AU2006323088B2 - Production of aromatic hydrocarbons from methane - Google Patents
Production of aromatic hydrocarbons from methane Download PDFInfo
- Publication number
- AU2006323088B2 AU2006323088B2 AU2006323088A AU2006323088A AU2006323088B2 AU 2006323088 B2 AU2006323088 B2 AU 2006323088B2 AU 2006323088 A AU2006323088 A AU 2006323088A AU 2006323088 A AU2006323088 A AU 2006323088A AU 2006323088 B2 AU2006323088 B2 AU 2006323088B2
- Authority
- AU
- Australia
- Prior art keywords
- catalyst
- zone
- reactor
- methane
- heating zone
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
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- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 title claims description 240
- 150000004945 aromatic hydrocarbons Chemical class 0.000 title claims description 25
- 238000004519 manufacturing process Methods 0.000 title description 7
- 239000003054 catalyst Substances 0.000 claims description 319
- 238000000034 method Methods 0.000 claims description 118
- 238000006243 chemical reaction Methods 0.000 claims description 111
- 230000008569 process Effects 0.000 claims description 100
- 239000007789 gas Substances 0.000 claims description 77
- 229910052739 hydrogen Inorganic materials 0.000 claims description 77
- 239000001257 hydrogen Substances 0.000 claims description 75
- 238000010438 heat treatment Methods 0.000 claims description 71
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 69
- 229930195733 hydrocarbon Natural products 0.000 claims description 58
- 150000002430 hydrocarbons Chemical class 0.000 claims description 58
- 239000000446 fuel Substances 0.000 claims description 49
- 230000008929 regeneration Effects 0.000 claims description 43
- 238000011069 regeneration method Methods 0.000 claims description 43
- 229910052760 oxygen Inorganic materials 0.000 claims description 40
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 39
- 239000001301 oxygen Substances 0.000 claims description 39
- 229910052751 metal Inorganic materials 0.000 claims description 32
- 239000002184 metal Substances 0.000 claims description 32
- 238000002485 combustion reaction Methods 0.000 claims description 30
- 230000000153 supplemental effect Effects 0.000 claims description 24
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- 230000015572 biosynthetic process Effects 0.000 claims description 19
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- 239000000126 substance Substances 0.000 claims description 5
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 72
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 42
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical class [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 40
- 239000002245 particle Substances 0.000 description 39
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 35
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 30
- 239000000047 product Substances 0.000 description 29
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 26
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- SIXSYDAISGFNSX-UHFFFAOYSA-N scandium atom Chemical compound [Sc] SIXSYDAISGFNSX-UHFFFAOYSA-N 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- 239000011949 solid catalyst Substances 0.000 description 2
- 239000008247 solid mixture Substances 0.000 description 2
- 229910052715 tantalum Inorganic materials 0.000 description 2
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 2
- 229910052716 thallium Inorganic materials 0.000 description 2
- BKVIYDNLLOSFOA-UHFFFAOYSA-N thallium Chemical compound [Tl] BKVIYDNLLOSFOA-UHFFFAOYSA-N 0.000 description 2
- 229910052718 tin Inorganic materials 0.000 description 2
- 239000011800 void material Substances 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- 229910052727 yttrium Inorganic materials 0.000 description 2
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 description 2
- QNLZIZAQLLYXTC-UHFFFAOYSA-N 1,2-dimethylnaphthalene Chemical class C1=CC=CC2=C(C)C(C)=CC=C21 QNLZIZAQLLYXTC-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 101100065715 Lytechinus variegatus ETS-2 gene Proteins 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 230000009471 action Effects 0.000 description 1
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- 229910000287 alkaline earth metal oxide Inorganic materials 0.000 description 1
- 150000004996 alkyl benzenes Chemical class 0.000 description 1
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- 229910021529 ammonia Inorganic materials 0.000 description 1
- 150000001491 aromatic compounds Chemical class 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000001588 bifunctional effect Effects 0.000 description 1
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
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- 239000003518 caustics Substances 0.000 description 1
- 238000001311 chemical methods and process Methods 0.000 description 1
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- 238000009826 distribution Methods 0.000 description 1
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- 230000008020 evaporation Effects 0.000 description 1
- 238000011066 ex-situ storage Methods 0.000 description 1
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- 239000007792 gaseous phase Substances 0.000 description 1
- 231100001261 hazardous Toxicity 0.000 description 1
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- 238000005342 ion exchange Methods 0.000 description 1
- 238000006317 isomerization reaction Methods 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
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- 150000002790 naphthalenes Chemical class 0.000 description 1
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- 238000005839 oxidative dehydrogenation reaction Methods 0.000 description 1
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- 239000011973 solid acid Substances 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
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- 229910052714 tellurium Inorganic materials 0.000 description 1
- PORWMNRCUJJQNO-UHFFFAOYSA-N tellurium atom Chemical compound [Te] PORWMNRCUJJQNO-UHFFFAOYSA-N 0.000 description 1
- 230000036962 time dependent Effects 0.000 description 1
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- 239000002918 waste heat Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- RNWHGQJWIACOKP-UHFFFAOYSA-N zinc;oxygen(2-) Chemical class [O-2].[Zn+2] RNWHGQJWIACOKP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/76—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation of hydrocarbons with partial elimination of hydrogen
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/76—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation of hydrocarbons with partial elimination of hydrogen
- C07C2/78—Processes with partial combustion
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/10—Feedstock materials
- C10G2300/1025—Natural gas
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/40—Characteristics of the process deviating from typical ways of processing
- C10G2300/4093—Catalyst stripping
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
- C10G2400/30—Aromatics
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/584—Recycling of catalysts
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S585/00—Chemistry of hydrocarbon compounds
- Y10S585/929—Special chemical considerations
- Y10S585/943—Synthesis from methane or inorganic carbon source, e.g. coal
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/US2005/044042 WO2006068814A2 (en) | 2004-12-22 | 2005-12-02 | Production of aromatic hydrocarbons from methane |
| AUPCT/US2005/044042 | 2005-12-02 | ||
| US11/408,861 US7683227B2 (en) | 2004-12-22 | 2006-04-21 | Production of aromatic hydrocarbons from methane |
| US11/408,861 | 2006-04-21 | ||
| PCT/US2006/043131 WO2007067285A1 (en) | 2005-12-02 | 2006-11-06 | Production of aromatic hydrocarbons from methane |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| AU2006323088A1 AU2006323088A1 (en) | 2007-06-14 |
| AU2006323088B2 true AU2006323088B2 (en) | 2011-02-24 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AU2006323088A Ceased AU2006323088B2 (en) | 2005-12-02 | 2006-11-06 | Production of aromatic hydrocarbons from methane |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US7683227B2 (2) |
| JP (2) | JP4934676B2 (2) |
| AR (1) | AR058244A1 (2) |
| AU (1) | AU2006323088B2 (2) |
| MY (1) | MY146011A (2) |
| RU (1) | RU2408565C2 (2) |
| WO (1) | WO2007067285A1 (2) |
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| RU2461537C2 (ru) * | 2007-07-24 | 2012-09-20 | Эксонмобил Кемикэл Пейтентс Инк. | Получение ароматических соединений из алифатических |
| WO2009065875A1 (en) * | 2007-11-19 | 2009-05-28 | Shell Internationale Research Maatschappij B.V. | Process for converting an oxygenate into an olefin-containing product, and reactor system |
| US20110160508A1 (en) * | 2008-05-21 | 2011-06-30 | Ding Ma | Production of aromatics from methane |
| ES2335175B1 (es) * | 2008-06-20 | 2010-12-30 | Universidad De Zaragoza | Procedimiento para la obtencion de hidrocarburos aromaticos a partir de metano. |
| US8017539B2 (en) * | 2008-10-22 | 2011-09-13 | Uop Llc | Once through regeneration for an olefin cracking reactor |
| US8378162B2 (en) * | 2009-03-13 | 2013-02-19 | Exxonmobil Chemical Patents Inc. | Process for methane conversion |
| WO2010104762A1 (en) | 2009-03-13 | 2010-09-16 | Exxonmobil Chemical Patents Inc. | Process for methane conversion |
| RU2529021C2 (ru) * | 2009-03-31 | 2014-09-27 | Чайна Петролеум & Кемикал Корпорейшн | Способ регенерации катализатора |
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| CN103221365B (zh) | 2010-08-10 | 2015-12-02 | 埃克森美孚化学专利公司 | 甲烷转化方法 |
| CN103140289B (zh) * | 2010-09-30 | 2016-01-20 | 埃克森美孚化学专利公司 | 含金属催化剂的再生 |
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2006
- 2006-04-21 US US11/408,861 patent/US7683227B2/en active Active
- 2006-11-06 AU AU2006323088A patent/AU2006323088B2/en not_active Ceased
- 2006-11-06 RU RU2008126741/04A patent/RU2408565C2/ru not_active IP Right Cessation
- 2006-11-06 WO PCT/US2006/043131 patent/WO2007067285A1/en not_active Ceased
- 2006-11-06 JP JP2008543295A patent/JP4934676B2/ja not_active Expired - Fee Related
- 2006-11-23 MY MYPI20064556A patent/MY146011A/en unknown
- 2006-11-28 AR ARP060105252A patent/AR058244A1/es active IP Right Grant
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| WO2003000826A2 (en) * | 2001-06-20 | 2003-01-03 | Conoco Inc. | Circulating catalyst system and method for conversion of light hydrocarbons to aromatics |
Also Published As
| Publication number | Publication date |
|---|---|
| US20070276171A9 (en) | 2007-11-29 |
| JP2009529063A (ja) | 2009-08-13 |
| RU2008126741A (ru) | 2010-01-10 |
| US20070129587A1 (en) | 2007-06-07 |
| RU2408565C2 (ru) | 2011-01-10 |
| MY146011A (en) | 2012-06-15 |
| AU2006323088A1 (en) | 2007-06-14 |
| AR058244A1 (es) | 2008-01-23 |
| WO2007067285A1 (en) | 2007-06-14 |
| US7683227B2 (en) | 2010-03-23 |
| JP2012107016A (ja) | 2012-06-07 |
| JP4934676B2 (ja) | 2012-05-16 |
| JP5305486B2 (ja) | 2013-10-02 |
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