ATE72660T1 - Herstellung von zeolith-l. - Google Patents

Herstellung von zeolith-l.

Info

Publication number
ATE72660T1
ATE72660T1 AT88301538T AT88301538T ATE72660T1 AT E72660 T1 ATE72660 T1 AT E72660T1 AT 88301538 T AT88301538 T AT 88301538T AT 88301538 T AT88301538 T AT 88301538T AT E72660 T1 ATE72660 T1 AT E72660T1
Authority
AT
Austria
Prior art keywords
zeolite
production
Prior art date
Application number
AT88301538T
Other languages
English (en)
Inventor
Johannes Petrus Verduijn
Pieter Ernst Gellings
Original Assignee
Exxon Chemical Patents Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxon Chemical Patents Inc filed Critical Exxon Chemical Patents Inc
Application granted granted Critical
Publication of ATE72660T1 publication Critical patent/ATE72660T1/de

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/60—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the type L, as exemplified by patent document US3216789
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/60—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the type L, as exemplified by patent document US3216789
    • B01J29/61—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the type L, as exemplified by patent document US3216789 containing iron group metals, noble metals or copper
    • B01J29/62—Noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7011—MAZ-type, e.g. Mazzite, Omega, ZSM-4 or LZ-202
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/80—Mixtures of different zeolites
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/32—Type L
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
    • C07C5/2206—Catalytic processes not covered by C07C5/23 - C07C5/31
    • C07C5/226—Catalytic processes not covered by C07C5/23 - C07C5/31 with metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/373—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen with simultaneous isomerisation
    • C07C5/393—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen with simultaneous isomerisation with cyclisation to an aromatic six-membered ring, e.g. dehydrogenation of n-hexane to benzene
    • C07C5/41—Catalytic processes
    • C07C5/415—Catalytic processes with metals
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G35/00—Reforming naphtha
    • C10G35/04—Catalytic reforming
    • C10G35/06—Catalytic reforming characterised by the catalyst used
    • C10G35/095—Catalytic reforming characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/26—After treatment, characterised by the effect to be obtained to stabilize the total catalyst structure
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/42—Addition of matrix or binder particles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/50—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the erionite or offretite type, e.g. zeolite T, as exemplified by patent document US2950952
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/60—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the type L
    • C07C2529/61—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the type L containing iron group metals, noble metals or copper
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S423/00—Chemistry of inorganic compounds
    • Y10S423/28—LTL, e.g. BA-G, L, AG-1, AG-2, AG-4, BA-6

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
AT88301538T 1987-02-25 1988-02-23 Herstellung von zeolith-l. ATE72660T1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB878704365A GB8704365D0 (en) 1987-02-25 1987-02-25 Zeolite l preparation
EP88301538A EP0284206B1 (de) 1987-02-25 1988-02-23 Herstellung von Zeolith-L

Publications (1)

Publication Number Publication Date
ATE72660T1 true ATE72660T1 (de) 1992-03-15

Family

ID=10612879

Family Applications (1)

Application Number Title Priority Date Filing Date
AT88301538T ATE72660T1 (de) 1987-02-25 1988-02-23 Herstellung von zeolith-l.

Country Status (14)

Country Link
US (4) US5486348A (de)
EP (1) EP0284206B1 (de)
JP (1) JP2547813B2 (de)
AR (1) AR245426A1 (de)
AT (1) ATE72660T1 (de)
AU (2) AU597796B2 (de)
BR (1) BR8800775A (de)
CA (1) CA1327561C (de)
DE (1) DE3868420D1 (de)
EG (1) EG18582A (de)
ES (1) ES2032011T3 (de)
GB (1) GB8704365D0 (de)
MX (1) MX169203B (de)
NO (1) NO175300C (de)

Families Citing this family (45)

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GB8704365D0 (en) * 1987-02-25 1987-04-01 Exxon Chemical Patents Inc Zeolite l preparation
ATE109429T1 (de) * 1987-12-15 1994-08-15 Uop Inc Ersatz von aluminium durch chrom und/oder zinn im gerüst eines molekularsiebes mittels einer behandlung mit fluoridsalzen.
GB8801067D0 (en) * 1988-01-19 1988-02-17 Exxon Chemical Patents Inc Zeolite l preparation
GB8924410D0 (en) * 1989-10-30 1989-12-20 Exxon Chemical Patents Inc Zeolite l
GB9101456D0 (en) * 1991-01-23 1991-03-06 Exxon Chemical Patents Inc Process for producing substantially binder-free zeolite
DE69330963T2 (de) * 1992-12-16 2002-04-25 Chevron U.S.A. Inc., San Ramon Herstellung von aluminosilikatzeolithen
CN1059424C (zh) * 1994-11-23 2000-12-13 埃克森化学专利公司 应用沸石结合沸石催化剂的烃转化过程
MX9701814A (es) 1995-07-10 1997-11-29 Exxon Chemical Patents Inc Zeolitas y procesos para su fabricacion.
CA2254893A1 (en) * 1996-05-29 1997-12-04 Exxon Chemical Patents, Inc. Process for producing aromatic compounds from aliphatic hydrocarbons
EA199801059A1 (ru) * 1996-05-29 1999-06-24 Эксон Кемикэл Пейтентс Инк. Металлосодержащий цеолитный катализатор, его получение и применение в конверсии углеводородов
CN1088049C (zh) 1996-05-29 2002-07-24 埃克森美孚化学专利公司 芳烃转化方法和适用的沸石催化剂
BR9709398A (pt) 1996-05-29 1999-08-10 Exxon Chemical Patents Inc Catalisador zeólito e seu uso em conversão de hidrocarboneto
ID18446A (id) * 1996-05-29 1998-04-09 Exxon Chemical Patents Inc Proses untuk isomerisasi hidrokarbon-hidrokarbon alkilaromatik
US5785945A (en) * 1996-07-31 1998-07-28 Chevron Chemical Company Llc Preparation of zeolite L
US6919491B1 (en) * 1997-05-08 2005-07-19 Exxonmobil Oil Corporation Process for preparing short chain alkyl aromatic compounds
US5851379A (en) * 1997-12-22 1998-12-22 Chevron Chemical Company Reforming process using monofunctional catalyst containing bismuth
US6063724A (en) * 1998-04-06 2000-05-16 The Board Of Regents Of The University Of Oklahoma Sulfur-tolerant aromatization catalysts
AU6254299A (en) 1998-09-22 2000-04-10 Exxon Chemical Patents Inc. Preparation of high silica zeolites bound by zeolite and use thereof
US6261534B1 (en) 1999-11-24 2001-07-17 Chevron U.S.A. Inc. Method for making ZSM-5 zeolites
KR20080023768A (ko) 2000-03-30 2008-03-14 화이트헤드 인스티튜트 포 바이오메디칼 리서치 Ｒｎａ 간섭의 ｒｎａ 서열 특이적인 매개체
CN100523215C (zh) 2000-12-01 2009-08-05 马普科技促进协会 介导rna干涉的小rna分子
US6632415B2 (en) 2001-04-09 2003-10-14 Chevron U.S.A. Inc. Methods for making molecular sieves
US6653518B2 (en) 2001-06-15 2003-11-25 Exxonmobil Chemical Patents Inc Reforming process for manufacture of para-xylene
US20050063901A1 (en) * 2003-09-24 2005-03-24 Miller Stephen J. Preparation of molecular sieves involving spray drying
JP2006305408A (ja) * 2005-04-26 2006-11-09 Tosoh Corp 芳香族化反応触媒とその触媒を用いた芳香族炭化水素の製造方法
US8557219B2 (en) 2006-02-14 2013-10-15 Exxonmobil Chemical Patents Inc. High throughput process for manufacturing molecular sieves
CN103193248A (zh) 2006-02-14 2013-07-10 埃克森美孚化学专利公司 用于制备mfs 结构型分子筛的方法及其应用
US8859836B2 (en) 2006-02-14 2014-10-14 Exxonmobil Chemical Patents Inc. Hydrocarbon conversion process using molecular sieve of MFS framework type
CN101384368A (zh) 2006-02-14 2009-03-11 埃克森美孚化学专利公司 分子筛组合物
WO2007094938A1 (en) 2006-02-14 2007-08-23 Exxonmobil Chemical Patents Inc. An mcm-22 family molecular sieve composition
WO2007094937A1 (en) 2006-02-14 2007-08-23 Exxonmobil Chemical Patents Inc. A process for manufacturing mcm-22 family molecular sieves
US7829062B2 (en) 2006-02-14 2010-11-09 Exxonmobil Chemical Patent Inc. Method of preparing a molecular sieve composition
US7902105B2 (en) * 2007-10-11 2011-03-08 Chevron Phillips Chemical Company Lp Aromatization catalyst comprising prolongated silica and methods of making and using same
US8398955B2 (en) 2007-10-26 2013-03-19 Exxonmobil Chemical Patents Inc. Method of preparing a molecular sieve composition
DE102010034005A1 (de) * 2010-08-11 2012-02-16 Süd-Chemie AG Hydrothermale Synthese von Zeolithen oder zeolithähnlichen Materialien unter Verwendung von modifizierten Mischoxiden
CN102476809B (zh) * 2010-11-29 2013-08-21 中国科学院大连化学物理研究所 一种高岭土预成型制备含钡l沸石的方法
US8557028B2 (en) * 2011-03-31 2013-10-15 Uop Llc Binderless zeolitic adsorbents, methods for producing binderless zeolitic adsorbents, and adsorptive separation processes using the binderless zeolitic adsorbents
US9573122B2 (en) * 2014-08-29 2017-02-21 Chevron U.S.A. Inc. Small crystal LTL framework type zeolites
WO2017189137A1 (en) * 2016-04-25 2017-11-02 Exxonmobil Chemical Patents Inc. Catalytic aromatization
US20180229198A1 (en) 2017-02-16 2018-08-16 Exxonmobil Research And Engineering Company Fixed bed radial flow reactor for light paraffin conversion
US11186784B2 (en) * 2018-10-15 2021-11-30 Uop Llc Dehydrogenation process having improved run time
US11097257B2 (en) * 2019-09-10 2021-08-24 Saudi Arabian Oil Company Catalytic hydrocarbon dehydrogenation
US11338269B2 (en) 2019-09-10 2022-05-24 Saudi Arabian Oil Company Catalytic hydrocarbon dehydrogenation
FR3123811A1 (fr) * 2021-06-11 2022-12-16 IFP Energies Nouvelles Procede de preparation d'un materiau composite a haute teneur en zeolithe kl et ayant une bonne resistance mecanique
FR3125727B1 (fr) * 2021-07-29 2025-08-01 Ifp Energies Now Procede de preparation d'un materiau zeolithique a haute teneur en zeolithe kl et de haute resistance mecanique

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CA1236817A (en) * 1983-11-10 1988-05-17 David E.W.. Vaughan Stoichiometric process for preparing a zeolite of the l type
CA1225387A (en) * 1983-11-10 1987-08-11 David E.W. Vaughan Process for preparing type l zeolites by nucleation technique
FR2565847B1 (fr) * 1984-06-18 1986-08-29 Inst Francais Du Petrole Synthese et utilisation de zeolithes preformees
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GB8704365D0 (en) * 1987-02-25 1987-04-01 Exxon Chemical Patents Inc Zeolite l preparation
US5491119A (en) * 1989-10-30 1996-02-13 Exxon Chemical Patents Inc. Zeolite L
GB9101456D0 (en) * 1991-01-23 1991-03-06 Exxon Chemical Patents Inc Process for producing substantially binder-free zeolite
CA2099194A1 (en) * 1992-07-08 1994-01-09 Gustavo Larsen Sulfur tolerant bimetallic zeolitic reforming catalysts
AU668645B2 (en) * 1992-11-12 1996-05-09 Uop Multimetallic and multigradient reforming catalyst for converting paraffins to aromatics
US5523271A (en) * 1994-12-13 1996-06-04 Intevep, S.A. Catalyst for the simultaneous selective hydrogenation of diolefins and nitriles and method of making same

Also Published As

Publication number Publication date
GB8704365D0 (en) 1987-04-01
AU5135290A (en) 1990-07-12
NO175300B (no) 1994-06-20
JP2547813B2 (ja) 1996-10-23
NO880812D0 (no) 1988-02-24
AU597796B2 (en) 1990-06-07
US5919722A (en) 1999-07-06
US5624656A (en) 1997-04-29
US5849967A (en) 1998-12-15
NO880812L (no) 1988-08-26
NO175300C (no) 1994-10-05
BR8800775A (pt) 1988-10-04
AR245426A1 (es) 1994-01-31
AU1216688A (en) 1988-09-01
DE3868420D1 (de) 1992-03-26
ES2032011T3 (es) 1993-01-01
US5486348A (en) 1996-01-23
EP0284206B1 (de) 1992-02-19
EG18582A (en) 1993-08-30
MX169203B (es) 1993-06-24
AU614222B2 (en) 1991-08-22
JPS63285115A (ja) 1988-11-22
CA1327561C (en) 1994-03-08
EP0284206A1 (de) 1988-09-28

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