ES2129709T3 - Iniciadores anionicos que contienen amina terciaria empleados para preparar polimeros y procedimiento para su preparacion. - Google Patents
Iniciadores anionicos que contienen amina terciaria empleados para preparar polimeros y procedimiento para su preparacion.Info
- Publication number
- ES2129709T3 ES2129709T3 ES95110370T ES95110370T ES2129709T3 ES 2129709 T3 ES2129709 T3 ES 2129709T3 ES 95110370 T ES95110370 T ES 95110370T ES 95110370 T ES95110370 T ES 95110370T ES 2129709 T3 ES2129709 T3 ES 2129709T3
- Authority
- ES
- Spain
- Prior art keywords
- procedure
- preparation
- amine used
- prepare polymers
- anionic initiators
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229920000642 polymer Polymers 0.000 title abstract 5
- 239000003999 initiator Substances 0.000 title abstract 2
- 150000001412 amines Chemical class 0.000 title 1
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 abstract 3
- -1 AMINO Chemical group 0.000 abstract 2
- 238000006243 chemical reaction Methods 0.000 abstract 2
- SDJHPPZKZZWAKF-UHFFFAOYSA-N 2,3-dimethylbuta-1,3-diene Chemical compound CC(=C)C(C)=C SDJHPPZKZZWAKF-UHFFFAOYSA-N 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F1/00—Compounds containing elements of Groups 1 or 11 of the Periodic Table
- C07F1/02—Lithium compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Polymerization Catalysts (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
SE PRESENTA UN SISTEMA INICIADOR ANIONICO FORMADO POR EL PRODUCTO DE LA REACCION DE: (1) UN COMPUESTO DE ORGANOLITIO CON (2) EL PRODUCTO DE REACCION DE A) UN AMINO SECUNDARIO Y B) BENCENO DE DIISOPROPENIL, EL SISTEMA INICIA LA POLIMERIZACION PARA PRODUCIR UN POLIMERO QUE CONTIENE ZONAS FUNCIONALES DE AMINO TERCIARIO INCORPORADAS EN LA CABEZA DE LA CADENA DEL POLIMERO. PUEDE COMPONERSE UNA SUBCLASE DE ESTOS POLIMEROS QUE EXHIBE UNA HISTERESIS REDUCIDA EN COMPARACION CON LOS POLIMEROS CONVENCIONALMENTE PREPARADOS.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US08/276,363 US5567815A (en) | 1994-07-18 | 1994-07-18 | Teritary amine containing antonic initiators used in preparing polymers and process for the preparation thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2129709T3 true ES2129709T3 (es) | 1999-06-16 |
Family
ID=23056357
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES95110370T Expired - Lifetime ES2129709T3 (es) | 1994-07-18 | 1995-07-03 | Iniciadores anionicos que contienen amina terciaria empleados para preparar polimeros y procedimiento para su preparacion. |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US5567815A (es) |
| EP (1) | EP0693500B1 (es) |
| JP (1) | JPH0848708A (es) |
| CA (1) | CA2153945A1 (es) |
| DE (1) | DE69508670T2 (es) |
| ES (1) | ES2129709T3 (es) |
Families Citing this family (53)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE69509448T2 (de) * | 1994-07-18 | 1999-09-02 | Bridgestone Corp. | Elastomere und Produkte mit niedriger Hysteresis und Verfahren zu deren Herstellung |
| US5912343A (en) * | 1996-12-31 | 1999-06-15 | Bridgestone Corporation | Tertiary amines containing side-chain organolithium structures and method for the preparation thereof |
| US5736617A (en) * | 1996-12-31 | 1998-04-07 | Bridgestone Corporation | Polymers, elastomeric compounds, and products thereof, terminated with novel amine compounds containing side-chain organohalide reactive moieties |
| US5786441A (en) * | 1996-12-31 | 1998-07-28 | Bridgestone Corporation | Polymers, elastomeric compounds and products thereof, derived from novel amine compounds containing side-chain organolithium moieties |
| US6605564B1 (en) * | 1997-11-14 | 2003-08-12 | Fmc Corporation | Compositions providing improved functionalization of terminal anions and processes for improved functionalization of terminal anions |
| US6545103B2 (en) | 1997-11-14 | 2003-04-08 | Fmc Corporation | Compositions providing improved functionalization of terminal anions and processes for improved functionalization of terminal anions |
| US6518214B2 (en) * | 2000-06-30 | 2003-02-11 | The Goodyear Tire & Rubber Company | Synthesis of functionalized lithium initiator |
| WO2002016491A2 (en) * | 2000-08-18 | 2002-02-28 | Bridgestone Corporation | Rubber compositions and vulcanizates including comb-branched polymers |
| WO2004007563A2 (en) * | 2002-07-11 | 2004-01-22 | Bridgestone Corporation | Preparation of functionalized anionic polymerization initiators |
| JP4744144B2 (ja) * | 2002-08-30 | 2011-08-10 | 株式会社ブリヂストン | 官能性ポリマー、及びそれにより改良された加硫物 |
| EP2277948B1 (en) | 2004-11-02 | 2015-02-18 | Bridgestone Corporation | Polyhedral-modified polymer |
| EP2193150B1 (en) | 2007-08-31 | 2020-09-23 | Bridgestone Corporation | Synthesis of a liquid polymer and a functionalized polymer |
| BRPI0806170B1 (pt) | 2007-10-22 | 2019-02-26 | Bridgestone Corporation | Polímero funcionalizado, método para preparar um polímero funcionalizado, e, composição compreendendo um polímero funcionalizado |
| KR20160110557A (ko) | 2007-12-28 | 2016-09-21 | 가부시키가이샤 브리지스톤 | 히드록시아릴 관능화 중합체 |
| FR2940294B1 (fr) | 2008-12-23 | 2011-02-18 | Michelin Soc Tech | Nouveau systeme d'amorcage pour polymerisation anionique de dienes conjugues, procede de preparation d'elastomeres dieniques. |
| KR101692089B1 (ko) | 2009-01-23 | 2017-01-02 | 가부시키가이샤 브리지스톤 | 폴리시아노 화합물로 관능화된 중합체 |
| KR101682733B1 (ko) | 2009-01-23 | 2016-12-05 | 가부시키가이샤 브리지스톤 | 보호된 아미노기를 함유하는 니트릴 화합물로 관능화된 중합체 |
| US9365660B2 (en) | 2009-06-30 | 2016-06-14 | Bridgestone Corporation | Anionic polymerization initiators and processes |
| CN102712214B (zh) | 2009-11-16 | 2015-04-01 | 株式会社普利司通 | 官能化聚合物 |
| US8338544B2 (en) * | 2009-12-21 | 2012-12-25 | Bridgestone Corporation | Polymers functionalized with polyoxime compounds and methods for their manufacture |
| EP2576490B1 (en) | 2010-05-31 | 2016-08-31 | Bridgestone Corporation | Hydroxyl group-containing methylstyrene and polymers incorporating same |
| US8748531B2 (en) | 2010-12-10 | 2014-06-10 | Bridgestone Corporation | Polymers functionalized with oxime compounds containing an acyl group |
| KR101946659B1 (ko) | 2011-02-05 | 2019-02-11 | 가부시키가이샤 브리지스톤 | 란타나이드 복합체 촉매 및 이를 이용한 중합 방법 |
| US8962766B2 (en) | 2011-09-15 | 2015-02-24 | Bridgestone Corporation | Polymers functionalized with polyhydrazone compounds |
| US9000070B2 (en) | 2011-10-19 | 2015-04-07 | Bridgestone Corporation | Mixing of telechelic rubber formulations |
| EP2797960B1 (en) | 2011-12-31 | 2018-02-28 | Bridgestone Corporation | Functionalized polymer |
| WO2014052957A1 (en) | 2012-09-30 | 2014-04-03 | Bridgestone Corporation | Organometallic catalyst complex and polymerization method employing same |
| CN105026448B (zh) | 2012-11-09 | 2017-10-17 | 株式会社普利司通 | 生物基苯乙烯的用途 |
| EP3738927A1 (en) | 2014-05-31 | 2020-11-18 | Bridgestone Corporation | Metallic complex catalyst, polymerization methods employing same and polymer products thereof |
| KR101800496B1 (ko) * | 2014-06-16 | 2017-11-22 | 주식회사 엘지화학 | 변성 공액 디엔계 중합체, 이를 포함하는 변성 고무 조성물 및 변성 공액 디엔계 중합체의 제조방법 |
| KR101775761B1 (ko) * | 2014-07-30 | 2017-09-19 | 주식회사 엘지화학 | 변성 공액 디엔계 중합체, 이를 포함하는 변성 고무 조성물 및 변성 공액 디엔계 중합체의 제조방법 |
| KR101748915B1 (ko) * | 2014-11-28 | 2017-06-19 | 주식회사 엘지화학 | 신규 음이온 중합 개시제 및 이를 이용한 공역디엔계 공중합체의 제조방법 |
| KR101768293B1 (ko) * | 2014-12-19 | 2017-08-14 | 주식회사 엘지화학 | 신규 음이온 중합 개시제 및 이를 이용한 공역디엔계 공중합체의 제조방법 |
| JP6789236B2 (ja) * | 2015-04-10 | 2020-11-25 | シントス エス.アー.Synthos S.A. | ジエンモノマーおよびビニル芳香族モノマーの共重合のための開始剤 |
| EP3325518B1 (en) | 2015-07-22 | 2021-05-12 | Bridgestone Corporation | Silane-functionalized polymer and process for making and using same |
| US10730961B2 (en) | 2015-07-29 | 2020-08-04 | Bridgestone Corporation | Processes for preparing functionahzed polymers, related functionalizing compound and preparation thereof |
| WO2017047923A1 (ko) | 2015-09-17 | 2017-03-23 | 주식회사 엘지화학 | 음이온 중합개시제의 제조방법, 제조장치 및 이로부터 제조되는 음이온 중합개시제 |
| KR102034443B1 (ko) * | 2016-04-01 | 2019-10-21 | 주식회사 엘지화학 | 연속 공정식 음이온 중합개시제의 제조방법 및 이로부터 제조되는 음이온 중합개시제 |
| WO2017047924A1 (ko) * | 2015-09-17 | 2017-03-23 | 주식회사 엘지화학 | 음이온 중합개시제의 제조방법, 제조장치 및 이로부터 제조되는 음이온 중합개시제 |
| KR102034447B1 (ko) * | 2016-04-01 | 2019-10-21 | 주식회사 엘지화학 | 연속 공정식 음이온 중합개시제의 제조방법 및 이로부터 제조되는 음이온 중합개시제 |
| WO2017087087A1 (en) | 2015-11-16 | 2017-05-26 | Bridgestone Corporation | Functional initiator for anionic polymerization |
| KR102034442B1 (ko) * | 2016-07-27 | 2019-10-21 | 주식회사 엘지화학 | 음이온 중합개시제의 제조장치 및 이를 이용한 음이온 중합개시제의 제조방법 |
| KR102067787B1 (ko) * | 2016-10-04 | 2020-01-17 | 주식회사 엘지화학 | 변성 개시제 및 이를 포함하는 변성 공액디엔계 중합체 |
| KR102111119B1 (ko) * | 2016-10-11 | 2020-05-14 | 주식회사 엘지화학 | 변성 개시제의 제조방법 및 이로부터 제조된 변성 개시제 |
| KR102041813B1 (ko) * | 2016-10-20 | 2019-11-07 | 주식회사 엘지화학 | 음이온 중합개시제의 제조방법, 이의 제조장치 및 이로부터 제조되는 음이온 중합개시제 조성물 |
| KR102034454B1 (ko) * | 2017-01-04 | 2019-10-21 | 주식회사 엘지화학 | 중합개시제 조성물, 이의 제조방법 및 이를 이용한 중합체의 제조방법 |
| CN111479836B (zh) | 2017-12-14 | 2023-05-23 | 株式会社普利司通 | 偶联聚合物产物、制备方法以及含有其的组合物 |
| EP3724244B1 (en) | 2017-12-15 | 2024-02-21 | Bridgestone Corporation | Functionalized polymer, process for preparing and rubber compositions containing the functionalized polymer |
| RU2666724C1 (ru) * | 2018-05-15 | 2018-09-12 | Публичное Акционерное Общество "Нижнекамскнефтехим" | Способ получения полимеров бутадиена или сополимеров бутадиена со стиролом с низким содержанием 1,2-звеньев в бутадиеновой части |
| KR102241925B1 (ko) | 2018-11-26 | 2021-04-20 | 주식회사 엘지화학 | 블록 공중합체 조성물, 이의 제조방법 및 이를 포함하는 아스팔트 조성물 |
| WO2020111644A1 (ko) * | 2018-11-26 | 2020-06-04 | 주식회사 엘지화학 | 블록 공중합체 조성물, 이의 제조방법 및 이를 포함하는 아스팔트 조성물 |
| KR20220013362A (ko) | 2019-05-22 | 2022-02-04 | 모멘티브 퍼포먼스 머티리얼즈 인크. | 티오에스테르-관능성 유기 폴리머, 그 제조 방법 및 조성물 |
| JP7568861B2 (ja) | 2020-12-18 | 2024-10-16 | 株式会社ブリヂストン | バガス含有グアユールゴムとシランとを組み合わせたゴム組成物及び関連する方法 |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3903168A (en) * | 1973-11-23 | 1975-09-02 | Du Pont | Stable anionic polymerization initiator |
| US4429091A (en) | 1983-03-09 | 1984-01-31 | The Firestone Tire & Rubber Company | Oligomeric oxolanyl alkanes as modifiers for polymerization of dienes using lithium-based initiators |
| US4935471A (en) | 1987-10-15 | 1990-06-19 | The Goodyear Tire & Rubber Company | Capped polydienes |
| US5066729A (en) | 1990-04-09 | 1991-11-19 | Bridgestone/Firestone, Inc. | Diene polymers and copolymers terminated by reaction with n-alkyl and n-aryl imines |
| US5153159A (en) * | 1990-04-09 | 1992-10-06 | Bridgestone/Firestone, Inc. | Elastomers and products having reduced hysteresis |
| US5039814A (en) * | 1990-05-02 | 1991-08-13 | Merck & Co., Inc. | Ortho-lithiation process for the synthesis of 2-substituted 1-(tetrazol-5-yl)benzenes |
| EP0594107B1 (en) * | 1992-10-19 | 1997-06-18 | Bridgestone Corporation | Process for preparing a polymer using lithium initiator prepared by in situ preparation |
-
1994
- 1994-07-18 US US08/276,363 patent/US5567815A/en not_active Expired - Lifetime
-
1995
- 1995-07-03 ES ES95110370T patent/ES2129709T3/es not_active Expired - Lifetime
- 1995-07-03 EP EP95110370A patent/EP0693500B1/en not_active Expired - Lifetime
- 1995-07-03 DE DE69508670T patent/DE69508670T2/de not_active Expired - Fee Related
- 1995-07-13 JP JP7200392A patent/JPH0848708A/ja active Pending
- 1995-07-14 CA CA002153945A patent/CA2153945A1/en not_active Abandoned
Also Published As
| Publication number | Publication date |
|---|---|
| DE69508670D1 (de) | 1999-05-06 |
| JPH0848708A (ja) | 1996-02-20 |
| DE69508670T2 (de) | 1999-07-22 |
| EP0693500A1 (en) | 1996-01-24 |
| CA2153945A1 (en) | 1996-01-19 |
| US5567815A (en) | 1996-10-22 |
| EP0693500B1 (en) | 1999-03-31 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG2A | Definitive protection |
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