AU608136B2 - Process for manufacturing polyglycerines - Google Patents

Process for manufacturing polyglycerines Download PDF

Info

Publication number: AU608136B2
Authority: AU; Australia
Prior art keywords: process according; polyglycerol; diglycerol; glycerol; reaction mixture
Prior art date: 1988-03-24
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

AU31624/89A

Other languages

English (en)

Other versions

AU3162489A (en

Inventor

Gerald Dr. Jakobson

Werner Dr. Siemanowski

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Solvay Elektrolysespezialitaeten GmbH

Original Assignee

Deutsche Solvay Werke GmbH

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1988-03-24

Filing date

1989-03-22

Publication date

1991-03-21

1989-03-22 Application filed by Deutsche Solvay Werke GmbH filed Critical Deutsche Solvay Werke GmbH

1989-09-28 Publication of AU3162489A publication Critical patent/AU3162489A/en

1991-03-21 Application granted granted Critical

1991-03-21 Publication of AU608136B2 publication Critical patent/AU608136B2/en

2000-09-07 Assigned to SOLVAY ELEKTROLYSESPEZIALITATEN GMBH reassignment SOLVAY ELEKTROLYSESPEZIALITATEN GMBH Alteration of Name(s) in Register under S187 Assignors: DEUTSCHE SOLVAY-WERKE GMBH

2009-03-22 Anticipated expiration legal-status Critical

Status Expired legal-status Critical Current

Links

238000000034 method Methods 0.000 title claims abstract description 43
238000004519 manufacturing process Methods 0.000 title 1
PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims abstract description 99
229920000223 polyglycerol Polymers 0.000 claims abstract description 46
GPLRAVKSCUXZTP-UHFFFAOYSA-N diglycerol Chemical compound OCC(O)COCC(O)CO GPLRAVKSCUXZTP-UHFFFAOYSA-N 0.000 claims abstract description 40
BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 claims abstract description 22
239000011541 reaction mixture Substances 0.000 claims abstract description 22
125000004122 cyclic group Chemical group 0.000 claims abstract description 15
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims abstract description 9
239000000460 chlorine Substances 0.000 claims abstract description 9
229910052801 chlorine Inorganic materials 0.000 claims abstract description 9
238000002360 preparation method Methods 0.000 claims abstract description 7
238000004508 fractional distillation Methods 0.000 claims abstract description 3
239000000203 mixture Substances 0.000 claims description 39
239000000243 solution Substances 0.000 claims description 31
150000001768 cations Chemical class 0.000 claims description 21
238000006243 chemical reaction Methods 0.000 claims description 20
150000001450 anions Chemical class 0.000 claims description 19
150000002500 ions Chemical class 0.000 claims description 13
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 10
229910000288 alkali metal carbonate Inorganic materials 0.000 claims description 9
150000008041 alkali metal carbonates Chemical class 0.000 claims description 9
CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 8
230000002378 acidificating effect Effects 0.000 claims description 6
230000008929 regeneration Effects 0.000 claims description 6
238000011069 regeneration method Methods 0.000 claims description 6
XENVCRGQTABGKY-ZHACJKMWSA-N chlorohydrin Chemical compound CC#CC#CC#CC#C\C=C\C(Cl)CO XENVCRGQTABGKY-ZHACJKMWSA-N 0.000 claims description 5
150000003839 salts Chemical class 0.000 claims description 5
239000007864 aqueous solution Substances 0.000 claims description 4
239000007788 liquid Substances 0.000 claims description 4
229910000029 sodium carbonate Inorganic materials 0.000 claims description 4
238000004438 BET method Methods 0.000 claims description 2
150000003945 chlorohydrins Chemical class 0.000 claims description 2
238000004821 distillation Methods 0.000 claims description 2
238000011033 desalting Methods 0.000 abstract 1
235000011187 glycerol Nutrition 0.000 description 21
AGNTUZCMJBTHOG-UHFFFAOYSA-N 3-[3-(2,3-dihydroxypropoxy)-2-hydroxypropoxy]propane-1,2-diol Chemical compound OCC(O)COCC(O)COCC(O)CO AGNTUZCMJBTHOG-UHFFFAOYSA-N 0.000 description 7
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 6
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 6
JYKSTGLAIMQDRA-UHFFFAOYSA-N tetraglycerol Chemical compound OCC(O)CO.OCC(O)CO.OCC(O)CO.OCC(O)CO JYKSTGLAIMQDRA-UHFFFAOYSA-N 0.000 description 5
239000012043 crude product Substances 0.000 description 4
238000010438 heat treatment Methods 0.000 description 4
238000010992 reflux Methods 0.000 description 3
239000002253 acid Substances 0.000 description 2
238000009835 boiling Methods 0.000 description 2
239000012467 final product Substances 0.000 description 2
230000007935 neutral effect Effects 0.000 description 2
239000000047 product Substances 0.000 description 2
230000035484 reaction time Effects 0.000 description 2
238000003756 stirring Methods 0.000 description 2
SSZWWUDQMAHNAQ-UHFFFAOYSA-N 3-chloropropane-1,2-diol Chemical compound OCC(O)CCl SSZWWUDQMAHNAQ-UHFFFAOYSA-N 0.000 description 1
150000007513 acids Chemical class 0.000 description 1
-1 aliphatic alcohols Chemical class 0.000 description 1
239000003513 alkali Substances 0.000 description 1
239000007795 chemical reaction product Substances 0.000 description 1
238000001704 evaporation Methods 0.000 description 1
230000008020 evaporation Effects 0.000 description 1
150000002314 glycerols Chemical class 0.000 description 1
229910052500 inorganic mineral Inorganic materials 0.000 description 1
239000000543 intermediate Substances 0.000 description 1
PSGAAPLEWMOORI-PEINSRQWSA-N medroxyprogesterone acetate Chemical compound C([C@@]12C)CC(=O)C=C1[C@@H](C)C[C@@H]1[C@@H]2CC[C@]2(C)[C@@](OC(C)=O)(C(C)=O)CC[C@H]21 PSGAAPLEWMOORI-PEINSRQWSA-N 0.000 description 1
239000011707 mineral Substances 0.000 description 1
238000006386 neutralization reaction Methods 0.000 description 1
239000003960 organic solvent Substances 0.000 description 1
238000010626 work up procedure Methods 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C43/00—Ethers; Compounds having groups, groups or groups
- C07C43/02—Ethers
- C07C43/03—Ethers having all ether-oxygen atoms bound to acyclic carbon atoms
- C07C43/04—Saturated ethers
- C07C43/13—Saturated ethers containing hydroxy or O-metal groups
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
- C07C41/01—Preparation of ethers
- C07C41/18—Preparation of ethers by reactions not forming ether-oxygen bonds
- C07C41/26—Preparation of ethers by reactions not forming ether-oxygen bonds by introduction of hydroxy or O-metal groups
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J41/00—Anion exchange; Use of material as anion exchangers; Treatment of material for improving the anion exchange properties
- B01J41/04—Processes using organic exchangers
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
- C07C41/01—Preparation of ethers
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
- C07C41/01—Preparation of ethers
- C07C41/02—Preparation of ethers from oxiranes
- C07C41/03—Preparation of ethers from oxiranes by reaction of oxirane rings with hydroxy groups
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
- C07C41/01—Preparation of ethers
- C07C41/34—Separation; Purification; Stabilisation; Use of additives
- C07C41/40—Separation; Purification; Stabilisation; Use of additives by change of physical state, e.g. by crystallisation
- C07C41/42—Separation; Purification; Stabilisation; Use of additives by change of physical state, e.g. by crystallisation by distillation

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Chemical Kinetics & Catalysis (AREA)
Crystallography & Structural Chemistry (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Saccharide Compounds (AREA)
Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)
Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)

AU31624/89A 1988-03-24 1989-03-22 Process for manufacturing polyglycerines Expired AU608136B2 (en)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
DE3809882A DE3809882A1 (de)	1988-03-24	1988-03-24	Verfahren zur herstellung von polyglycerinen
DE3809882		1988-03-24

Publications (2)

Publication Number	Publication Date
AU3162489A AU3162489A (en)	1989-09-28
AU608136B2 true AU608136B2 (en)	1991-03-21

Family

ID=6350540

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
AU31624/89A Expired AU608136B2 (en)	1988-03-24	1989-03-22	Process for manufacturing polyglycerines

Country Status (11)

Country	Link
US (1)	US4960953A (2)
EP (1)	EP0333984B1 (2)
JP (1)	JP2786235B2 (2)
KR (1)	KR960008647B1 (2)
AT (1)	ATE87898T1 (2)
AU (1)	AU608136B2 (2)
CA (1)	CA1304757C (2)
DE (2)	DE3809882A1 (2)
ES (1)	ES2053823T3 (2)
GR (1)	GR3008142T3 (2)
IL (1)	IL89692A (2)

Families Citing this family (41)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE3842692A1 (de) *	1988-12-19	1990-06-21	Solvay Werke Gmbh	Verfahren zur herstellung von polyglycerinen
US5302728A (en) *	1991-03-19	1994-04-12	Shell Oil Company	Polycondensation of phenolic hydroxyl-containing compounds and polyhydric alcohols and thermal condensation to form polyethercyclipolyols
US5233055A (en) *	1991-03-19	1993-08-03	Shell Oil Company	Copolymerization of polyethercyclicpolyols with epoxy resins
US5338870A (en) *	1991-03-19	1994-08-16	Shell Oil Company	Thermal condensation of polyhydric alcohols to form polyethercyclicpolyols
US5302695A (en) *	1991-03-19	1994-04-12	Shell Oil Company	Polycondensation of epoxy alcohols with polyhydric alcohols and thermal condensation to form polyethercyclicpolyols
US5371244A (en) *	1991-03-19	1994-12-06	Shell Oil Company	Polycondensation of dihydric alcohols and polyhydric alcohols and thermal condensation to form polyethercyclicpolyols
US5198532A (en) *	1991-03-19	1993-03-30	Shell Oil Company	Polycondensation of epihalohydrin and polyhydric alcohols and thermal condensation to form polyethercyclicpolyols
AU647595B2 (en) *	1991-03-19	1994-03-24	Shell Internationale Research Maatschappij B.V.	Method of preparing polyethercyclicopolyols
US5204444A (en) *	1991-03-19	1993-04-20	Shell Oil Company	Polycondensation of epoxy alcohols with polyhdric alcohols and thermal condensation to form polyethercyclicpolyols
DE4132171A1 (de) *	1991-09-27	1993-04-01	Solvay Werke Gmbh	Verfahren zur herstellung von diglycerin und/oder polyglycerin
US5349094A (en) *	1992-06-12	1994-09-20	Henkel Kommanditgesellschaft Auf Aktien	Process for the production of oligoglycerol mixtures of increased diglycerol content
DE4228147A1 (de) *	1992-08-25	1994-03-03	Solvay Fluor & Derivate	Verfahren und Vorrichtung zur Herstellung von Diglycerin
US5371243A (en) *	1992-10-13	1994-12-06	Shell Oil Company	Polyethercyclicpolyols from epihalohydrins, polyhydric alcohols, and metal hydroxides
US5286882A (en) *	1992-10-13	1994-02-15	Shell Oil Company	Polyethercyclicpolyols from epihalohydrins, polyhydric alcohols and metal hydroxides or epoxy alcohol and optionally polyhydric alcohols with addition of epoxy resins
US5428178A (en) *	1992-10-13	1995-06-27	Shell Oil Company	Polyethercyclipolyols from epihalohydrins, polyhydric alcohols, and metal hydroxides or epoxy alcohols and optionally polyhydric alcohols with thermal condensation
WO1994012105A1 (fr) *	1992-12-02	1994-06-09	Shiseido Company, Ltd.	Milieu de contact pour une sonde d'un appareil diagnostique a ultrasons
AU2002227308A1 (en)	2000-11-06	2002-05-15	Lonza Inc.	Processes for preparing linear polyglycerols and polyglycerol esters
US6723304B2 (en)	2001-11-13	2004-04-20	Noville, Inc.	Oral care compositions comprising diglycerol
US6770264B2 (en) *	2001-11-13	2004-08-03	Noville, Inc.	Chewing gum compositions comprising diglycerol
ATE501997T1 (de) *	2003-11-20	2011-04-15	Solvay	Verfahren zur herstellung von dichlorpropanol
CN100577622C (zh) *	2003-11-20	2010-01-06	索尔维公司	从甘油生产二氯丙醇的方法,甘油最终来自生物柴油生产中动物脂肪的转化
CA2608722A1 (en) *	2005-05-20	2006-09-28	Solvay (Societe Anonyme)	Method for making an epoxide starting with a polyhydroxylated aliphatic hydrocarbon and a chlorinating agent
KR20080037613A (ko) *	2005-05-20	2008-04-30	솔베이(소시에떼아노님)	폴리히드록실화 지방족 탄화수소의 클로로히드린으로의전환 방법
MY142392A (en) *	2005-10-26	2010-11-30	Malaysian Palm Oil Board	A process for preparing polymers of polyhydric alcohols
CN101068761B (zh) *	2005-11-08	2011-11-23	索尔维公司	通过甘油的氯化制备二氯丙醇的方法
KR100979372B1 (ko) *	2006-06-14	2010-08-31	솔베이(소시에떼아노님)	조 글리세롤계 생성물, 그 정제방법 및 디클로로프로판올의제조에의 그 용도
FR2913421B1 (fr) *	2007-03-07	2009-05-15	Solvay	Procede de fabrication de dichloropropanol.
FR2913684B1 (fr) *	2007-03-14	2012-09-14	Solvay	Procede de fabrication de dichloropropanol
TW200911740A (en) *	2007-06-01	2009-03-16	Solvay	Process for manufacturing a chlorohydrin
TW200911773A (en)	2007-06-12	2009-03-16	Solvay	Epichlorohydrin, manufacturing process and use
TW200911693A (en)	2007-06-12	2009-03-16	Solvay	Aqueous composition containing a salt, manufacturing process and use
JP2011502032A (ja) *	2007-10-02	2011-01-20	ソルヴェイ（ソシエテアノニム）	容器の耐腐食性を向上させるためのケイ素を含有する組成物の使用
FR2925045B1 (fr)	2007-12-17	2012-02-24	Solvay	Produit a base de glycerol, procede pour son obtention et son utilisation dans la fabrication de dichloropropanol
TWI478875B (zh)	2008-01-31	2015-04-01	Solvay	使水性組成物中之有機物質降解之方法
WO2009121853A1 (en)	2008-04-03	2009-10-08	Solvay (Société Anonyme)	Composition comprising glycerol, process for obtaining same and use thereof in the manufacture of dichloropropanol
FR2935968B1 (fr) *	2008-09-12	2010-09-10	Solvay	Procede pour la purification de chlorure d'hydrogene
JP5502349B2 (ja) *	2009-03-13	2014-05-28	出光興産株式会社	水系潤滑剤
US8101045B2 (en) *	2010-01-05	2012-01-24	Nalco Company	Modifying agent for yankee coatings
JP6049087B2 (ja)	2010-09-30	2016-12-21	ソルヴェイ（ソシエテアノニム）	天然起源のエピクロロヒドリンの誘導体
WO2017200737A1 (en)	2016-05-20	2017-11-23	Stepan Company	Polyetheramine compositions for laundry detergents
US11261295B2 (en)	2017-01-24	2022-03-01	Cargill, Incorporated	Polyglycerol compositions

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE510422C (de) *	1925-12-19	1930-10-18	I G Farbenindustrie Akt Ges	Verfahren zur Herstellung von Oxalkylaethern des Glycerins
US2520670A (en) *	1946-10-24	1950-08-29	Gen Mills Inc	Polyglycerols
US4053525A (en) *	1976-11-01	1977-10-11	Shell Oil Company	Process for production of glycerine
DE3410520A1 (de) *	1984-03-22	1985-09-26	Deutsche Solvay-Werke Gmbh, 5650 Solingen	Verfahren zur herstellung von polyglycerinen durch reinigung und trennung einer waessrigen loesung eines polyglycerinhaltigen produktes

1988
- 1988-03-24 DE DE3809882A patent/DE3809882A1/de not_active Withdrawn
1989
- 1989-01-17 EP EP89100700A patent/EP0333984B1/de not_active Expired - Lifetime
- 1989-01-17 ES ES89100700T patent/ES2053823T3/es not_active Expired - Lifetime
- 1989-01-17 AT AT89100700T patent/ATE87898T1/de not_active IP Right Cessation
- 1989-01-17 DE DE8989100700T patent/DE58903995D1/de not_active Expired - Lifetime
- 1989-03-08 KR KR89002863A patent/KR960008647B1/ko not_active Expired - Fee Related
- 1989-03-20 CA CA000594196A patent/CA1304757C/en not_active Expired - Lifetime
- 1989-03-21 IL IL89692A patent/IL89692A/xx unknown
- 1989-03-22 AU AU31624/89A patent/AU608136B2/en not_active Expired
- 1989-03-23 JP JP1069430A patent/JP2786235B2/ja not_active Expired - Lifetime
- 1989-03-24 US US07/328,316 patent/US4960953A/en not_active Expired - Lifetime
1993
- 1993-06-15 GR GR920403221T patent/GR3008142T3/el unknown

Also Published As

Publication number	Publication date
DE58903995D1 (de)	1993-05-13
DE3809882A1 (de)	1989-10-05
IL89692A0 (en)	1989-09-28
KR890014419A (ko)	1989-10-23
US4960953A (en)	1990-10-02
ATE87898T1 (de)	1993-04-15
AU3162489A (en)	1989-09-28
EP0333984A2 (de)	1989-09-27
EP0333984B1 (de)	1993-04-07
CA1304757C (en)	1992-07-07
GR3008142T3 (2)	1993-09-30
IL89692A (en)	1993-02-21
JPH01283246A (ja)	1989-11-14
KR960008647B1 (en)	1996-06-28
EP0333984A3 (en)	1990-06-13
JP2786235B2 (ja)	1998-08-13
ES2053823T3 (es)	1994-08-01

Legal Events

Date	Code	Title	Description
2000-09-07	PC	Assignment registered	Owner name: ON="SOLVAY" ELEKTROLYSESPEZIALITATEN GMBH; FT="FORMER"

Publication	Publication Date	Title
AU608136B2 (en)	1991-03-21	Process for manufacturing polyglycerines
JP2732921B2 (ja)	1998-03-30	ポリグリセリンの製造法
KR100394184B1 (ko)	2003-11-28	알킬렌글리콜의제조방법
CN101980995B (zh)	2014-06-18	包含甘油的组合物、获得该组合物的方法以及它们在二氯丙醇生产中的用途
AU622013B2 (en)	1992-03-26	Process for reducing propenyl ether concentration in hydroxy-functional polyether compounds
US5354912A (en)	1994-10-11	Method for the removal of dimethyl ether from methyl tertiary butyl ether
US8822736B2 (en)	2014-09-02	Process for preparing polymers of polyhydric alcohols
US7405330B2 (en)	2008-07-29	Preparation of polytrimethylene ether glycol and copolymers thereof
US7238772B2 (en)	2007-07-03	Preparation of polytrimethylene ether glycol and copolymers thereof
US4992594A (en)	1991-02-12	Process for the preparation of polyglycerols
US5043486A (en)	1991-08-27	Aquathermolytic cleavage of ethers
US5072049A (en)	1991-12-10	Process for the preparation of bis(4-hydroxyphenyl) sulfone
WO2001014298A1 (en)	2001-03-01	Process for the purification of fluorinated hydroxyl compounds
US6201137B1 (en)	2001-03-13	Process for purifying tetrahydrofurans used as starting material for polyether polyols
JP3172079B2 (ja)	2001-06-04	プロペニルエーテル化合物の製造方法
KR100210561B1 (ko)	1999-07-15	디알킬아미노프로판디올의 제조방법
JPH0959198A (ja)	1997-03-04	メチルｔｅｒｔ−ブチルエーテルの水洗・回収方法
AU610952B2 (en)	1991-05-30	Process for the preparation of alpha-alkylacroleins
JPH10130181A (ja)	1998-05-19	エチレンオキサイド付加物の製造方法
JPH1017509A (ja)	1998-01-20	ビスフェノール類の製造方法
JPH10139705A (ja)	1998-05-26	エーテル化合物の製造法
JPH0768160B2 (ja)	1995-07-26	アルコキシメチルベンズアルデヒドの製造法
JPH04187653A (ja)	1992-07-06	グリセリンモノアリルエーテルの製法
JPH06329655A (ja)	1994-11-29	ポリアルキル−２−アルコキシ−７−ヒドロキシクロマンの製造方法
JPS5893721A (ja)	1983-06-03	ポリオキシアルキレン−ジシクロペンテニルエ−テルの製造方法