ATE411350T1 - Polymerisation von alkylenoxiden unter der verwendung von cyanidkatalysatoren und ungesättigten initiator-verbindungen - Google Patents

Polymerisation von alkylenoxiden unter der verwendung von cyanidkatalysatoren und ungesättigten initiator-verbindungen

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Publication number
ATE411350T1
ATE411350T1 AT00943410T AT00943410T ATE411350T1 AT E411350 T1 ATE411350 T1 AT E411350T1 AT 00943410 T AT00943410 T AT 00943410T AT 00943410 T AT00943410 T AT 00943410T AT E411350 T1 ATE411350 T1 AT E411350T1
Authority
AT
Austria
Prior art keywords
polymerization
alkylene oxides
initiator compounds
cyanide catalysts
unsaturated initiator
Prior art date
Application number
AT00943410T
Other languages
English (en)
Inventor
Louis Walker
Richard Wehmeyer
Robert Whitmarsh
Katherine Clement
Wanda Rauscher
Original Assignee
Dow Global Technologies Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
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First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=27558276&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=ATE411350(T1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Dow Global Technologies Inc filed Critical Dow Global Technologies Inc
Application granted granted Critical
Publication of ATE411350T1 publication Critical patent/ATE411350T1/de

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/26Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/26Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
    • C08G65/2642Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the catalyst used
    • C08G65/2645Metals or compounds thereof, e.g. salts
    • C08G65/2663Metal cyanide catalysts, i.e. DMC's
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/24Nitrogen compounds
    • B01J27/26Cyanides
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/26Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
    • C08G65/2603Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds the other compounds containing oxygen
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/26Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
    • C08G65/2603Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds the other compounds containing oxygen
    • C08G65/2606Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds the other compounds containing oxygen containing hydroxyl groups
    • C08G65/2609Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds the other compounds containing oxygen containing hydroxyl groups containing aliphatic hydroxyl groups
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/26Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
    • C08G65/2618Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds the other compounds containing nitrogen
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/26Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
    • C08G65/2642Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the catalyst used
    • C08G65/2693Supported catalysts
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/26Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
    • C08G65/2696Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the process or apparatus used

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Toxicology (AREA)
  • General Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Polyethers (AREA)
AT00943410T 1999-07-09 2000-07-07 Polymerisation von alkylenoxiden unter der verwendung von cyanidkatalysatoren und ungesättigten initiator-verbindungen ATE411350T1 (de)

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
US14308299P 1999-07-09 1999-07-09
US14307599P 1999-07-09 1999-07-09
US14307899P 1999-07-09 1999-07-09
US14308199P 1999-07-09 1999-07-09
US14307999P 1999-07-09 1999-07-09
US20577200P 2000-05-19 2000-05-19

Publications (1)

Publication Number Publication Date
ATE411350T1 true ATE411350T1 (de) 2008-10-15

Family

ID=27558276

Family Applications (1)

Application Number Title Priority Date Filing Date
AT00943410T ATE411350T1 (de) 1999-07-09 2000-07-07 Polymerisation von alkylenoxiden unter der verwendung von cyanidkatalysatoren und ungesättigten initiator-verbindungen

Country Status (14)

Country Link
US (1) US6355845B1 (de)
EP (1) EP1214368B1 (de)
JP (1) JP2003534392A (de)
KR (1) KR20020030779A (de)
CN (1) CN100391999C (de)
AR (1) AR025851A1 (de)
AT (1) ATE411350T1 (de)
AU (1) AU5788500A (de)
BR (1) BR0011792A (de)
CA (1) CA2376034A1 (de)
CO (1) CO5160376A1 (de)
DE (1) DE60040549D1 (de)
MX (1) MXPA02000298A (de)
WO (1) WO2001004178A1 (de)

Families Citing this family (39)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6429166B1 (en) * 2000-05-19 2002-08-06 Dow Global Technologies Inc. Method for preparing metal cyanide catalyst/polyol initiator slurries
US20020091219A1 (en) * 2001-01-08 2002-07-11 Clement Katherine Sue Certain silicone polyethers, methods for making them and uses
US6977236B2 (en) * 2002-06-14 2005-12-20 Shell Oil Company Preparation of a double metal cyanide catalyst
US6716788B2 (en) * 2002-06-14 2004-04-06 Shell Oil Company Preparation of a double metal cyanide catalyst
DE10243366A1 (de) * 2002-09-18 2004-04-01 Basf Ag Herstellung von Alkoxylaten bei optimierten Reaktionsdrücken
JP3990365B2 (ja) * 2004-02-20 2007-10-10 埼玉日本電気株式会社 折り畳み式電子機器
MX221601B (en) * 2004-05-14 2004-07-22 Basf Ag Functional fluids containing alkylene oxide copolymers having low pulmonary toxicity
MX2007004991A (es) * 2004-10-25 2007-06-14 Dow Global Technologies Inc Poliuretanos hechos de acidos grasos conteniendo hidroxi-metilo o esteres de alquilo de tales acidos grasos.
BRPI0516275A (pt) * 2004-10-25 2008-09-02 Dow Global Technologies Inc polìmero poliol tendo uma fase contìnua de poliol e partìculas poliméricas dispersas, método para preparar um polìmero poliol, dispersão de partìculas poliméricas numa fase contìnua e polìmero de poliuretano
WO2006047431A1 (en) * 2004-10-25 2006-05-04 Dow Global Technologies, Inc. Aqueous polyurethane dispersions made from hydroxymethyl containing polyester polyols derived from faty acids
AU2005299520A1 (en) * 2004-10-25 2006-05-04 Dow Global Technologies, Inc. Prepolymers made from hydroxmethyl-containing polyester polyols derived from fatty acids
ES2405277T3 (es) * 2004-10-25 2013-05-30 Dow Global Technologies Inc. Respaldos de alfombras de poliuretano realizados con polioles de poliéster hidroximetilados
DE102005012794A1 (de) 2005-03-19 2006-09-21 Bayer Materialscience Ag Poly(etherester)polyole und Verfahren zu ihrer Herstellung
DE102005020347A1 (de) * 2005-05-02 2006-11-09 Basf Ag Verfahren zur Herstellung von Doppelmetallcyanidkomplex-Katalysatoren
US20080132729A1 (en) 2006-12-01 2008-06-05 Mcdaniel Kenneth G Continuous process for the production of ethoxylates
US7473677B2 (en) 2007-04-16 2009-01-06 Bayer Materialscience Llc High productivity process for alkylphenol ethoxylates
US20080255378A1 (en) * 2007-04-16 2008-10-16 Bayer Materialscience Llc High productivity process for non-phenolic ethoxylates
US9109077B2 (en) 2007-11-14 2015-08-18 Basf Se Foamed polyurethanes having improved flexing endurance properties
EP2408841B1 (de) 2009-03-17 2014-11-19 Basf Se POLYURETHANFORMKÖRPER MIT VERBESSERTER WEITERREIßFESTIGKEIT UND VERBESSERTEM DAUERBIEGEVERHALTEN
CN102471445B (zh) 2009-07-20 2014-05-28 巴斯夫欧洲公司 制备粘弹性聚氨酯软质泡沫材料的方法
RU2012117414A (ru) 2009-09-30 2013-11-10 Басф Се Алкоксилированные полимеры
ES2544886T3 (es) 2009-12-11 2015-09-04 Basf Se Cuerpos moldeados de espuma de poliuretano con estabilidad dimensional
WO2012098145A1 (de) 2011-01-21 2012-07-26 Basf Se Mikrozelluläre schäume mit verbesserten mechanischen eigenschaften
US20140235127A1 (en) 2013-02-21 2014-08-21 Henkel Corporation Elastic attachment adhesive and use thereof
KR102387647B1 (ko) * 2016-06-30 2022-04-19 다우 글로벌 테크놀로지스 엘엘씨 폴리에테르 디올 제조 공정
WO2018166870A1 (de) 2017-03-16 2018-09-20 Basf Se Verfahren zur herstellung von polyurethan-stiefeln
AU2018309737B9 (en) 2017-07-31 2024-03-14 P2 Science, Inc. Polyether derivatives, uses, and methods of making the same
JP7850411B2 (ja) * 2018-03-07 2026-04-23 ピー2・サイエンス・インコーポレイテッド ポリエーテル誘導体、使用およびその製造方法
EP4058489B1 (de) 2020-01-14 2026-03-04 P2 Science, Inc. Diacylderivate von polyetherpolymeren
AU2021231700C1 (en) 2020-03-05 2025-01-23 P2 Science, Inc. Cosmetic compositions comprising polyether polymers
EP4185628A1 (de) 2020-07-24 2023-05-31 Basf Se Mehrschichtige struktur und verfahren zu ihrer herstellung
CN113201128B (zh) * 2021-03-09 2022-12-09 中国科学院过程工程研究所 一种用于环氧化合物开环聚合的引发剂
US12215120B1 (en) 2021-05-17 2025-02-04 P2 Science, Inc. Terpene O-glycosides
US12209069B2 (en) 2021-05-17 2025-01-28 P2 Science, Inc. Fatty acid terpene alcohol esters
US12528991B2 (en) 2021-07-15 2026-01-20 P2 Science, Inc. Citronellol alkoxylate surfactants
JP2024546638A (ja) 2021-12-16 2024-12-26 ダウ グローバル テクノロジーズ エルエルシー 新規な非イオン性界面活性剤及びそれを製造するための方法
EP4705370A1 (de) 2023-05-02 2026-03-11 Basf Se Polyurethanschaumformkörper niedriger dichte mit glatter haut
WO2025090154A1 (en) 2023-10-25 2025-05-01 Dow Global Technologies Llc Enhanced oil recovery process with hydrocarbon-soluble surfactant
WO2025111037A1 (en) 2023-11-20 2025-05-30 Dow Global Technologies Llc Fracturing process with hydrocarbon-soluble surfactant

Family Cites Families (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3021341A (en) 1960-02-23 1962-02-13 Miles Lab Methylene dioxanes
US3427335A (en) 1963-02-14 1969-02-11 Gen Tire & Rubber Co Double metal cyanides complexed with an acyclic aliphatic saturated monoether,an ester and a cyclic ether and methods for making the same
US3427334A (en) 1963-02-14 1969-02-11 Gen Tire & Rubber Co Double metal cyanides complexed with an alcohol aldehyde or ketone to increase catalytic activity
US3291607A (en) 1965-05-28 1966-12-13 Gen Aniline & Film Corp Water-soluble polyoxyalkylenated butyne-2-diol-1, 4 development accelerators
GB1245943A (en) 1968-08-08 1971-09-15 Ici Ltd Polyoxyalkylene derivatives
US3829505A (en) 1970-02-24 1974-08-13 Gen Tire & Rubber Co Polyethers and method for making the same
US4053422A (en) 1976-06-16 1977-10-11 Texaco Inc. Drilling fluids containing polyethoxylated tetraalkyl acetylenic diols
JPS5764629A (en) 1980-10-03 1982-04-19 Continental Oil Co Alkoxylation of unsaturated alcohols
US4843054A (en) 1987-02-26 1989-06-27 Arco Chemical Technology, Inc. Preparation of filterable double metal cyanide complex catalyst for propylene oxide polymerization
JP2995568B2 (ja) * 1989-05-09 1999-12-27 旭硝子株式会社 ポリアルキレンオキシド誘導体の製造法
JP2636954B2 (ja) * 1989-08-15 1997-08-06 日信化学工業株式会社 アセチレングリコールのプロピレンオキサイド付加物及びその製造方法
JPH05209052A (ja) * 1991-07-19 1993-08-20 Asahi Glass Co Ltd ポリエーテルマクロマーおよびその重合体
US5382642A (en) 1993-07-28 1995-01-17 Arco Chemical Technology, L.P. Copolymers of allyl alcohol propoxylates and vinyl aromatic monomers
US5451652A (en) 1994-04-28 1995-09-19 Arco Chemical Technology, L.P. Polymers from propoxylated allyl alcohol
EP0693513B1 (de) 1994-07-18 2001-01-10 Asahi Glass Company Ltd. Verfahren zur Polyetherreinigung
JPH08208426A (ja) 1995-02-03 1996-08-13 Nippon Oil & Fats Co Ltd 化粧品基材
US5856369A (en) 1996-07-30 1999-01-05 Osi Specialties, Inc. Polyethers and polysiloxane copolymers manufactured with double metal cyanide catalysts
US5786514A (en) 1996-12-18 1998-07-28 Arco Chemical Technology, L.P. Process for alkoxylating carbonyl-functionalized phenols using double metal cyanide catalysts
US5854386A (en) * 1997-08-25 1998-12-29 Arco Chemical Technology, L.P. Stabilizers for polymer polyols
BR9813009A (pt) * 1997-08-25 2000-08-15 Arco Chem Tech Preparação de poliéteres funcionalizados

Also Published As

Publication number Publication date
EP1214368A1 (de) 2002-06-19
BR0011792A (pt) 2002-03-12
US6355845B1 (en) 2002-03-12
KR20020030779A (ko) 2002-04-25
DE60040549D1 (de) 2008-11-27
WO2001004178A1 (en) 2001-01-18
JP2003534392A (ja) 2003-11-18
CN1359402A (zh) 2002-07-17
CO5160376A1 (es) 2002-05-30
CA2376034A1 (en) 2001-01-18
MXPA02000298A (es) 2002-06-21
AU5788500A (en) 2001-01-30
CN100391999C (zh) 2008-06-04
EP1214368B1 (de) 2008-10-15
AR025851A1 (es) 2002-12-18

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