ATE313567T1 - Polymerisationsverfahren unter verwendung von verbesserten sperrigen liganden metallocen- katalysatoren - Google Patents

Polymerisationsverfahren unter verwendung von verbesserten sperrigen liganden metallocen- katalysatoren

Info

Publication number
ATE313567T1
ATE313567T1 AT99945045T AT99945045T ATE313567T1 AT E313567 T1 ATE313567 T1 AT E313567T1 AT 99945045 T AT99945045 T AT 99945045T AT 99945045 T AT99945045 T AT 99945045T AT E313567 T1 ATE313567 T1 AT E313567T1
Authority
AT
Austria
Prior art keywords
polymerization process
bulky ligand
ligand metallocene
metallocene catalysts
improved bulky
Prior art date
Application number
AT99945045T
Other languages
English (en)
Inventor
Laughlin G Mccullough
Original Assignee
Univation Tech Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Univation Tech Llc filed Critical Univation Tech Llc
Application granted granted Critical
Publication of ATE313567T1 publication Critical patent/ATE313567T1/de

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Polymerization Catalysts (AREA)
AT99945045T 1998-08-21 1999-08-12 Polymerisationsverfahren unter verwendung von verbesserten sperrigen liganden metallocen- katalysatoren ATE313567T1 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US9740198P 1998-08-21 1998-08-21
US09/191,916 US6632901B2 (en) 1998-08-21 1998-11-13 Polymerization process using an improved bulky ligand metallocene-type catalyst system
PCT/US1999/018368 WO2000011047A1 (en) 1998-08-21 1999-08-12 Polymerization process using an improved bulky ligand metallocene-type catalyst system

Publications (1)

Publication Number Publication Date
ATE313567T1 true ATE313567T1 (de) 2006-01-15

Family

ID=26793216

Family Applications (1)

Application Number Title Priority Date Filing Date
AT99945045T ATE313567T1 (de) 1998-08-21 1999-08-12 Polymerisationsverfahren unter verwendung von verbesserten sperrigen liganden metallocen- katalysatoren

Country Status (10)

Country Link
US (1) US6632901B2 (de)
EP (1) EP1112293B1 (de)
JP (1) JP4234327B2 (de)
AT (1) ATE313567T1 (de)
AU (1) AU756665C (de)
BR (1) BR9913144B1 (de)
CA (1) CA2332045A1 (de)
DE (1) DE69929064T2 (de)
ES (1) ES2253909T3 (de)
WO (1) WO2000011047A1 (de)

Families Citing this family (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6894131B2 (en) * 1998-08-21 2005-05-17 Univation Technologies, Llc Polymerization process using a metallocene catalyst system
US6303718B1 (en) 1999-09-17 2001-10-16 Bayer Aktiengesellschaft Composition based on fluorine-containing metal complexes
JP2003505543A (ja) * 1999-07-14 2003-02-12 バイエル アクチェンゲゼルシャフト フッ素含有金属錯体をベースとする触媒系
GB0025195D0 (en) 2000-10-13 2000-11-29 Borealis Tech Oy Liquid container
US6841504B2 (en) * 2002-01-28 2005-01-11 Univation Technologies, Llc Polymerization catalyst activator and its use in a polymerization process
US6884748B2 (en) * 2002-09-04 2005-04-26 Univation Technologies, Llc Process for producing fluorinated catalysts
US6875828B2 (en) 2002-09-04 2005-04-05 Univation Technologies, Llc Bimodal polyolefin production process and films therefrom
US6753390B2 (en) 2002-09-04 2004-06-22 Univation Technologies, Llc Gas phase polymerization process
US8461072B2 (en) * 2002-10-25 2013-06-11 Exxonmobil Chemical Patents Inc. Late transition metal catalysts for olefin oligomerizations
US6869903B2 (en) 2002-11-07 2005-03-22 Univation Technologies, Llc Synthesis of polymerization catalyst components
US6890876B2 (en) * 2002-11-26 2005-05-10 Univation Technologies, Llc Processes for producing fluorided catalysts from nitrogenous metallocenes
US7244795B2 (en) * 2003-12-08 2007-07-17 Univation Technologies, Llc Polymerization process using metallocene catalyst systems
US7119153B2 (en) 2004-01-21 2006-10-10 Jensen Michael D Dual metallocene catalyst for producing film resins with good machine direction (MD) elmendorf tear strength
US6967184B2 (en) * 2004-02-17 2005-11-22 Univation Technologies, Llc Fluoroalcohol leaving group for non-metallocene olefin polymerization catalysts
US20070049711A1 (en) * 2005-09-01 2007-03-01 Chi-I Kuo Catalyst compositions comprising support materials having an improved particle-size distribution
KR101753549B1 (ko) 2009-06-16 2017-07-03 셰브론 필립스 케미컬 컴퍼니 엘피 메탈로센-ｓｓａ 촉매시스템을 이용한 알파 올레핀 올리고머화 및 윤활제 블렌드 제조를 위한 생성된 폴리알파올레핀의 용도
US20110082323A1 (en) * 2009-10-06 2011-04-07 Chevron Phillips Chemical Company Lp Oligomerization of olefin waxes using metallocene-based catalyst systems
DE102013005049A1 (de) 2013-03-22 2014-09-25 Unify Gmbh & Co. Kg Verfahren und Vorrichtung zur Steuerung einer Sprachkommunikation sowie Verwendung derselben
WO2015158790A2 (en) * 2014-04-17 2015-10-22 Borealis Ag Improved catalyst system for producing polyethylene copolymers in a high temperature solution polymerization process
US9732300B2 (en) 2015-07-23 2017-08-15 Chevron Phillipa Chemical Company LP Liquid propylene oligomers and methods of making same
WO2018022263A1 (en) 2016-07-29 2018-02-01 Exxonmobil Chemical Patents Inc. Polymerization processes using high molecular weight polyhydric quenching agents
KR102533626B1 (ko) 2021-03-29 2023-05-16 디엘케미칼 주식회사 폴리올레핀 수지 및 이의 제조 방법

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4588790A (en) 1982-03-24 1986-05-13 Union Carbide Corporation Method for fluidized bed polymerization
DE3678024D1 (de) 1985-03-26 1991-04-18 Mitsui Petrochemical Ind Fluessiges statisches ethylencopolymer, verfahren zur herstellung und anwendung desselben.
US4808561A (en) 1985-06-21 1989-02-28 Exxon Chemical Patents Inc. Supported polymerization catalyst
US4874880A (en) 1987-03-10 1989-10-17 Chisso Corporation Bis(di-, tri- or tetra-substituted-cyclopentadienyl)-zirconium dihalides
CA2071706C (en) 1991-06-20 1996-09-17 Junichi Imuta Catalyst for olefin polymerization, process for the polymerization of olefin, and transition metal compound employable for the catalyst
JP3077940B2 (ja) * 1993-04-26 2000-08-21 エクソン・ケミカル・パテンツ・インク 流動層重合法のための安定な操作条件を決定する方法
ES2156153T3 (es) 1993-06-15 2001-06-16 Idemitsu Kosan Co Procedimiento de produccion de polimero olefinico, y catalizador para la polimerizacion de una olefina.
DE4332009A1 (de) 1993-09-21 1995-03-30 Hoechst Ag Verfahren zur Herstellung von Organometallfluoriden
US5763543A (en) * 1994-09-14 1998-06-09 Exxon Chemical Patents Inc. Olefin polymerization process with little or no scavenger present
EP0857179A1 (de) 1995-08-18 1998-08-12 Basell Polyolefine GmbH Katalysatorkomponente und katalysatorsystem mit hoher polymerisationsaktivität zur herstellung von polymeren
DE19706027A1 (de) 1997-02-17 1998-08-20 Bayer Ag Titanocene für Lösungspolymerisation
EP0960144B1 (de) 1997-02-17 2002-05-29 Bayer Aktiengesellschaft Neues kalalysatorsystem, dessen verwendung zur polymerisation von dienen in lösung, suspension und gasphase und verwendung der somit herstellbaren dienkautschuke
US6303718B1 (en) 1999-09-17 2001-10-16 Bayer Aktiengesellschaft Composition based on fluorine-containing metal complexes

Also Published As

Publication number Publication date
BR9913144B1 (pt) 2009-08-11
CA2332045A1 (en) 2000-03-02
US6632901B2 (en) 2003-10-14
AU756665B2 (en) 2003-01-23
JP4234327B2 (ja) 2009-03-04
JP2002523530A (ja) 2002-07-30
DE69929064T2 (de) 2006-08-31
BR9913144A (pt) 2001-10-02
ES2253909T3 (es) 2006-06-01
AU756665C (en) 2004-01-08
EP1112293A1 (de) 2001-07-04
US20020032287A1 (en) 2002-03-14
DE69929064D1 (de) 2006-01-26
AU5774199A (en) 2000-03-14
WO2000011047A1 (en) 2000-03-02
EP1112293B1 (de) 2005-12-21

Similar Documents

Publication Publication Date Title
ATE313567T1 (de) Polymerisationsverfahren unter verwendung von verbesserten sperrigen liganden metallocen- katalysatoren
BR0016197A (pt) Sistema catalisador múltiplo
BR0016725A (pt) Sistema catalisador, uso do mesmo, e, processo para preparar poliolefinas
ATE297928T1 (de) Verbesserte verfahren zur herstellung von vernetzt verbrückten macropolycyclen
ATE227299T1 (de) Polymerisationskatalysator
TR200100010T2 (tr) Bir katalizör terkibi, ve bunu hazırlamak ve bir polimerizasyon işleminde kullanmak için yöntemler
TR200201083T2 (tr) Katalizör sistemleri ve bu sistemlerin bir polimerizasyon işleminde kullanımları.
ATE353333T1 (de) Metallocene
FI971565A7 (fi) Olefiinien polymerointiin tarkoitettujen katalysaattorisysteemien substituoituja metalloseeniyhdisteitä, niiden välituotteet ja valmistusmenetelmä
BR0017027A (pt) Método de polimerização
DE69919102D1 (de) Metallocenkatalysatoren für Olefinpolymerisation, Verfahren zur Herstellung von Olefinpolymeren mit Metallocenkatalysatoren
EA200401474A1 (ru) Способ получения катализатора полимеризации олефинов
ES2175066T3 (es) Antagonistas triciclicos de la vasopresina.
BR9906428A (pt) Componentes catalìticos, catalisador e processo para a (co)polimerização de olefinas ch2= chr
TR970073A2 (tr) Alfa adrenerjik resentör antagonistleri olarak pirimidindion pirimidintrion,triazindion, tetrahidrokinazolindion türevleri.
ATE424422T1 (de) Dual-site- olefinpolymerisationskatalysatorzusammensetzung
DE69903399D1 (de) Prepolymerisierte katalysatorkomponente für die polymerisierung von olefinen
DE69609186D1 (de) Verbrückte metallocenverbindungen, verfahren zu deren herstellung und deren verwendung als olefinpolymerisationskatalysator
IT1299068B1 (it) Legandi fosforati chirali e loro complessi organometallici, utili come catalizzatori in sintesi stereoselettive
DE69926339D1 (de) Verbrückte metallocene, herstellung und verwendung als olefinpolymerisationskatalysator
DE69708848D1 (de) Mischung von erdalkalialkylarylsulfonaten, ihre verwendung als schmierölzusatz und herstellungsmethode
ATE234869T1 (de) Verfahren zur herstellung von geträgertem metallocen-katalysator und olefin- polymerisationsverfahren unter dessen verwendung
TR199600365A2 (tr) Kendiliginden kivrilan iki komponentli polimer fiberlerin üretim yöntemi.
BR9605253A (pt) Sistema catalítico para a (co) polimerizaçao de alfa olefinas
DE60306672D1 (de) Verwendung von metallkomplexverbindungen als oxidationskatalysatoren

Legal Events

Date Code Title Description
RER Ceased as to paragraph 5 lit. 3 law introducing patent treaties