ATE388119T1 - Verfahren zur katalytischen autothermen dampfreformierung von gemischen von höheren alkoholen, insbesondere ethanol mit kohlenwasserstoffen - Google Patents

Verfahren zur katalytischen autothermen dampfreformierung von gemischen von höheren alkoholen, insbesondere ethanol mit kohlenwasserstoffen

Info

Publication number
ATE388119T1
ATE388119T1 AT02026344T AT02026344T ATE388119T1 AT E388119 T1 ATE388119 T1 AT E388119T1 AT 02026344 T AT02026344 T AT 02026344T AT 02026344 T AT02026344 T AT 02026344T AT E388119 T1 ATE388119 T1 AT E388119T1
Authority
AT
Austria
Prior art keywords
alcohols
hydrocarbons
steam reforming
mixtures
higher alcohols
Prior art date
Application number
AT02026344T
Other languages
English (en)
Inventor
Stefan Wieland
Frank Baumann
Original Assignee
Umicore Ag & Co Kg
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Umicore Ag & Co Kg filed Critical Umicore Ag & Co Kg
Application granted granted Critical
Publication of ATE388119T1 publication Critical patent/ATE388119T1/de

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
    • C01B3/02—Production of hydrogen; Production of gaseous mixtures containing hydrogen
    • C01B3/22—Production of hydrogen; Production of gaseous mixtures containing hydrogen by decomposition of gaseous or liquid organic compounds
    • C01B3/24—Production of hydrogen; Production of gaseous mixtures containing hydrogen by decomposition of gaseous or liquid organic compounds of hydrocarbons
    • C01B3/26—Production of hydrogen; Production of gaseous mixtures containing hydrogen by decomposition of gaseous or liquid organic compounds of hydrocarbons using catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
    • C01B3/02—Production of hydrogen; Production of gaseous mixtures containing hydrogen
    • C01B3/32—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air
    • C01B3/323—Catalytic reaction of gaseous or liquid organic compounds other than hydrocarbons with gasifying agents
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C01B2203/0244—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being an autothermal reforming step, e.g. secondary reforming processes
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08—Methods of heating or cooling
    • C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
    • C01B2203/0838—Methods of heating the process for making hydrogen or synthesis gas by heat exchange with exothermic reactions, other than by combustion of fuel
    • C01B2203/0844—Methods of heating the process for making hydrogen or synthesis gas by heat exchange with exothermic reactions, other than by combustion of fuel the non-combustive exothermic reaction being another reforming reaction as defined in groups C01B2203/02 - C01B2203/0294
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1005—Arrangement or shape of catalyst
    • C01B2203/1023—Catalysts in the form of a monolith or honeycomb
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1005—Arrangement or shape of catalyst
    • C01B2203/1029—Catalysts in the form of a foam
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1047—Group VIII metal catalysts
    • C01B2203/1064—Platinum group metal catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1082—Composition of support materials
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205—Composition of the feed
    • C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C01B2203/1217—Alcohols
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205—Composition of the feed
    • C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C01B2203/1235—Hydrocarbons
    • C01B2203/1247—Higher hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/80—Aspect of integrated processes for the production of hydrogen or synthesis gas not covered by groups C01B2203/02 - C01B2203/1695
    • C01B2203/82—Several process steps of C01B2203/02 - C01B2203/08 integrated into a single apparatus
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Catalysts (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
AT02026344T 2001-11-22 2002-11-22 Verfahren zur katalytischen autothermen dampfreformierung von gemischen von höheren alkoholen, insbesondere ethanol mit kohlenwasserstoffen ATE388119T1 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE10157155A DE10157155A1 (de) 2001-11-22 2001-11-22 Verfahren zur katalytischen autothermen Dampfreformierung von höheren Alkoholen, insbesondere Ethanol

Publications (1)

Publication Number Publication Date
ATE388119T1 true ATE388119T1 (de) 2008-03-15

Family

ID=7706480

Family Applications (1)

Application Number Title Priority Date Filing Date
AT02026344T ATE388119T1 (de) 2001-11-22 2002-11-22 Verfahren zur katalytischen autothermen dampfreformierung von gemischen von höheren alkoholen, insbesondere ethanol mit kohlenwasserstoffen

Country Status (8)

Country Link
US (1) US6949683B2 (de)
EP (1) EP1314688B1 (de)
JP (1) JP2003183002A (de)
KR (1) KR100908401B1 (de)
AT (1) ATE388119T1 (de)
BR (1) BR0204774B1 (de)
CA (1) CA2412328C (de)
DE (2) DE10157155A1 (de)

Families Citing this family (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10136768B4 (de) * 2001-07-27 2012-03-01 Robert Bosch Gmbh Brennstoffzellenanlage mit zwei Umformeinheiten zur katalytischen Dekomposition und Verfahren zur katalytischen Dekomposition
DE10157155A1 (de) 2001-11-22 2003-06-12 Omg Ag & Co Kg Verfahren zur katalytischen autothermen Dampfreformierung von höheren Alkoholen, insbesondere Ethanol
US7274043B2 (en) * 2003-04-15 2007-09-25 Luminus Devices, Inc. Light emitting diode systems
JP4875295B2 (ja) * 2003-10-29 2012-02-15 株式会社日本触媒 部分酸化用改質触媒および改質方法
US7585339B2 (en) * 2004-09-15 2009-09-08 Haldor Topsoe A/S Process for reforming ethanol to hydrogen-rich products
KR100647331B1 (ko) * 2005-08-02 2006-11-23 삼성에스디아이 주식회사 연료전지용 쉬프트 반응기, 이를 채용한 연료전지 시스템및 상기 연료전지용 쉬프트 반응기의 운전 방법
FR2892323B1 (fr) * 2005-10-20 2008-08-15 Cie D Etudes Des Technologies Catalyseur pour la production d'un gaz riche en hydrogene.
US7951350B1 (en) 2007-01-26 2011-05-31 West Biofuels, Llc Fuel-gas reforming systems and methods
US20090014689A1 (en) * 2007-07-09 2009-01-15 Range Fuels, Inc. Methods and apparatus for producing syngas and alcohols
US20090093555A1 (en) * 2007-07-09 2009-04-09 Range Fuels, Inc. Methods and apparatus for producing syngas
US8153027B2 (en) * 2007-07-09 2012-04-10 Range Fuels, Inc. Methods for producing syngas
US8142530B2 (en) * 2007-07-09 2012-03-27 Range Fuels, Inc. Methods and apparatus for producing syngas and alcohols
MX2010000234A (es) * 2007-07-09 2010-03-22 Range Fuels Inc Metodo y aparato para la produccion de gas de sintesis.
US20090165368A1 (en) * 2007-12-28 2009-07-02 Yunquan Liu Process and apparatus for reforming gaseous and liquid fuels
WO2009136909A1 (en) * 2008-05-06 2009-11-12 West Biofuels, Llc Fuel-gas reforming systems and methods
JP5376222B2 (ja) * 2009-05-14 2013-12-25 独立行政法人産業技術総合研究所 エタノール水蒸気改質用触媒
US8207084B2 (en) 2009-06-23 2012-06-26 Ford Global Technologies, Llc Urea-resistant catalytic units and methods of using the same
US9611437B2 (en) * 2010-01-12 2017-04-04 Lummus Technology Inc. Producing low methane syngas from a two-stage gasifier
KR101463543B1 (ko) * 2014-02-13 2014-11-19 고천일 개선된 개질연료 제조장치 및 제조방법
JP6541339B2 (ja) * 2014-12-01 2019-07-10 クラリアント・プロドゥクテ・（ドイチュラント）・ゲゼルシャフト・ミト・ベシュレンクテル・ハフツング 炭化水素含有ガスの水蒸気改質触媒、水素製造装置、及び水素製造方法
KR101581235B1 (ko) * 2015-04-14 2015-12-30 고천일 개질연료 제조장치 및 제조방법
US12382670B2 (en) * 2020-11-04 2025-08-05 Samsung Electronics Co., Ltd. Thin film structure and semiconductor device comprising the same
CN116119708B (zh) * 2023-01-10 2024-12-17 广东工业大学 低层数反蛋白石结构二氧化锡电子传输层、制备方法及应用

Family Cites Families (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5815013B2 (ja) * 1980-07-17 1983-03-23 株式会社豊田中央研究所 水蒸気改質用触媒とその製造方法
US4415484A (en) * 1982-04-26 1983-11-15 United Technologies Corporation Autothermal reforming catalyst
DE3382193D1 (de) 1982-09-30 1991-04-11 Engelhard Corp Verfahren zur herstellung von wasserstoffreichem gas aus kohlenwasserstoffen.
DE3340569A1 (de) * 1983-11-09 1985-05-23 Sued Chemie Ag Katalysator zur herstellung von synthesegas bzw. von wasserstoff und verfahren zu dessen herstellung
US4755498A (en) * 1986-04-30 1988-07-05 International Fuel Cells Corporation Steam reforming catalyst
EP0303438A3 (de) * 1987-08-14 1989-12-27 DAVY McKEE CORPORATION Herstellung von Synthesegas aus kohlenwasserstoffhaltigem Rohrstoff
US5112527A (en) * 1991-04-02 1992-05-12 Amoco Corporation Process for converting natural gas to synthesis gas
DE4427665A1 (de) * 1994-08-04 1996-02-08 Sued Chemie Ag Katalysator für die Methandampfreformierung und/oder Methanoxidation
US6293979B1 (en) * 1994-12-19 2001-09-25 Council Of Scientific & Industrial Research Process for the catalytic conversion of methane or natural gas to syngas or a mixture of carbon monoxide and hydrogen
DE69825576T2 (de) * 1997-04-11 2005-08-11 Chiyoda Corp., Yokohama Katalysator für die herstellung von synthesegas und verfahren zur herstellung von kohlenmonoxid
US6267912B1 (en) * 1997-04-25 2001-07-31 Exxon Research And Engineering Co. Distributed injection catalytic partial oxidation process and apparatus for producing synthesis gas
US5883138A (en) * 1997-04-25 1999-03-16 Exxon Research And Engineering Company Rapid injection catalytic partial oxidation process and apparatus for producing synthesis gas (law 562)
US6110861A (en) 1997-06-02 2000-08-29 The University Of Chicago Partial oxidation catalyst
US20020007595A1 (en) * 1997-06-24 2002-01-24 Uli Maier-Roeltgen Method for reforming hydrocarbons autothermally
DE19727841A1 (de) 1997-06-24 1999-01-07 Fraunhofer Ges Forschung Verfahren und Vorrichtung zur autothermen Reformierung von Kohlenwasserstoffen
DE19753738A1 (de) * 1997-12-04 1999-06-10 Degussa Verfahren zur Herstellung eines Katalysators
GB9806199D0 (en) 1998-03-24 1998-05-20 Johnson Matthey Plc Catalytic generation of hydrogen
GR1003235B (el) * 1998-05-22 1999-10-13 Διεργασια παραγωγης υδρογονου και ηλεκτρικης ενεργειας απο αναμορφωση βιο-αιθανολης, με χρηση κυψελιδων καυσιμου και με μηδενικη εκπομπη ρυπων
US6146472A (en) * 1998-05-28 2000-11-14 The Timken Company Method of making case-carburized steel components with improved core toughness
WO1999064150A1 (en) 1998-06-09 1999-12-16 Idemitsu Kosan Co., Ltd. Catalyst and process for reforming hydrocarbon
CA2282948A1 (en) * 1998-09-16 2000-03-16 University Technologies International, Inc. Low temperature autothermal steam reformation of methane in a fluidized bed
US6524550B1 (en) * 1999-05-03 2003-02-25 Prashant S. Chintawar Process for converting carbon monoxide and water in a reformate stream
AU2001231082A1 (en) 2000-01-24 2001-07-31 International Fuel Cells, Llc Autothermal fuel gas reformer assemblage
US6458334B1 (en) * 2000-03-02 2002-10-01 The Boc Group, Inc. Catalytic partial oxidation of hydrocarbons
DE10025032A1 (de) 2000-05-20 2001-11-29 Dmc2 Degussa Metals Catalysts Verfahren zur autothermen, katalytischen Dampfreformierung von Kohlenwasserstoffen
US6436363B1 (en) * 2000-08-31 2002-08-20 Engelhard Corporation Process for generating hydrogen-rich gas
US7025903B2 (en) * 2001-02-15 2006-04-11 Delphi Technologies, Inc. Reformer system process
DE10157155A1 (de) 2001-11-22 2003-06-12 Omg Ag & Co Kg Verfahren zur katalytischen autothermen Dampfreformierung von höheren Alkoholen, insbesondere Ethanol

Also Published As

Publication number Publication date
JP2003183002A (ja) 2003-07-03
DE10157155A1 (de) 2003-06-12
CA2412328C (en) 2011-03-22
DE60225404D1 (de) 2008-04-17
US6949683B2 (en) 2005-09-27
BR0204774A (pt) 2003-09-16
CA2412328A1 (en) 2003-05-22
EP1314688A3 (de) 2003-12-17
KR100908401B1 (ko) 2009-07-21
US20030116472A1 (en) 2003-06-26
BR0204774B1 (pt) 2011-03-09
EP1314688A2 (de) 2003-05-28
EP1314688B1 (de) 2008-03-05
KR20030042433A (ko) 2003-05-28
DE60225404T2 (de) 2009-03-12

Similar Documents

Publication Publication Date Title
ATE388119T1 (de) Verfahren zur katalytischen autothermen dampfreformierung von gemischen von höheren alkoholen, insbesondere ethanol mit kohlenwasserstoffen
ATE325075T1 (de) Verfahren zur autothermen, katalytischen dampfreformierung von kohlenwasserstoffen
DE60012499D1 (de) Verfahren zur umwandlung von kohlenstoffmonoxid und wasser in einem reformatgasstrom und vorrichtung dazu
DE50114668D1 (de) Verfahren zur katalytischen Umsetzung von Kohlenmonoxid in einem Wasserstoff enthaltenden Gasgemisch
ATE502894T1 (de) Verfahren zur herstellung von synthesegas
DE69104735D1 (de) Dampfreformierungsverfahren mit Wärmeaustausch und Reaktorsystem.
GB2399516A (en) Process and apparatus for steam-methane reforming
BR0207275A (pt) Catalisador e método de reforma com vapor
ATE290998T1 (de) Verfahren zur autothermen dampfreformierung einer höhere kohlenwasserstoffe enthaltenden kohlenwasserstoffeinspeisung
DE60141606D1 (de) Verbessertes hydroprocessing-verfahren und verfahren zur umrüstung bestehender hydroprocessing-reaktoren
ATE332289T1 (de) Verfahren zur katalytischen oxydation von kohlenwasserstoffen
ATE440071T1 (de) Verfahren zur autothermen herstellung von wasserstoff
DE60104176D1 (de) Verfahren zur katalytischen Wasserstoffbehandlung von Silizium enthaltendem Naphtha
EA199800356A1 (ru) Способ и технологический блок получения газовой смеси для синтеза аммиака
DE60027341D1 (de) Verfahren zur Herstellung von Ammoniak und Ammoniak-Synthese-Katalysator
ATE241421T1 (de) Verfahren zur entfernung von schwefelverbindungen aus gasen
BRPI0210981B8 (pt) processo de preparação de complexos metálicos e processo de hidrossililação de compostos etilenicamente e/ou acetilenicamente insaturados
ITTO970223A1 (it) Procedimento per la generazione di un'atmosfera protettiva a basso punto di rugiada ed esente da ossigeno, per l'effettuazione di
DE60222417D1 (de) Verfahren zur herstellung von hydroxylammonium
MXPA02007608A (es) Catalizador y proceso de hidroconversion de hidrocarburos.
WO2004043890A3 (de) Verbesserter katalysator und verfahren zur herstellung von alkoholen durch hydrierung an diesem katalysator
DE59300490D1 (de) Verfahren zur herstellung einer mehrschichtigen lackierung, nicht-wässrige lacke und selbstvernetzbare polyacrylatharze.
KR970706204A (ko) 암모니아 또는 상응하는 아민, 수소 및 산소로부터 히드록실아민을 제조하는 방법(method of producing hydroxylamines from ammonia or the associated aminis, hydrogen and oxygen)
DE60030219D1 (de) Verfahren für die Reformierung von Methan mit Kohlendioxid
DE59403838D1 (de) Verfahren zur katalytischen Dehydrierung von Butandiol-1,4

Legal Events

Date Code Title Description
RER Ceased as to paragraph 5 lit. 3 law introducing patent treaties