GR1003235B - Διεργασια παραγωγης υδρογονου και ηλεκτρικης ενεργειας απο αναμορφωση βιο-αιθανολης, με χρηση κυψελιδων καυσιμου και με μηδενικη εκπομπη ρυπων - Google Patents
Διεργασια παραγωγης υδρογονου και ηλεκτρικης ενεργειας απο αναμορφωση βιο-αιθανολης, με χρηση κυψελιδων καυσιμου και με μηδενικη εκπομπη ρυπωνInfo
- Publication number
- GR1003235B GR1003235B GR980100180A GR980100180A GR1003235B GR 1003235 B GR1003235 B GR 1003235B GR 980100180 A GR980100180 A GR 980100180A GR 980100180 A GR980100180 A GR 980100180A GR 1003235 B GR1003235 B GR 1003235B
- Authority
- GR
- Greece
- Prior art keywords
- ethanol
- hydrogen
- mixture
- reactor
- bio
- Prior art date
Links
Classifications
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
- H01M8/0606—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants
- H01M8/0612—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants from carbon-containing material
- H01M8/0625—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants from carbon-containing material in a modular combined reactor/fuel cell structure
- H01M8/0631—Reactor construction specially adapted for combination reactor/fuel cell
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
- C01B3/02—Production of hydrogen; Production of gaseous mixtures containing hydrogen
- C01B3/32—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air
- C01B3/323—Catalytic reaction of gaseous or liquid organic compounds other than hydrocarbons with gasifying agents
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
- H01M8/0606—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants
- H01M8/0612—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants from carbon-containing material
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
- H01M8/0606—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants
- H01M8/0612—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants from carbon-containing material
- H01M8/0643—Gasification of solid fuel
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/10—Biofuels, e.g. bio-diesel
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Sustainable Development (AREA)
- Manufacturing & Machinery (AREA)
- Electrochemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Sustainable Energy (AREA)
- General Health & Medical Sciences (AREA)
- Combustion & Propulsion (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Hydrogen, Water And Hydrids (AREA)
- Fuel Cell (AREA)
- Preparation Of Compounds By Using Micro-Organisms (AREA)
- Catalysts (AREA)
Abstract
Μια διεργασία παραγωγής υδρογόνου και ηλεκτρικής ενέργειας, με μηδενική εκπομπή ρύπων, από αιθανόλη παραγόμενη από βιομάζα, που χαρακτηρίζεται από την μερική οξείδωση/αναμόρφωση της αιθανόλης με νερό για παραγωγή υδρογόνου το οποίο στη συνέχεια παρέχεται σε κυψελίδα καυσίμου για παραγωγή ηλεκτρικής ενέργειας, ειδικότερα όπου υδατικό διάλυμα αιθανόλης που προέρχεται από ζύμωση βιομάζας διαχωρίζεται με απόσταξη ή οποιαδήποτε άλλη τεχνική έτσι ώστε να περιέχει περίπου 40-70 % κατά βάρος αιθανόλη, κατά προτίμηση 50-60 %, το μίγμα αυτό, αναμιγνυόμενο με κατάλληλη ποσότητα αέρα, έτσι ώστε ο λόγος mol οξυγόνου προς αιθανόλη να είναι από μηδέν έως 0,5, παρέχεται σε αντιδραστήρα στον οποίο διεξάγονται οι αντιδράσεις μερικής οξείδωσης και αναμόρφωσης της αιθανόλης, σε κατάλληλο καταλύτη, όπου στον ίδιο ή σε διαφορετικό αντιδραστήρα διεξάγεται και η αντίδραση μετατόπισης και, εάν είναι αναγκαίο η αντίδραση καύσης του μονοξειδίου του άνθρακα ή μετατροπής του σε μεθάνιο, όπου το αέριο μίγμα στην έξοδο των αντιδραστήρων το οποίο περιέχει υδρογόνο σε μίγμα με διοξείδιο του άνθρακα, άζωτο, μεθάνιο ή άλλα αέρια σε μικρές ποσότητες, διαχωρίζεται στον βαθμό που είναι επιθυμητός για οποιαδήποτε χρήση.ΰ
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GR98100180 | 1998-05-22 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GR1003235B true GR1003235B (el) | 1999-10-13 |
Family
ID=10943392
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GR980100180A GR1003235B (el) | 1998-05-22 | 1998-05-22 | Διεργασια παραγωγης υδρογονου και ηλεκτρικης ενεργειας απο αναμορφωση βιο-αιθανολης, με χρηση κυψελιδων καυσιμου και με μηδενικη εκπομπη ρυπων |
Country Status (11)
| Country | Link |
|---|---|
| US (2) | US6387554B1 (el) |
| EP (1) | EP1007472B1 (el) |
| AT (1) | ATE248766T1 (el) |
| CA (2) | CA2704690A1 (el) |
| DE (1) | DE69910957T2 (el) |
| DK (1) | DK1007472T3 (el) |
| EA (1) | EA002382B1 (el) |
| ES (1) | ES2209430T3 (el) |
| GR (1) | GR1003235B (el) |
| PT (1) | PT1007472E (el) |
| WO (1) | WO1999061369A1 (el) |
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| EP1375628A3 (en) * | 2000-01-21 | 2004-12-08 | Integrated Environmental Technologies, Llc. | Methods and apparatus for treating waste |
| US7025875B2 (en) * | 2001-05-14 | 2006-04-11 | Delphi Technologies, Inc. | Diesel fuel reforming strategy |
| JP4098508B2 (ja) * | 2001-08-20 | 2008-06-11 | 財団法人 ひろしま産業振興機構 | 炭化水素と水蒸気とを反応させるための触媒の製造方法および当該触媒を使用した炭化水素から水素を製造する方法 |
| DE10157155A1 (de) * | 2001-11-22 | 2003-06-12 | Omg Ag & Co Kg | Verfahren zur katalytischen autothermen Dampfreformierung von höheren Alkoholen, insbesondere Ethanol |
| US6699457B2 (en) * | 2001-11-29 | 2004-03-02 | Wisconsin Alumni Research Foundation | Low-temperature hydrogen production from oxygenated hydrocarbons |
| NZ533175A (en) * | 2001-11-29 | 2006-03-31 | Wisconsin Alumni Res Found | Low-temperature hydrogen production from oxygenated hydrocarbons |
| CN1310851C (zh) * | 2002-05-10 | 2007-04-18 | 威斯康星旧生研究基金会 | 由氧化烃低温生产烃 |
| AUPS244802A0 (en) * | 2002-05-21 | 2002-06-13 | Ceramic Fuel Cells Limited | Fuel cell system |
| US7255848B2 (en) | 2002-10-01 | 2007-08-14 | Regents Of The Univeristy Of Minnesota | Production of hydrogen from alcohols |
| US7262334B2 (en) | 2002-11-13 | 2007-08-28 | Regents Of The University Of Minnesota | Catalytic partial oxidation of hydrocarbons |
| US7276306B2 (en) * | 2003-03-12 | 2007-10-02 | The Regents Of The University Of California | System for the co-production of electricity and hydrogen |
| US7195059B2 (en) * | 2003-05-06 | 2007-03-27 | H2Gen Innovations, Inc. | Heat exchanger and method of performing chemical processes |
| EP1652257A2 (en) * | 2003-08-07 | 2006-05-03 | CBH2 Technologies, Inc. | Hypergolic hydrogen generation system for fuel cell power plants |
| DE102004006516A1 (de) * | 2004-02-10 | 2005-08-25 | Voith Paper Patent Gmbh | Verfahren zur Erzeugung von Prozesswärme und/oder elektrischer Energie |
| WO2005097319A1 (en) * | 2004-04-08 | 2005-10-20 | Sulzer Metco (Canada) Inc. | Supported catalyst for steam methane reforming and autothermal reforming reactions |
| US20050226808A1 (en) * | 2004-04-12 | 2005-10-13 | King Fahd University Of Petroleum And Minerals | Laser photo-catalytic process for the production of hydrogen |
| US7683232B2 (en) | 2004-05-25 | 2010-03-23 | Regents Of The University Of Minnesota | Production of olefins having a functional group |
| CA2573476C (en) * | 2004-07-12 | 2013-12-24 | Sumitomo Seika Chemicals Co., Ltd. | Hydrogen production system and reforming apparatus |
| CA2577844A1 (en) * | 2004-08-23 | 2006-03-02 | Enviroplus Gmbh | Self-sustaining and continuous system and method of anaerobically digesting ethanol stillage |
| US7585339B2 (en) * | 2004-09-15 | 2009-09-08 | Haldor Topsoe A/S | Process for reforming ethanol to hydrogen-rich products |
| EP1669323B1 (en) * | 2004-12-08 | 2017-07-05 | Karlsruher Institut für Technologie | Reactor and method for the production of hydrogen |
| US20080028675A1 (en) * | 2005-05-10 | 2008-02-07 | Nbe,Llc | Biomass treatment of organic waste materials in fuel production processes to increase energy efficiency |
| WO2007002503A1 (en) * | 2005-06-23 | 2007-01-04 | Cop Energy Technologies Llc | Hydrogen production using electrochemical reforming and electrolyte regeneration |
| BRPI0520657A2 (pt) * | 2005-10-07 | 2009-05-19 | Midwest Research Inst | catalisador de reforma fluidizável resistente ao atrito |
| JP2009515036A (ja) * | 2005-10-14 | 2009-04-09 | オハイオ ユニバーシティ | アルカリ媒体中におけるアンモニア及びエタノールを酸化するためのカーボンファイバー電極触媒、ならびに水素生成、燃料電池および精製プロセスへのその適用 |
| CA2634712C (en) * | 2005-12-21 | 2015-11-24 | Virent Energy Systems, Inc. | Catalysts and methods for reforming oxygenated compounds |
| KR100711509B1 (ko) | 2006-01-02 | 2007-04-27 | 재단법인서울대학교산학협력재단 | 자열개질 반응에 의해 물과 에탄올 혼합물로부터 수소를 제조하는데 사용되는 복합 금속 담지 촉매, 그 제조 방법 및 상기 촉매를 이용하여 수소를 제조하는 방법 |
| WO2007118148A2 (en) | 2006-04-07 | 2007-10-18 | Thermal Kinetics Engineering P | Production of dry alcohol |
| US7428810B2 (en) * | 2006-04-25 | 2008-09-30 | Caterpillar Inc. | System for increasing efficiency of an SCR catalyst |
| ES2547913T3 (es) | 2006-05-08 | 2015-10-09 | Virent, Inc. | Métodos para generar polioles |
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| AU2007353527B2 (en) * | 2006-12-20 | 2012-12-20 | Virent, Inc. | Reactor system for producing gaseous products |
| RU2472840C2 (ru) * | 2007-03-08 | 2013-01-20 | Вайрент, Инк. | Синтез жидкого топлива и химических реактивов из кислородсодержащих углеводородов |
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| GR20070100315A (el) * | 2007-05-25 | 2008-12-19 | . | Υψηλα θερμικα ολοκληρωμενος επεξεργαστης καυσιμουγια παραγωγη υδρογονου |
| GR1006128B (el) * | 2007-05-25 | 2008-11-03 | . | Υψηλα θερμικα ολοκληρωμενος αναμορφωτης για παραγωγη υδρογονου |
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| US8697924B2 (en) * | 2008-09-05 | 2014-04-15 | Shell Oil Company | Liquid fuel compositions |
| KR101417235B1 (ko) | 2008-12-01 | 2014-07-08 | 란자테크 뉴질랜드 리미티드 | 최적화된 발효 배지 |
| KR101008025B1 (ko) * | 2008-12-22 | 2011-01-14 | 삼성에스디아이 주식회사 | 탄화수소 개질촉매, 그의 제조 방법 및 이를 포함하는 연료전지 |
| US20100187822A1 (en) * | 2009-01-23 | 2010-07-29 | Louisville Clean Energy, Llc | Multi-process method of combined heat and power generation, biodiesel production, ethanol production, town gas production, methane production, and syngas production |
| US20100187818A1 (en) * | 2009-01-23 | 2010-07-29 | Louisville Clean Energy, Llc | Multi-process method of combined heat and power generation, biodiesel production, ethanol production, town gas production and methane production |
| EP2448675A2 (en) * | 2009-06-30 | 2012-05-09 | Virent, Inc. | Process and reactor systems for converting sugars and sugar alcohols |
| US8026087B2 (en) * | 2009-09-23 | 2011-09-27 | Russell W Spitz | Method of continuously producing ethanol and electricity from a sustainable renewable biomass feedstock |
| US7818969B1 (en) * | 2009-12-18 | 2010-10-26 | Energyield, Llc | Enhanced efficiency turbine |
| US9303226B2 (en) | 2009-12-31 | 2016-04-05 | Shell Oil Company | Direct aqueous phase reforming of bio-based feedstocks |
| US9447347B2 (en) | 2009-12-31 | 2016-09-20 | Shell Oil Company | Biofuels via hydrogenolysis-condensation |
| EP2547619B1 (en) * | 2010-03-16 | 2017-10-25 | Shell Oil Company | A process for producing hydrogen |
| CN102791618A (zh) | 2010-03-16 | 2012-11-21 | 国际壳牌研究有限公司 | 制氢方法 |
| EP2547620A1 (en) * | 2010-03-16 | 2013-01-23 | Shell Oil Company | A process for producing hydrogen |
| AU2011253083B2 (en) | 2010-05-12 | 2014-08-21 | Shell Internationale Research Maatschappij B.V. | Process including hydrogenolysis of biomass followed by dehydrogenation and aldol condensation to produce alkanes |
| US9428704B2 (en) | 2010-05-12 | 2016-08-30 | Shell Oil Company | Direct aqueous phase reforming and aldol condensation to form bio-based fuels |
| US20120045699A1 (en) * | 2010-08-20 | 2012-02-23 | Shailesh Atreya | Fuel Cell Power and Water Generation |
| EP2455334A1 (en) | 2010-11-18 | 2012-05-23 | Tecnicas Reunidas, S.A. | Ethanol processing system |
| WO2013117948A1 (en) | 2012-02-06 | 2013-08-15 | Helbio Societé Anonyme Hydrogen And Energy Production Systems | Heat integrated reformer with catalytic combustion for hydrogen production |
| US11607657B2 (en) | 2012-02-06 | 2023-03-21 | Helbio S.A. | Heat integrated reformer with catalytic combustion for hydrogen production |
| JP2015517175A (ja) | 2012-03-08 | 2015-06-18 | ヘルビオ ソシエテ アノニム ハイドロジェン アンド エナジー プロダクション システムズ | 燃料電池のための触媒を支持する置換可能な構造化支持部を含む触媒加熱式燃料処理装置 |
| EP2671842A1 (en) * | 2012-06-06 | 2013-12-11 | Ammonia Casale S.A. | A process for gas-heated reforming of a hydrocarbon source and a related plant |
| CN107302100A (zh) * | 2017-07-31 | 2017-10-27 | 北京理工大学 | 一种基于乙醇重整制氢的氢燃料电池系统及其发电方法 |
| CN111048809A (zh) * | 2019-12-13 | 2020-04-21 | 沈阳航空航天大学 | 基于秸秆乙醇发酵重整制氢气的氢氧燃料电池智能发电系统 |
| CN118062807B (zh) * | 2024-02-26 | 2024-11-19 | 中国矿业大学 | 镍铁镧三元负载型催化剂在微波驱动低碳醇水蒸气重整制氢反应中的应用 |
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| JPS59189935A (ja) * | 1983-04-14 | 1984-10-27 | Mitsubishi Heavy Ind Ltd | エタノ−ル改質用触媒 |
| JPS6339626A (ja) * | 1986-08-01 | 1988-02-20 | Yamaha Motor Co Ltd | 燃料電池用改質装置 |
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1998
- 1998-05-22 GR GR980100180A patent/GR1003235B/el not_active IP Right Cessation
-
1999
- 1999-05-19 EP EP99919449A patent/EP1007472B1/en not_active Expired - Lifetime
- 1999-05-19 EA EA199901058A patent/EA002382B1/ru not_active IP Right Cessation
- 1999-05-19 AT AT99919449T patent/ATE248766T1/de not_active IP Right Cessation
- 1999-05-19 CA CA2704690A patent/CA2704690A1/en not_active Abandoned
- 1999-05-19 US US09/446,561 patent/US6387554B1/en not_active Expired - Fee Related
- 1999-05-19 DE DE69910957T patent/DE69910957T2/de not_active Expired - Lifetime
- 1999-05-19 CA CA002294361A patent/CA2294361A1/en not_active Abandoned
- 1999-05-19 ES ES99919449T patent/ES2209430T3/es not_active Expired - Lifetime
- 1999-05-19 WO PCT/GR1999/000020 patent/WO1999061369A1/en not_active Ceased
- 1999-05-19 PT PT99919449T patent/PT1007472E/pt unknown
- 1999-05-19 DK DK99919449T patent/DK1007472T3/da active
-
2000
- 2000-12-01 US US09/728,569 patent/US6605376B2/en not_active Expired - Fee Related
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| JPS59189935A (ja) * | 1983-04-14 | 1984-10-27 | Mitsubishi Heavy Ind Ltd | エタノ−ル改質用触媒 |
| JPS6339626A (ja) * | 1986-08-01 | 1988-02-20 | Yamaha Motor Co Ltd | 燃料電池用改質装置 |
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Also Published As
| Publication number | Publication date |
|---|---|
| US6387554B1 (en) | 2002-05-14 |
| CA2294361A1 (en) | 1999-12-02 |
| WO1999061369A1 (en) | 1999-12-02 |
| DK1007472T3 (da) | 2003-12-22 |
| EP1007472A1 (en) | 2000-06-14 |
| EA002382B1 (ru) | 2002-04-25 |
| ES2209430T3 (es) | 2004-06-16 |
| US20010023034A1 (en) | 2001-09-20 |
| CA2704690A1 (en) | 1999-12-02 |
| EA199901058A1 (ru) | 2000-10-30 |
| ATE248766T1 (de) | 2003-09-15 |
| EP1007472B1 (en) | 2003-09-03 |
| DE69910957D1 (de) | 2003-10-09 |
| US6605376B2 (en) | 2003-08-12 |
| DE69910957T2 (de) | 2004-08-12 |
| PT1007472E (pt) | 2004-01-30 |
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