ATE333936T1 - Fischer-tropsch-verfahren mit verbesserter katalysatorregenerierung - Google Patents

Fischer-tropsch-verfahren mit verbesserter katalysatorregenerierung

Info

Publication number: ATE333936T1
Authority: AT; Austria
Prior art keywords: catalyst; reactor; decreasing; ammonium salts; fischer
Prior art date: 2002-01-29

Application number

AT03700681T

Other languages

English (en)

Inventor

Russell John Koveal

Michel Daage

Eric Baochun Shen

Original Assignee

Exxonmobil Res & Eng Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2002-01-29

Filing date

2003-01-03

Publication date

2006-08-15

2003-01-03 Application filed by Exxonmobil Res & Eng Co filed Critical Exxonmobil Res & Eng Co

2006-08-15 Application granted granted Critical

2006-08-15 Publication of ATE333936T1 publication Critical patent/ATE333936T1/de

Links

239000003054 catalyst Substances 0.000 title abstract 5
238000000034 method Methods 0.000 title abstract 2
230000008929 regeneration Effects 0.000 title 1
238000011069 regeneration method Methods 0.000 title 1
229930195733 hydrocarbon Natural products 0.000 abstract 4
150000002430 hydrocarbons Chemical class 0.000 abstract 4
239000004215 Carbon black (E152) Substances 0.000 abstract 3
230000001590 oxidative effect Effects 0.000 abstract 3
QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 abstract 2
230000003247 decreasing effect Effects 0.000 abstract 2
UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 abstract 1
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
230000003213 activating effect Effects 0.000 abstract 1
125000005210 alkyl ammonium group Chemical group 0.000 abstract 1
229910021529 ammonia Inorganic materials 0.000 abstract 1
150000003863 ammonium salts Chemical class 0.000 abstract 1
230000015572 biosynthetic process Effects 0.000 abstract 1
229910002091 carbon monoxide Inorganic materials 0.000 abstract 1
229910052739 hydrogen Inorganic materials 0.000 abstract 1
239000001257 hydrogen Substances 0.000 abstract 1
229910052751 metal Inorganic materials 0.000 abstract 1
239000002184 metal Substances 0.000 abstract 1
239000000203 mixture Substances 0.000 abstract 1
150000007524 organic acids Chemical class 0.000 abstract 1
235000005985 organic acids Nutrition 0.000 abstract 1
239000007800 oxidant agent Substances 0.000 abstract 1
238000003786 synthesis reaction Methods 0.000 abstract 1

Classifications

- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
- C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
- C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
- C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
- C10G2/331—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals
- C10G2/332—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals of the iron-group
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/90—Regeneration or reactivation
- B01J23/94—Regeneration or reactivation of catalysts comprising metals, oxides or hydroxides of the iron group metals or copper
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/90—Regeneration or reactivation
- B01J23/96—Regeneration or reactivation of catalysts comprising metals, oxides or hydroxides of the noble metals
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J38/00—Regeneration or reactivation of catalysts, in general
- B01J38/04—Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst
- B01J38/10—Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst using elemental hydrogen
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J38/00—Regeneration or reactivation of catalysts, in general
- B01J38/04—Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst
- B01J38/12—Treating with free oxygen-containing gas
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J38/00—Regeneration or reactivation of catalysts, in general
- B01J38/48—Liquid treating or treating in liquid phase, e.g. dissolved or suspended
- B01J38/60—Liquid treating or treating in liquid phase, e.g. dissolved or suspended using acids
- B01J38/62—Liquid treating or treating in liquid phase, e.g. dissolved or suspended using acids organic
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J38/00—Regeneration or reactivation of catalysts, in general
- B01J38/48—Liquid treating or treating in liquid phase, e.g. dissolved or suspended
- B01J38/64—Liquid treating or treating in liquid phase, e.g. dissolved or suspended using alkaline material; using salts
- B01J38/66—Liquid treating or treating in liquid phase, e.g. dissolved or suspended using alkaline material; using salts using ammonia or derivatives thereof
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J38/00—Regeneration or reactivation of catalysts, in general
- B01J38/48—Liquid treating or treating in liquid phase, e.g. dissolved or suspended
- B01J38/70—Wet oxidation of material submerged in liquid
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
- C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
- C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
- C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
- C10G2/331—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals
- C10G2/333—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals of the platinum-group
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- B01J21/063—Titanium; Oxides or hydroxides thereof
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper

Landscapes

Chemical & Material Sciences (AREA)
Engineering & Computer Science (AREA)
Organic Chemistry (AREA)
Chemical Kinetics & Catalysis (AREA)
Materials Engineering (AREA)
Oil, Petroleum & Natural Gas (AREA)
General Chemical & Material Sciences (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Catalysts (AREA)
Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

AT03700681T 2002-01-29 2003-01-03 Fischer-tropsch-verfahren mit verbesserter katalysatorregenerierung ATE333936T1 (de)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
US10/059,916 US6753354B2 (en)	2002-01-29	2002-01-29	Fischer-tropsch catalyst enhancement

Publications (1)

Publication Number	Publication Date
ATE333936T1 true ATE333936T1 (de)	2006-08-15

Family

ID=27658270

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
AT03700681T ATE333936T1 (de)	2002-01-29	2003-01-03	Fischer-tropsch-verfahren mit verbesserter katalysatorregenerierung

Country Status (12)

Country	Link
US (1)	US6753354B2 (de)
EP (1)	EP1478612B1 (de)
JP (1)	JP4500548B2 (de)
CN (1)	CN100398501C (de)
AT (1)	ATE333936T1 (de)
AU (1)	AU2003201821B8 (de)
CA (1)	CA2471600A1 (de)
DE (1)	DE60307057T2 (de)
DK (1)	DK1478612T3 (de)
ES (1)	ES2269972T3 (de)
WO (1)	WO2003064356A1 (de)
ZA (1)	ZA200404478B (de)

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GB0318027D0 (en) *	2003-08-01	2003-09-03	Accentus Plc	Catalyst structure and catalytic reactor
US7612013B2 (en) *	2004-02-24	2009-11-03	Japan Oil, Gas And Metals National Corporation	Hydrocarbon-producing catalyst, process for producing the same, and process for producing hydrocarbons using the catalyst
JP2008525172A (ja) *	2004-12-23	2008-07-17	シエル・インターナシヨネイル・リサーチ・マーチヤツピイ・ベー・ウイ	触媒の製造方法
US7524787B2 (en) *	2005-01-11	2009-04-28	Sasol Technology (Proprietary Limited)	Producing supported cobalt catalysts for the Fisher-Tropsch synthesis
AU2006325209B2 (en) *	2005-12-16	2010-11-04	Shell Internationale Research Maatschappij B.V.	Process for preparing a hydrocarbon synthesis catalyst
US7825055B2 (en) *	2006-04-21	2010-11-02	Chevron U.S.A. Inc.	Regeneration of ionic liquid catalyst using a regeneration metal in the presence of added hydrogen
US8614158B2 (en) *	2008-02-29	2013-12-24	Schlumberger Technology Corporation	Fischer-trospch and oxygenate synthesis catalyst activation/regeneration in a micro scale process
US8293805B2 (en) *	2008-05-29	2012-10-23	Schlumberger Technology Corporation	Tracking feedstock production with micro scale gas-to-liquid units
US20100152022A1 (en) *	2008-12-17	2010-06-17	Qi Sun	Catalyst regeneration method
JP2012512735A (ja) *	2008-12-18	2012-06-07	シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー	酸化し、炭酸アンモニウム、水酸化アンモニウムおよび水の混合物を用いて処理することによるフィッシャー・トロプシュ触媒の再生
AU2010338450B2 (en) *	2009-12-16	2013-06-27	Shell Internationale Research Maatschappij B.V.	Process for regenerating a catalyst
GB2482905B (en) *	2010-08-19	2016-01-13	Gtl F1 Ag	Fischer-tropsch catalyst regeneration
US8729140B2 (en) *	2010-12-23	2014-05-20	Shell Oil Company	Process for regenerating a catalyst
FR2970187B1 (fr)	2011-01-11	2013-02-08	Eurecat Sa	Procede de regeneration hors site de catalyseurs solides.
US8389431B2 (en) *	2011-02-03	2013-03-05	Steag Energy Services Gmbh	Method for treating SCR catalysts having accumulated iron compounds
WO2014070857A2 (en)	2012-10-31	2014-05-08	Thermochem Recovery International, Inc.	System and method for processing raw gas with in-situ catalyst regeneration
BR112017010259B1 (pt)	2014-11-20	2020-12-01	Sasol Technology Proprietary Limited	síntese de fischer-tropsch
US10099213B2 (en) *	2015-11-23	2018-10-16	Clariant Corporation	Processes for regenerating catalysts useful in Fischer-Tropsch processes
CN107952461B (zh) *	2016-10-17	2020-10-27	中国石油化工股份有限公司	一种负载型纳米钴催化剂及其应用
CN111282574B (zh) *	2020-02-03	2020-12-15	中国矿业大学(北京)	一种费托合成铁系催化剂的回收方法
CN114425439A (zh) *	2020-09-18	2022-05-03	中国石油化工股份有限公司	一种废催化裂化催化剂复活方法

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2002
- 2002-01-29 US US10/059,916 patent/US6753354B2/en not_active Expired - Fee Related
2003
- 2003-01-03 JP JP2003563983A patent/JP4500548B2/ja not_active Expired - Fee Related
- 2003-01-03 AT AT03700681T patent/ATE333936T1/de not_active IP Right Cessation
- 2003-01-03 EP EP03700681A patent/EP1478612B1/de not_active Expired - Lifetime
- 2003-01-03 ES ES03700681T patent/ES2269972T3/es not_active Expired - Lifetime
- 2003-01-03 DK DK03700681T patent/DK1478612T3/da active
- 2003-01-03 AU AU2003201821A patent/AU2003201821B8/en not_active Ceased
- 2003-01-03 WO PCT/US2003/000202 patent/WO2003064356A1/en not_active Ceased
- 2003-01-03 DE DE60307057T patent/DE60307057T2/de not_active Expired - Lifetime
- 2003-01-03 CN CNB038024691A patent/CN100398501C/zh not_active Expired - Fee Related
- 2003-01-03 CA CA002471600A patent/CA2471600A1/en not_active Abandoned
2004
- 2004-06-07 ZA ZA200404478A patent/ZA200404478B/en unknown

Also Published As

Publication number	Publication date
EP1478612B1 (de)	2006-07-26
DK1478612T3 (da)	2006-11-20
DE60307057D1 (de)	2006-09-07
US20030166451A1 (en)	2003-09-04
EP1478612A4 (de)	2005-03-16
ZA200404478B (en)	2006-02-22
ES2269972T3 (es)	2007-04-01
CN100398501C (zh)	2008-07-02
DE60307057T2 (de)	2006-12-28
EP1478612A1 (de)	2004-11-24
US6753354B2 (en)	2004-06-22
CA2471600A1 (en)	2003-08-07
WO2003064356A1 (en)	2003-08-07
JP2005515893A (ja)	2005-06-02
JP4500548B2 (ja)	2010-07-14
AU2003201821B2 (en)	2008-05-01
CN1620411A (zh)	2005-05-25
AU2003201821B8 (en)	2008-06-26

Legal Events

Date	Code	Title	Description
2007-01-15	RER	Ceased as to paragraph 5 lit. 3 law introducing patent treaties

Publication	Publication Date	Title
ATE333936T1 (de)	2006-08-15	Fischer-tropsch-verfahren mit verbesserter katalysatorregenerierung
EP1480931A4 (de)	2005-03-16	Verbesserter katalysator
EA200500981A1 (ru)	2005-12-29	Способ каталитического селективного окисления сернистых соединений
WO2008149591A1 (ja)	2008-12-11	低級炭化水素の芳香族化触媒の再生方法
RU2427608C2 (ru)	2011-08-27	Способ демеркаптанизации углеводородного сырья
KR960700810A (ko)	1996-02-24	비닐 아세테이트 합성에 유용한 팔라듐-금 촉매의 전처리 방법(Pretreatment of Palladium-Gold Catalysts Useful in Vinyl Acetate Synthesis)
CA2472245A1 (en)	2003-08-21	Fischer-tropsch supported catalyst activation
ATE528274T1 (de)	2011-10-15	Verfahren und anlage zur herstellung von methanol
ATE275436T1 (de)	2004-09-15	Verfahren zur herstellung von kohlenstoffhaltigen rückständen mit katalytischer wirkung
PT1497014E (pt)	2006-10-31	Metodo de desnitrificacao
ATE246535T1 (de)	2003-08-15	Verfahren und vorrichtung zur selektiven katalytischen reduktion von stickoxiden in einem sauerstoffhaltigen gasförmigen medium
ATE164781T1 (de)	1998-04-15	Katalytischer kohlenstoff, verfahren zu seiner herstellung und seine verwendung zur zersetzung von peroxiden
BR9916551B1 (pt)	2009-05-05	processo de remoção de monóxido de carbono de um reformado de hidrocarbono.
ATE270249T1 (de)	2004-07-15	Verfahren zur herstellung von synthesisgas unter verwendung von aus hydrotalcit abgeleiteten nickelkatalisatoren
CA2114205A1 (en)	1994-08-02	Integrated Production of Fuel Gas and Oxygenated Organic Compounds from Synthesis Gas
RU2011129680A (ru)	2013-01-27	Регенерация катализатора фишера-тропша путем его окисления и обработки смесью карбоната аммония, гидроксида аммония и воды
EG23804A (en)	2007-08-28	Method for catalytically dehydrating hydrocarbons
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