ATE496880T1 - Prozess zur hydrierung von nicht-aktivierten iminen unter verwendung von ruthenium-komplexen als katalysatoren - Google Patents

Prozess zur hydrierung von nicht-aktivierten iminen unter verwendung von ruthenium-komplexen als katalysatoren

Info

Publication number
ATE496880T1
ATE496880T1 AT03720057T AT03720057T ATE496880T1 AT E496880 T1 ATE496880 T1 AT E496880T1 AT 03720057 T AT03720057 T AT 03720057T AT 03720057 T AT03720057 T AT 03720057T AT E496880 T1 ATE496880 T1 AT E496880T1
Authority
AT
Austria
Prior art keywords
sup
hydrogenation
alkenyl
sub
optionally substituted
Prior art date
Application number
AT03720057T
Other languages
English (en)
Inventor
Kamaluddin Abdur-Rashid
Robert Morris
Original Assignee
Kamaluddin Abdur-Rashid
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kamaluddin Abdur-Rashid filed Critical Kamaluddin Abdur-Rashid
Application granted granted Critical
Publication of ATE496880T1 publication Critical patent/ATE496880T1/de

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D453/00Heterocyclic compounds containing quinuclidine or iso-quinuclidine ring systems, e.g. quinine alkaloids
    • C07D453/02Heterocyclic compounds containing quinuclidine or iso-quinuclidine ring systems, e.g. quinine alkaloids containing not further condensed quinuclidine ring systems
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/44Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of carboxylic acids or esters thereof in presence of ammonia or amines, or by reduction of nitriles, carboxylic acid amides, imines or imino-ethers
    • C07C209/52Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of carboxylic acids or esters thereof in presence of ammonia or amines, or by reduction of nitriles, carboxylic acid amides, imines or imino-ethers by reduction of imines or imino-ethers
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07BGENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B2200/00Indexing scheme relating to specific properties of organic compounds
    • C07B2200/07Optical isomers
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00Systems containing only non-condensed rings
    • C07C2601/02Systems containing only non-condensed rings with a three-membered ring
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00Systems containing only non-condensed rings
    • C07C2601/04Systems containing only non-condensed rings with a four-membered ring

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Nitrogen Condensed Heterocyclic Rings (AREA)
AT03720057T 2002-05-15 2003-05-15 Prozess zur hydrierung von nicht-aktivierten iminen unter verwendung von ruthenium-komplexen als katalysatoren ATE496880T1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US38025602P 2002-05-15 2002-05-15
PCT/CA2003/000689 WO2003097571A1 (en) 2002-05-15 2003-05-15 Process for hydrogenating unactivated imines using ruthenium complexes as catalysts

Publications (1)

Publication Number Publication Date
ATE496880T1 true ATE496880T1 (de) 2011-02-15

Family

ID=29549943

Family Applications (1)

Application Number Title Priority Date Filing Date
AT03720057T ATE496880T1 (de) 2002-05-15 2003-05-15 Prozess zur hydrierung von nicht-aktivierten iminen unter verwendung von ruthenium-komplexen als katalysatoren

Country Status (9)

Country Link
US (1) US7256311B2 (de)
EP (1) EP1503979B9 (de)
JP (1) JP2005525426A (de)
AT (1) ATE496880T1 (de)
AU (1) AU2003223806B2 (de)
CA (1) CA2489158C (de)
DE (1) DE60335874D1 (de)
IL (1) IL164915A (de)
WO (1) WO2003097571A1 (de)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB0205455D0 (en) 2002-03-07 2002-04-24 Molecular Sensing Plc Nucleic acid probes, their synthesis and use
WO2004096735A2 (en) 2003-05-02 2004-11-11 Kamaluddin Abdur-Rashid Transfer hydrogenation processes and catalysts
US7816533B2 (en) * 2003-12-15 2010-10-19 Kamaluddin Abdur-Rashid Asymmetric imine hydrogenation processes
JP4800213B2 (ja) * 2004-07-07 2011-10-26 浜理薬品工業株式会社 光学活性フェニルプロピルアミン誘導体の製法
EP2094624A1 (de) * 2006-12-22 2009-09-02 DSMIP Assets B.V. Asymmetrische hydrierung prochiraler verbindungen
EP2623509A1 (de) 2012-02-01 2013-08-07 Kanto Kagaku Kabushiki Kaisha Verfahren zur Herstellung einer optisch aktiven Aminverbindung durch katalytische asymmetrische Hydrierung mittels eines Ruthenium-diphosphin Komplexes
US11498901B2 (en) 2018-03-02 2022-11-15 Firmenich Sa Hydrogenation of imines with Ru complexes
JP7127808B2 (ja) * 2018-05-29 2022-08-30 国立大学法人山口大学 フルオロアルキル基を含有するイミン類の製造方法
CN109400508B (zh) * 2018-11-13 2020-12-22 上海交通大学 不对称钯催化氢化z式大位阻亚胺制备大位阻手性胺的方法
WO2021023627A1 (en) 2019-08-08 2021-02-11 Firmenich Sa Hydrogenation of imines with ru complexes
GB202216812D0 (en) 2022-11-10 2022-12-28 Univ Court Univ St Andrews Process

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0256982B1 (de) * 1986-08-04 1991-08-28 Ciba-Geigy Ag Verfahren zur Herstellung von optisch aktiven sekundären Arylaminen
JP2912572B2 (ja) * 1995-12-06 1999-06-28 科学技術振興事業団 光学活性アミン類の製造方法
JP4004123B2 (ja) * 1997-12-26 2007-11-07 独立行政法人科学技術振興機構 ルテニウム錯体を触媒とするアルコール化合物の製造方法
DE60106928T2 (de) * 2000-07-24 2005-03-10 Chirotech Technology Ltd. Rutheniumkomplexe und ihre verwendung zur asymmetrischen hydrierung
IL154822A0 (en) * 2000-09-13 2003-10-31 Firmenich & Cie Catalytic hydrogenation processes

Also Published As

Publication number Publication date
CA2489158C (en) 2010-08-03
EP1503979B9 (de) 2014-10-29
IL164915A (en) 2010-12-30
DE60335874D1 (de) 2011-03-10
AU2003223806A1 (en) 2003-12-02
EP1503979B1 (de) 2011-01-26
US20050209487A1 (en) 2005-09-22
WO2003097571A1 (en) 2003-11-27
US7256311B2 (en) 2007-08-14
CA2489158A1 (en) 2003-11-27
JP2005525426A (ja) 2005-08-25
IL164915A0 (en) 2005-12-18
AU2003223806B2 (en) 2009-01-08
EP1503979A1 (de) 2005-02-09

Similar Documents

Publication Publication Date Title
Sortais et al. Cycloruthenated primary and secondary amines as efficient catalyst precursors for asymmetric transfer hydrogenation
Hesp et al. Rhodium‐and Iridium‐Catalyzed Hydroamination of Alkenes
Fleury‐Brégeot et al. Highlights of Transition Metal‐Catalyzed Asymmetric Hydrogenation of Imines
Ohmiya et al. Cu (I)-catalyzed intramolecular hydroamination of unactivated alkenes bearing a primary or secondary amino group in alcoholic solvents
Mantilli et al. Platinum metals in the catalytic asymmetric isomerization of allylic alcohols
ATE496880T1 (de) Prozess zur hydrierung von nicht-aktivierten iminen unter verwendung von ruthenium-komplexen als katalysatoren
Eberhardt et al. BINOL-derived phosphoramidites in asymmetric hydrogenation: can the presence of a functionality in the amino group influence the catalytic outcome?
Agbossou-Niedercorn et al. Chiral aminophosphine phosphinite ligands and related auxiliaries: Recent advances in their design, coordination chemistry, and use in enantioselective catalysis
RU2004132221A (ru) Бисфосфины в качестве бидентатных лигандов
MX9401464A (es) Difosfinas de ferroceno como ligandos para catalizadores homogeneos.
DE60123093D1 (de) Katalysator für asymmetrische hydrogenierung
Caballero et al. Ruthenium arene derivatives with PN hemilabile ligands. P− C cleavage and phosphine to phosphinite transformation
DE60304034D1 (de) Bisphosphit-ligande für carbonylierungsverfahren
CA2415738A1 (en) Ruthenium complexes and their use in asymmetric hydrogenation
RU2004138567A (ru) Гидроксидифосфины и их применение в качестве катализаторов
ATE378344T1 (de) Rutheniumkomplexe von phosphinaminophosphinliganden
ATE370959T1 (de) Biphosphinrutheniumkomplexe mit chiralen diaminliganden als katalysatoren
RU2006143155A (ru) Ферроценильные лиганды для гомогенных энантиоселективных катализаторов гидрирования
RU2005138144A (ru) Замещенные ферроценилдифосфины в качестве лигандов для гомогенных катализаторов гидрирования
Kitamura et al. Mechanistic insight into NOYORI asymmetric hydrogenations
Dahlenburg et al. Iridium Complexes with Chiral and Achiral β‐Aminophosphane Ligands: Catalysts for> C= O Hydrogenation and H/D Exchange Involving both Homo‐and Heterolytic H2 Activation
Inui et al. Asymmetric Rh-catalyzed intermolecular hydroacylation of 1, 5-hexadiene with salicylaldehyde
Li et al. Synthesis, structure, and catalytic behavior of a PSiP pincer-type iridium (III) complex
Stemmler et al. Planar-chiral cyrhetrenes for the Rhodium-catalyzed asymmetric 1, 4-addition and the hydrogenation of enamides
Andrieu et al. Synthesis of new phosphino amino alcohol ligands via ortho-alkyllithiation reactions. Versatile coordination behavior toward copper (I) and palladium (II)

Legal Events

Date Code Title Description
RER Ceased as to paragraph 5 lit. 3 law introducing patent treaties