ATE395314T1 - Katalytisches hydrierungsverfahren - Google Patents

Katalytisches hydrierungsverfahren

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Publication number
ATE395314T1
ATE395314T1 AT01958310T AT01958310T ATE395314T1 AT E395314 T1 ATE395314 T1 AT E395314T1 AT 01958310 T AT01958310 T AT 01958310T AT 01958310 T AT01958310 T AT 01958310T AT E395314 T1 ATE395314 T1 AT E395314T1
Authority
AT
Austria
Prior art keywords
line
formulae
phosphino
catalytic hydrogenation
hydrogenation process
Prior art date
Application number
AT01958310T
Other languages
English (en)
Inventor
Valentin Rautenstrauch
Rene Challand
Rapha L Churlaud
Robert Morris
Kamaluddin Abdur-Rashid
Eric Brazi
Hubert Mimoun
Original Assignee
Firmenich & Cie
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Firmenich & Cie filed Critical Firmenich & Cie
Application granted granted Critical
Publication of ATE395314T1 publication Critical patent/ATE395314T1/de

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/189—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms containing both nitrogen and phosphorus as complexing atoms, including e.g. phosphino moieties, in one at least bidentate or bridging ligand
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B01J31/2409—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring with more than one complexing phosphine-P atom
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B41/00—Formation or introduction of functional groups containing oxygen
    • C07B41/02—Formation or introduction of functional groups containing oxygen of hydroxy or O-metal groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B43/00—Formation or introduction of functional groups containing nitrogen
    • C07B43/04—Formation or introduction of functional groups containing nitrogen of amino groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/44—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of carboxylic acids or esters thereof in presence of ammonia or amines, or by reduction of nitriles, carboxylic acid amides, imines or imino-ethers
    • C07C209/52—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of carboxylic acids or esters thereof in presence of ammonia or amines, or by reduction of nitriles, carboxylic acid amides, imines or imino-ethers by reduction of imines or imino-ethers
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/14—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group
    • C07C29/141—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group with hydrogen or hydrogen-containing gases
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/143—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of ketones
    • C07C29/145—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of ketones with hydrogen or hydrogen-containing gases
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
    • C07F15/0046—Ruthenium compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
    • C07F15/0046—Ruthenium compounds
    • C07F15/0053—Ruthenium compounds without a metal-carbon linkage
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/60—Reduction reactions, e.g. hydrogenation
    • B01J2231/64—Reductions in general of organic substrates, e.g. hydride reductions or hydrogenations
    • B01J2231/641—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes
    • B01J2231/643—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes of R2C=O or R2C=NR (R= C, H)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/821—Ruthenium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B2200/00—Indexing scheme relating to specific properties of organic compounds
    • C07B2200/07—Optical isomers
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/06—Systems containing only non-condensed rings with a five-membered ring
    • C07C2601/08—Systems containing only non-condensed rings with a five-membered ring the ring being saturated
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/16—Systems containing only non-condensed rings with a six-membered ring the ring being unsaturated

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
AT01958310T 2000-09-13 2001-09-11 Katalytisches hydrierungsverfahren ATE395314T1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US23214400P 2000-09-13 2000-09-13
IB0001303 2000-09-13

Publications (1)

Publication Number Publication Date
ATE395314T1 true ATE395314T1 (de) 2008-05-15

Family

ID=26318616

Family Applications (1)

Application Number Title Priority Date Filing Date
AT01958310T ATE395314T1 (de) 2000-09-13 2001-09-11 Katalytisches hydrierungsverfahren

Country Status (10)

Country Link
US (2) US7317131B2 (de)
EP (1) EP1366004B1 (de)
JP (2) JP5345270B2 (de)
AT (1) ATE395314T1 (de)
AU (1) AU2001280028A1 (de)
CA (1) CA2422029C (de)
DE (1) DE60134052D1 (de)
ES (1) ES2305095T3 (de)
IL (2) IL154822A0 (de)
WO (1) WO2002022526A2 (de)

Families Citing this family (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ATE496880T1 (de) * 2002-05-15 2011-02-15 Kamaluddin Abdur-Rashid Prozess zur hydrierung von nicht-aktivierten iminen unter verwendung von ruthenium-komplexen als katalysatoren
US7446236B2 (en) 2002-12-02 2008-11-04 Solvias Ag Catalytic hydrogenation of carbon-heteroatom double bonds
JP4704812B2 (ja) * 2004-06-09 2011-06-22 エム． カレイラ エリック モノホスフィン化合物、その遷移金属錯体および該錯体を不斉触媒として用いる光学活性化合物の製造方法
JP5388570B2 (ja) * 2005-04-05 2014-01-15 フイルメニツヒ ソシエテ アノニム Ｒｕ／四座配位子錯体を用いたエステルの水素化
MX2007012299A (es) * 2005-04-05 2007-10-16 Firmenich & Cie Hidrogenacion de esteres con complejos de ligandos de ru/bidentados.
WO2007082928A2 (de) * 2006-01-23 2007-07-26 Basf Se Verfahren zur herstellung eines ruthenium-katalysators
JP2007314433A (ja) * 2006-05-23 2007-12-06 Univ Of Tokyo 光学活性三級ホスフィン化合物、これを配位子とする金属錯体およびその用途
CN100465144C (zh) * 2006-12-01 2009-03-04 华南理工大学 一种负载型非晶态含钌硼催化剂催化加氢还原羰基化合物制备醇的方法
CA2591126A1 (en) 2007-06-08 2008-12-08 Kanata Chemical Technologies Inc. Process for the preparation of aminiphosphine ligands and their use in metal catalysts
CA2690437C (en) * 2007-07-06 2015-09-08 Kanata Chemical Technologies Inc. Method for the preparation of cis-4-tert-butylcyclohexanol
CA2636947C (en) 2007-07-06 2015-05-19 Kamaluddin Abdur-Rashid Ruthenium catalysts for catalytic hydrogenation
EP2215069B1 (de) 2007-10-23 2011-07-06 Firmenich S.A. Verfahren zur herstellung von tetranorlabdanderivaten
EP2215101A4 (de) * 2007-10-30 2013-04-24 Kanata Chemical Technologies Inc Kationische übergangsmetallkatalysatoren
US7615671B2 (en) 2007-11-30 2009-11-10 Eastman Chemical Company Hydrogenation process for the preparation of 1,2-diols
JP5451209B2 (ja) 2008-07-08 2014-03-26 国立大学法人東京工業大学 エステル類およびラクトン類の実用的な還元方法
WO2010043027A1 (en) 2008-10-17 2010-04-22 Kanata Chemical Technologies Inc. Method for preparing a metal catalyst
WO2010061350A1 (en) 2008-11-28 2010-06-03 Firmenich Sa Hydrogenation of ester, ketone or aldehyde groups with ruthenium complexes having a di-amine and a phosphorous-nitrogen bidentate ligand
EP2236487B1 (de) 2009-04-02 2015-09-02 International Flavors & Fragrances Inc. Verfahren zur Herstellung von Levosandal
US8038855B2 (en) * 2009-04-29 2011-10-18 Freeport-Mcmoran Corporation Anode structure for copper electrowinning
JP6080774B2 (ja) 2010-12-21 2017-02-15 フイルメニツヒ ソシエテ アノニムＦｉｒｍｅｎｉｃｈ Ｓａ 四座アミノ／イミノ−チオエーテルベースのルテニウム錯体によるエステル基又はカルボニル基の水素化
JP6138138B2 (ja) 2011-10-06 2017-05-31 フイルメニツヒ ソシエテ アノニムＦｉｒｍｅｎｉｃｈ Ｓａ Ｒｕ／二座配位子錯体によるアルデヒドの選択的水素化
BR112015022807A2 (pt) * 2013-03-15 2017-07-18 Firmenich & Cie hidrogenação seletiva de aldeídos com complexos de ligantes de ru/bidentados
GB201509664D0 (en) * 2015-06-03 2015-07-15 Johnson Matthey Plc And Universit Di Udine Process
WO2019193483A1 (en) 2018-04-06 2019-10-10 Kamal Pharmachem Inc. Catalytic conversion of carbon dioxide to methanol
CN109553509A (zh) * 2018-12-17 2019-04-02 西安近代化学研究所 一种2,2,3,3,3-五氟丙醇的制备方法

Family Cites Families (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2739254B2 (ja) * 1990-10-01 1998-04-15 高砂香料工業株式会社 イリジウム―光学活性ホスフィン錯体及びこれを用いた光学活性アルコールの製造方法
FR2693190B1 (fr) * 1992-07-02 1994-09-23 Elf Aquitaine Procédé d'hydrogénation énantiosélectif de la double liaison C=O OXO.
JP2731377B2 (ja) * 1994-12-07 1998-03-25 科学技術振興事業団 光学活性アルコール類の製造方法
JP2935453B2 (ja) * 1994-12-07 1999-08-16 科学技術振興事業団 アルコール類の製造方法
DE69518497T2 (de) 1994-12-07 2001-04-19 Japan Science And Technology Corp., Kawaguchi Verfahren zur Herstellung eines Alkohols
JP2962668B2 (ja) * 1995-12-06 1999-10-12 科学技術振興事業団 光学活性アルコール類の製造方法
JP2912572B2 (ja) * 1995-12-06 1999-06-28 科学技術振興事業団 光学活性アミン類の製造方法
US6184381B1 (en) * 1995-12-06 2001-02-06 Japan Science & Technology Corp. Process for preparing optically active compounds
DE19548399A1 (de) * 1995-12-22 1997-06-26 Basf Ag Rutheniumkomplexe mit einem chiralen, zweizähnigen Phosphinoxazolin-Liganden zur enantioselektiven Transferhydrierung von prochiralen Ketonen
JP3771615B2 (ja) * 1995-12-28 2006-04-26 高砂香料工業株式会社 光学活性ベンズヒドロール化合物の製造方法
JPH09241194A (ja) * 1996-03-07 1997-09-16 Takasago Internatl Corp シス−４−ｔ−ブチルシクロヘキサノールの製造法
JPH10273456A (ja) * 1997-03-31 1998-10-13 Kagaku Gijutsu Shinko Jigyodan 光学活性アルコール類の製造方法
CN1047597C (zh) * 1997-06-02 1999-12-22 厦门大学 手性胺膦金属配合物及其制备方法和在不对称催化氢化的应用
JP4144814B2 (ja) * 1997-09-05 2008-09-03 長谷川香料株式会社 光学活性アルコール化合物の製造方法
JPH11124350A (ja) * 1997-10-21 1999-05-11 Mitsubishi Chemical Corp 光学活性アルコールの製造方法
JP4004123B2 (ja) * 1997-12-26 2007-11-07 独立行政法人科学技術振興機構 ルテニウム錯体を触媒とするアルコール化合物の製造方法
JP2000026344A (ja) * 1998-07-01 2000-01-25 Ryoji Noyori 光学活性な１−（４−イソブチルフェニル）ブタン−１−オールの製造方法
JP3771070B2 (ja) 1998-12-24 2006-04-26 高砂香料工業株式会社 軸不斉化合物の製造方法、その製造中間体、新規な軸不斉化合物を配位子とする遷移金属錯体、不斉水素化触媒及び不斉炭素−炭素結合形成触媒
JP2001294594A (ja) * 2000-02-10 2001-10-23 Toray Ind Inc ホスフィン含有アミノ化合物、その製造方法、ルテニウム錯体およびアルコールの製造方法
US6878852B2 (en) * 2000-11-17 2005-04-12 Firmenich Sa Process for hydrogenation of carbonyl and iminocarbonyl compounds using ruthenium catalysts comprising tetradentate diimino-diphosphine ligands

Also Published As

Publication number Publication date
JP2004509087A (ja) 2004-03-25
WO2002022526A2 (en) 2002-03-21
DE60134052D1 (de) 2008-06-26
IL154822A0 (en) 2003-10-31
WO2002022526A3 (en) 2003-09-12
EP1366004B1 (de) 2008-05-14
JP2012087138A (ja) 2012-05-10
CA2422029C (en) 2008-11-18
JP5345270B2 (ja) 2013-11-20
AU2001280028A1 (en) 2002-03-26
US7317131B2 (en) 2008-01-08
US20080015376A1 (en) 2008-01-17
US20040063966A1 (en) 2004-04-01
US20050245748A9 (en) 2005-11-03
CA2422029A1 (en) 2002-03-21
ES2305095T3 (es) 2008-11-01
EP1366004A2 (de) 2003-12-03
IL154822A (en) 2009-11-18
US7579295B2 (en) 2009-08-25

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