ATE512128T1 - Hydrierung aromatischer amine zu alicyclischen aminen unter verwendung eines ruthenium- katalysators auf einem lithiumaluminat-träger - Google Patents
Hydrierung aromatischer amine zu alicyclischen aminen unter verwendung eines ruthenium- katalysators auf einem lithiumaluminat-trägerInfo
- Publication number
- ATE512128T1 ATE512128T1 AT06019510T AT06019510T ATE512128T1 AT E512128 T1 ATE512128 T1 AT E512128T1 AT 06019510 T AT06019510 T AT 06019510T AT 06019510 T AT06019510 T AT 06019510T AT E512128 T1 ATE512128 T1 AT E512128T1
- Authority
- AT
- Austria
- Prior art keywords
- hydrogenation
- ruthenium catalyst
- amine
- lithium aluminate
- aluminate support
- Prior art date
Links
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 title abstract 3
- 150000004982 aromatic amines Chemical class 0.000 title abstract 3
- 239000003054 catalyst Substances 0.000 title abstract 3
- 238000005984 hydrogenation reaction Methods 0.000 title abstract 3
- 229910052707 ruthenium Inorganic materials 0.000 title abstract 3
- YQNQTEBHHUSESQ-UHFFFAOYSA-N lithium aluminate Chemical compound [Li+].[O-][Al]=O YQNQTEBHHUSESQ-UHFFFAOYSA-N 0.000 title abstract 2
- 150000001412 amines Chemical class 0.000 title 1
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 abstract 2
- PAFZNILMFXTMIY-UHFFFAOYSA-N cyclohexylamine Chemical compound NC1CCCCC1 PAFZNILMFXTMIY-UHFFFAOYSA-N 0.000 abstract 2
- 238000000034 method Methods 0.000 abstract 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- 125000002015 acyclic group Chemical group 0.000 abstract 1
- 238000009903 catalytic hydrogenation reaction Methods 0.000 abstract 1
- 230000000694 effects Effects 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C211/00—Compounds containing amino groups bound to a carbon skeleton
- C07C211/33—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of rings other than six-membered aromatic rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
- C07C209/68—Preparation of compounds containing amino groups bound to a carbon skeleton from amines, by reactions not involving amino groups, e.g. reduction of unsaturated amines, aromatisation, or substitution of the carbon skeleton
- C07C209/70—Preparation of compounds containing amino groups bound to a carbon skeleton from amines, by reactions not involving amino groups, e.g. reduction of unsaturated amines, aromatisation, or substitution of the carbon skeleton by reduction of unsaturated amines
- C07C209/72—Preparation of compounds containing amino groups bound to a carbon skeleton from amines, by reactions not involving amino groups, e.g. reduction of unsaturated amines, aromatisation, or substitution of the carbon skeleton by reduction of unsaturated amines by reduction of six-membered aromatic rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C211/00—Compounds containing amino groups bound to a carbon skeleton
- C07C211/33—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of rings other than six-membered aromatic rings
- C07C211/34—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of rings other than six-membered aromatic rings of a saturated carbon skeleton
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2601/00—Systems containing only non-condensed rings
- C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
- C07C2601/14—The ring being saturated
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US11/233,439 US7465833B2 (en) | 2005-09-22 | 2005-09-22 | Hydrogenation of aromatic amines to alicyclic amines using a lithium aluminate-based catalyst |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ATE512128T1 true ATE512128T1 (de) | 2011-06-15 |
Family
ID=37493113
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AT06019510T ATE512128T1 (de) | 2005-09-22 | 2006-09-18 | Hydrierung aromatischer amine zu alicyclischen aminen unter verwendung eines ruthenium- katalysators auf einem lithiumaluminat-träger |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US7465833B2 (de) |
| EP (1) | EP1767520B1 (de) |
| JP (1) | JP4874749B2 (de) |
| KR (1) | KR100815047B1 (de) |
| CN (1) | CN1970528B (de) |
| AT (1) | ATE512128T1 (de) |
| BR (1) | BRPI0603815B1 (de) |
| CA (1) | CA2559787A1 (de) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102008002002A1 (de) | 2008-05-27 | 2009-12-03 | Evonik Degussa Gmbh | Chlor armes mehrstufiges Verfahren zur Herstellung von cycloaliphatischen Diisocyanaten |
| WO2010143195A1 (en) * | 2009-06-09 | 2010-12-16 | Hindustan Organic Chemicals Limited | A process for the production of cyclohexylamine at low pressure |
| DE102013203420A1 (de) | 2013-02-28 | 2014-08-28 | Evonik Industries Ag | Hydrogenolyse von Furfurylalkohol zu 1,2-Pentandiol |
| CA2948001C (en) | 2014-05-12 | 2023-03-14 | Johna Leddy | Lanthanide electrochemistry |
| GB201417035D0 (en) | 2014-09-26 | 2014-11-12 | Swan Thomas & Co Ltd | Enantioselective hydrogenation |
| WO2017060922A1 (en) | 2015-10-07 | 2017-04-13 | Council Of Scientific & Industrial Research | An eco-friendly process for hydrogenation or/and hydrodeoxygenation of organic compound using hydrous ruthenium oxide catalyst |
| CN112851454B (zh) * | 2019-11-12 | 2022-11-04 | 中国医学科学院药物研究所 | 一种芳族化合物氢化及氢化脱氧的方法及其应用 |
| WO2023275038A1 (de) * | 2021-07-02 | 2023-01-05 | Evonik Operations Gmbh | Hydrierung von aromatischen aminen aus pu-zersetzungsprozessen |
Family Cites Families (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2606928A (en) | 1947-11-18 | 1952-08-12 | Du Pont | Preparation of amino alicyclic compounds |
| US2511028A (en) | 1947-12-04 | 1950-06-13 | Du Pont | 4-[(para-aminophenyl) alkyl] cyclo-hexylamine |
| US2606924A (en) | 1949-06-09 | 1952-08-12 | Du Pont | Bis (4-aminocyclohexyl)-methane |
| US2606925A (en) | 1949-12-15 | 1952-08-12 | Du Pont | Ruthenium catalyzed hydrogenation process for obtaining aminocyclohexyl compounds |
| US2822392A (en) * | 1954-09-20 | 1958-02-04 | Abbott Lab | Process for producing cyclohexylamine |
| US3636108A (en) * | 1965-12-23 | 1972-01-18 | Du Pont | Catalytic hydrogenation of aromatic nitrogen containing compounds over alkali moderated ruthenium |
| CH515882A (de) * | 1965-12-23 | 1971-11-30 | Du Pont | Verfahren zur Herstellung von 4,4'-Methylen-di-(cyclohexylamin) |
| US3644522A (en) | 1969-04-04 | 1972-02-22 | Du Pont | Catalytic hydrogenation of nitrogen containing compounds over supported ruthenium catalysts |
| US3697449A (en) | 1970-12-14 | 1972-10-10 | Du Pont | Alkali moderation of supported ruthenium catalysts |
| DE2132547C2 (de) | 1971-06-30 | 1982-11-11 | Basf Ag, 6700 Ludwigshafen | Verfahren zur Hydrierung ein- oder mehrkerniger aromatischer Diamine zu den entsprechenden cycloaliphatischen Aminen |
| US3959374A (en) | 1974-05-30 | 1976-05-25 | Jefferson Chemical Company, Inc. | Process for the preparation of mixed isomeric methylene-bridged polycyclohexylpolyamines |
| US4448995A (en) | 1982-12-13 | 1984-05-15 | Mobay Chemical Corporation | Catalytic hydrogenation of di(4-aminophenyl)methane |
| US4754070A (en) | 1986-01-23 | 1988-06-28 | Air Products And Chemicals, Inc. | Hydrogenation of methylenedianiline to produce bis(para-aminocyclohexyl)methane |
| DE3801755A1 (de) | 1988-01-22 | 1989-07-27 | Bayer Ag | Ruthenium-traegerkatalysator, seine herstellung und sein einsatz bei der herstellung von gegebenenfalls substituiertem cyclohexylamin und gegebenenfalls substituiertem dicyclohexylamin |
| US4960941A (en) | 1988-03-30 | 1990-10-02 | Air Products And Chemicals, Inc. | Hydrogenation of aromatic amines to produce their ring hydrogenated counterparts |
| JP2855284B2 (ja) * | 1990-05-11 | 1999-02-10 | 川研ファインケミカル株式会社 | 芳香族アミン類の水素化用触媒およびシクロヘキシルアミン類の製造方法 |
| DE4207314A1 (de) | 1992-03-07 | 1993-09-09 | Basf Ag | Verfahren zur herstellung von cycloaliphatischen aminen |
| DE19533718A1 (de) | 1995-09-12 | 1997-03-13 | Basf Ag | Verfahren zur Hydrierung von aromatischen Verbindungen, in denen mindestens eine Aminogruppe an einen aromatischen Kern gebunden ist |
| JPH1147597A (ja) | 1997-07-29 | 1999-02-23 | Ube Ind Ltd | 水素化反応用触媒、及び水素化法 |
| US6184416B1 (en) * | 2000-04-28 | 2001-02-06 | Air Products And Chemicals, Inc. | Lithium aluminate as a catalyst support for hydrogenation of aromatic amines |
| US7038088B2 (en) | 2004-05-19 | 2006-05-02 | Air Products And Chemicals, Inc. | Hydrogenation of highly contaminated methylenedianiline |
| US6998507B1 (en) * | 2004-08-24 | 2006-02-14 | Air Products And Chemicals, Inc. | Hydrogenation of methylenedianiline |
-
2005
- 2005-09-22 US US11/233,439 patent/US7465833B2/en not_active Expired - Fee Related
-
2006
- 2006-09-15 CA CA002559787A patent/CA2559787A1/en not_active Abandoned
- 2006-09-18 EP EP06019510A patent/EP1767520B1/de not_active Not-in-force
- 2006-09-18 AT AT06019510T patent/ATE512128T1/de not_active IP Right Cessation
- 2006-09-18 BR BRPI0603815A patent/BRPI0603815B1/pt not_active IP Right Cessation
- 2006-09-21 KR KR1020060091664A patent/KR100815047B1/ko not_active Expired - Fee Related
- 2006-09-21 JP JP2006256015A patent/JP4874749B2/ja not_active Expired - Fee Related
- 2006-09-22 CN CN2006101395333A patent/CN1970528B/zh not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| JP2007084546A (ja) | 2007-04-05 |
| KR100815047B1 (ko) | 2008-03-18 |
| US20070066849A1 (en) | 2007-03-22 |
| CN1970528B (zh) | 2012-11-14 |
| JP4874749B2 (ja) | 2012-02-15 |
| BRPI0603815A (pt) | 2007-08-14 |
| EP1767520A1 (de) | 2007-03-28 |
| CA2559787A1 (en) | 2007-03-22 |
| KR20070033912A (ko) | 2007-03-27 |
| US7465833B2 (en) | 2008-12-16 |
| EP1767520B1 (de) | 2011-06-08 |
| BRPI0603815B1 (pt) | 2016-07-19 |
| CN1970528A (zh) | 2007-05-30 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| RER | Ceased as to paragraph 5 lit. 3 law introducing patent treaties |