ATE47381T1 - Verfahren zur herstellung von ameisensaeure. - Google Patents
Verfahren zur herstellung von ameisensaeure.Info
- Publication number
- ATE47381T1 ATE47381T1 AT85306865T AT85306865T ATE47381T1 AT E47381 T1 ATE47381 T1 AT E47381T1 AT 85306865 T AT85306865 T AT 85306865T AT 85306865 T AT85306865 T AT 85306865T AT E47381 T1 ATE47381 T1 AT E47381T1
- Authority
- AT
- Austria
- Prior art keywords
- formic acid
- base
- production
- formate salt
- high boiling
- Prior art date
Links
- BDAGIHXWWSANSR-UHFFFAOYSA-N Formic acid Chemical compound OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 title abstract 9
- 235000019253 formic acid Nutrition 0.000 title abstract 4
- 238000000034 method Methods 0.000 title abstract 4
- 238000004519 manufacturing process Methods 0.000 title abstract 2
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 abstract 3
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 abstract 3
- 150000004675 formic acid derivatives Chemical class 0.000 abstract 3
- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 abstract 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 abstract 2
- 238000009835 boiling Methods 0.000 abstract 2
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 abstract 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- 239000001569 carbon dioxide Substances 0.000 abstract 1
- 229910002092 carbon dioxide Inorganic materials 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 238000000746 purification Methods 0.000 abstract 1
- 238000011084 recovery Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/02—Preparation of carboxylic acids or their salts, halides or anhydrides from salts of carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/15—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction of organic compounds with carbon dioxide, e.g. Kolbe-Schmitt synthesis
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Investigating Or Analyzing Materials By The Use Of Ultrasonic Waves (AREA)
- Ultra Sonic Daignosis Equipment (AREA)
- Steroid Compounds (AREA)
- Diaphragms For Electromechanical Transducers (AREA)
- Catalysts (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB848424672A GB8424672D0 (en) | 1984-09-29 | 1984-09-29 | Production of formic acid |
| EP85306865A EP0181078B2 (de) | 1984-09-29 | 1985-09-26 | Verfahren zur Herstellung von Ameisensäure |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ATE47381T1 true ATE47381T1 (de) | 1989-11-15 |
Family
ID=10567483
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AT85306865T ATE47381T1 (de) | 1984-09-29 | 1985-09-26 | Verfahren zur herstellung von ameisensaeure. |
Country Status (14)
| Country | Link |
|---|---|
| US (1) | US4855496A (de) |
| EP (1) | EP0181078B2 (de) |
| JP (1) | JPH075507B2 (de) |
| AT (1) | ATE47381T1 (de) |
| AU (1) | AU583550B2 (de) |
| BR (1) | BR8506948A (de) |
| CA (1) | CA1246606A (de) |
| DE (1) | DE3573773D1 (de) |
| FI (1) | FI86842C (de) |
| GB (1) | GB8424672D0 (de) |
| NO (1) | NO164770C (de) |
| NZ (1) | NZ213636A (de) |
| WO (1) | WO1986002066A1 (de) |
| ZA (1) | ZA857488B (de) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102011000077A1 (de) * | 2011-01-11 | 2012-07-12 | Rheinisch-Westfälische Technische Hochschule Aachen | CO2-Hydrierungsverfahren zu Ameisensäure |
Families Citing this family (50)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NZ227890A (en) * | 1988-02-17 | 1992-02-25 | Bp Chemical Ltd | Production of formic acid from a nitrogenous base, carbon dioxide and hydrogen |
| DE68920933T2 (de) * | 1988-08-20 | 1995-05-24 | Bp Chem Int Ltd | Produktion von Formiat-Salzen von Stickstoffbasen. |
| US5239117A (en) * | 1991-09-18 | 1993-08-24 | Board Of Regents Of The University Of Oklahoma | Rhodium catalyzed hydrogen transfer redox reactions |
| EP0597151A1 (de) * | 1992-11-10 | 1994-05-18 | Universiteit Twente | Verfahren zur Herstellung von Ameisensäure |
| DE10063937A1 (de) | 2000-12-20 | 2002-07-18 | Bayer Ag | Verfahren zur Herstellung von Trimethylolverbindungen und Ameisensäure |
| AR038161A1 (es) | 2002-01-24 | 2004-12-29 | Basf Ag | Procedimiento para separar acidos de mezclas de reaccion quimicas con la ayuda de liquidos ionicos |
| US8313634B2 (en) | 2009-01-29 | 2012-11-20 | Princeton University | Conversion of carbon dioxide to organic products |
| CN102574762B (zh) * | 2009-06-26 | 2014-08-13 | 巴斯夫欧洲公司 | 生产甲酸的方法 |
| UA104324C2 (ru) * | 2009-06-26 | 2014-01-27 | Басф Се | Способ получения муравьиной кислоты |
| US20110114502A1 (en) * | 2009-12-21 | 2011-05-19 | Emily Barton Cole | Reducing carbon dioxide to products |
| US8721866B2 (en) * | 2010-03-19 | 2014-05-13 | Liquid Light, Inc. | Electrochemical production of synthesis gas from carbon dioxide |
| US8500987B2 (en) | 2010-03-19 | 2013-08-06 | Liquid Light, Inc. | Purification of carbon dioxide from a mixture of gases |
| US8845877B2 (en) | 2010-03-19 | 2014-09-30 | Liquid Light, Inc. | Heterocycle catalyzed electrochemical process |
| US8901350B2 (en) | 2010-06-29 | 2014-12-02 | Basf Se | Process for the preparation of formic acid |
| US8791297B2 (en) | 2010-06-29 | 2014-07-29 | Basf Se | Process for preparing formic acid by reaction of carbon dioxide with hydrogen |
| WO2012000964A1 (de) | 2010-06-29 | 2012-01-05 | Basf Se | Verfahren zur herstellung von ameisensäure |
| US8877965B2 (en) | 2010-06-29 | 2014-11-04 | Basf Se | Process for preparing formic acid by reaction of carbon dioxide with hydrogen |
| CN103080061A (zh) * | 2010-06-29 | 2013-05-01 | 巴斯夫欧洲公司 | 通过二氧化碳与氢气反应制备甲酸的方法 |
| WO2012000799A1 (de) | 2010-06-29 | 2012-01-05 | Basf Se | Verfahren zur herstellung von ameisensäure durch umsetzung von kohlendioxid mit wasserstoff |
| US8845878B2 (en) | 2010-07-29 | 2014-09-30 | Liquid Light, Inc. | Reducing carbon dioxide to products |
| US8524066B2 (en) | 2010-07-29 | 2013-09-03 | Liquid Light, Inc. | Electrochemical production of urea from NOx and carbon dioxide |
| WO2012034991A1 (de) | 2010-09-17 | 2012-03-22 | Basf Se | Verfahren zur herstellung von formamiden |
| US8568581B2 (en) | 2010-11-30 | 2013-10-29 | Liquid Light, Inc. | Heterocycle catalyzed carbonylation and hydroformylation with carbon dioxide |
| US8961774B2 (en) | 2010-11-30 | 2015-02-24 | Liquid Light, Inc. | Electrochemical production of butanol from carbon dioxide and water |
| RU2013133653A (ru) | 2010-12-21 | 2015-01-27 | Басф Се | Способ получения муравьиной кислоты в результате взаимодействия диоксида углерода с водородом |
| US20120157711A1 (en) * | 2010-12-21 | 2012-06-21 | Basf Se | Process for preparing formic acid by reacting carbon dioxide with hydrogen |
| US9090976B2 (en) | 2010-12-30 | 2015-07-28 | The Trustees Of Princeton University | Advanced aromatic amine heterocyclic catalysts for carbon dioxide reduction |
| US8562811B2 (en) | 2011-03-09 | 2013-10-22 | Liquid Light, Inc. | Process for making formic acid |
| EP2718256A1 (de) | 2011-06-09 | 2014-04-16 | Basf Se | Verfahren zur herstellung von ameisensäure |
| US8742171B2 (en) | 2011-06-09 | 2014-06-03 | Basf Se | Process for preparing formic acid |
| WO2013006710A2 (en) | 2011-07-06 | 2013-01-10 | Liquid Light, Inc. | Carbon dioxide capture and conversion to organic products |
| EP2729601B1 (de) | 2011-07-06 | 2018-05-09 | Avantium Knowledge Centre B.V. | Reduktion von kohlenstoffdioxid zu oxalsäure, und deren hydrierung |
| KR20140044891A (ko) * | 2011-07-07 | 2014-04-15 | 바스프 에스이 | 이산화탄소와 수소의 반응에 의한 포름산의 제조 방법 |
| DE102012014159A1 (de) | 2011-07-27 | 2013-01-31 | Basf Se | Verfahren zur Herstellung von Methylformiat |
| DE102012016959A1 (de) | 2011-09-09 | 2013-03-14 | Basf Se | Verfahren zur Herstellung von Ameisensäure durch Umsetzung von Kohlendioxid mit Wasserstoff |
| CA2851175A1 (en) | 2011-10-07 | 2013-04-11 | Basf Se | Process for preparing formic acid by reacting carbon dioxide with hydrogen |
| US8946462B2 (en) | 2011-11-10 | 2015-02-03 | Basf Se | Process for preparing formic acid by reaction of carbon dioxide with hydrogen |
| DE102012021568A1 (de) | 2011-11-10 | 2013-05-16 | Basf Se | Eisenkomplexverbindungen enthaltend Eisen und mindestens einen Phosphanliganden mit mindestens einem organischen Rest mit mindestens 12 Kohlenstoffatomen, Verfahren zur Herstellung von Ameisensäure und Verwendung der Eisenkomplexverbindungen als Katalysatoren für die Hydrierung von Kohlendioxid |
| CA2854047A1 (en) | 2011-11-10 | 2013-05-16 | Basf Se | Process for preparing formic acid by reaction of carbon dioxide with hydrogen |
| US8835683B2 (en) | 2011-12-20 | 2014-09-16 | Basf Se | Process for preparing formic acid |
| CA2856959A1 (en) | 2011-12-20 | 2013-06-27 | Basf Se | Process for preparing formic acid |
| US8889905B2 (en) | 2011-12-20 | 2014-11-18 | Basf Se | Process for preparing formic acid |
| KR20140105577A (ko) | 2011-12-20 | 2014-09-01 | 바스프 에스이 | 포름산의 제조 방법 |
| DE102012112404A1 (de) | 2011-12-22 | 2013-06-27 | Basf Se | Verfahren zur kombinierten Herstellung von Ameisensäure, Methylformiat, Formamidverbindungen und Metallformiaten |
| EP2858970A1 (de) | 2012-06-11 | 2015-04-15 | Basf Se | Verfahren zur herstellung von methansäure |
| DE102015208706A1 (de) | 2015-05-11 | 2016-11-17 | Basf Se | Verfahren zur Herstellung von Ameisensäure |
| DE102015208708A1 (de) | 2015-05-11 | 2016-11-17 | Basf Se | Verfahren zur Herstellung von Ameisensäure |
| WO2020101413A1 (ko) * | 2018-11-16 | 2020-05-22 | 한국과학기술연구원 | 이산화탄소의 수소화 반응에 의한 포름산 제조 방법 및 제조 장치 |
| KR102285717B1 (ko) * | 2018-11-16 | 2021-08-04 | 한국과학기술연구원 | 이산화탄소의 수소화 반응에 의한 포름산 제조 방법 및 제조 장치 |
| CN117463312B (zh) * | 2023-12-28 | 2024-08-16 | 太原理工大学 | 一种类水滑石结构的镍基催化剂及其制备方法和应用 |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1233398B (de) * | 1964-03-14 | 1967-02-02 | Bayer Ag | Herstellung von aus Ameisensaeure und tertiaeren organischen Basen bestehenden Additionsverbindungen |
| DE2744313A1 (de) * | 1977-10-01 | 1979-04-12 | Basf Ag | Verfahren zur herstellung von ameisensaeure |
| AU6811981A (en) * | 1980-03-19 | 1981-09-24 | Wadsley, M. | Formate ion production |
| US4474959A (en) * | 1982-05-22 | 1984-10-02 | Bp Chemicals Limited | Production of formate salts from carbon dioxide, hydrogen and amines |
| GB8307611D0 (en) * | 1983-03-18 | 1983-04-27 | Bp Chem Int Ltd | Formic acid |
-
1984
- 1984-09-29 GB GB848424672A patent/GB8424672D0/en active Pending
-
1985
- 1985-09-26 DE DE8585306865T patent/DE3573773D1/de not_active Expired
- 1985-09-26 BR BR8506948A patent/BR8506948A/pt not_active IP Right Cessation
- 1985-09-26 US US06/864,725 patent/US4855496A/en not_active Expired - Fee Related
- 1985-09-26 JP JP60504293A patent/JPH075507B2/ja not_active Expired - Lifetime
- 1985-09-26 EP EP85306865A patent/EP0181078B2/de not_active Expired - Lifetime
- 1985-09-26 AT AT85306865T patent/ATE47381T1/de active
- 1985-09-26 WO PCT/GB1985/000443 patent/WO1986002066A1/en not_active Ceased
- 1985-09-26 AU AU49557/85A patent/AU583550B2/en not_active Ceased
- 1985-09-27 ZA ZA857488A patent/ZA857488B/xx unknown
- 1985-09-27 NZ NZ213636A patent/NZ213636A/xx unknown
- 1985-09-27 CA CA000491706A patent/CA1246606A/en not_active Expired
-
1986
- 1986-05-13 NO NO86861905A patent/NO164770C/no unknown
- 1986-05-14 FI FI862012A patent/FI86842C/fi not_active IP Right Cessation
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102011000077A1 (de) * | 2011-01-11 | 2012-07-12 | Rheinisch-Westfälische Technische Hochschule Aachen | CO2-Hydrierungsverfahren zu Ameisensäure |
Also Published As
| Publication number | Publication date |
|---|---|
| DE3573773D1 (en) | 1989-11-23 |
| CA1246606A (en) | 1988-12-13 |
| NO164770C (no) | 1990-11-14 |
| EP0181078B2 (de) | 1994-09-14 |
| FI86842C (fi) | 1992-10-26 |
| GB8424672D0 (en) | 1984-11-07 |
| ZA857488B (en) | 1987-05-27 |
| AU583550B2 (en) | 1989-05-04 |
| EP0181078B1 (de) | 1989-10-18 |
| JPS62500303A (ja) | 1987-02-05 |
| US4855496A (en) | 1989-08-08 |
| NZ213636A (en) | 1989-02-24 |
| NO164770B (no) | 1990-08-06 |
| FI86842B (fi) | 1992-07-15 |
| FI862012L (fi) | 1986-05-14 |
| FI862012A0 (fi) | 1986-05-14 |
| AU4955785A (en) | 1986-04-17 |
| JPH075507B2 (ja) | 1995-01-25 |
| WO1986002066A1 (en) | 1986-04-10 |
| BR8506948A (pt) | 1986-12-23 |
| EP0181078A1 (de) | 1986-05-14 |
| NO861905L (no) | 1986-05-13 |
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