ATE430764T1 - Zusammensetzung zum abbruch einer radikalischen emulsionspolymerisation - Google Patents

Zusammensetzung zum abbruch einer radikalischen emulsionspolymerisation

Info

Publication number: ATE430764T1
Authority: AT; Austria
Prior art keywords: composition; inhibitors; radical emulsion; terminating; emulsion polymerization
Prior art date: 1999-09-09

Application number

AT00307753T

Other languages

English (en)

Inventor

Jianfeng Lou

Thomas S Buszta

Michael D Gernon

Original Assignee

Arkema France

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1999-09-09

Filing date

2000-09-08

Publication date

2009-05-15

2000-09-08 Application filed by Arkema France filed Critical Arkema France

2009-05-15 Application granted granted Critical

2009-05-15 Publication of ATE430764T1 publication Critical patent/ATE430764T1/de

Links

239000000203 mixture Substances 0.000 title abstract 5
238000007720 emulsion polymerization reaction Methods 0.000 title abstract 2
239000003112 inhibitor Substances 0.000 abstract 3
CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 abstract 2
XKLJHFLUAHKGGU-UHFFFAOYSA-N nitrous amide Chemical compound ON=N XKLJHFLUAHKGGU-UHFFFAOYSA-N 0.000 abstract 2
150000005208 1,4-dihydroxybenzenes Chemical class 0.000 abstract 1
150000001412 amines Chemical class 0.000 abstract 1
229960005070 ascorbic acid Drugs 0.000 abstract 1
235000010323 ascorbic acid Nutrition 0.000 abstract 1
239000011668 ascorbic acid Substances 0.000 abstract 1
230000015572 biosynthetic process Effects 0.000 abstract 1
229920001971 elastomer Polymers 0.000 abstract 1
238000004945 emulsification Methods 0.000 abstract 1
229920000126 latex Polymers 0.000 abstract 1
238000000034 method Methods 0.000 abstract 1
150000004005 nitrosamines Chemical class 0.000 abstract 1
230000009935 nitrosation Effects 0.000 abstract 1
238000007034 nitrosation reaction Methods 0.000 abstract 1
150000002989 phenols Chemical class 0.000 abstract 1
229920000642 polymer Polymers 0.000 abstract 1
238000002360 preparation method Methods 0.000 abstract 1
150000003141 primary amines Chemical class 0.000 abstract 1
150000003233 pyrroles Chemical class 0.000 abstract 1
150000003254 radicals Chemical class 0.000 abstract 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
- C08F2/42—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation using short-stopping agents
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/22—Emulsion polymerisation
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Polymerisation Methods In General (AREA)
Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Compositions Of Macromolecular Compounds (AREA)
Agricultural Chemicals And Associated Chemicals (AREA)
Preparation Of Compounds By Using Micro-Organisms (AREA)
Electrical Discharge Machining, Electrochemical Machining, And Combined Machining (AREA)

AT00307753T 1999-09-09 2000-09-08 Zusammensetzung zum abbruch einer radikalischen emulsionspolymerisation ATE430764T1 (de)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US15315099P	1999-09-09	1999-09-09
US09/631,756 US6495065B1 (en)	1999-09-09	2000-08-03	Nitrosamine-inhibiting compositions for shortstopping of free radical emulsion polymerizations

Publications (1)

Publication Number	Publication Date
ATE430764T1 true ATE430764T1 (de)	2009-05-15

Family

ID=26850220

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
AT00307753T ATE430764T1 (de)	1999-09-09	2000-09-08	Zusammensetzung zum abbruch einer radikalischen emulsionspolymerisation

Country Status (12)

Country	Link
US (1)	US6495065B1 (de)
EP (1)	EP1083185B1 (de)
JP (1)	JP4846897B2 (de)
KR (1)	KR100730904B1 (de)
CN (1)	CN1288014A (de)
AT (1)	ATE430764T1 (de)
BR (1)	BR0004048A (de)
CA (1)	CA2317087C (de)
DE (1)	DE60042145D1 (de)
ES (1)	ES2325200T3 (de)
PL (1)	PL199774B1 (de)
TW (1)	TWI265936B (de)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US6723255B2 (en) *	2000-03-07	2004-04-20	Atofina Chemicals, Inc.	Compositions for shortstopping free radical emulsion polymerizations and stabilizing latices made therefrom
WO2002038617A1 (en) *	2000-11-07	2002-05-16	Dow Global Technologies Inc.	Method for shortstopping polymerization processes in the manufacture of synthetic rubbers
US6761833B2 (en) *	2001-03-20	2004-07-13	Atofina Chemicals, Inc.	Stabilization of monomers by compositions based on alkylhydroxylamines
US7374711B2 (en) *	2002-10-10	2008-05-20	Apex Medical Technologies, Inc.	Accelerator-free thin-walled rubber vulcanizates from latex
EP1944604A1 (de)	2007-01-09	2008-07-16	Total Petrochemicals Research Feluy	Verfahren zum Beobachten der Bildung eines Polymers mit interner mechanischer Spannung mittels Schallemissionsanalyse
FR2986003B1 (fr) *	2012-01-24	2015-01-16	Arkema France	Procede de preparation de polymeres halogenes
BR112014030662B1 (pt)	2012-06-14	2021-07-06	Dow Global Technologies Llc	método para finalizar uma reação de polimerização de emulsão iniciada por radical livre e método para produzir um elastômero
WO2014052212A1 (en) *	2012-09-28	2014-04-03	Dow Global Technologies Llc	Alkyl hydroxylamine compounds and their use for shortstopping free radical polymerizations
CN108203486A (zh) *	2016-12-20	2018-06-26	中国石油天然气股份有限公司	一种环保型充油丁苯橡胶的制备方法
CN112830996B (zh) *	2019-11-25	2022-11-01	中国石油天然气股份有限公司	用于终止乳液聚合反应的组合物及其应用
US12409255B2 (en)	2020-10-22	2025-09-09	Thai Nippon Rubber Industry Public Company Limited	Synthetic polyisoprene latex condoms with reduced nitrosamine

Family Cites Families (25)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE295646C (de)
NL131752C (de) *	1960-09-08
US6090414A (en) *	1970-05-20	2000-07-18	Life Science Labs, Inc.	Method and composition to reduce cancer incidence
DE2301158A1 (de) *	1973-01-11	1974-07-18	Bayer Ag	Emulsionspolymerisation von chloropren mit diaethylhydroxylamin als desaktivator
CA1135450A (en) *	1979-08-01	1982-11-09	Ahti A. Koski	Short-stop
US4456526A (en) *	1982-09-24	1984-06-26	Atlantic Richfield Company	Method for minimizing fouling of heat exchangers
DE3836777A1 (de) *	1988-10-28	1990-05-03	Bunawerke Huels Gmbh	Verfahren zum desaktivieren von radikalen
DE3939474A1 (de)	1989-11-29	1991-06-06	Gerhard Prof Dr Eisenbrand	Verwendung von polyethylenimin zur verhinderung oder hemmung der nitrosaminbildung
GB9000436D0 (en) *	1990-01-09	1990-03-07	Shell Int Research	Process for shortstopping an emulsion polymerization
US5087671A (en) *	1990-06-25	1992-02-11	The Curators Of The University Of Missouri	Polymers for scavenging nitrosating agents
KR100193146B1 (ko) *	1990-07-20	1999-06-15	월터 클리웨인, 한스-피터 위트린	안정화된 단량체 조성물
US5290888A (en) *	1990-07-20	1994-03-01	Ciba-Geigy Corporation	Process for stabilizing ethylenically unsaturated compounds and stabilized monomer compositions
US5070130A (en)	1990-09-19	1991-12-03	The B. F. Goodrich Company	Alkaline earth oxides and hydroxides to reduce nitrosamine formation from vulcanization accelerators
DE4033903A1 (de)	1990-10-25	1992-04-30	Bayer Ag	Verwendung von maleinsaeurehalbestern und ihren salzen zur verminderung der nitrosaminbildung bei der schwefelvulkanisation
GB9102311D0 (en) *	1991-02-02	1991-03-20	Albright & Wilson	Nitrosamine inhibition
GB9301836D0 (en) *	1993-01-29	1993-03-17	Albright & Wilson	Nitrosamine inhibition
AU7811094A (en) *	1993-11-27	1995-06-13	Knoll Aktiengesellschaft	Compositions comprising iminium ion scavengers and/or nitrite scavengers
IT1265250B1 (it) *	1993-12-03	1996-10-31	Enichem Elastomers	Procedimento per la terminazione di polimerizzazione in emulsione che non genera nitrosammine
US5384372A (en)	1994-03-30	1995-01-24	The Goodyear Tire & Rubber Company	Shortstopping of free radical polymerizations
DE19505649C2 (de)	1995-02-18	2002-11-14	Freudenberg Carl Kg	Verwendung von blockierten Isocyanaten zur Verhinderung oder Verringerung der Entstehung von Aminen und N-Nitrosaminen bei Fertigung und Gebrauch von Elastomeren
GB2310858A (en)	1996-03-04	1997-09-10	Rhone Poulenc Chemicals	Inhibiting nitrosamine formation in rubber
JP4049818B2 (ja) *	1996-07-23	2008-02-20	日本ゼオン株式会社	浸漬成形用ラテックス組成物およびこれを用いた浸漬成形ゴム製品
WO1998051714A1 (en) *	1997-05-16	1998-11-19	Angus Chemical Company	N-ethylhydroxylamine as a shortstopping agent for free radical polymerization
US5880230A (en) *	1997-12-31	1999-03-09	Nalco/Exxon Energy Chemicals, L.P.	Shortstop agents for vinyl polymerizations
JP2000248008A (ja) *	1999-03-01	2000-09-12	Mitsubishi Chemicals Corp	乳化重合ゴムの製造方法

2000
- 2000-08-03 US US09/631,756 patent/US6495065B1/en not_active Expired - Fee Related
- 2000-08-30 CA CA002317087A patent/CA2317087C/en not_active Expired - Fee Related
- 2000-09-06 BR BR0004048-7A patent/BR0004048A/pt not_active Application Discontinuation
- 2000-09-07 KR KR1020000053044A patent/KR100730904B1/ko not_active Expired - Fee Related
- 2000-09-08 PL PL342437A patent/PL199774B1/pl not_active IP Right Cessation
- 2000-09-08 TW TW089118452A patent/TWI265936B/zh not_active IP Right Cessation
- 2000-09-08 EP EP00307753A patent/EP1083185B1/de not_active Expired - Lifetime
- 2000-09-08 CN CN00128969A patent/CN1288014A/zh active Pending
- 2000-09-08 AT AT00307753T patent/ATE430764T1/de not_active IP Right Cessation
- 2000-09-08 ES ES00307753T patent/ES2325200T3/es not_active Expired - Lifetime
- 2000-09-08 DE DE60042145T patent/DE60042145D1/de not_active Expired - Lifetime
- 2000-09-11 JP JP2000274847A patent/JP4846897B2/ja not_active Expired - Fee Related

Also Published As

Publication number	Publication date
BR0004048A (pt)	2001-04-24
TWI265936B (en)	2006-11-11
CN1288014A (zh)	2001-03-21
EP1083185B1 (de)	2009-05-06
ES2325200T3 (es)	2009-08-28
PL199774B1 (pl)	2008-10-31
US6495065B1 (en)	2002-12-17
PL342437A1 (en)	2001-03-12
CA2317087A1 (en)	2001-03-09
JP4846897B2 (ja)	2011-12-28
KR100730904B1 (ko)	2007-06-22
EP1083185A1 (de)	2001-03-14
CA2317087C (en)	2009-08-11
JP2001122913A (ja)	2001-05-08
KR20010067164A (ko)	2001-07-12
DE60042145D1 (de)	2009-06-18

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Legal Events

Date	Code	Title	Description
2009-11-15	RER	Ceased as to paragraph 5 lit. 3 law introducing patent treaties