ATE439384T1 - Verfahren zur stabilisierung von vinylaromatischen monomeren mit verwendung von ausgewählten polymerisierungsinhibitoren sowie daraus hergestellte polymere - Google Patents

Verfahren zur stabilisierung von vinylaromatischen monomeren mit verwendung von ausgewählten polymerisierungsinhibitoren sowie daraus hergestellte polymere

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Publication number
ATE439384T1
ATE439384T1 AT07112448T AT07112448T ATE439384T1 AT E439384 T1 ATE439384 T1 AT E439384T1 AT 07112448 T AT07112448 T AT 07112448T AT 07112448 T AT07112448 T AT 07112448T AT E439384 T1 ATE439384 T1 AT E439384T1
Authority
AT
Austria
Prior art keywords
vinyl aromatic
disclosed
aromatic monomer
inhibit polymerization
aromatic monomers
Prior art date
Application number
AT07112448T
Other languages
English (en)
Inventor
James T Merrill
Original Assignee
Total Petrochemicals Res Feluy
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
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Application filed by Total Petrochemicals Res Feluy filed Critical Total Petrochemicals Res Feluy
Application granted granted Critical
Publication of ATE439384T1 publication Critical patent/ATE439384T1/de

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Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C4/00Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms
    • C07C4/08Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms by splitting-off an aliphatic or cycloaliphatic part from the molecule
    • C07C4/12Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms by splitting-off an aliphatic or cycloaliphatic part from the molecule from hydrocarbons containing a six-membered aromatic ring, e.g. propyltoluene to vinyltoluene
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C7/00Purification; Separation; Use of additives
    • C07C7/20Use of additives, e.g. for stabilisation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F112/00Homopolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F112/02Monomers containing only one unsaturated aliphatic radical
    • C08F112/04Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F112/06Hydrocarbons
    • C08F112/08Styrene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/38Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • C08F2/40Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation using retarding agents

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Water Supply & Treatment (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Polymerisation Methods In General (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
AT07112448T 2002-05-06 2003-04-22 Verfahren zur stabilisierung von vinylaromatischen monomeren mit verwendung von ausgewählten polymerisierungsinhibitoren sowie daraus hergestellte polymere ATE439384T1 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US10/139,524 US6960279B2 (en) 2002-05-06 2002-05-06 Method for stabilizing vinyl aromatic monomers using selected polymerization inhibitors and polymers prepared therewith

Publications (1)

Publication Number Publication Date
ATE439384T1 true ATE439384T1 (de) 2009-08-15

Family

ID=29269562

Family Applications (2)

Application Number Title Priority Date Filing Date
AT03076188T ATE370110T1 (de) 2002-05-06 2003-04-22 Verfahren zur stabilisierung von vinylaromatischen monomeren mit verwendung von ausgewählten polymerisierungsinhibitoren sowie daraus hergestellte polymere
AT07112448T ATE439384T1 (de) 2002-05-06 2003-04-22 Verfahren zur stabilisierung von vinylaromatischen monomeren mit verwendung von ausgewählten polymerisierungsinhibitoren sowie daraus hergestellte polymere

Family Applications Before (1)

Application Number Title Priority Date Filing Date
AT03076188T ATE370110T1 (de) 2002-05-06 2003-04-22 Verfahren zur stabilisierung von vinylaromatischen monomeren mit verwendung von ausgewählten polymerisierungsinhibitoren sowie daraus hergestellte polymere

Country Status (10)

Country Link
US (2) US6960279B2 (de)
EP (2) EP1837322B1 (de)
JP (2) JP4418641B2 (de)
KR (1) KR20030086928A (de)
CN (2) CN101054335A (de)
AT (2) ATE370110T1 (de)
CA (1) CA2423209A1 (de)
DE (2) DE60328839D1 (de)
ES (2) ES2291589T3 (de)
TW (2) TWI278338B (de)

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20050107811A (ko) * 2003-03-17 2005-11-15 하쿠토 가부시키가이샤 방향족 비닐 화합물의 중합 억제제 및 중합 억제 방법
DE102007052891A1 (de) 2007-11-02 2009-05-07 Evonik Degussa Gmbh Verfahren zur Stabilisierung von olefinisch ungesättigten Monomeren
US8187346B2 (en) * 2008-12-29 2012-05-29 Fina Technology, Inc. Stabilization of pygas for storage
US7651635B1 (en) * 2009-02-05 2010-01-26 Nalco Company Polymer inhibition of vinyl aromatic monomers using a quinone methide/alkyl hydroxylamine combination
US8298440B2 (en) * 2010-06-03 2012-10-30 General Electric Company Methods and compositions for inhibiting vinyl aromatic monomer polymerization
US8969498B2 (en) 2010-08-02 2015-03-03 Dow Global Technologies Llc Compositions and method of inhibiting polymerization of vinyl-aryl monomers
US9090526B2 (en) * 2011-06-13 2015-07-28 Nalco Company Synergistic combination for inhibiting polymerization of vinyl monomers
FR2979348B1 (fr) * 2011-08-25 2013-08-09 Rhodia Operations Procede de preparation d'une composition inhibitrice comprenant un compose a base d'au moins deux solides inhibiteurs de polymerisation
EP2748207B1 (de) * 2011-08-26 2016-04-06 Dorf Ketal Chemicals (India) Private Limited Additivzusammensetzung zur kontrolle und hemmung der polymerisation von styrol sowie verfahren zu seiner herstellung und verwendung
US9206268B2 (en) * 2011-09-16 2015-12-08 General Electric Company Methods and compositions for inhibiting polystyrene formation during styrene production
US8901362B2 (en) * 2012-02-02 2014-12-02 General Electric Company Methods and compositions for styrene inhibition via in situ generation of quinone methides
DE102013204950A1 (de) 2013-03-20 2014-09-25 Evonik Industries Ag Verfahren und Zusammensetzung zur Inhibierung der Polymerisation von Cyclopentadienverbindungen
CN112513005A (zh) 2018-07-13 2021-03-16 埃科莱布美国股份有限公司 氧化胺和甲基化醌的组合物作为乙烯单体的抗污剂
KR102763249B1 (ko) 2018-07-13 2025-02-04 에코랍 유에스에이 인코퍼레이티드 니트록사이드 억제제, 퀴논 메티드 지연제 및 아민 안정화제를 포함하는 단량체 중합 억제용 조성물
JP7247630B2 (ja) * 2019-02-13 2023-03-29 栗田工業株式会社 不飽和芳香族単量体の重合を抑制する方法
CN114163290B (zh) * 2021-12-06 2024-02-27 万华化学集团股份有限公司 一种碱洗塔黄油抑制剂及其制备方法
CN116553996A (zh) * 2023-07-07 2023-08-08 吉林金海化工新材料有限公司 一种阻聚剂及其应用

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4003800A (en) * 1976-01-02 1977-01-18 Gulf Research & Development Company Styrene purification process
US4032547A (en) * 1976-02-23 1977-06-28 Gulf Research & Development Company Quinone alkide synthesis system
US4434307A (en) * 1982-12-27 1984-02-28 Atlantic Richfield Company Inhibiting polymerization of vinyl aromatic monomers
US4466904A (en) * 1983-01-10 1984-08-21 Cosden Technology, Inc. Polymerization co-inhibitors for vinyl aromatic compounds
US4616774A (en) * 1984-03-01 1986-10-14 Plus Corporation Stapler
US5254760A (en) * 1992-07-29 1993-10-19 Ciba-Geigy Corporation Inhibiting polymerization of vinyl aromatic monomers
SG49028A1 (en) * 1994-01-25 1998-05-18 Sumitomo Chemical Co A method fo inhibiting polymerization of vinyl compound and polymerization inhibitor used therein
US5616774A (en) * 1995-04-14 1997-04-01 Ciba-Geigy Corporation Inhibition of unsaturated monomers with 7-aryl quinone methides
US5583247A (en) * 1995-04-14 1996-12-10 Ciba-Geigy Corporation 7-substituted quinone methides as inhibitors for unsaturated monomers
WO1999024402A1 (en) * 1997-11-12 1999-05-20 Mitsubishi Rayon Co., Ltd. N-oxyl compounds, process for the preparation thereof, and process for inhibiting the polymerization of vinyl monomers with the same
US6024894A (en) * 1998-03-25 2000-02-15 Betzdearborn Inc. Compositions and methods for inhibiting vinyl aromatic monomer polymerization
JP4248875B2 (ja) * 2000-10-16 2009-04-02 ケムチュア コーポレイション 重合抑制剤としての、キノンアルカイドとニトロキシル化合物の混合物
US6685823B2 (en) * 2000-10-16 2004-02-03 Uniroyal Chemical Company, Inc. C-nitrosoaniline compounds and their blends as polymerization inhibitors
US20040034247A1 (en) * 2002-08-16 2004-02-19 Sherif Eldin Compositions and methods for inhibiting vinyl aromatic monomer polymerization

Also Published As

Publication number Publication date
ES2330799T3 (es) 2009-12-15
EP1837322B1 (de) 2009-08-12
EP1837322A2 (de) 2007-09-26
DE60328839D1 (de) 2009-09-24
DE60315542T2 (de) 2008-05-15
EP1837322A3 (de) 2008-04-30
DE60315542D1 (de) 2007-09-27
CN1456542A (zh) 2003-11-19
US20060020089A1 (en) 2006-01-26
KR20030086928A (ko) 2003-11-12
US6960279B2 (en) 2005-11-01
TW200402318A (en) 2004-02-16
ES2291589T3 (es) 2008-03-01
CA2423209A1 (en) 2003-11-06
JP4418641B2 (ja) 2010-02-17
JP2010013483A (ja) 2010-01-21
EP1362838A3 (de) 2004-03-24
CN1326816C (zh) 2007-07-18
TW200710101A (en) 2007-03-16
JP2003321401A (ja) 2003-11-11
EP1362838B1 (de) 2007-08-15
TWI278338B (en) 2007-04-11
CN101054335A (zh) 2007-10-17
US20030205452A1 (en) 2003-11-06
ATE370110T1 (de) 2007-09-15
EP1362838A2 (de) 2003-11-19

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