ATE333936T1 - Fischer-tropsch-verfahren mit verbesserter katalysatorregenerierung - Google Patents

Fischer-tropsch-verfahren mit verbesserter katalysatorregenerierung

Info

Publication number
ATE333936T1
ATE333936T1 AT03700681T AT03700681T ATE333936T1 AT E333936 T1 ATE333936 T1 AT E333936T1 AT 03700681 T AT03700681 T AT 03700681T AT 03700681 T AT03700681 T AT 03700681T AT E333936 T1 ATE333936 T1 AT E333936T1
Authority
AT
Austria
Prior art keywords
catalyst
reactor
decreasing
ammonium salts
fischer
Prior art date
Application number
AT03700681T
Other languages
English (en)
Inventor
Russell John Koveal
Michel Daage
Eric Baochun Shen
Original Assignee
Exxonmobil Res & Eng Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxonmobil Res & Eng Co filed Critical Exxonmobil Res & Eng Co
Application granted granted Critical
Publication of ATE333936T1 publication Critical patent/ATE333936T1/de

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Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C10G2/33Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
    • C10G2/331Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals
    • C10G2/332Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals of the iron-group
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/90Regeneration or reactivation
    • B01J23/94Regeneration or reactivation of catalysts comprising metals, oxides or hydroxides of the iron group metals or copper
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/90Regeneration or reactivation
    • B01J23/96Regeneration or reactivation of catalysts comprising metals, oxides or hydroxides of the noble metals
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00Regeneration or reactivation of catalysts, in general
    • B01J38/04Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst
    • B01J38/10Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst using elemental hydrogen
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00Regeneration or reactivation of catalysts, in general
    • B01J38/04Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst
    • B01J38/12Treating with free oxygen-containing gas
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00Regeneration or reactivation of catalysts, in general
    • B01J38/48Liquid treating or treating in liquid phase, e.g. dissolved or suspended
    • B01J38/60Liquid treating or treating in liquid phase, e.g. dissolved or suspended using acids
    • B01J38/62Liquid treating or treating in liquid phase, e.g. dissolved or suspended using acids organic
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00Regeneration or reactivation of catalysts, in general
    • B01J38/48Liquid treating or treating in liquid phase, e.g. dissolved or suspended
    • B01J38/64Liquid treating or treating in liquid phase, e.g. dissolved or suspended using alkaline material; using salts
    • B01J38/66Liquid treating or treating in liquid phase, e.g. dissolved or suspended using alkaline material; using salts using ammonia or derivatives thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00Regeneration or reactivation of catalysts, in general
    • B01J38/48Liquid treating or treating in liquid phase, e.g. dissolved or suspended
    • B01J38/70Wet oxidation of material submerged in liquid
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C10G2/33Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
    • C10G2/331Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals
    • C10G2/333Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals of the platinum-group
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/063Titanium; Oxides or hydroxides thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
AT03700681T 2002-01-29 2003-01-03 Fischer-tropsch-verfahren mit verbesserter katalysatorregenerierung ATE333936T1 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US10/059,916 US6753354B2 (en) 2002-01-29 2002-01-29 Fischer-tropsch catalyst enhancement

Publications (1)

Publication Number Publication Date
ATE333936T1 true ATE333936T1 (de) 2006-08-15

Family

ID=27658270

Family Applications (1)

Application Number Title Priority Date Filing Date
AT03700681T ATE333936T1 (de) 2002-01-29 2003-01-03 Fischer-tropsch-verfahren mit verbesserter katalysatorregenerierung

Country Status (12)

Country Link
US (1) US6753354B2 (de)
EP (1) EP1478612B1 (de)
JP (1) JP4500548B2 (de)
CN (1) CN100398501C (de)
AT (1) ATE333936T1 (de)
AU (1) AU2003201821B8 (de)
CA (1) CA2471600A1 (de)
DE (1) DE60307057T2 (de)
DK (1) DK1478612T3 (de)
ES (1) ES2269972T3 (de)
WO (1) WO2003064356A1 (de)
ZA (1) ZA200404478B (de)

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GB0318027D0 (en) * 2003-08-01 2003-09-03 Accentus Plc Catalyst structure and catalytic reactor
EP2559482A1 (de) * 2004-02-24 2013-02-20 Japan Oil, Gas and Metals National Corporation Katalysator und Verfahren zur Herstellung von Kohlenwassertoffen
RU2007127896A (ru) * 2004-12-23 2009-01-27 Шелл Интернэшнл Рисерч Маатсхаппий Б.В. (NL) Способ получения катализатора и катализатор
US7524787B2 (en) * 2005-01-11 2009-04-28 Sasol Technology (Proprietary Limited) Producing supported cobalt catalysts for the Fisher-Tropsch synthesis
EP1965918A1 (de) * 2005-12-16 2008-09-10 Shell Internationale Research Maatschappij B.V. Verfahren zur herstellung eines kohlenwasserstoff-synthese-katalysators
US7825055B2 (en) * 2006-04-21 2010-11-02 Chevron U.S.A. Inc. Regeneration of ionic liquid catalyst using a regeneration metal in the presence of added hydrogen
US8614158B2 (en) * 2008-02-29 2013-12-24 Schlumberger Technology Corporation Fischer-trospch and oxygenate synthesis catalyst activation/regeneration in a micro scale process
US8293805B2 (en) * 2008-05-29 2012-10-23 Schlumberger Technology Corporation Tracking feedstock production with micro scale gas-to-liquid units
US20100152022A1 (en) * 2008-12-17 2010-06-17 Qi Sun Catalyst regeneration method
MY156352A (en) * 2008-12-18 2016-02-15 Shell Int Research Regeneration of a fischer tropsch catalyst by oxidating it and treating it with a mixture of ammonium carbonate, ammonium hydroxide and water
US8470725B2 (en) 2009-12-16 2013-06-25 Shell Oil Company Process for regenerating a catalyst
GB2482905B (en) 2010-08-19 2016-01-13 Gtl F1 Ag Fischer-tropsch catalyst regeneration
US8729140B2 (en) * 2010-12-23 2014-05-20 Shell Oil Company Process for regenerating a catalyst
FR2970187B1 (fr) * 2011-01-11 2013-02-08 Eurecat Sa Procede de regeneration hors site de catalyseurs solides.
US8389431B2 (en) 2011-02-03 2013-03-05 Steag Energy Services Gmbh Method for treating SCR catalysts having accumulated iron compounds
WO2014070857A2 (en) 2012-10-31 2014-05-08 Thermochem Recovery International, Inc. System and method for processing raw gas with in-situ catalyst regeneration
US10190057B2 (en) 2014-11-20 2019-01-29 Sasol Technology Proprietary Limited Fischer-tropsch synthesis
WO2017091400A1 (en) * 2015-11-23 2017-06-01 Clariant Corporation Processes for regenerating catalysts useful in fischer-tropsch processes
CN107952461B (zh) * 2016-10-17 2020-10-27 中国石油化工股份有限公司 一种负载型纳米钴催化剂及其应用
CN111282574B (zh) * 2020-02-03 2020-12-15 中国矿业大学(北京) 一种费托合成铁系催化剂的回收方法
CN114425439A (zh) * 2020-09-18 2022-05-03 中国石油化工股份有限公司 一种废催化裂化催化剂复活方法

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Also Published As

Publication number Publication date
JP4500548B2 (ja) 2010-07-14
EP1478612A4 (de) 2005-03-16
CN100398501C (zh) 2008-07-02
ZA200404478B (en) 2006-02-22
DE60307057D1 (de) 2006-09-07
CA2471600A1 (en) 2003-08-07
EP1478612B1 (de) 2006-07-26
DK1478612T3 (da) 2006-11-20
AU2003201821B2 (en) 2008-05-01
JP2005515893A (ja) 2005-06-02
EP1478612A1 (de) 2004-11-24
DE60307057T2 (de) 2006-12-28
US6753354B2 (en) 2004-06-22
WO2003064356A1 (en) 2003-08-07
US20030166451A1 (en) 2003-09-04
ES2269972T3 (es) 2007-04-01
CN1620411A (zh) 2005-05-25
AU2003201821B8 (en) 2008-06-26

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