ATE503562T1 - Verfahren zur herstellung einer strahlungsbrennstoffzellenmembran mit verbesserter chemischer stabilität und membranelektrodenanordnung - Google Patents

Verfahren zur herstellung einer strahlungsbrennstoffzellenmembran mit verbesserter chemischer stabilität und membranelektrodenanordnung

Info

Publication number: ATE503562T1
Authority: AT; Austria
Prior art keywords: membrane; fuel cell; membrane electrode; film; electrode assembly
Prior art date: 2005-02-11

Application number

AT06706468T

Other languages

English (en)

Inventor

Guenther Scherer

Lorenz Gubler

Michal Slaski

Original Assignee

Scherrer Inst Paul

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2005-02-11

Filing date

2006-01-28

Publication date

2011-04-15

2006-01-28 Application filed by Scherrer Inst Paul filed Critical Scherrer Inst Paul

2011-04-15 Application granted granted Critical

2011-04-15 Publication of ATE503562T1 publication Critical patent/ATE503562T1/de

Links

239000012528 membrane Substances 0.000 title abstract 6
239000000446 fuel Substances 0.000 title abstract 3
230000005855 radiation Effects 0.000 title abstract 2
210000000170 cell membrane Anatomy 0.000 title 1
238000004519 manufacturing process Methods 0.000 title 1
239000000126 substance Substances 0.000 title 1
238000000034 method Methods 0.000 abstract 2
LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 abstract 1
GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 abstract 1
229920005601 base polymer Polymers 0.000 abstract 1
230000015572 biosynthetic process Effects 0.000 abstract 1
229920000578 graft copolymer Polymers 0.000 abstract 1
230000001678 irradiating effect Effects 0.000 abstract 1
239000000463 material Substances 0.000 abstract 1
239000000203 mixture Substances 0.000 abstract 1
239000000178 monomer Substances 0.000 abstract 1
239000002245 particle Substances 0.000 abstract 1
239000005518 polymer electrolyte Substances 0.000 abstract 1
229920006254 polymer film Polymers 0.000 abstract 1
238000010526 radical polymerization reaction Methods 0.000 abstract 1

Classifications

- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
- B01D67/0081—After-treatment of organic or inorganic membranes
- B01D67/009—After-treatment of organic or inorganic membranes with wave-energy, particle-radiation or plasma
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
- B01D67/0081—After-treatment of organic or inorganic membranes
- B01D67/0093—Chemical modification
- B01D67/00931—Chemical modification by introduction of specific groups after membrane formation, e.g. by grafting
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/34—Introducing sulfur atoms or sulfur-containing groups
- C08F8/36—Sulfonation; Sulfation
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/28—Treatment by wave energy or particle radiation
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/20—Manufacture of shaped structures of ion-exchange resins
- C08J5/22—Films, membranes or diaphragms
- C08J5/2206—Films, membranes or diaphragms based on organic and/or inorganic macromolecular compounds
- C08J5/2218—Synthetic macromolecular compounds
- C08J5/2231—Synthetic macromolecular compounds based on macromolecular compounds obtained by reactions involving unsaturated carbon-to-carbon bonds
- C08J5/2243—Synthetic macromolecular compounds based on macromolecular compounds obtained by reactions involving unsaturated carbon-to-carbon bonds obtained by introduction of active groups capable of ion-exchange into compounds of the type C08J5/2231
- C08J5/225—Synthetic macromolecular compounds based on macromolecular compounds obtained by reactions involving unsaturated carbon-to-carbon bonds obtained by introduction of active groups capable of ion-exchange into compounds of the type C08J5/2231 containing fluorine
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
- H01M8/1018—Polymeric electrolyte materials
- H01M8/102—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
- H01M8/1023—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having only carbon, e.g. polyarylenes, polystyrenes or polybutadiene-styrenes
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
- H01M8/1018—Polymeric electrolyte materials
- H01M8/1069—Polymeric electrolyte materials characterised by the manufacturing processes
- H01M8/1072—Polymeric electrolyte materials characterised by the manufacturing processes by chemical reactions, e.g. in situ polymerisation or in situ crosslinking
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
- H01M8/1018—Polymeric electrolyte materials
- H01M8/1069—Polymeric electrolyte materials characterised by the manufacturing processes
- H01M8/1086—After-treatment of the membrane other than by polymerisation
- H01M8/1088—Chemical modification, e.g. sulfonation
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2323/00—Details relating to membrane preparation
- B01D2323/30—Cross-linking
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2323/00—Details relating to membrane preparation
- B01D2323/38—Graft polymerization
- B01D2323/385—Graft polymerization involving radiation
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
- C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
- C08J2327/12—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2351/00—Characterised by the use of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2300/00—Electrolytes
- H01M2300/0017—Non-aqueous electrolytes
- H01M2300/0065—Solid electrolytes
- H01M2300/0082—Organic polymers
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/1004—Fuel cells with solid electrolytes characterised by membrane-electrode assemblies [MEA]
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product

Landscapes

Chemical & Material Sciences (AREA)
Engineering & Computer Science (AREA)
Manufacturing & Machinery (AREA)
Chemical Kinetics & Catalysis (AREA)
General Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Life Sciences & Earth Sciences (AREA)
Medicinal Chemistry (AREA)
Organic Chemistry (AREA)
Inorganic Chemistry (AREA)
Polymers & Plastics (AREA)
Sustainable Development (AREA)
Sustainable Energy (AREA)
Electrochemistry (AREA)
Crystallography & Structural Chemistry (AREA)
Physics & Mathematics (AREA)
Transplantation (AREA)
Plasma & Fusion (AREA)
Materials Engineering (AREA)
Graft Or Block Polymers (AREA)
Fuel Cell (AREA)
Manufacture Of Macromolecular Shaped Articles (AREA)
Inert Electrodes (AREA)

AT06706468T 2005-02-11 2006-01-28 Verfahren zur herstellung einer strahlungsbrennstoffzellenmembran mit verbesserter chemischer stabilität und membranelektrodenanordnung ATE503562T1 (de)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
EP05002875A EP1693101A1 (de)	2005-02-11	2005-02-11	Verfahren zur Herstellung einer unter Bestrahlung gepfropften Brennstoffzellen-Membran mit erhöhter chemischen Stabilität sowie eine Membran-Elektroden Anordnung
PCT/EP2006/000752 WO2006084591A1 (en)	2005-02-11	2006-01-28	A method for preparing a radiation grafted fuel cell membrane with enhanced chemical stability and a membrane electrode assembly

Publications (1)

Publication Number	Publication Date
ATE503562T1 true ATE503562T1 (de)	2011-04-15

Family

ID=34933688

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
AT06706468T ATE503562T1 (de)	2005-02-11	2006-01-28	Verfahren zur herstellung einer strahlungsbrennstoffzellenmembran mit verbesserter chemischer stabilität und membranelektrodenanordnung

Country Status (6)

Country	Link
US (1)	US20080199754A1 (de)
EP (2)	EP1693101A1 (de)
CN (1)	CN101115546B (de)
AT (1)	ATE503562T1 (de)
DE (1)	DE602006021018D1 (de)
WO (1)	WO2006084591A1 (de)

Families Citing this family (19)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
EP2334709B1 (de) *	2008-09-17	2014-04-09	Belenos Clean Power Holding AG	Verfahren zur herstellung von strahlung-pfropfcopolymeren.
EP2228403A1 (de) *	2009-02-05	2010-09-15	Paul Scherrer Institut	Verfharen zur Herstellung einer verstärkten Protonenaustauschmembran und verstärkte Protonenaustauschmembran
CN102321266B (zh) *	2011-07-13	2012-08-15	上海大学	燃料电池用质子交换膜的制备方法
CN102477163B (zh) *	2011-07-29	2014-04-16	深圳光启高等理工研究院	一种基于高分子材料的微结构的制备方法
WO2013184366A1 (en) *	2012-06-05	2013-12-12	3M Innovative Properties Company	Graft copolymer functionalized article
CN103447089B (zh) *	2013-09-18	2015-06-10	凯瑞环保科技股份有限公司	一种低碳烯烃叠合催化剂及其制备方法
CN103537320B (zh) *	2013-10-17	2016-04-13	凯瑞环保科技股份有限公司	一种用于苯酚羟基化的树脂催化剂及其制备方法
CN103551061A (zh) *	2013-11-15	2014-02-05	天津工业大学	一种用于去除水中Cr(VI)的高负电荷密度中空纤维纳滤膜的制备方法
EP2996184A1 (de) *	2014-09-09	2016-03-16	Paul Scherrer Institut	Verfahren zur herstellung einer gasdiffusionsschicht und brennstoffzelle mit einer gasdiffusionsschicht
US10335742B2 (en) *	2014-12-24	2019-07-02	Hydroxsys Holdings Limited	Asymmetric composite membranes and modified substrates used in their preparation
CN104779404A (zh) *	2015-04-09	2015-07-15	深圳市万越新能源科技有限公司	一种采用射线辐照接枝法制备全钒电池均相离子交换膜的方法
EP3576201A1 (de) *	2018-05-31	2019-12-04	Paul Scherrer Institut	Amphotere elektrolytmembran und redox-durchflussbatterie mit einer elektrolytmembran
CN110391440B (zh) *	2019-07-17	2021-03-30	深圳质子航新能源科技有限公司	聚合物质子交换膜及其制备方法
CN112909277B (zh) *	2020-12-31	2022-02-11	大连融科储能技术发展有限公司	一种离子交换膜及其制备方法和应用
CN114763314B (zh) *	2021-01-11	2024-09-27	中国石油天然气股份有限公司	混合c4烃叠合反应工艺及叠合树脂催化剂
FR3123507A1 (fr) *	2021-05-31	2022-12-02	Arkema France	Membrane echangeuse de protons
FR3123508A1 (fr) *	2021-05-31	2022-12-02	Arkema France	Membrane echangeuse de protons
CN114832652B (zh) *	2022-04-25	2024-05-31	上海师范大学	一种功能聚合物纳滤膜材料及其制备方法
FR3142609B1 (fr) *	2022-11-29	2024-10-18	Arkema France	Membrane echangeuse de protons a base de pvdf sous forme de granules cryobroyes

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US2802809A (en) *	1953-11-30	1957-08-13	Firestone Tire & Rubber Co	Compositions of vinyl chloride resins and graft copolymers of acrylonitrile-type monomer compositions upon diene polymers and articles formed therefrom
US2913511A (en) *	1955-06-29	1959-11-17	Gen Electric	Fuel cell
US5216062A (en) *	1989-02-18	1993-06-01	Basf Aktiengesellschaft	Thermoplastic polyurethane molding composition
JPH09102322A (ja) *	1995-07-31	1997-04-15	Imura Zairyo Kaihatsu Kenkyusho:Kk	燃料電池用の固体高分子電解質膜およびその製造方法
JP4473967B2 (ja) *	1997-03-04	2010-06-02	日本ゼオン株式会社	電池用バインダー、電池用バインダー組成物、電池電極用スラリー、リチウム二次電池用電極およびリチウム二次電池
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JP2002198068A (ja) *	2000-12-26	2002-07-12	Aisin Seiki Co Ltd	固体高分子電解質膜及びその製造方法
US20040009305A1 (en) *	2002-07-12	2004-01-15	Ballard Power Systems Inc.	Process for preparing graft copolymer membranes
EP2334709B1 (de) *	2008-09-17	2014-04-09	Belenos Clean Power Holding AG	Verfahren zur herstellung von strahlung-pfropfcopolymeren.

2005
- 2005-02-11 EP EP05002875A patent/EP1693101A1/de not_active Withdrawn
2006
- 2006-01-28 US US11/884,059 patent/US20080199754A1/en not_active Abandoned
- 2006-01-28 AT AT06706468T patent/ATE503562T1/de not_active IP Right Cessation
- 2006-01-28 CN CN2006800045805A patent/CN101115546B/zh not_active Expired - Fee Related
- 2006-01-28 WO PCT/EP2006/000752 patent/WO2006084591A1/en not_active Ceased
- 2006-01-28 DE DE602006021018T patent/DE602006021018D1/de not_active Expired - Lifetime
- 2006-01-28 EP EP06706468A patent/EP1893323B1/de not_active Expired - Lifetime

Also Published As

Publication number	Publication date
CN101115546B (zh)	2010-06-23
CN101115546A (zh)	2008-01-30
EP1893323A1 (de)	2008-03-05
EP1693101A1 (de)	2006-08-23
DE602006021018D1 (de)	2011-05-12
WO2006084591A1 (en)	2006-08-17
EP1893323B1 (de)	2011-03-30
US20080199754A1 (en)	2008-08-21

Legal Events

Date	Code	Title	Description
2011-09-15	RER	Ceased as to paragraph 5 lit. 3 law introducing patent treaties

Publication	Publication Date	Title
DE602006021018D1 (de)	2011-05-12	Verfahren zur herstellung einer strahlungsbrennstoffzellenmembran mit verbesserter chemischer stabilität und membranelektrodenanordnung
Singha et al.	2016	Highly efficient sulfonated polybenzimidazole as a proton exchange membrane for microbial fuel cells
DE602004018380D1 (de)	2009-01-22	Polymerelektrolyt mit aromatischer sulfonvernetzung
ATE310766T1 (de)	2005-12-15	Polymermembran und verfahren zu deren herstellung
Yuan et al.	2013	Facile synthesis of amphoteric ion exchange membrane by radiation grafting of sodium styrene sulfonate and N, N‐dimethylaminoethyl methacrylate for vanadium redox flow battery
JP4621344B2 (ja)	2011-01-26	プロトン伝導性膜又はフィルムとそれらを用いてなる燃料電池
Ghorai et al.	2020	Chemically stable sulfonated polytriazoles containing trifluoromethyl and phosphine oxide moieties for proton exchange membranes
Li et al.	2004	Pre-irradiation induced grafting of styrene into crosslinked and non-crosslinked polytetrafluoroethylene films for polymer electrolyte fuel cell applications. I: Influence of styrene grafting conditions
Sadeghi et al.	2018	Enhancing proton conductivity via sub-micron structures in proton conducting membranes originating from sulfonated PVDF powder by radiation-induced grafting
EP1909347A4 (de)	2009-05-27	Zusammengesetzte poröse membran, verfahren zu ihrer herstellung, festpolymer-elektrolytmembran und brennstoffzelle
KR101896179B1 (ko)	2018-09-06	이온 교환막의 제조방법 및 이에 따라 제조된 이온 교환막
DE60216973T2 (de)	2007-11-22	Verbessertes verfahren zur modifizierung einer polymeroberfläche
EP1879198A4 (de)	2009-08-19	Festpolymerelektrolyt-membran, herstellungsverfahren dafür und brennstoffzelle
Atanasov et al.	2015	ETFE-g-pentafluorostyrene: Functionalization and proton conductivity
Sohn et al.	2012	Radiation-grafted proton exchange membranes based on co-grafting from binary monomer mixtures into poly (ethylene-co-tetrafluoroethylene)(ETFE) film
Ismail et al.	2005	Physico-chemical study of sulfonated polystyrene pore-filled electrolyte membranes by electrons induced grafting
Stigler et al.	2023	Modification of phosphonated poly (pentafluorostyrene) toward ductile membranes for electrochemical applications
JP4827331B2 (ja)	2011-11-30	プロトン伝導性膜又はフィルムとそれらを用いてなる燃料電池
MX2012005124A (es)	2012-09-28	Preparacion de menbrana ionica.
JP2011501857A (ja)	2011-01-13	ラジオグラフティングによる燃料電池用のプロトン伝導膜の製造方法
Sohn et al.	2012	Radiation grafting of binary monomers for the preparation of organic/inorganic hybrid membrane for proton exchange membrane fuel cell application
KR101239883B1 (ko)	2013-03-06	방사선 동시조사법을 이용한 화학적 안정성이 향상된 가교 불소고분자막의 제조방법 및 이에 따라 제조된 불소고분자막
US20080312350A1 (en)	2008-12-18	Crosslinked aromatic polymer electrolyte membrane and method for producing same
Chen et al.	2006	Preparation of ETFE-based fuel cell membranes using UV-induced photografting and electron beam-induced crosslinking techniques
Park et al.	2016	Radiolytic preparation and characterization of hydrophilic poly (acrylonitrile-co-vinylsulfonate)-grafted porous poly (tetrafluoroethylene) substrates