ATE319757T1 - Wasser- und öl-abweisende eigenschaften verleihende urethanoligomere, umfassend perfluoralkyleinheiten - Google Patents

Wasser- und öl-abweisende eigenschaften verleihende urethanoligomere, umfassend perfluoralkyleinheiten

Info

Publication number
ATE319757T1
ATE319757T1 AT01994352T AT01994352T ATE319757T1 AT E319757 T1 ATE319757 T1 AT E319757T1 AT 01994352 T AT01994352 T AT 01994352T AT 01994352 T AT01994352 T AT 01994352T AT E319757 T1 ATE319757 T1 AT E319757T1
Authority
AT
Austria
Prior art keywords
perfluoralkyle
units
oil repellent
providing water
repellent properties
Prior art date
Application number
AT01994352T
Other languages
English (en)
Inventor
Zai-Ming Qiu
John C Clark
Wayne W Fan
Original Assignee
3M Innovative Properties Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 3M Innovative Properties Co filed Critical 3M Innovative Properties Co
Application granted granted Critical
Publication of ATE319757T1 publication Critical patent/ATE319757T1/de

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/46—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with organic materials
    • C04B41/48—Macromolecular compounds
    • C04B41/488—Other macromolecular compounds obtained otherwise than by reactions only involving unsaturated carbon-to-carbon bonds
    • C04B41/4884—Polyurethanes; Polyisocyanates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/38—Low-molecular-weight compounds having heteroatoms other than oxygen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/38—Low-molecular-weight compounds having heteroatoms other than oxygen
    • C08G18/3802—Low-molecular-weight compounds having heteroatoms other than oxygen having halogens
    • C08G18/3804—Polyhydroxy compounds
    • C08G18/3812—Polyhydroxy compounds having fluorine atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/38—Low-molecular-weight compounds having heteroatoms other than oxygen
    • C08G18/3819—Low-molecular-weight compounds having heteroatoms other than oxygen having nitrogen
    • C08G18/3821—Carboxylic acids; Esters thereof with monohydroxyl compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/38—Low-molecular-weight compounds having heteroatoms other than oxygen
    • C08G18/3855—Low-molecular-weight compounds having heteroatoms other than oxygen having sulfur
    • C08G18/3857—Low-molecular-weight compounds having heteroatoms other than oxygen having sulfur having nitrogen in addition to sulfur
    • C08G18/3861—Low-molecular-weight compounds having heteroatoms other than oxygen having sulfur having nitrogen in addition to sulfur containing sulfonamide and/or sulfonylhydrazide groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/73—Polyisocyanates or polyisothiocyanates acyclic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
    • C08G18/7614—Polyisocyanates or polyisothiocyanates cyclic aromatic containing only one aromatic ring
    • C08G18/7628—Polyisocyanates or polyisothiocyanates cyclic aromatic containing only one aromatic ring containing at least one isocyanate or isothiocyanate group linked to the aromatic ring by means of an aliphatic group
    • C08G18/765—Polyisocyanates or polyisothiocyanates cyclic aromatic containing only one aromatic ring containing at least one isocyanate or isothiocyanate group linked to the aromatic ring by means of an aliphatic group alpha, alpha, alpha', alpha', -tetraalkylxylylene diisocyanate or homologues substituted on the aromatic ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
    • C08G18/78—Nitrogen
    • C08G18/7806—Nitrogen containing -N-C=0 groups
    • C08G18/7818—Nitrogen containing -N-C=0 groups containing ureum or ureum derivative groups
    • C08G18/7831—Nitrogen containing -N-C=0 groups containing ureum or ureum derivative groups containing biuret groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/80—Masked polyisocyanates
    • C08G18/8061—Masked polyisocyanates masked with compounds having only one group containing active hydrogen
    • C08G18/807—Masked polyisocyanates masked with compounds having only one group containing active hydrogen with nitrogen containing compounds
    • C08G18/8077—Oximes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04—Polyurethanes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/402—Amides imides, sulfamic acids
    • D06M13/425—Carbamic or thiocarbamic acids or derivatives thereof, e.g. urethanes
    • D06M13/428—Carbamic or thiocarbamic acids or derivatives thereof, e.g. urethanes containing fluorine atoms
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/564—Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
    • D06M15/576—Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them containing fluorine
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20—Resistance against chemical, physical or biological attack
    • C04B2111/203—Oil-proof or grease-repellant materials
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20—Resistance against chemical, physical or biological attack
    • C04B2111/27—Water resistance, i.e. waterproof or water-repellent materials
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/10—Repellency against liquids
    • D06M2200/11—Oleophobic properties
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/10—Repellency against liquids
    • D06M2200/12—Hydrophobic properties
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Textile Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Paints Or Removers (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Materials Applied To Surfaces To Minimize Adherence Of Mist Or Water (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Lubricants (AREA)
AT01994352T 2001-03-09 2001-12-26 Wasser- und öl-abweisende eigenschaften verleihende urethanoligomere, umfassend perfluoralkyleinheiten ATE319757T1 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US09/803,702 US6803109B2 (en) 2001-03-09 2001-03-09 Water-and oil-repellency imparting urethane oligomers comprising perfluoroalkyl moieties

Publications (1)

Publication Number Publication Date
ATE319757T1 true ATE319757T1 (de) 2006-03-15

Family

ID=25187217

Family Applications (1)

Application Number Title Priority Date Filing Date
AT01994352T ATE319757T1 (de) 2001-03-09 2001-12-26 Wasser- und öl-abweisende eigenschaften verleihende urethanoligomere, umfassend perfluoralkyleinheiten

Country Status (13)

Country Link
US (1) US6803109B2 (de)
EP (1) EP1370596B1 (de)
JP (1) JP4220244B2 (de)
KR (1) KR100775150B1 (de)
CN (1) CN1227280C (de)
AT (1) ATE319757T1 (de)
AU (1) AU2002246759B2 (de)
BR (1) BR0116917B1 (de)
CA (1) CA2439252C (de)
DE (1) DE60117862T2 (de)
ES (1) ES2259681T3 (de)
MX (1) MXPA03007987A (de)
WO (1) WO2002072657A1 (de)

Families Citing this family (117)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2447132C (en) * 2001-05-14 2008-10-07 Omnova Solutions Inc. Polymeric surfactants derived from cyclic monomers having pendant fluorinated carbon groups
US6632040B1 (en) * 2001-12-04 2003-10-14 Robert L. Newell Adhesive applicator brushes furnished in adhesive containers, and method
US7056846B2 (en) * 2001-12-04 2006-06-06 3M Innovative Properties Company Repellent fluorochemical compositions
DE10252866B3 (de) 2002-11-12 2004-04-29 Kronotec Ag Paneel und Verfahren zur Herstellung eines Paneels
DE10252863B4 (de) 2002-11-12 2007-04-19 Kronotec Ag Holzfaserplatte, insbesondere Fussbodenpaneel
US7617651B2 (en) 2002-11-12 2009-11-17 Kronotec Ag Floor panel
DE50309830D1 (de) 2002-11-15 2008-06-26 Flooring Technologies Ltd Einrichtung bestehend aus zwei miteinander verbindbaren Bauplatten und einem Einsatz zum Verriegeln dieser Bauplatten
US7320739B2 (en) 2003-01-02 2008-01-22 3M Innovative Properties Company Sound absorptive multilayer composite
US20040138083A1 (en) * 2003-01-10 2004-07-15 Kimbrell Wiliam C. Substrates having reversibly adaptable surface energy properties and method for making the same
US20040147188A1 (en) * 2003-01-28 2004-07-29 3M Innovative Properties Company Fluorochemical urethane composition for treatment of fibrous substrates
DE10306118A1 (de) 2003-02-14 2004-09-09 Kronotec Ag Bauplatte
US7678425B2 (en) 2003-03-06 2010-03-16 Flooring Technologies Ltd. Process for finishing a wooden board and wooden board produced by the process
DE20304761U1 (de) 2003-03-24 2004-04-08 Kronotec Ag Einrichtung zum Verbinden von Bauplatten, insbesondere Bodenpaneele
ITMI20031105A1 (it) * 2003-06-03 2004-12-04 Solvay Solexis Spa Uso per il trattamento oleorepellente della carta di perfluoropolieteri carbossilici
DE10325094B4 (de) * 2003-06-03 2006-02-16 Rudolf Gmbh & Co. Kg Chemische Fabrik Zubereitungen für die öl- und wasserabweisende Ausrüstung von Flächengebilden und deren Anwendung
US20050005956A1 (en) * 2003-07-11 2005-01-13 Maytag Corporation Fluorine gas treatment of washing machine parts
DE10331483A1 (de) * 2003-07-11 2005-02-10 Construction Research & Technology Gmbh Fluormodifizierte ein- oder zweikomponentige Polyurethanharze, Verfahren zu ihrer Herstellung und deren Verwendung
DE10332152A1 (de) * 2003-07-15 2005-02-03 Degussa Ag (Poly-)Uretdione mit chemisch gekoppelten Perfluoralkylverbindungen und Verfahren zu ihrer Herstellung
DE10341172B4 (de) 2003-09-06 2009-07-23 Kronotec Ag Verfahren zum Versiegeln einer Bauplatte
US20050058779A1 (en) * 2003-09-12 2005-03-17 Goldbaum Richard H. Suppression of repellency in polyolefins
DE20315676U1 (de) 2003-10-11 2003-12-11 Kronotec Ag Paneel, insbesondere Bodenpaneel
US7506481B2 (en) 2003-12-17 2009-03-24 Kronotec Ag Building board for use in subfloors
US7199197B2 (en) * 2003-12-31 2007-04-03 3M Innovative Properties Company Water- and oil-repellent fluoroacrylates
US7943567B2 (en) 2004-01-30 2011-05-17 E.I. Du Pont De Nemours And Company Production processes and systems, compositions, surfactants, monomer units, metal complexes, phosphate esters, glycols, aqueous film forming foams, and foam stabilizers
DE102004005047B3 (de) 2004-01-30 2005-10-20 Kronotec Ag Verfahren und Einrichtung zum Einbringen eines die Feder einer Platte bildenden Streifens
TWI289599B (en) * 2004-02-12 2007-11-11 Jintex Corp Ltd Solvent base fluorine water-repellent and oil-repellent agent and manufacturing method thereof
DE102004011931B4 (de) 2004-03-11 2006-09-14 Kronotec Ag Dämmstoffplatte aus einem Holzwerkstoff-Bindemittelfaser-Gemisch
US20050249940A1 (en) * 2004-05-07 2005-11-10 3M Innovative Properties Company Fluoropolyether poly(meth)acryl compounds
US7101618B2 (en) * 2004-05-07 2006-09-05 3M Innovative Properties Company Article comprising fluorochemical surface layer
US7288619B2 (en) * 2004-05-07 2007-10-30 3M Innovative Properties Company Fluorinated polyether polyamine and method of making the same
US20050249956A1 (en) * 2004-05-07 2005-11-10 Naiyong Jing Stain repellent optical hard coating
US7342080B2 (en) * 2004-05-07 2008-03-11 3M Innovative Properties Company Polymerizable compositions, methods of making the same, and composite articles therefrom
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US7300976B2 (en) * 2004-06-10 2007-11-27 3M Innovative Properties Company Fluorochemical oligomeric polish composition
US20100301254A1 (en) * 2004-06-23 2010-12-02 University Of Maine System Board Of Trustees Barrier compositions and articles produced with the compositions
US7737200B2 (en) 2004-06-23 2010-06-15 University Of Maine System Board Of Trustees Barrier compositions and articles produced with the compositions
US20060013983A1 (en) * 2004-07-15 2006-01-19 3M Innovative Properties Company Adhesive delivery of oil and water repellents
US7500541B2 (en) 2004-09-30 2009-03-10 Kimberly-Clark Worldwide, Inc. Acoustic material with liquid repellency
US7345123B2 (en) * 2004-12-28 2008-03-18 3M Innovative Properties Company Fluoroacrylate-multifunctional acrylate copolymer compositions
US20060142530A1 (en) * 2004-12-28 2006-06-29 Moore George G Water- and oil-repellent fluorourethanes and fluoroureas
US7291688B2 (en) * 2004-12-28 2007-11-06 3M Innovative Properties Company Fluoroacrylate-mercaptofunctional copolymers
US7411020B2 (en) * 2004-12-28 2008-08-12 3M Innovative Properties Company Water-based release coating containing fluorochemical
US7253241B2 (en) * 2004-12-28 2007-08-07 3M Innovative Properties Company Fluorochemical containing low adhesion backsize
US7160480B2 (en) * 2005-02-22 2007-01-09 E. I. Du Pont De Nemours And Company Leather treated with fluorochemicals
US20060188729A1 (en) * 2005-02-22 2006-08-24 Kai-Volker Schubert Washable leather with repellency
MX2008000251A (es) * 2005-06-29 2008-03-18 3M Innovative Properties Co Poliuretanos derivados de fluoroacrilatos oligomericos.
AU2006278511A1 (en) * 2005-08-05 2007-02-15 3M Innovative Properties Company Repellent materials
US20070029085A1 (en) * 2005-08-05 2007-02-08 Panga Mohan K Prevention of Water and Condensate Blocks in Wells
US7459186B2 (en) * 2005-08-05 2008-12-02 Wacker Chemical Corporation Masonry sealing compositions comprising semi-crystalline ethylene-vinyl acetate polymer emulsions
US7854986B2 (en) 2005-09-08 2010-12-21 Flooring Technologies Ltd. Building board and method for production
DE102005042658B3 (de) 2005-09-08 2007-03-01 Kronotec Ag Bauplatte, insbesondere Fußbodenpaneel
DE102005042657B4 (de) 2005-09-08 2010-12-30 Kronotec Ag Bauplatte und Verfahren zur Herstellung
DE102005063034B4 (de) 2005-12-29 2007-10-31 Flooring Technologies Ltd. Paneel, insbesondere Bodenpaneel
DE102006006124A1 (de) 2006-02-10 2007-08-23 Flooring Technologies Ltd. Einrichtung zum Verriegeln zweier Bauplatten
DE102006007976B4 (de) 2006-02-21 2007-11-08 Flooring Technologies Ltd. Verfahren zur Veredelung einer Bauplatte
WO2007102991A1 (en) * 2006-03-08 2007-09-13 3M Innovative Properties Company Controlled architecture materials
US20070244289A1 (en) * 2006-04-13 2007-10-18 3M Innovative Properties Company Method of making urethane based fluorinated monomers
US7722955B2 (en) * 2006-04-13 2010-05-25 3M Innovative Properties Company Flooring substrate having a coating of a curable composition
US20070275174A1 (en) * 2006-05-24 2007-11-29 Hanson Eric L Fishing fly and fly fishing line with fluorocarbon coating
US7728098B2 (en) * 2006-07-27 2010-06-01 3M Innovative Properties Company Fluorochemical composition comprising fluorinated oligomeric silane
JP2013035849A (ja) * 2006-09-29 2013-02-21 Fujifilm Corp フッ素アルコールおよびこれを用いた撥水性ポリウレタン用組成物
US20080114177A1 (en) * 2006-11-15 2008-05-15 3M Innovative Properties Company Method for preparing fluorinated benzotriazole compounds
EP2121789A1 (de) * 2006-12-20 2009-11-25 3M Innovative Properties Company Fluorchemische urethanverbindungen mit seitenständigen silylgruppen
US7652116B2 (en) * 2007-06-20 2010-01-26 3M Innovative Properties Company Fluorochemical urethane-silane compounds and aqueous compositions thereof
US7652117B2 (en) * 2007-06-20 2010-01-26 3M Innovative Properties Company Fluorochemical urethane compounds and aqueous compositions thereof
US8318656B2 (en) 2007-07-03 2012-11-27 E. I. Du Pont De Nemours And Company Production processes and systems, compositions, surfactants, monomer units, metal complexes, phosphate esters, glycols, aqueous film forming foams, and foam stabilizers
US20090110840A1 (en) * 2007-10-24 2009-04-30 Peter Michael Murphy Hydrophillic fluorinated soil resist copolymers
US20100272941A1 (en) * 2007-11-15 2010-10-28 Entek Membranes Llc Durable water- and oil- resistant, breathable microporous membrane
US20090148654A1 (en) * 2007-12-06 2009-06-11 E. I. Du Pont De Nemours And Company Fluoropolymer compositions and treated substrates
WO2009114572A2 (en) 2008-03-11 2009-09-17 3M Innovative Properties Company Phototools having a protective layer
US8071953B2 (en) * 2008-04-29 2011-12-06 Redlen Technologies, Inc. ACF attachment for radiation detector
US7968669B2 (en) 2008-05-16 2011-06-28 E.I. Du Pont De Nemours And Company Fluoropolymer compositions and treated substrates
CN102282191A (zh) * 2008-11-25 2011-12-14 3M创新有限公司 氟化醚尿烷及其使用方法
CN102459495B (zh) * 2009-06-24 2014-11-26 旭硝子株式会社 斥水斥油剂及斥水斥油剂组合物
US7901589B2 (en) * 2009-06-29 2011-03-08 E.I. Du Pont De Nemours And Company Propanediol soil resist compositions
JP5583210B2 (ja) 2009-07-21 2014-09-03 スリーエム イノベイティブ プロパティズ カンパニー 硬化性組成物、フォトツールをコーティングする方法、及びコーティングされたフォトツール
DE102009029153A1 (de) 2009-09-03 2011-03-17 Evonik Degussa Gmbh Waschpermanente Wandbeläge
WO2011034845A1 (en) 2009-09-16 2011-03-24 3M Innovative Properties Company Fluorinated coating and phototools made therewith
US8420281B2 (en) * 2009-09-16 2013-04-16 3M Innovative Properties Company Epoxy-functionalized perfluoropolyether polyurethanes
EP2478033A1 (de) 2009-09-16 2012-07-25 3M Innovative Properties Company Fluorierte beschichtungen und damit hergestellte fotowerkzeuge
GB0919014D0 (en) 2009-10-30 2009-12-16 3M Innovative Properties Co Soll and stain resistant coating composition for finished leather substrates
AU2010327975B2 (en) * 2009-12-10 2015-10-22 Invista Technologies S.Ar.L. Soil repellency aqueous dispersions, soil repellant soft articles, and methods of making the same
JP5846118B2 (ja) * 2010-06-04 2016-01-20 旭硝子株式会社 撥水撥油剤および撥水撥油剤組成物
CN101851068B (zh) * 2010-06-12 2012-07-18 重庆龙者低碳环保科技有限公司 一种玻璃表面喷涂隔热膜的方法
WO2013085864A2 (en) * 2011-12-06 2013-06-13 3M Innovative Properties Company Fluorinated oligomers having pendant functional groups
EP2841639A1 (de) * 2012-04-24 2015-03-04 3M Innovative Properties Company Tensidhaltige fluorchemische zusammensetzungen, artikel und verfahren
US20140170917A1 (en) * 2012-12-19 2014-06-19 3M Innovative Properties Company Polyurethane polymer, synthetic leather, and method
KR102084073B1 (ko) * 2012-12-21 2020-03-04 에스케이하이닉스 주식회사 반도체 장치의 표면 처리 방법
US9938306B2 (en) 2013-10-04 2018-04-10 3M Innovative Properties Company Fluoroalkylsilanes and coatings therefrom
EP3052546A1 (de) 2013-10-04 2016-08-10 3M Innovative Properties Company Fluoralkylsilikonzusammensetzungen
US20150112036A1 (en) * 2013-10-17 2015-04-23 E I Du Pont De Nemours And Company Partially fluorinated polymers
JP2017517587A (ja) 2014-03-31 2017-06-29 スリーエム イノベイティブ プロパティズ カンパニー フルオロアルキルシリコーン
KR20170077162A (ko) 2014-10-28 2017-07-05 쓰리엠 이노베이티브 프로퍼티즈 컴파니 반발 표면을 포함하는 스프레이 적용 시스템 구성 요소 및 방법
KR101619636B1 (ko) 2014-11-07 2016-05-10 현대자동차주식회사 내구성이 향상된 스티어링 휠 커버용 인조 피혁 및 그 제조방법
US10066121B2 (en) * 2015-04-24 2018-09-04 3M Innovative Properties Company Two-part polyurethane erosion resistant coatings
CN108350290B (zh) 2015-10-28 2021-10-15 3M创新有限公司 包括拒斥性表面的经历冰形成的制品
CN108348937A (zh) 2015-10-28 2018-07-31 3M创新有限公司 包括拒液表面的喷雾施用系统部件和方法
EP3448944A4 (de) 2016-04-26 2019-11-13 3M Innovative Properties Company Gegenstände, die eisbildung ausgesetzt sind, mit einer abweisenden oberfläche mit einem siloxanmaterial
EP3448945A4 (de) * 2016-04-26 2019-12-11 3M Innovative Properties Company Für eisbildung anfällige artikel mit abweisender oberfläche mit einem fluorchemischen stoff
EP3475290B1 (de) * 2016-06-27 2020-08-05 3M Innovative Properties Company Fluorchemische piperazincarboxamide
CN109689623B (zh) * 2016-09-09 2021-10-01 3M创新有限公司 部分氟化的芳族酯
EP3635022B1 (de) * 2017-05-19 2025-05-21 Etna-Tec, Ltd Verfahren zur herstellung von funktionalisierten fluorierten monomeren, fluorierte monomere und zusammensetzungen zur herstellung davon
CN107286319A (zh) * 2017-07-14 2017-10-24 黄山万丽美油墨科技有限公司 一种有机氟改性的水性uv固化树脂及其制备方法
US20190118221A1 (en) 2017-10-24 2019-04-25 The Boeing Company Conformal fluoropolymer coatings
KR102783254B1 (ko) * 2017-12-13 2025-03-19 도날드슨 컴파니, 인코포레이티드 소유성 폴리아미드 미세 섬유, 방법, 필터 매체, 및 필터 요소
CN108211986B (zh) * 2017-12-29 2019-10-29 苏州昊通仪器科技有限公司 一种高分子表面活性剂、其制备方法及应用
KR102281760B1 (ko) 2018-07-12 2021-07-23 주식회사 엘지화학 다공성 불소계 수지 복합막 및 이의 제조 방법
US11214707B2 (en) * 2018-09-21 2022-01-04 The Boeing Company Compositions and methods for fabricating coatings
CN109438643A (zh) * 2018-11-08 2019-03-08 合众（佛山）化工有限公司 一种生物基氟改性水性聚氨酯树脂及其制备方法
CN115869468B (zh) 2018-12-28 2025-02-14 黄玲惠 生物支架和用于制备其的方法
CN110511327B (zh) * 2019-09-02 2021-12-17 广州市白云化工实业有限公司 含氟增粘树脂及其制备、应用
WO2021165223A1 (en) * 2020-02-18 2021-08-26 Akzo Nobel Coatings International B.V. Waterborne uv curable coating composition for anti-stain and anti-scratch coatings
CN113278128B (zh) * 2021-04-08 2022-11-11 四川嘉宝莉涂料有限公司 一种具有含氟侧链的水性聚氨酯/聚脲及其制备方法
CN114605613B (zh) * 2022-02-21 2024-05-10 宁德师范学院 一种有机氟改性水性聚氨酯皮革涂饰剂及其制备方法
CN120835908A (zh) * 2023-03-03 2025-10-24 大金工业株式会社 含氟化合物
CN117402319A (zh) * 2023-10-18 2024-01-16 广州医科大学 一类基于含氟氨基甲酸酯预聚物的添加剂及制备和在制备医用含氟抗凝血聚氨酯材料的应用
CN118085226B (zh) * 2024-02-22 2026-02-27 苏州心岭迈德医疗科技有限公司 一种抗污材料及其制备方法和应用

Family Cites Families (55)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2803615A (en) 1956-01-23 1957-08-20 Minnesota Mining & Mfg Fluorocarbon acrylate and methacrylate esters and polymers
US2803656A (en) 1956-01-23 1957-08-20 Minnesota Mining & Mfg Fluorocarbonsulfonamidoalkanols and sulfates thereof
GB858671A (en) 1956-04-23 1961-01-11 Minnesota Mining & Mfg Fluorocarbon acid and derivatives
US3102103A (en) 1957-08-09 1963-08-27 Minnesota Mining & Mfg Perfluoroalkyl acrylate polymers and process of producing a latex thereof
NL124492C (de) 1959-08-10
DE1468295A1 (de) * 1960-09-02 1969-05-29 Minnesota Mining & Mfg Perfluoralkylgruppen enthaltende Urethane und Verfahren zu deren Herstellung
US3094547A (en) 1961-02-06 1963-06-18 Minnesota Mining & Mfg Perfluoroalkylsulfonamidoalkyl esters of phosphorus acids
US3341497A (en) 1966-01-21 1967-09-12 Minnesota Mining & Mfg Organic solvent soluble perfluorocarbon copolymers
GB1215861A (en) 1967-02-09 1970-12-16 Minnesota Mining & Mfg Cleanable stain-resistant fabrics or fibers and polymers therefor
US3478116A (en) 1967-07-26 1969-11-11 Du Pont Fluorinated alcohols
US3671493A (en) 1969-04-16 1972-06-20 Sergio Lo Monaco Fluorocarbon-containing compounds and method of imparting oil-and water-repellency to textiles,paper,leather and the like
US4289892A (en) 1970-03-03 1981-09-15 Minnesota Mining And Manufacturing Company Fluorochemical foam stabilizer and foamed polyurethanes made therewith
DE2024909B2 (de) 1970-05-22 1977-09-29 Bayer Ag, 5090 Leverkusen Verfahren zur herstellung von n-hydroxyalkyl-perfluoralkansulfonamiden und einige n,n-bis-(hydroxyalkyl)-perfluor-alkansulfonamide
US3759874A (en) 1971-08-30 1973-09-18 Fmc Corp Fluorinated polyurethanes as soil release agents
US3916053A (en) 1971-09-12 1975-10-28 Minnesota Mining & Mfg Carpet treating and treated carpet
BE789363A (fr) 1971-09-27 1973-03-27 Fmc Corp Composes fluores utilisables comme agents antitaches pour textiles
US3787351A (en) 1972-02-28 1974-01-22 Minnesota Mining & Mfg Use of soluble fluoroaliphatic oligomers in resin composite articles
US3987227A (en) 1973-04-02 1976-10-19 Minnesota Mining And Manufacturing Company Durably stain-repellant and soil-resistant pile fabric and process
US3968066A (en) 1974-04-18 1976-07-06 Ciba-Geigy Corporation Oil and water repellent textile composition containing a fluorochemical polyurethane resin and a quaternary ammonium salt
US4043923A (en) 1974-02-26 1977-08-23 Minnesota Mining And Manufacturing Company Textile treatment composition
US3987182A (en) 1974-06-17 1976-10-19 Schering Corporation Novel benzimidazoles useful as anti-androgens
US4215205A (en) 1977-01-12 1980-07-29 Minnesota Mining And Manufacturing Company Fluoroaliphatic radical and carbodiimide containing compositions for fabric treatment
US4247656A (en) 1979-03-14 1981-01-27 Minnesota Mining And Manufacturing Company Poly(urethane-isocyanurate) foams
US4508916A (en) 1979-04-11 1985-04-02 Minnesota Mining And Manufacturing Company Curable substituted urethane acrylates
US4468527A (en) 1980-12-08 1984-08-28 Minnesota Mining And Manufacturing Company Fluorinated alcohols
US4426466A (en) 1982-06-09 1984-01-17 Minnesota Mining And Manufacturing Company Paper treatment compositions containing fluorochemical carboxylic acid and epoxidic cationic resin
JPS5933315A (ja) 1982-08-20 1984-02-23 Asahi Glass Co Ltd 防汚加工剤の製造方法
US4529658A (en) 1982-10-13 1985-07-16 Minnesota Mining And Manufacturing Company Fluorochemical copolymers and ovenable paperboard and textile fibers treated therewith
US4540497A (en) 1982-11-09 1985-09-10 Minnesota Mining And Manufacturing Company Fluoroaliphatic radical-containing, substituted guanidines and fibrous substrates treated therewith
US4533713A (en) 1983-05-06 1985-08-06 Minnesota Mining And Manufacturing Company Fluoroaliphaticsulfonamides containing oxirane groups and/or N-β-hydroxyalkylene groups
DE3319368A1 (de) 1983-05-27 1984-11-29 Bayer Ag, 5090 Leverkusen Perfluoralkylgruppen-enthaltende polyurethane und verfahren zu ihrer herstellung
US4566981A (en) 1984-03-30 1986-01-28 Minnesota Mining And Manufacturing Company Fluorochemicals and fibrous substrates treated therewith: compositions of cationic and non-ionic fluorochemicals
US4668406A (en) 1984-04-02 1987-05-26 Minnesota Mining And Manufacturing Company Fluorochemical biuret compositions and fibrous substrates treated therewith
US4606737A (en) 1984-06-26 1986-08-19 Minnesota Mining And Manufacturing Company Fluorochemical allophanate compositions and fibrous substrates treated therewith
US4958039A (en) 1984-08-24 1990-09-18 E. I. Du Pont De Nemours And Company Modified fluorocarbonylimino biurets
DE3611302A1 (de) 1986-04-04 1987-10-08 Hoechst Ag Fluorierte, mehrwertige alkohole, verfahren zu ihrer herstellung und ihre verwendung
US5025052A (en) 1986-09-12 1991-06-18 Minnesota Mining And Manufacturing Company Fluorochemical oxazolidinones
US5204441A (en) 1990-03-12 1993-04-20 Fluorochem Inc. Polyfluorinated, branched-chain diols and diisocyanantes and fluorinated polyurethanes prepared therefrom
DE4012630A1 (de) 1990-04-20 1991-10-24 Bayer Ag Perfluoralkylgruppen enthaltende pfropfcopolymerisate
US5149576A (en) 1990-11-26 1992-09-22 Kimberly-Clark Corporation Multilayer nonwoven laminiferous structure
US5145727A (en) 1990-11-26 1992-09-08 Kimberly-Clark Corporation Multilayer nonwoven composite structure
US5276175A (en) 1991-04-02 1994-01-04 Minnesota Mining And Manufacturing Company Isocyanate derivatives comprising flourochemical oligomers
DE4143390A1 (en) 1991-04-26 1993-04-01 Fluorine contg. (co)polymers, useful for water- and oil repellent treatment of substrates
AU2297692A (en) * 1991-07-10 1993-02-11 Minnesota Mining And Manufacturing Company Aqueous oil and water repellent compositions
US5451622A (en) 1992-09-30 1995-09-19 Minnesota Mining And Manufacturing Company Composition comprising thermoplastic polymer and fluorochemical piperazine compound
DE4300799C2 (de) 1993-01-14 1996-09-19 Bayer Ag Acrylat- und/oder methacrylatgruppenhaltige fluorierte Carbonsäureester von Phosphono- und Phosphinocarbonsäuren, ein Verfahren zu ihrer Herstellung sowie deren Verwendung
DE4300800C2 (de) 1993-01-14 1996-09-19 Bayer Ag Hydroxy- und/oder mercaptogruppenhaltige fluorierte Carbonsäureester von Phosphono- und Phosphinocarbonsäuren, ein Verfahren zu ihrer Herstellung sowie deren Verwendung
US5674951A (en) 1994-05-20 1997-10-07 Gencorp Inc. Abrasion-resistant and low friction coating compositions
US5543200A (en) * 1994-12-19 1996-08-06 Gencorp Inc. Abrasion-resistant article coated with a coating compositions based on fluorinated monohydric alcohol
US5725789A (en) 1995-03-31 1998-03-10 Minnesota Mining And Manufacturing Company Aqueous oil and water repellent compositions
US6037429A (en) 1995-06-16 2000-03-14 3M Innovative Properties Company Water-soluble fluorochemical polymers for use in water and oil repellent masonry treatments
US5688884A (en) 1995-08-31 1997-11-18 E. I. Du Pont De Nemours And Company Polymerization process
US5637772A (en) 1995-09-22 1997-06-10 Aerojet General Corporation Fluorinated diamines and polymers formed therefrom
FR2749309A1 (fr) * 1996-05-29 1997-12-05 Atochem Elf Sa Oligomeres urethanes fluores et leur application au traitement hydrofuge et oleofuge de substrats divers
US6001923A (en) * 1997-03-27 1999-12-14 Pilkington Aerospace Inc. Transparent fluorinated polyurethane coating compositions and methods of use thereof

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US6803109B2 (en) 2004-10-12
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US20030026997A1 (en) 2003-02-06
BR0116917A (pt) 2004-04-27
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