ATE503562T1 - Verfahren zur herstellung einer strahlungsbrennstoffzellenmembran mit verbesserter chemischer stabilität und membranelektrodenanordnung - Google Patents

Verfahren zur herstellung einer strahlungsbrennstoffzellenmembran mit verbesserter chemischer stabilität und membranelektrodenanordnung

Info

Publication number
ATE503562T1
ATE503562T1 AT06706468T AT06706468T ATE503562T1 AT E503562 T1 ATE503562 T1 AT E503562T1 AT 06706468 T AT06706468 T AT 06706468T AT 06706468 T AT06706468 T AT 06706468T AT E503562 T1 ATE503562 T1 AT E503562T1
Authority
AT
Austria
Prior art keywords
membrane
fuel cell
membrane electrode
film
electrode assembly
Prior art date
Application number
AT06706468T
Other languages
English (en)
Inventor
Guenther Scherer
Lorenz Gubler
Michal Slaski
Original Assignee
Scherrer Inst Paul
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Scherrer Inst Paul filed Critical Scherrer Inst Paul
Application granted granted Critical
Publication of ATE503562T1 publication Critical patent/ATE503562T1/de

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0081—After-treatment of organic or inorganic membranes
    • B01D67/009—After-treatment of organic or inorganic membranes with wave-energy, particle-radiation or plasma
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0081—After-treatment of organic or inorganic membranes
    • B01D67/0093—Chemical modification
    • B01D67/00931—Chemical modification by introduction of specific groups after membrane formation, e.g. by grafting
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/34—Introducing sulfur atoms or sulfur-containing groups
    • C08F8/36—Sulfonation; Sulfation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00—Processes of treating or compounding macromolecular substances
    • C08J3/28—Treatment by wave energy or particle radiation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/20—Manufacture of shaped structures of ion-exchange resins
    • C08J5/22—Films, membranes or diaphragms
    • C08J5/2206—Films, membranes or diaphragms based on organic and/or inorganic macromolecular compounds
    • C08J5/2218—Synthetic macromolecular compounds
    • C08J5/2231—Synthetic macromolecular compounds based on macromolecular compounds obtained by reactions involving unsaturated carbon-to-carbon bonds
    • C08J5/2243—Synthetic macromolecular compounds based on macromolecular compounds obtained by reactions involving unsaturated carbon-to-carbon bonds obtained by introduction of active groups capable of ion-exchange into compounds of the type C08J5/2231
    • C08J5/225—Synthetic macromolecular compounds based on macromolecular compounds obtained by reactions involving unsaturated carbon-to-carbon bonds obtained by introduction of active groups capable of ion-exchange into compounds of the type C08J5/2231 containing fluorine
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/102—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
    • H01M8/1023—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having only carbon, e.g. polyarylenes, polystyrenes or polybutadiene-styrenes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/1069—Polymeric electrolyte materials characterised by the manufacturing processes
    • H01M8/1072—Polymeric electrolyte materials characterised by the manufacturing processes by chemical reactions, e.g. in situ polymerisation or in situ crosslinking
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/1069—Polymeric electrolyte materials characterised by the manufacturing processes
    • H01M8/1086—After-treatment of the membrane other than by polymerisation
    • H01M8/1088—Chemical modification, e.g. sulfonation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2323/00—Details relating to membrane preparation
    • B01D2323/30—Cross-linking
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2323/00—Details relating to membrane preparation
    • B01D2323/38—Graft polymerization
    • B01D2323/385—Graft polymerization involving radiation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
    • C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
    • C08J2327/12—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2351/00—Characterised by the use of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00—Electrolytes
    • H01M2300/0017—Non-aqueous electrolytes
    • H01M2300/0065—Solid electrolytes
    • H01M2300/0082—Organic polymers
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1004—Fuel cells with solid electrolytes characterised by membrane-electrode assemblies [MEA]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50—Manufacturing or production processes characterised by the final manufactured product

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Organic Chemistry (AREA)
  • Sustainable Development (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Electrochemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Sustainable Energy (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Plasma & Fusion (AREA)
  • Transplantation (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Graft Or Block Polymers (AREA)
  • Fuel Cell (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
  • Inert Electrodes (AREA)
AT06706468T 2005-02-11 2006-01-28 Verfahren zur herstellung einer strahlungsbrennstoffzellenmembran mit verbesserter chemischer stabilität und membranelektrodenanordnung ATE503562T1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP05002875A EP1693101A1 (de) 2005-02-11 2005-02-11 Verfahren zur Herstellung einer unter Bestrahlung gepfropften Brennstoffzellen-Membran mit erhöhter chemischen Stabilität sowie eine Membran-Elektroden Anordnung
PCT/EP2006/000752 WO2006084591A1 (en) 2005-02-11 2006-01-28 A method for preparing a radiation grafted fuel cell membrane with enhanced chemical stability and a membrane electrode assembly

Publications (1)

Publication Number Publication Date
ATE503562T1 true ATE503562T1 (de) 2011-04-15

Family

ID=34933688

Family Applications (1)

Application Number Title Priority Date Filing Date
AT06706468T ATE503562T1 (de) 2005-02-11 2006-01-28 Verfahren zur herstellung einer strahlungsbrennstoffzellenmembran mit verbesserter chemischer stabilität und membranelektrodenanordnung

Country Status (6)

Country Link
US (1) US20080199754A1 (de)
EP (2) EP1693101A1 (de)
CN (1) CN101115546B (de)
AT (1) ATE503562T1 (de)
DE (1) DE602006021018D1 (de)
WO (1) WO2006084591A1 (de)

Families Citing this family (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2334709B1 (de) * 2008-09-17 2014-04-09 Belenos Clean Power Holding AG Verfahren zur herstellung von strahlung-pfropfcopolymeren.
EP2228403A1 (de) * 2009-02-05 2010-09-15 Paul Scherrer Institut Verfharen zur Herstellung einer verstärkten Protonenaustauschmembran und verstärkte Protonenaustauschmembran
CN102321266B (zh) * 2011-07-13 2012-08-15 上海大学 燃料电池用质子交换膜的制备方法
CN102477163B (zh) * 2011-07-29 2014-04-16 深圳光启高等理工研究院 一种基于高分子材料的微结构的制备方法
WO2013184366A1 (en) * 2012-06-05 2013-12-12 3M Innovative Properties Company Graft copolymer functionalized article
CN103447089B (zh) * 2013-09-18 2015-06-10 凯瑞环保科技股份有限公司 一种低碳烯烃叠合催化剂及其制备方法
CN103537320B (zh) * 2013-10-17 2016-04-13 凯瑞环保科技股份有限公司 一种用于苯酚羟基化的树脂催化剂及其制备方法
CN103551061A (zh) * 2013-11-15 2014-02-05 天津工业大学 一种用于去除水中Cr(VI)的高负电荷密度中空纤维纳滤膜的制备方法
EP2996184A1 (de) * 2014-09-09 2016-03-16 Paul Scherrer Institut Verfahren zur herstellung einer gasdiffusionsschicht und brennstoffzelle mit einer gasdiffusionsschicht
AU2015370441B2 (en) * 2014-12-24 2017-12-07 Hydroxsys Holdings Limited Asymmetric composite membranes and modified substrates used in their preparation
CN104779404A (zh) * 2015-04-09 2015-07-15 深圳市万越新能源科技有限公司 一种采用射线辐照接枝法制备全钒电池均相离子交换膜的方法
EP3576201A1 (de) 2018-05-31 2019-12-04 Paul Scherrer Institut Amphotere elektrolytmembran und redox-durchflussbatterie mit einer elektrolytmembran
CN110391440B (zh) * 2019-07-17 2021-03-30 深圳质子航新能源科技有限公司 聚合物质子交换膜及其制备方法
CN112909277B (zh) * 2020-12-31 2022-02-11 大连融科储能技术发展有限公司 一种离子交换膜及其制备方法和应用
CN114763314B (zh) * 2021-01-11 2024-09-27 中国石油天然气股份有限公司 混合c4烃叠合反应工艺及叠合树脂催化剂
FR3123507A1 (fr) * 2021-05-31 2022-12-02 Arkema France Membrane echangeuse de protons
FR3123508A1 (fr) * 2021-05-31 2022-12-02 Arkema France Membrane echangeuse de protons
CN114832652B (zh) * 2022-04-25 2024-05-31 上海师范大学 一种功能聚合物纳滤膜材料及其制备方法
FR3142609B1 (fr) * 2022-11-29 2024-10-18 Arkema France Membrane echangeuse de protons a base de pvdf sous forme de granules cryobroyes

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US2913511A (en) * 1955-06-29 1959-11-17 Gen Electric Fuel cell
US5216062A (en) * 1989-02-18 1993-06-01 Basf Aktiengesellschaft Thermoplastic polyurethane molding composition
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JP4473967B2 (ja) * 1997-03-04 2010-06-02 日本ゼオン株式会社 電池用バインダー、電池用バインダー組成物、電池電極用スラリー、リチウム二次電池用電極およびリチウム二次電池
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JP4103975B2 (ja) * 1998-09-10 2008-06-18 富士フイルム株式会社 電解質、光電気化学電池、及び電解質層を形成する方法
JP2002198068A (ja) * 2000-12-26 2002-07-12 Aisin Seiki Co Ltd 固体高分子電解質膜及びその製造方法
US20040009305A1 (en) * 2002-07-12 2004-01-15 Ballard Power Systems Inc. Process for preparing graft copolymer membranes
EP2334709B1 (de) * 2008-09-17 2014-04-09 Belenos Clean Power Holding AG Verfahren zur herstellung von strahlung-pfropfcopolymeren.

Also Published As

Publication number Publication date
US20080199754A1 (en) 2008-08-21
EP1893323A1 (de) 2008-03-05
DE602006021018D1 (de) 2011-05-12
EP1693101A1 (de) 2006-08-23
CN101115546A (zh) 2008-01-30
EP1893323B1 (de) 2011-03-30
WO2006084591A1 (en) 2006-08-17
CN101115546B (zh) 2010-06-23

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