ATE395972T1 - Presulfatierter und prenitrierter katalysator, enhaltend platinum auf träger bestehend aus magnesiumoxid und ceroxid für die reduktion von no zu n2 mit wasserstoff unter nox- oxidationsbedingungen - Google Patents
Presulfatierter und prenitrierter katalysator, enhaltend platinum auf träger bestehend aus magnesiumoxid und ceroxid für die reduktion von no zu n2 mit wasserstoff unter nox- oxidationsbedingungenInfo
- Publication number
- ATE395972T1 ATE395972T1 AT03704721T AT03704721T ATE395972T1 AT E395972 T1 ATE395972 T1 AT E395972T1 AT 03704721 T AT03704721 T AT 03704721T AT 03704721 T AT03704721 T AT 03704721T AT E395972 T1 ATE395972 T1 AT E395972T1
- Authority
- AT
- Austria
- Prior art keywords
- oxidation conditions
- ceo2
- prenitired
- presulfated
- ceroxide
- Prior art date
Links
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 title abstract 7
- 239000003054 catalyst Substances 0.000 title abstract 4
- 229910052697 platinum Inorganic materials 0.000 title abstract 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical class [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title abstract 2
- 239000001257 hydrogen Substances 0.000 title abstract 2
- 229910052739 hydrogen Inorganic materials 0.000 title abstract 2
- 230000003647 oxidation Effects 0.000 title abstract 2
- 238000007254 oxidation reaction Methods 0.000 title abstract 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 title 1
- 239000000395 magnesium oxide Substances 0.000 title 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 title 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract 4
- 229910000422 cerium(IV) oxide Inorganic materials 0.000 abstract 3
- MWUXSHHQAYIFBG-UHFFFAOYSA-N Nitric oxide Chemical compound O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 abstract 2
- 238000006243 chemical reaction Methods 0.000 abstract 2
- 229910052757 nitrogen Inorganic materials 0.000 abstract 2
- -1 5 % vol) Chemical compound 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- CETPSERCERDGAM-UHFFFAOYSA-N ceric oxide Chemical compound O=[Ce]=O CETPSERCERDGAM-UHFFFAOYSA-N 0.000 abstract 1
- 239000003638 chemical reducing agent Substances 0.000 abstract 1
- 239000013078 crystal Substances 0.000 abstract 1
- 230000000694 effects Effects 0.000 abstract 1
- 239000007789 gas Substances 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 239000011541 reaction mixture Substances 0.000 abstract 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/02—Sulfur, selenium or tellurium; Compounds thereof
- B01J27/053—Sulfates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
- B01D53/8621—Removing nitrogen compounds
- B01D53/8625—Nitrogen oxides
- B01D53/8628—Processes characterised by a specific catalyst
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
- B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
- B01D53/9404—Removing only nitrogen compounds
- B01D53/9409—Nitrogen oxides
- B01D53/9413—Processes characterised by a specific catalyst
- B01D53/9418—Processes characterised by a specific catalyst for removing nitrogen oxides by selective catalytic reduction [SCR] using a reducing agent in a lean exhaust gas
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/10—Magnesium; Oxides or hydroxides thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
- B01J23/63—Platinum group metals with rare earths or actinides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2251/00—Reactants
- B01D2251/20—Reductants
- B01D2251/202—Hydrogen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/10—Noble metals or compounds thereof
- B01D2255/102—Platinum group metals
- B01D2255/1021—Platinum
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/20—Metals or compounds thereof
- B01D2255/204—Alkaline earth metals
- B01D2255/2047—Magnesium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/20—Metals or compounds thereof
- B01D2255/206—Rare earth metals
- B01D2255/2065—Cerium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
- B01J23/58—Platinum group metals with alkali- or alkaline earth metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
- B01J35/391—Physical properties of the active metal ingredient
- B01J35/394—Metal dispersion value, e.g. percentage or fraction
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/03—Precipitation; Co-precipitation
- B01J37/036—Precipitation; Co-precipitation to form a gel or a cogel
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/12—Oxidising
- B01J37/14—Oxidising with gases containing free oxygen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/16—Reducing
- B01J37/18—Reducing with gases containing free hydrogen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/20—Sulfiding
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Environmental & Geological Engineering (AREA)
- Health & Medical Sciences (AREA)
- Biomedical Technology (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Combustion & Propulsion (AREA)
- Catalysts (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ES200200368A ES2192985B1 (es) | 2002-02-15 | 2002-02-15 | Nuevo catalizador para la reduccion de no a n2 con hidrogeno en condiciones de nox oxidantes. |
| PCT/ES2003/000083 WO2003068390A1 (es) | 2002-02-15 | 2003-02-14 | Nuevo catalizador para la reduccion de no a n2 con hidrogeno en condiciones de nox oxidantes |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ATE395972T1 true ATE395972T1 (de) | 2008-06-15 |
Family
ID=27675924
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AT03704721T ATE395972T1 (de) | 2002-02-15 | 2003-02-14 | Presulfatierter und prenitrierter katalysator, enhaltend platinum auf träger bestehend aus magnesiumoxid und ceroxid für die reduktion von no zu n2 mit wasserstoff unter nox- oxidationsbedingungen |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US7105137B2 (de) |
| EP (1) | EP1475149B1 (de) |
| JP (1) | JP2005516767A (de) |
| AT (1) | ATE395972T1 (de) |
| AU (1) | AU2003206981A1 (de) |
| DE (1) | DE60321136D1 (de) |
| ES (2) | ES2192985B1 (de) |
| WO (1) | WO2003068390A1 (de) |
Families Citing this family (26)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7521392B1 (en) * | 2004-11-19 | 2009-04-21 | Nanostellar, Inc. | Supported catalysts having platinum particles |
| JP2006281033A (ja) * | 2005-03-31 | 2006-10-19 | Mazda Motor Corp | 排気ガス用浄化触媒 |
| EP1810751A1 (de) | 2006-01-20 | 2007-07-25 | Universität Karlsruhe (TH) | Verfahren zur Herstellung eines eisenhaltigen SCR-Katalysators |
| DE102006012206A1 (de) * | 2006-03-16 | 2007-09-20 | Linde Ag | Verfahren zur Entfernung von Stickoxiden aus Rauchgasen von Verbrennungsöfen |
| JP2007260641A (ja) * | 2006-03-30 | 2007-10-11 | Toyota Motor Corp | 排ガス浄化用触媒およびその製造方法 |
| US20100018476A1 (en) * | 2007-05-31 | 2010-01-28 | Svetlana Mikhailovna Zemskova | On-board hydrogen generator |
| US8691170B2 (en) * | 2007-05-31 | 2014-04-08 | Siemens Energy, Inc. | System and method for selective catalytic reduction of nitrogen oxides in combustion exhaust gases |
| US7744840B2 (en) | 2008-05-16 | 2010-06-29 | Siemens Energy, Inc. | Selective catalytic reduction system and process using a pre-sulfated zirconia binder |
| US7976805B2 (en) * | 2008-05-16 | 2011-07-12 | Siemens Energy, Inc. | Selective catalytic reduction system and process for treating NOx emissions using a palladium and rhodium or ruthenium catalyst |
| US7718153B2 (en) * | 2008-05-16 | 2010-05-18 | Siemens Energy, Inc. | Catalytic process for control of NOx emissions using hydrogen |
| US7988940B2 (en) * | 2008-05-16 | 2011-08-02 | Siemens Energy, Inc. | Selective catalytic reduction system and process for treating NOx emissions using a zinc or titanium promoted palladium-zirconium catalyst |
| WO2009155063A1 (en) * | 2008-05-28 | 2009-12-23 | Battelle Memorial Institute | Composite catalyst materials and method for the selective reduction of nitrogen oxides |
| DE102008041291A1 (de) | 2008-08-15 | 2010-02-18 | INSTITUT FüR MIKROTECHNIK MAINZ GMBH | NOx Reduktion in Abgasen |
| EP2177257A1 (de) | 2008-10-15 | 2010-04-21 | Linde AG | Platinhaltiger Katalysator auf einer Stütze aus Nano-Kristallmagnesiumoxid und Ceroxid-Dioxid mit H2-SCR-Tendenz |
| EP2177256A1 (de) * | 2008-10-15 | 2010-04-21 | Linde AG | Katalysator mit Platinum und Palladium zur selektiven Reduktion von NOX mit Wasserstoff (H2-SCR) |
| KR101613997B1 (ko) * | 2008-10-17 | 2016-04-20 | 유미코어 니폰 쇼쿠바이 가부시키가이샤 | 배기 가스 정화용 촉매 및 그것을 이용한 정화 방법 |
| EP2269729A1 (de) | 2009-06-16 | 2011-01-05 | Linde AG | Katalysator aus Platin auf dotiertem gemischten Magnesiumoxid und Cerdioxid zum H2-SCR |
| US7989385B2 (en) * | 2009-11-05 | 2011-08-02 | Siemens Energy, Inc. | Process of activation of a palladium catalyst system |
| DE102010040808A1 (de) | 2010-09-15 | 2012-03-15 | Karlsruher Institut für Technologie | Katalysator zur Verwendung bei einer selektiven NOx-Reduktion |
| EP2468399A1 (de) | 2010-12-23 | 2012-06-27 | Cyprus University of Technology | Katalysator zur Reduzierung von NO zu N2 mit Ethanol oder Ethanol und Wasserstoff unter mageren DENOx-Bedingungen |
| US9283548B2 (en) | 2013-11-19 | 2016-03-15 | Toyota Motor Engineering & Manufacturing North America, Inc. | Ceria-supported metal catalysts for the selective reduction of NOx |
| ES2621416B1 (es) * | 2015-12-01 | 2018-04-16 | Inyecciones Plásticas Mecacontrol, S.L. | Procedimiento para la reducción selectiva de óxidos de nitrógeno |
| DE102016107466A1 (de) | 2016-04-22 | 2017-10-26 | Keyou GmbH | Katalysator, Vorrichtung und Verfahren zur selektiven NOx-Reduktion mittels Wasserstoff in NOx-haltigen Abgasen |
| DE102017124541B4 (de) | 2017-10-20 | 2026-07-02 | Technische Universität Bergakademie Freiberg | Vorrichtung zur Nachbehandlung von Abgasen eines Verbrennungsmotors |
| KR20200044362A (ko) * | 2018-10-19 | 2020-04-29 | 희성촉매 주식회사 | 내황성 냉간 시동 촉매 |
| DE102018127219A1 (de) | 2018-10-31 | 2020-04-30 | Keyou GmbH | Katalysator zur Verwendung bei einer selektiven NOx-Reduktion in NOx-haltigen Abgasen, Verfahren zur Herstellung eines Katalysators, Vorrichtung zur selektiven NOx-Reduktion und Verfahren zur selektiven NOx-Reduktion |
Family Cites Families (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2742437A (en) * | 1949-05-24 | 1956-04-17 | Oxy Catalyst Inc | Catalytic structure and composition |
| US2525073A (en) * | 1950-03-22 | 1950-10-10 | Standard Oil Dev Co | Magnesia-ceria and magnesiaberyllia catalysts |
| US4239656A (en) * | 1978-04-04 | 1980-12-16 | Kabushiki Kaisha Toyota Chuo Kenkyusho | Catalyst for purifying exhaust gases and carrier for the catalyst |
| JPS5610334A (en) * | 1979-07-06 | 1981-02-02 | Toyota Motor Corp | Catalyst for cleaning up exhaust gas and manufacture of said catalyst |
| FR2530489B1 (fr) * | 1982-07-26 | 1987-02-27 | Pro Catalyse | Procede de fabrication de catalyseurs pour le traitement des gaz d'echappement des moteurs a combustion interne |
| DE3809226C2 (de) * | 1987-03-20 | 1994-10-27 | Toshiba Kawasaki Kk | Hochtemperatur-Verbrennungskatalysator und Verfahren zu seiner Herstellung |
| US4760044A (en) * | 1987-06-15 | 1988-07-26 | Allied-Signal Inc. | Catalyst for minimizing the H2 S emissions from automotive exhaust and method of its manufacture |
| US4977129A (en) * | 1989-03-13 | 1990-12-11 | W. R Grace & Co.-Conn. | Auto exhaust catalyst composition having low H2 S emissions and method of making the catalyst |
| DE3940758A1 (de) * | 1989-12-09 | 1991-06-13 | Degussa | Verfahren zur reinigung der abgase von dieselmotoren |
| US5041407A (en) * | 1989-12-14 | 1991-08-20 | Allied-Signal Inc. | High-temperature three-way catalyst for treating automotive exhaust gases |
| US20030078162A1 (en) * | 1992-06-29 | 2003-04-24 | Gerard Martin | Absorbent sulfur oxide composition and associated use |
| US6284210B1 (en) * | 1994-11-15 | 2001-09-04 | Institut Francais Du Petrole | Combustion catalyst and combustion process using such a catalyst |
| US5874057A (en) * | 1995-07-12 | 1999-02-23 | Engelhard Corporation | Lean NOx catalyst/trap method |
| JP3965711B2 (ja) * | 1996-10-25 | 2007-08-29 | 株式会社日立製作所 | 窒素酸化物の浄化触媒及び浄化方法 |
| KR100326747B1 (ko) * | 1998-03-09 | 2002-03-13 | 하나와 요시카즈 | 산소 과잉 배기 가스의 정화 장치 |
| US6511642B1 (en) * | 1999-01-12 | 2003-01-28 | Kabushiki Kaisha Toyota Chuo Kenkyusho | Porous material, catalyst, method of producing the porous material and method for purifying exhaust gas |
| EP1066874B1 (de) * | 1999-07-09 | 2009-09-23 | Nissan Motor Company, Limited | Abgasreinigungskatalysator und Verfahren zu seiner Herstellung |
| JP4590733B2 (ja) * | 2000-02-22 | 2010-12-01 | マツダ株式会社 | 排気ガス浄化用触媒及び該触媒による排気ガス浄化方法 |
| JP4006976B2 (ja) * | 2000-11-15 | 2007-11-14 | 株式会社豊田中央研究所 | 複合酸化物粉末とその製造方法及び触媒 |
| JP2002177781A (ja) * | 2000-12-12 | 2002-06-25 | Ict:Kk | 排ガス浄化用触媒 |
| US6866834B2 (en) * | 2001-03-12 | 2005-03-15 | Nissan Motor Co., Ltd. | NOx reduction catalyst and NOx reduction system |
-
2002
- 2002-02-15 ES ES200200368A patent/ES2192985B1/es not_active Expired - Fee Related
-
2003
- 2003-02-14 DE DE60321136T patent/DE60321136D1/de not_active Expired - Lifetime
- 2003-02-14 AT AT03704721T patent/ATE395972T1/de active
- 2003-02-14 ES ES03704721T patent/ES2306855T3/es not_active Expired - Lifetime
- 2003-02-14 WO PCT/ES2003/000083 patent/WO2003068390A1/es not_active Ceased
- 2003-02-14 EP EP03704721A patent/EP1475149B1/de not_active Expired - Lifetime
- 2003-02-14 JP JP2003567568A patent/JP2005516767A/ja active Pending
- 2003-02-14 AU AU2003206981A patent/AU2003206981A1/en not_active Abandoned
-
2004
- 2004-08-11 US US10/915,961 patent/US7105137B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| ES2192985A1 (es) | 2003-10-16 |
| DE60321136D1 (de) | 2008-07-03 |
| ES2306855T3 (es) | 2008-11-16 |
| JP2005516767A (ja) | 2005-06-09 |
| EP1475149B1 (de) | 2008-05-21 |
| US20050090393A1 (en) | 2005-04-28 |
| ES2192985B1 (es) | 2005-02-16 |
| EP1475149A1 (de) | 2004-11-10 |
| AU2003206981A1 (en) | 2003-09-04 |
| WO2003068390A1 (es) | 2003-08-21 |
| US7105137B2 (en) | 2006-09-12 |
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