ATE449150T1 - Polycarbonatzusammensetzungen und daraus gebildete formkörper - Google Patents
Polycarbonatzusammensetzungen und daraus gebildete formkörperInfo
- Publication number
- ATE449150T1 ATE449150T1 AT07716898T AT07716898T ATE449150T1 AT E449150 T1 ATE449150 T1 AT E449150T1 AT 07716898 T AT07716898 T AT 07716898T AT 07716898 T AT07716898 T AT 07716898T AT E449150 T1 ATE449150 T1 AT E449150T1
- Authority
- AT
- Austria
- Prior art keywords
- polycarbonate
- sulfonate
- composition
- molded bodies
- made therefrom
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title abstract 4
- 229920000515 polycarbonate Polymers 0.000 title abstract 4
- 239000004417 polycarbonate Substances 0.000 title abstract 4
- 125000003118 aryl group Chemical group 0.000 abstract 2
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 abstract 2
- LBLYYCQCTBFVLH-UHFFFAOYSA-N 2-Methylbenzenesulfonic acid Chemical compound CC1=CC=CC=C1S(O)(=O)=O LBLYYCQCTBFVLH-UHFFFAOYSA-N 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 239000003365 glass fiber Substances 0.000 abstract 1
- 229910052736 halogen Inorganic materials 0.000 abstract 1
- 150000002367 halogens Chemical class 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- GGRIQDPLLHVRDU-UHFFFAOYSA-M potassium;2-(benzenesulfonyl)benzenesulfonate Chemical compound [K+].[O-]S(=O)(=O)C1=CC=CC=C1S(=O)(=O)C1=CC=CC=C1 GGRIQDPLLHVRDU-UHFFFAOYSA-M 0.000 abstract 1
- 159000000000 sodium salts Chemical class 0.000 abstract 1
- 150000003457 sulfones Chemical class 0.000 abstract 1
- 239000011885 synergistic combination Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L69/00—Compositions of polycarbonates; Compositions of derivatives of polycarbonates
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K21/00—Fireproofing materials
- C09K21/14—Macromolecular materials
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/02—Fibres or whiskers
- C08K7/04—Fibres or whiskers inorganic
- C08K7/14—Glass
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
- C08L83/10—Block- or graft-copolymers containing polysiloxane sequences
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
- C08K5/41—Compounds containing sulfur bound to oxygen
- C08K5/42—Sulfonic acids; Derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
- C08L25/04—Homopolymers or copolymers of styrene
- C08L25/08—Copolymers of styrene
- C08L25/12—Copolymers of styrene with unsaturated nitriles
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/12—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
- C08L27/18—Homopolymers or copolymers or tetrafluoroethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
- C08L83/04—Polysiloxanes
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US11/353,732 US7728059B2 (en) | 2006-02-14 | 2006-02-14 | Polycarbonate compositions and articles formed therefrom |
| PCT/US2007/001689 WO2007094927A1 (en) | 2006-02-14 | 2007-01-23 | Polycarbonate compositions and articles formed therefrom |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ATE449150T1 true ATE449150T1 (de) | 2009-12-15 |
Family
ID=38117036
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AT07716898T ATE449150T1 (de) | 2006-02-14 | 2007-01-23 | Polycarbonatzusammensetzungen und daraus gebildete formkörper |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US7728059B2 (de) |
| EP (1) | EP1984472B1 (de) |
| JP (1) | JP2009526898A (de) |
| KR (1) | KR101136957B1 (de) |
| CN (1) | CN101384684B (de) |
| AT (1) | ATE449150T1 (de) |
| DE (1) | DE602007003323D1 (de) |
| WO (1) | WO2007094927A1 (de) |
Families Citing this family (58)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20080014446A1 (en) * | 2004-10-07 | 2008-01-17 | General Electric Company | Window shade and a multi-layered article, and methods of making the same |
| US7557153B2 (en) * | 2005-10-31 | 2009-07-07 | Sabic Innovative Plastics Ip Bv | Ionizing radiation stable thermoplastic composition, method of making, and articles formed therefrom |
| US20070191519A1 (en) * | 2006-02-14 | 2007-08-16 | General Electric Company | Halogen-free polycarbonate compositions and articles formed therefrom |
| US7632881B2 (en) * | 2006-06-22 | 2009-12-15 | Sabic Innovative Plastics Ip B.V. | Polycarbonate compositions and articles formed therefrom |
| JP5342767B2 (ja) * | 2007-11-13 | 2013-11-13 | 出光興産株式会社 | ポリカーボネート樹脂組成物、ポリカーボネート樹脂成形品、及びその製造方法 |
| US7732516B2 (en) * | 2008-01-31 | 2010-06-08 | Sabic Innovative Plastics Ip B.V. | Flame retardant polyimide/polyester-polycarbonate compositions, methods of manufacture, and articles formed therefrom |
| KR100905089B1 (ko) * | 2008-05-15 | 2009-06-30 | 제일모직주식회사 | 내광성 및 치수 안정성이 우수한 폴리카보네이트 수지조성물 |
| US7994254B2 (en) * | 2008-06-20 | 2011-08-09 | Sabic Innovative Plastics Ip B.V. | Polysiloxane-polycarbonate compositions, and related methods and articles |
| US8445568B2 (en) * | 2008-09-25 | 2013-05-21 | Sabic Innovative Plastics Ip B.V. | Flame retardant thermoplastic composition and articles formed therefrom |
| US8771829B2 (en) * | 2008-09-25 | 2014-07-08 | Sabic Innovative Plastics Ip B.V. | Flame retardant thermoplastic polymer composition, method of manufacture, and articles formed therefrom |
| US20100280159A1 (en) * | 2008-09-25 | 2010-11-04 | Christianus Johannes Jacobus Maas | Flame retardant thermoplastic composition and articles formed therefrom |
| US7994248B2 (en) | 2008-12-11 | 2011-08-09 | Sabic Innovative Plastics Ip B.V. | Flame retardant thermoplastic polycarbonate compositions |
| WO2011155490A1 (ja) * | 2010-06-09 | 2011-12-15 | 出光興産株式会社 | ポリカーボネート系樹脂組成物及びその成形品 |
| JP5706667B2 (ja) * | 2010-11-08 | 2015-04-22 | 出光興産株式会社 | ポリカーボネート系樹脂組成物、成形品、及び太陽光発電用構造部材 |
| KR101333589B1 (ko) | 2010-12-29 | 2013-11-28 | 제일모직주식회사 | 난연성이 우수한 유리섬유 보강 폴리카보네이트 수지 조성물 |
| CN102311625B (zh) * | 2011-07-06 | 2012-07-25 | 惠州市昌亿科技股份有限公司 | 耐寒智能电表壳体用聚碳酸酯/玻璃纤维合金及制备方法 |
| CN102311629B (zh) * | 2011-07-06 | 2012-07-25 | 惠州市昌亿科技股份有限公司 | 一种智能水表壳体用聚碳酸酯/玻璃纤维合金及其制备方法 |
| EP2776506B1 (de) * | 2011-11-08 | 2019-12-25 | SABIC Global Technologies B.V. | Hochhitzebeständige polycarbonat- und siloxan-copolycarbonat-mischungen mit duktilen hochhitzebeständigen optionen für flammhemmende anwendungen |
| WO2013079631A1 (de) * | 2011-11-30 | 2013-06-06 | Bayer Intellectual Property Gmbh | Glasfaserverstärkte, flammgeschützte polycarbonatzusammensetzungen |
| US9023922B2 (en) | 2012-05-24 | 2015-05-05 | Sabic Global Technologies B.V. | Flame retardant compositions, articles comprising the same and methods of manufacture thereof |
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| CN104684983B (zh) | 2012-09-28 | 2017-02-22 | 沙特基础全球技术有限公司 | 改善的脱模聚碳酸酯组合物 |
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| CN103788610B (zh) * | 2012-10-30 | 2016-04-20 | 上海长伟锦磁工程塑料有限公司 | 高透明耐低温冲击阻燃聚碳酸酯复合材料及其制备方法 |
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| CN103275523B (zh) * | 2013-05-31 | 2014-09-17 | 中山市华山高新陶瓷材料有限公司 | 用于食品包装塑料中的桔黄颜料及其制备方法 |
| KR101823619B1 (ko) | 2013-06-21 | 2018-01-30 | 사빅 글로벌 테크놀러지스 비.브이. | 고 품질 및 우수한 가공성을 구비한 광학 특성 제품을 제조하기 위한 폴리카보네이트 조성물 |
| US9365720B2 (en) | 2014-01-14 | 2016-06-14 | Sabic Global Technologies B.V. | Interior train components having low smoke and low heat release, and methods of their manufacture |
| US9718956B2 (en) * | 2014-01-14 | 2017-08-01 | Sabic Global Technologies B.V. | Interior aircraft components and methods of manufacture |
| WO2015132740A1 (en) | 2014-03-06 | 2015-09-11 | Sabic Global Technologies B.V. | Enhanced polycarbonate extrusion grades |
| CN104086972B (zh) * | 2014-07-17 | 2015-12-02 | 应璐 | 一种抗雾聚碳酸酯镜片材料及其制备方法 |
| CN104559107A (zh) * | 2014-12-15 | 2015-04-29 | 深圳市富恒新材料股份有限公司 | 一种玻纤增强聚碳酸酯复合材料及其制备方法 |
| KR102480605B1 (ko) * | 2015-01-20 | 2022-12-26 | 코베스트로 도이칠란트 아게 | 실록산-함유 폴리카르보네이트 블록 공축합물을 함유하며 유리 섬유를 함유하는 난연성 성형 배합물 |
| US10487208B2 (en) | 2015-01-20 | 2019-11-26 | Covestro Deutschland Ag | Flame-retardant molding compounds containing siloxane-containing polycarbonate block co-condensate |
| CN105131550B (zh) * | 2015-08-28 | 2017-05-31 | 金发科技股份有限公司 | 一种聚碳酸酯组合物及其制备方法 |
| KR102287397B1 (ko) * | 2016-03-09 | 2021-08-09 | 이데미쓰 고산 가부시키가이샤 | 폴리카보네이트계 수지 조성물 및 그 성형품 |
| JP6971225B2 (ja) * | 2016-05-19 | 2021-11-24 | クラレノリタケデンタル株式会社 | 歯科用樹脂組成物 |
| US20190284391A1 (en) * | 2016-05-26 | 2019-09-19 | Sabic Global Technologies B.V. | High heat, high impact polycarbonate compositions and articles made therefrom |
| WO2018159779A1 (ja) * | 2017-03-01 | 2018-09-07 | 出光興産株式会社 | ポリカーボネート系樹脂組成物及びその成形品 |
| WO2018159781A1 (ja) * | 2017-03-01 | 2018-09-07 | 出光興産株式会社 | ポリカーボネート系樹脂組成物及びその成形品 |
| CN110402270B (zh) * | 2017-03-01 | 2022-06-14 | 出光兴产株式会社 | 阻燃性聚碳酸酯系树脂组合物及其成形品 |
| EP3615603A1 (de) * | 2017-04-25 | 2020-03-04 | SABIC Global Technologies B.V. | Brominfreies und chlorfreies flammschutzmittel, glasgefülltes polycarbonat mit verbesserter multiaxialer stärke |
| CN107189399A (zh) * | 2017-07-26 | 2017-09-22 | 深圳市普特美橡塑原料有限公司 | 一种pc/san/gf复合材料及其制备方法 |
| JP2021028350A (ja) * | 2017-09-13 | 2021-02-25 | 出光興産株式会社 | ポリカーボネート系樹脂組成物及びその成形品 |
| EP3685645A4 (de) | 2017-09-22 | 2021-08-25 | 3M Innovative Properties Company | Verbundartikel |
| CN112218906A (zh) | 2018-06-04 | 2021-01-12 | Sabic环球技术有限责任公司 | 透明的支化聚碳酸酯 |
| EP3725847B1 (de) * | 2019-01-04 | 2024-04-24 | SHPP Global Technologies B.V. | Aus hochhitzebeständigen, hochschlagzähen polycarbonatzusammensetzungen hergestellte artikel und verfahren zur herstellung |
| EP3757158A1 (de) | 2019-06-28 | 2020-12-30 | SABIC Global Technologies B.V. | Verstärkte polycarbonatzusammensetzungen mit verbesserter wärmebeständigkeit |
| EP4077541B1 (de) | 2019-12-16 | 2025-01-22 | SHPP Global Technologies B.V. | Verstärkte flammhemmende polycarbonatzusammensetzungen mit verbesserten schmelzvolumenraten |
| CN116348528A (zh) * | 2020-07-30 | 2023-06-27 | 国际人造丝公司 | 阻燃且耐水解的聚酯组合物及由其制成的连接器 |
| CN112457644B (zh) * | 2020-10-21 | 2022-03-22 | 金发科技股份有限公司 | 高韧性、高流动阻燃聚碳酸酯组合物及其制备方法和应用 |
| CN112552668A (zh) * | 2020-10-21 | 2021-03-26 | 金发科技股份有限公司 | 一种长期稳定的聚碳酸酯组合物及其制备方法 |
| KR102472429B1 (ko) * | 2020-12-28 | 2022-12-01 | 주식회사 삼양사 | 내스크래치성이 향상되고 내충격성이 우수한 공중합체 및 그 제조방법 |
| EP4194509B1 (de) * | 2021-12-07 | 2025-01-01 | SHPP Global Technologies B.V. | Polycarbonatzusammensetzungen |
| CN121889462A (zh) * | 2023-08-17 | 2026-04-17 | 盛禧奥欧洲有限责任公司 | 未用pfas添加剂配制的阻燃聚碳酸酯组合物 |
| EP4509563A1 (de) * | 2023-08-17 | 2025-02-19 | Trinseo Europe GmbH | Pfas-verbindungsfreie flammhemmende polycarbonatzusammensetzungen |
| CN120040939A (zh) * | 2023-11-27 | 2025-05-27 | 帝人株式会社 | 一种聚碳酸酯组合物及成型品 |
| WO2026109257A1 (en) | 2024-11-25 | 2026-05-28 | Sabic Global Technologies B.V. | Flame retardant thermoplastic composition |
Family Cites Families (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AT297333B (de) | 1969-06-13 | 1972-03-27 | Bayer Ag | Verfahren zur Herstellung von Polycarbonaten mit verminderter Brennbarkeit |
| US3671487A (en) | 1971-05-05 | 1972-06-20 | Gen Electric | Glass reinforced polyester resins containing polytetrafluoroethylene and flame retardant additives |
| US3723373A (en) | 1971-10-04 | 1973-03-27 | American Cyanamid Co | 0.1% to about 2.0% by weight polytetrafluoroethylene emulsion modified polyethylene terephthalate with improved processing characteristics |
| US3971756A (en) | 1974-08-09 | 1976-07-27 | General Electric Company | Flame retardant polycarbonate composition |
| US4028297A (en) | 1975-07-18 | 1977-06-07 | General Electric Company | Novel flame retardant polycarbonate compositions |
| US4110299A (en) | 1976-10-15 | 1978-08-29 | General Electric Company | Flame-retardant polycarbonate composition |
| US4130530A (en) | 1977-04-08 | 1978-12-19 | General Electric Company | Cyclic siloxane plasticized polycarbonate composition |
| US4303575A (en) | 1980-02-07 | 1981-12-01 | Mobay Chemical Corporation | Flame retardant polycarbonate compositions |
| US4335038A (en) | 1980-09-26 | 1982-06-15 | The Dow Chemical Company | Polycarbonate containing a metal perfluoroborate and an organosilane as ignition depressants |
| DE3203905A1 (de) | 1982-02-05 | 1983-08-11 | Bayer Ag, 5090 Leverkusen | Polycarbonat-formmassen mit verbesserter flammwidrigkeit |
| GB8806497D0 (en) | 1988-03-18 | 1988-04-20 | Mortile Acoustic Ind Ltd | Non-toxic fire retardant thermoplastic material |
| US4916194A (en) | 1989-03-06 | 1990-04-10 | General Electric Company | Flame retardant aromatic polycarbonate blends |
| EP0522751B1 (de) * | 1991-07-01 | 1998-04-01 | General Electric Company | Polycarbonat-Polysiloxan-Blockcopolymere |
| US5508323A (en) | 1992-06-29 | 1996-04-16 | Dow Corning Corporation | Method for imparting fire retardancy to organic resins |
| US5360861A (en) | 1993-05-28 | 1994-11-01 | General Electric Company | Polyester-carbonate resin compositions of improved impact-resistance |
| US6405759B1 (en) | 1997-08-05 | 2002-06-18 | Owens Corning Composites Sprl | Apparatus for the continuous preparation of glass fiber sizing compositions |
| KR20010082298A (ko) | 1998-11-13 | 2001-08-29 | 빌프리더 하이더 | 염소 및 브롬을 함유하지 않는 내연성 폴리카르보네이트성형 조성물 |
| US6353046B1 (en) | 2000-04-28 | 2002-03-05 | General Electric Company | Fire-retarded polycarbonate resin composition |
| US6673864B2 (en) | 2000-11-30 | 2004-01-06 | General Electric Company | Conductive polyester/polycarbonate blends, methods for preparation thereof, and articles derived therefrom |
| US6727302B2 (en) * | 2001-04-03 | 2004-04-27 | General Electric Company | Transparent, fire-resistant polycarbonate |
| US6613824B2 (en) | 2001-11-12 | 2003-09-02 | General Electric Company | Flame retardant resinous compositions and method |
| US6790899B2 (en) * | 2002-10-29 | 2004-09-14 | General Electric Company | Method for making fire-retarded polycarbonate and related compositions |
| US20070191519A1 (en) * | 2006-02-14 | 2007-08-16 | General Electric Company | Halogen-free polycarbonate compositions and articles formed therefrom |
| US7632881B2 (en) * | 2006-06-22 | 2009-12-15 | Sabic Innovative Plastics Ip B.V. | Polycarbonate compositions and articles formed therefrom |
-
2006
- 2006-02-14 US US11/353,732 patent/US7728059B2/en active Active
-
2007
- 2007-01-23 CN CN2007800054781A patent/CN101384684B/zh active Active
- 2007-01-23 KR KR1020087019292A patent/KR101136957B1/ko active Active
- 2007-01-23 DE DE602007003323T patent/DE602007003323D1/de active Active
- 2007-01-23 EP EP07716898A patent/EP1984472B1/de active Active
- 2007-01-23 AT AT07716898T patent/ATE449150T1/de not_active IP Right Cessation
- 2007-01-23 WO PCT/US2007/001689 patent/WO2007094927A1/en not_active Ceased
- 2007-01-23 JP JP2008555242A patent/JP2009526898A/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| DE602007003323D1 (de) | 2009-12-31 |
| KR20080093039A (ko) | 2008-10-17 |
| KR101136957B1 (ko) | 2012-04-24 |
| CN101384684B (zh) | 2012-01-04 |
| WO2007094927A1 (en) | 2007-08-23 |
| JP2009526898A (ja) | 2009-07-23 |
| CN101384684A (zh) | 2009-03-11 |
| EP1984472B1 (de) | 2009-11-18 |
| US20070191518A1 (en) | 2007-08-16 |
| US7728059B2 (en) | 2010-06-01 |
| EP1984472A1 (de) | 2008-10-29 |
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