ATE395973T1 - Verfahren zur herstellung eines ein additiv enthaltenden mischmetallkatalysators - Google Patents
Verfahren zur herstellung eines ein additiv enthaltenden mischmetallkatalysatorsInfo
- Publication number
- ATE395973T1 ATE395973T1 AT01969342T AT01969342T ATE395973T1 AT E395973 T1 ATE395973 T1 AT E395973T1 AT 01969342 T AT01969342 T AT 01969342T AT 01969342 T AT01969342 T AT 01969342T AT E395973 T1 ATE395973 T1 AT E395973T1
- Authority
- AT
- Austria
- Prior art keywords
- additive
- metal components
- group viii
- producing
- vib metal
- Prior art date
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/06—Halogens; Compounds thereof
- B01J27/128—Halogens; Compounds thereof with iron group metals or platinum group metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/88—Molybdenum
- B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/8878—Chromium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/888—Tungsten
- B01J23/8885—Tungsten containing also molybdenum
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0201—Oxygen-containing compounds
- B01J31/0202—Alcohols or phenols
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0201—Oxygen-containing compounds
- B01J31/0209—Esters of carboxylic or carbonic acids
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/04—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing carboxylic acids or their salts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
- B01J37/0018—Addition of a binding agent or of material, later completely removed among others as result of heat treatment, leaching or washing,(e.g. forming of pores; protective layer, desintegrating by heat)
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/03—Precipitation; Co-precipitation
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
- C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
- C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
- C10G45/06—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof
- C10G45/08—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof in combination with chromium, molybdenum, or tungsten metals, or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G49/00—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00
- C10G49/02—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00 characterised by the catalyst used
- C10G49/04—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00 characterised by the catalyst used containing nickel, cobalt, chromium, molybdenum, or tungsten metals, or compounds thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0236—Drying, e.g. preparing a suspension, adding a soluble salt and drying
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- General Chemical & Material Sciences (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP00202468 | 2000-07-12 | ||
| US27773301P | 2001-03-21 | 2001-03-21 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ATE395973T1 true ATE395973T1 (de) | 2008-06-15 |
Family
ID=37502491
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AT01969342T ATE395973T1 (de) | 2000-07-12 | 2001-07-05 | Verfahren zur herstellung eines ein additiv enthaltenden mischmetallkatalysators |
Country Status (10)
| Country | Link |
|---|---|
| EP (1) | EP1299186B1 (de) |
| JP (1) | JP5201496B2 (de) |
| KR (1) | KR100769798B1 (de) |
| CN (1) | CN1177643C (de) |
| AT (1) | ATE395973T1 (de) |
| AU (1) | AU2001289625A1 (de) |
| CA (1) | CA2415417C (de) |
| DK (1) | DK1299186T3 (de) |
| RU (1) | RU2287367C2 (de) |
| WO (1) | WO2002004117A1 (de) |
Families Citing this family (35)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2216404C1 (ru) * | 2002-06-06 | 2003-11-20 | ООО "Компания Катахим" | Способ приготовления катализатора гидрооблагораживания нефтяных фракций |
| JP4444690B2 (ja) * | 2004-02-26 | 2010-03-31 | 株式会社ジャパンエナジー | 水素化処理触媒前駆体およびその製造方法並びに精製炭化水素油の製造方法 |
| CA2579616C (en) * | 2004-09-22 | 2011-02-01 | Exxonmobil Research And Engineering Company | Bulk ni-mo-w catalysts made from precursors containing an organic agent |
| MXPA05009283A (es) * | 2005-08-31 | 2007-02-27 | Mexicano Inst Petrol | Procedimiento para la preparacion de una composicion catalitica para el hidroprocesamiento de fracciones del petroleo. |
| US8216958B2 (en) * | 2006-01-17 | 2012-07-10 | Exxonmobil Research And Engineering Company | Selective catalysts having silica supports for naphtha hydrodesulfurization |
| HUE027017T2 (en) * | 2006-01-17 | 2016-08-29 | Exxonmobil Res & Eng Co | Process for the preparation of a catalyst for hydrodesulfurization of petrol |
| CN104250563B (zh) * | 2006-01-17 | 2017-04-12 | 埃克森美孚研究工程公司 | 用于石脑油加氢脱硫的选择性催化剂 |
| CN100569921C (zh) * | 2006-06-16 | 2009-12-16 | 中国石油化工股份有限公司 | 一种单段加氢裂化方法 |
| CN100590180C (zh) * | 2006-06-16 | 2010-02-17 | 中国石油化工股份有限公司 | 一种柴油馏分改质降凝方法 |
| CN100590179C (zh) * | 2006-06-16 | 2010-02-17 | 中国石油化工股份有限公司 | 一种柴油馏分加氢改质方法 |
| CN100569920C (zh) * | 2006-06-16 | 2009-12-16 | 中国石油化工股份有限公司 | 一种加氢处理方法 |
| CN100569923C (zh) * | 2006-06-16 | 2009-12-16 | 中国石油化工股份有限公司 | 一种两段加氢裂化方法 |
| CA2666349C (en) * | 2006-10-11 | 2016-02-16 | Exxonmobil Research And Engineering Company | Hydroprocessing methods for bulk group viii/group vib metal catalysts |
| CN101578352B (zh) * | 2006-10-11 | 2014-04-16 | 埃克森美孚研究工程公司 | 本体第viii族/第vib族金属催化剂及其制备方法 |
| US7951746B2 (en) * | 2006-10-11 | 2011-05-31 | Exxonmobil Research And Engineering Company | Bulk group VIII/group VIB metal catalysts and method of preparing same |
| RU2312886C1 (ru) * | 2006-10-13 | 2007-12-20 | Институт Катализа Им. Г.К. Борескова Сибирского Отделения Российской Академии Наук | Способ получения дизельного топлива |
| US8173570B2 (en) | 2007-10-31 | 2012-05-08 | Chevron U.S.A. Inc. | Hydroconversion processes employing multi-metallic catalysts and method for making thereof |
| EP2217373B1 (de) * | 2007-11-09 | 2019-03-06 | ExxonMobil Research and Engineering Company | Herstellung von metallischen gruppe-viii- und/oder gruppe-vib-metall-vollkatalysatoren |
| CN101664684B (zh) * | 2008-09-04 | 2012-10-10 | 中国石油化工股份有限公司 | 一种加氢催化剂组合物及其应用 |
| US8080492B2 (en) * | 2009-04-29 | 2011-12-20 | Chevron U.S.A. Inc. | Hydroconversion multi-metallic catalyst and method for making thereof |
| US7931799B2 (en) * | 2009-04-29 | 2011-04-26 | Chevron U.S.A. Inc. | Hydroconversion multi-metallic catalyst and method for making thereof |
| US8058203B2 (en) * | 2009-04-29 | 2011-11-15 | Chevron U.S.A. Inc. | Hydroconversion multi-metallic catalyst and method for making thereof |
| US7964525B2 (en) * | 2009-04-29 | 2011-06-21 | Chevron U.S.A. Inc. | Hydroconversion multi-metallic catalyst and method for making thereof |
| EP2424663B1 (de) * | 2009-04-29 | 2019-05-22 | Chevron U.S.A., Inc. | Herstellungsverfahren für einen multimetall-hydrokonversionskatalysator |
| EP2424659A4 (de) * | 2009-04-29 | 2014-08-27 | Chevron Usa Inc | Multimetall-hydrokonversionskatalysator und herstellungsverfahren dafür |
| US7964526B2 (en) * | 2009-04-29 | 2011-06-21 | Chevron U.S.A. Inc. | Hydroconversion multi-metallic catalyst and method for making thereof |
| US7964524B2 (en) * | 2009-04-29 | 2011-06-21 | Chevron U.S.A. Inc. | Hydroconversion multi-metallic catalyst and method for making thereof |
| CN103037968B (zh) | 2010-06-01 | 2016-08-24 | 埃克森美孚研究工程公司 | 加氢处理催化剂和它们的制备 |
| WO2012035004A2 (en) * | 2010-09-17 | 2012-03-22 | Shell Internationale Research Maatschappij B.V. | Hydrocracking catalyst composition |
| EP2726578B1 (de) * | 2011-06-28 | 2020-04-29 | Shell International Research Maatschappij B.V. | Mit einem etheraminzusatz imprägnierte zusammensetzung für katalytisches hydroprocessing von kohlenwasserstoffen und verfahren zur herstellung einer derartigen zusammensetzung |
| JP6254165B2 (ja) | 2012-09-05 | 2017-12-27 | シェブロン ユー.エス.エー. インコーポレイテッド | 水素化変換多金属触媒及びそれを調製する方法 |
| FR3014707B1 (fr) * | 2013-12-13 | 2017-03-31 | Ifp Energies Now | Procede de preparation d'un catalyseur, catalyseur et son utilisation dans un procede d'hydroconversion et/ou d'hydrotraitement |
| AU2017215121B2 (en) * | 2016-02-01 | 2020-10-29 | Albemarle Europe Sprl | Nickel containing mixed metal-oxide/carbon bulk hydroprocessing catalysts and their application |
| FR3090414B1 (fr) * | 2018-12-19 | 2022-07-29 | Ifp Energies Now | Catalyseur sélectif en hydrogénolyse des éthyl-aromatiques par conservation des méthyl-aromatiques. |
| FR3109899B1 (fr) * | 2020-05-07 | 2023-11-24 | Ifp Energies Now | Catalyseur d’hydrogénation comprenant un support et un ratio NiMo spécifique |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3678124A (en) * | 1968-10-24 | 1972-07-18 | Gennady Arkadievich Stepanov | Process for the production of mono- and diolefin hydrocarbons |
| FR2060171A6 (de) * | 1968-12-30 | 1971-06-18 | Inst Francais Du Petrole | |
| JPH0813330B2 (ja) * | 1990-03-30 | 1996-02-14 | 株式会社コスモ総合研究所 | 炭化水素油の水素化脱硫触媒組成物の製造法 |
| JP2974826B2 (ja) * | 1991-07-17 | 1999-11-10 | 三菱レイヨン株式会社 | メタクロレイン及びメタクリル酸製造用触媒の調製法 |
| JPH0576766A (ja) * | 1991-09-20 | 1993-03-30 | Cosmo Oil Co Ltd | 炭化水素油の水素化脱硫用触媒の製造方法 |
| JP2900771B2 (ja) * | 1992-11-18 | 1999-06-02 | 住友金属鉱山株式会社 | 炭化水素油の水素化処理触媒の製造方法 |
| JPH06198184A (ja) * | 1992-12-30 | 1994-07-19 | Sekiyu Sangyo Kasseika Center | 水素化脱硫触媒の製造法 |
| RU2052285C1 (ru) * | 1993-03-23 | 1996-01-20 | Институт катализа им.Г.К.Борескова РАН | Катализатор для гидрообработки углеводородного сырья нефтяного и углехимического происхождения и способ его получения |
| NL9420024A (nl) * | 1993-05-04 | 1996-05-01 | Cri International | Werkwijze voor het behandelen van spontaan ontbrandbare katalysatoren. |
| RU2074879C1 (ru) * | 1994-11-08 | 1997-03-10 | Мунд Сергей Львович | Способ гидрооблагораживания отбензиненной нефти |
| JP3676849B2 (ja) * | 1995-06-10 | 2005-07-27 | 財団法人石油産業活性化センター | 軽油の水素化脱硫触媒 |
| JP3537937B2 (ja) * | 1995-12-01 | 2004-06-14 | 株式会社コスモ総合研究所 | 軽油の水素化脱硫触媒 |
| US6156695A (en) * | 1997-07-15 | 2000-12-05 | Exxon Research And Engineering Company | Nickel molybdotungstate hydrotreating catalysts |
-
2001
- 2001-07-05 AT AT01969342T patent/ATE395973T1/de not_active IP Right Cessation
- 2001-07-05 KR KR1020027017981A patent/KR100769798B1/ko not_active Expired - Lifetime
- 2001-07-05 WO PCT/EP2001/007733 patent/WO2002004117A1/en not_active Ceased
- 2001-07-05 DK DK01969342T patent/DK1299186T3/da active
- 2001-07-05 EP EP01969342A patent/EP1299186B1/de not_active Expired - Lifetime
- 2001-07-05 CN CNB018126138A patent/CN1177643C/zh not_active Expired - Lifetime
- 2001-07-05 JP JP2002508565A patent/JP5201496B2/ja not_active Expired - Lifetime
- 2001-07-05 RU RU2003104018/04A patent/RU2287367C2/ru active
- 2001-07-05 AU AU2001289625A patent/AU2001289625A1/en not_active Abandoned
- 2001-07-05 CA CA2415417A patent/CA2415417C/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| CN1441696A (zh) | 2003-09-10 |
| CA2415417C (en) | 2010-05-04 |
| RU2287367C2 (ru) | 2006-11-20 |
| CA2415417A1 (en) | 2002-01-17 |
| EP1299186B1 (de) | 2008-05-21 |
| JP5201496B2 (ja) | 2013-06-05 |
| CN1177643C (zh) | 2004-12-01 |
| KR100769798B1 (ko) | 2007-10-25 |
| KR20030014290A (ko) | 2003-02-15 |
| DK1299186T3 (da) | 2008-08-11 |
| EP1299186A1 (de) | 2003-04-09 |
| JP2004511326A (ja) | 2004-04-15 |
| WO2002004117A1 (en) | 2002-01-17 |
| AU2001289625A1 (en) | 2002-01-21 |
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