2 (en) * | 2011-01-21 | 2012-10-02 | The United States Of America As Represented By The Secretary Of The Navy | Aluminum alloy coated pigments and corrosion-resistant coatings |
| US20070095436A1 (en) * | 2005-11-01 | 2007-05-03 | The U.S. Of America As Represented By The Secretary Of The Navy | Non-chromium coatings for aluminum |
| US20070095437A1 (en) * | 2005-11-01 | 2007-05-03 | The U.S. Of America As Represented By The Secretarty Of The Navy | Non-chromium conversion coatings for ferrous alloys |
| US20070099022A1 (en) * | 2005-11-01 | 2007-05-03 | The U.S. Of America As Represented By The Secretary Of The Navy | Non-chromium post-treatment for aluminum coated steel |
| CN101384751B (zh) * | 2006-02-14 | 2013-01-02 | 汉高股份及两合公司 | 在金属表面上使用的原地干燥的三价铬抗腐蚀涂料的组合物与方法 |
| DE202006019880U1 (de) | 2006-02-24 | 2007-09-27 | Gerhard Heiche Gmbh | Korrosionsbeständiges Substrat |
| EP2044239B1 (de) * | 2006-05-10 | 2014-09-03 | Henkel AG & Co. KGaA | Verfahren zur herstellung einer korrosionsbeständigen metalloberflächenbeschichtung unter verwendung einer verbesserten dreiwertigen chromhaltigen zusammensetzung |
| DE102006031492A1 (de) | 2006-07-06 | 2008-01-10 | Gerhard Heiche Gmbh | Korrosionsbeständiges Substrat und Verfahren zu dessen Herstellung |
| US20090242081A1 (en) * | 2008-03-26 | 2009-10-01 | Richard Bauer | Aluminum Treatment Composition |
| US20110070429A1 (en) * | 2009-09-18 | 2011-03-24 | Thomas H. Rochester | Corrosion-resistant coating for active metals |
| US20110206844A1 (en) * | 2010-02-24 | 2011-08-25 | Jacob Grant Wiles | Chromium-free passivation of vapor deposited aluminum surfaces |
| US9347134B2 (en) | 2010-06-04 | 2016-05-24 | Prc-Desoto International, Inc. | Corrosion resistant metallate compositions |
| US20110300406A1 (en) | 2010-06-04 | 2011-12-08 | Allfast Fastening Systems, Inc. | Painted metal parts with non-hexavalent chromium chemical conversion coating and process |
| US8574396B2 (en) | 2010-08-30 | 2013-11-05 | United Technologies Corporation | Hydration inhibitor coating for adhesive bonds |
| US20140017409A1 (en) | 2011-03-30 | 2014-01-16 | Mahindra & Mahindra Limited | Corrosion resistance passivation formulation and process of preparation thereof |
| EP2825691B1 (de) | 2012-03-15 | 2021-05-26 | Carrier Corporation | Mehrschichtige schutzschicht für einen aluminiumwärmetauscher |
| EP2711444A1 (de) | 2012-09-20 | 2014-03-26 | Coventya SAS | Wässrige Alkalinlösung zum Verbessern der Korrosionsbeständigkeit einer Cr(III)-Umwandlungsbeschichtung und Verfahren zum Herstellen der Beschichtung und ihre Verwendung |
| DE102012021241A1 (de) * | 2012-10-29 | 2014-04-30 | Airbus Operations Gmbh | Zusammensetzung für die lokale Applikation von chemischen Konversionsschichten |
| CN102982860A (zh) * | 2012-11-28 | 2013-03-20 | 安徽埃克森科技集团有限公司 | 一种防冻电缆芯及其制备方法 |
| CN103993304A (zh) * | 2013-02-17 | 2014-08-20 | 武汉风帆电镀技术股份有限公司 | 一种铝及铝合金的三价铬前处理液 |
| CN103132067B (zh) * | 2013-02-17 | 2015-03-04 | 武汉风帆电镀技术股份有限公司 | 铝及铝合金表面用前处理剂 |
| CN103993303A (zh) * | 2013-02-17 | 2014-08-20 | 武汉风帆电镀技术股份有限公司 | 铝及铝合金的三价铬耐蚀性钝化液 |
| ES2835811T3 (es) | 2013-03-01 | 2021-06-23 | Carrier Corp | Intercambiador de calor de aluminio con revestimiento resistente a la corrosión |
| US10156016B2 (en) | 2013-03-15 | 2018-12-18 | Henkel Ag & Co. Kgaa | Trivalent chromium-containing composition for aluminum and aluminum alloys |
| CN103526254A (zh) * | 2013-10-11 | 2014-01-22 | 上海英汇科技发展有限公司 | 一种耐酸性气候腐蚀的本色阳极氧化薄膜处理工艺 |
| CN104109849A (zh) * | 2014-06-19 | 2014-10-22 | 锐展(铜陵)科技有限公司 | 一种稳定高附着的铝合金表面处理剂 |
| CN104109850A (zh) * | 2014-06-19 | 2014-10-22 | 锐展(铜陵)科技有限公司 | 一种耐盐雾铝合金表面处理剂 |
| TWI673391B (zh) * | 2014-12-26 | 2019-10-01 | 日商迪普索股份有限公司 | 鋅或鋅合金基材用之3價鉻化學轉換處理液及化學轉換被膜 |
| WO2017011503A1 (en) * | 2015-07-15 | 2017-01-19 | Siqing Song-Destro | Method of manufacture and applications for fire retardant, heat, fungi, and insect resistant, and strength enhancing additive |
| US10435806B2 (en) | 2015-10-12 | 2019-10-08 | Prc-Desoto International, Inc. | Methods for electrolytically depositing pretreatment compositions |
| US20170327955A1 (en) | 2016-05-10 | 2017-11-16 | Hamilton Sundstrand Corporation | Conversion coating treatment |
| FR3053352A1 (fr) | 2016-07-04 | 2018-01-05 | Airbus Safran Launchers Sas | Composition de protection anticorrosion |
| US10274468B2 (en) | 2016-11-16 | 2019-04-30 | Raytheon Company | Methods and kit for determining presence of trivalent chromium conversion coating |
| EP4092087B1 (de) | 2017-02-01 | 2025-08-13 | Chemeon Surface Technology, LLC | Gefärbte trivalente chromumwandlungsbeschichtungen und verfahren zu ihrer verwendung |
| US20180320282A1 (en) | 2017-05-05 | 2018-11-08 | Hamilton Sundstrand Corporation | Method of making aluminum-coated metal |
| CN111670266A (zh) | 2018-01-30 | 2020-09-15 | Prc-迪索托国际公司 | 用于处理金属基材的系统和方法 |
| CN108838050A (zh) * | 2018-07-16 | 2018-11-20 | 苏州艾斯肯机电设备有限公司 | 一种机电制品用防腐蚀处理工艺 |
| US10662338B2 (en) * | 2018-09-06 | 2020-05-26 | The United States Of America As Represented By The Secretary Of The Navy | Passive coatings for bulk aluminum and powder pigments |
| CN109518174B (zh) * | 2019-01-10 | 2021-01-01 | 廊坊师范学院 | 铝材涂装前表面处理液的制备工艺 |
| FR3106838B1 (fr) * | 2020-01-31 | 2022-01-14 | Safran Aircraft Engines | Procede de colmatage des alliages d’aluminium |
| FR3117131B1 (fr) * | 2020-12-03 | 2022-12-09 | Safran Electronics & Defense | Procede de protection d’une piece en alliage a base d’aluminium |
| DE102022105844A1 (de) | 2022-03-14 | 2023-09-14 | Carl Freudenberg Kg | Passivierungsschicht für metallhaltige Substrate |
| US20240125567A1 (en) * | 2022-10-13 | 2024-04-18 | Modine Manufacturing Company | Waterborne top coatings for aluminum heat exchangers |
Family Cites Families (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3539403A (en) * | 1966-12-07 | 1970-11-10 | Collardin Gmbh Gerhard | Solutions for the deposition of protective layers on zinc surfaces and process therefor |
| US3986970A (en) * | 1973-05-02 | 1976-10-19 | The Furukawa Electric Co., Ltd. | Solution for chemical dissolution treatment of tin or alloys thereof |
| US3912548A (en) | 1973-07-13 | 1975-10-14 | Amchem Prod | Method for treating metal surfaces with compositions comprising zirconium and a polymer |
| US4148670A (en) | 1976-04-05 | 1979-04-10 | Amchem Products, Inc. | Coating solution for metal surface |
| US4273592A (en) | 1979-12-26 | 1981-06-16 | Amchem Products, Inc. | Coating solution for metal surfaces |
| CA1162504A (en) | 1980-11-25 | 1984-02-21 | Mobuyuki Oda | Treating tin plated steel sheet with composition containing titanium or zirconium compounds |
| JPS61587A (ja) * | 1984-06-12 | 1986-01-06 | C Uyemura & Co Ltd | 化成処理液 |
| SU1450400A1 (ru) * | 1984-12-03 | 1990-11-07 | Институт Химии И Химической Технологии Ан Литсср | Раствор дл хроматировани цинковой поверхности |
| SU1448767A1 (ru) * | 1984-12-03 | 1990-11-07 | Институт Химии И Химической Технологии Ан Литсср | Раствор дл хромировани кадмиевой поверхности |
| JPS6256580A (ja) * | 1985-09-05 | 1987-03-12 | Nippon Parkerizing Co Ltd | 亜鉛系メツキ鋼板のクロメ−ト塗布液 |
| GB8802788D0 (en) | 1988-02-08 | 1988-03-09 | Brent Chemicals Int | Composition & process for treating metal surfaces |
| US4921552A (en) | 1988-05-03 | 1990-05-01 | Betz Laboratories, Inc. | Composition and method for non-chromate coating of aluminum |
| JPH07100873B2 (ja) * | 1989-09-27 | 1995-11-01 | 日本パーカライジング株式会社 | 亜鉛系メッキ鋼板のクロメート塗布液 |
| JPH04193957A (ja) | 1990-11-28 | 1992-07-14 | Nippon Parkerizing Co Ltd | クリヤー塗装下地用クロメート処理液 |
| US5226976A (en) | 1991-04-15 | 1993-07-13 | Henkel Corporation | Metal treatment |
| US5304257A (en) | 1993-09-27 | 1994-04-19 | The United States Of America As Represented By The Secretary Of The Navy | Trivalent chromium conversion coatings for aluminum |
| EP0915996A4 (de) * | 1996-04-26 | 2001-06-13 | Henkel Corp | Chromatpassivierung und einlagerungsbeständige konzentratlösung dafür |
| AU757539B2 (en) * | 1997-08-21 | 2003-02-27 | Henkel Kommanditgesellschaft Auf Aktien | Process for coating and/or touching up coatings on metal surfaces |
-
2000
- 2000-10-31 US US09/702,225 patent/US6375726B1/en not_active Expired - Lifetime
-
2001
- 2001-10-31 JP JP2002556402A patent/JP4391085B2/ja not_active Expired - Lifetime
- 2001-10-31 CA CA2425661A patent/CA2425661C/en not_active Expired - Lifetime
- 2001-10-31 ES ES01993197T patent/ES2241898T3/es not_active Expired - Lifetime
- 2001-10-31 DE DE60110470T patent/DE60110470T2/de not_active Expired - Lifetime
- 2001-10-31 CN CNB018183646A patent/CN1252314C/zh not_active Expired - Lifetime
- 2001-10-31 AT AT01993197T patent/ATE294260T1/de not_active IP Right Cessation
- 2001-10-31 EP EP01993197A patent/EP1404894B1/de not_active Expired - Lifetime
- 2001-10-31 WO PCT/US2001/045434 patent/WO2002055758A2/en not_active Ceased
Also Published As
| Publication number | Publication date |
|---|---|
| US6375726B1 (en) | 2002-04-23 |
| DE60110470T2 (de) | 2006-01-26 |
| DE60110470D1 (de) | 2005-06-02 |
| EP1404894A2 (de) | 2004-04-07 |
| JP2004529265A (ja) | 2004-09-24 |
| EP1404894B1 (de) | 2005-04-27 |
| JP4391085B2 (ja) | 2009-12-24 |
| CN1520467A (zh) | 2004-08-11 |
| CA2425661C (en) | 2011-09-27 |
| CA2425661A1 (en) | 2002-07-18 |
| WO2002055758A3 (en) | 2004-02-12 |
| WO2002055758A9 (en) | 2003-02-06 |
| CN1252314C (zh) | 2006-04-19 |
| ES2241898T3 (es) | 2005-11-01 |
| WO2002055758A2 (en) | 2002-07-18 |
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