ATE333936T1 - Fischer-tropsch-verfahren mit verbesserter katalysatorregenerierung - Google Patents

Fischer-tropsch-verfahren mit verbesserter katalysatorregenerierung

Info

Publication number
ATE333936T1
ATE333936T1 AT03700681T AT03700681T ATE333936T1 AT E333936 T1 ATE333936 T1 AT E333936T1 AT 03700681 T AT03700681 T AT 03700681T AT 03700681 T AT03700681 T AT 03700681T AT E333936 T1 ATE333936 T1 AT E333936T1
Authority
AT
Austria
Prior art keywords
catalyst
reactor
decreasing
ammonium salts
fischer
Prior art date
Application number
AT03700681T
Other languages
English (en)
Inventor
Russell John Koveal
Michel Daage
Eric Baochun Shen
Original Assignee
Exxonmobil Res & Eng Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxonmobil Res & Eng Co filed Critical Exxonmobil Res & Eng Co
Application granted granted Critical
Publication of ATE333936T1 publication Critical patent/ATE333936T1/de

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
    • C10G2/331—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals
    • C10G2/332—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals of the iron-group
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/90—Regeneration or reactivation
    • B01J23/94—Regeneration or reactivation of catalysts comprising metals, oxides or hydroxides of the iron group metals or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/90—Regeneration or reactivation
    • B01J23/96—Regeneration or reactivation of catalysts comprising metals, oxides or hydroxides of the noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B01J38/04—Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst
    • B01J38/10—Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst using elemental hydrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B01J38/04—Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst
    • B01J38/12—Treating with free oxygen-containing gas
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B01J38/48—Liquid treating or treating in liquid phase, e.g. dissolved or suspended
    • B01J38/60—Liquid treating or treating in liquid phase, e.g. dissolved or suspended using acids
    • B01J38/62—Liquid treating or treating in liquid phase, e.g. dissolved or suspended using acids organic
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B01J38/48—Liquid treating or treating in liquid phase, e.g. dissolved or suspended
    • B01J38/64—Liquid treating or treating in liquid phase, e.g. dissolved or suspended using alkaline material; using salts
    • B01J38/66—Liquid treating or treating in liquid phase, e.g. dissolved or suspended using alkaline material; using salts using ammonia or derivatives thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B01J38/48—Liquid treating or treating in liquid phase, e.g. dissolved or suspended
    • B01J38/70—Wet oxidation of material submerged in liquid
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
    • C10G2/331—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals
    • C10G2/333—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals of the platinum-group
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/063—Titanium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
AT03700681T 2002-01-29 2003-01-03 Fischer-tropsch-verfahren mit verbesserter katalysatorregenerierung ATE333936T1 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US10/059,916 US6753354B2 (en) 2002-01-29 2002-01-29 Fischer-tropsch catalyst enhancement

Publications (1)

Publication Number Publication Date
ATE333936T1 true ATE333936T1 (de) 2006-08-15

Family

ID=27658270

Family Applications (1)

Application Number Title Priority Date Filing Date
AT03700681T ATE333936T1 (de) 2002-01-29 2003-01-03 Fischer-tropsch-verfahren mit verbesserter katalysatorregenerierung

Country Status (12)

Country Link
US (1) US6753354B2 (de)
EP (1) EP1478612B1 (de)
JP (1) JP4500548B2 (de)
CN (1) CN100398501C (de)
AT (1) ATE333936T1 (de)
AU (1) AU2003201821B8 (de)
CA (1) CA2471600A1 (de)
DE (1) DE60307057T2 (de)
DK (1) DK1478612T3 (de)
ES (1) ES2269972T3 (de)
WO (1) WO2003064356A1 (de)
ZA (1) ZA200404478B (de)

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AU2005215337B2 (en) * 2004-02-24 2009-12-03 Cosmo Oil Co., Ltd. Catalyst for producing hydrocarbons, method for preparing the same, and method for producing hydrocarbons using the same
EP1827690A1 (de) * 2004-12-23 2007-09-05 Shell Internationale Research Maatschappij B.V. Verfahren zur herstellung eines katalysators
US7524787B2 (en) * 2005-01-11 2009-04-28 Sasol Technology (Proprietary Limited) Producing supported cobalt catalysts for the Fisher-Tropsch synthesis
JP2009519123A (ja) * 2005-12-16 2009-05-14 シエル・インターナシヨネイル・リサーチ・マーチヤツピイ・ベー・ウイ 炭化水素合成触媒の製造方法
US7825055B2 (en) * 2006-04-21 2010-11-02 Chevron U.S.A. Inc. Regeneration of ionic liquid catalyst using a regeneration metal in the presence of added hydrogen
US8614158B2 (en) * 2008-02-29 2013-12-24 Schlumberger Technology Corporation Fischer-trospch and oxygenate synthesis catalyst activation/regeneration in a micro scale process
US8293805B2 (en) * 2008-05-29 2012-10-23 Schlumberger Technology Corporation Tracking feedstock production with micro scale gas-to-liquid units
US20100152022A1 (en) * 2008-12-17 2010-06-17 Qi Sun Catalyst regeneration method
EP2367630A1 (de) * 2008-12-18 2011-09-28 Shell Internationale Research Maatschappij B.V. Regeneration eines fischer-tropsch-katalysators durch oxidation und behandlung mit einer mischung von ammoniumcarbonat, ammoniumhydroxid und wasser
WO2011080073A2 (en) * 2009-12-16 2011-07-07 Shell Internationale Research Maatschappij B.V. Process for regenerating a catalyst
GB2482905B (en) * 2010-08-19 2016-01-13 Gtl F1 Ag Fischer-tropsch catalyst regeneration
US8729140B2 (en) * 2010-12-23 2014-05-20 Shell Oil Company Process for regenerating a catalyst
FR2970187B1 (fr) * 2011-01-11 2013-02-08 Eurecat Sa Procede de regeneration hors site de catalyseurs solides.
US8389431B2 (en) * 2011-02-03 2013-03-05 Steag Energy Services Gmbh Method for treating SCR catalysts having accumulated iron compounds
US9677019B2 (en) 2012-10-31 2017-06-13 Thermochem Recovery International, Inc. System and method for processing raw gas with in-situ catalyst regeneration
US10190057B2 (en) 2014-11-20 2019-01-29 Sasol Technology Proprietary Limited Fischer-tropsch synthesis
CN108348911B (zh) * 2015-11-23 2021-07-06 科莱恩公司 用于再生可用于费-托方法的催化剂的方法
CN107952461B (zh) * 2016-10-17 2020-10-27 中国石油化工股份有限公司 一种负载型纳米钴催化剂及其应用
CN111282574B (zh) * 2020-02-03 2020-12-15 中国矿业大学(北京) 一种费托合成铁系催化剂的回收方法
CN114425439A (zh) * 2020-09-18 2022-05-03 中国石油化工股份有限公司 一种废催化裂化催化剂复活方法

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Also Published As

Publication number Publication date
CA2471600A1 (en) 2003-08-07
DK1478612T3 (da) 2006-11-20
ZA200404478B (en) 2006-02-22
DE60307057D1 (de) 2006-09-07
JP2005515893A (ja) 2005-06-02
AU2003201821B8 (en) 2008-06-26
JP4500548B2 (ja) 2010-07-14
CN1620411A (zh) 2005-05-25
CN100398501C (zh) 2008-07-02
EP1478612B1 (de) 2006-07-26
EP1478612A1 (de) 2004-11-24
US6753354B2 (en) 2004-06-22
US20030166451A1 (en) 2003-09-04
AU2003201821B2 (en) 2008-05-01
EP1478612A4 (de) 2005-03-16
WO2003064356A1 (en) 2003-08-07
ES2269972T3 (es) 2007-04-01
DE60307057T2 (de) 2006-12-28

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