AU624094B2 - Stable detergents containing fluorescent whitening agents - Google Patents

Stable detergents containing fluorescent whitening agents Download PDF

Info

Publication number: AU624094B2
Authority: AU; Australia
Prior art keywords: detergent; textiles; salts; fluorescent whitening; bleaching
Prior art date: 1987-12-23
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Ceased

Application number

AU25932/88A

Other languages

English (en)

Other versions

AU2593288A (en

Inventor

Claude Eckhardt

Jurgen Kaschig

Dieter Reinehr

Kurt Weber

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

BASF Schweiz AG

Original Assignee

Ciba Geigy AG

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1987-12-23

Filing date

1988-11-25

Publication date

1992-06-04

1988-11-25 Application filed by Ciba Geigy AG filed Critical Ciba Geigy AG

1989-07-06 Publication of AU2593288A publication Critical patent/AU2593288A/en

1992-06-04 Application granted granted Critical

1992-06-04 Publication of AU624094B2 publication Critical patent/AU624094B2/en

1997-05-08 Assigned to CIBA SPECIALTY CHEMICALS HOLDING INC. reassignment CIBA SPECIALTY CHEMICALS HOLDING INC. Alteration of Name(s) in Register under S187 Assignors: CIBA-GEIGY AG

2008-11-25 Anticipated expiration legal-status Critical

Status Ceased legal-status Critical Current

Links

239000003599 detergent Substances 0.000 title claims description 42
239000006081 fluorescent whitening agent Substances 0.000 title claims description 28
150000003839 salts Chemical class 0.000 claims description 17
239000004753 textile Substances 0.000 claims description 15
238000004061 bleaching Methods 0.000 claims description 12
239000000203 mixture Substances 0.000 claims description 12
238000005406 washing Methods 0.000 claims description 12
238000000034 method Methods 0.000 claims description 9
150000004966 inorganic peroxy acids Chemical class 0.000 claims description 8
239000002253 acid Substances 0.000 claims description 7
238000004140 cleaning Methods 0.000 claims description 4
150000001768 cations Chemical class 0.000 claims description 2
150000001875 compounds Chemical class 0.000 claims description 2
238000009472 formulation Methods 0.000 claims description 2
229910052736 halogen Inorganic materials 0.000 claims description 2
125000005843 halogen group Chemical group 0.000 claims description 2
229910052739 hydrogen Inorganic materials 0.000 claims description 2
239000001257 hydrogen Substances 0.000 claims description 2
125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 2
238000002156 mixing Methods 0.000 claims description 2
JRKICGRDRMAZLK-UHFFFAOYSA-L peroxydisulfate Chemical compound [O-]S(=O)(=O)OOS([O-])(=O)=O JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 claims description 2
238000002360 preparation method Methods 0.000 claims description 2
MWNQXXOSWHCCOZ-UHFFFAOYSA-L sodium;oxido carbonate Chemical compound [Na+].[O-]OC([O-])=O MWNQXXOSWHCCOZ-UHFFFAOYSA-L 0.000 claims description 2
239000003054 catalyst Substances 0.000 claims 1
150000004965 peroxy acids Chemical class 0.000 description 8
239000011734 sodium Substances 0.000 description 7
239000007844 bleaching agent Substances 0.000 description 6
239000008187 granular material Substances 0.000 description 4
-1 magnesium or calcium Chemical class 0.000 description 4
150000004967 organic peroxy acids Chemical class 0.000 description 3
239000000843 powder Substances 0.000 description 3
229920002134 Carboxymethyl cellulose Polymers 0.000 description 2
IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 2
KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 2
BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 2
238000002835 absorbance Methods 0.000 description 2
150000001340 alkali metals Chemical class 0.000 description 2
235000010948 carboxy methyl cellulose Nutrition 0.000 description 2
239000001768 carboxy methyl cellulose Substances 0.000 description 2
239000008112 carboxymethyl-cellulose Substances 0.000 description 2
239000003795 chemical substances by application Substances 0.000 description 2
UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 2
238000001035 drying Methods 0.000 description 2
230000000694 effects Effects 0.000 description 2
239000000835 fiber Substances 0.000 description 2
239000011777 magnesium Substances 0.000 description 2
229910052751 metal Inorganic materials 0.000 description 2
239000002184 metal Substances 0.000 description 2
239000000344 soap Substances 0.000 description 2
235000019832 sodium triphosphate Nutrition 0.000 description 2
UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 description 2
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
235000021357 Behenic acid Nutrition 0.000 description 1
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical class [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
102000004190 Enzymes Human genes 0.000 description 1
108090000790 Enzymes Proteins 0.000 description 1
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical class [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical class OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 1
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
239000004902 Softening Agent Substances 0.000 description 1
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
238000010521 absorption reaction Methods 0.000 description 1
NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
229920006243 acrylic copolymer Polymers 0.000 description 1
239000012190 activator Substances 0.000 description 1
229910052783 alkali metal Inorganic materials 0.000 description 1
229910052910 alkali metal silicate Inorganic materials 0.000 description 1
229910052784 alkaline earth metal Inorganic materials 0.000 description 1
229910052915 alkaline earth metal silicate Inorganic materials 0.000 description 1
150000001342 alkaline earth metals Chemical class 0.000 description 1
150000003863 ammonium salts Chemical class 0.000 description 1
239000002280 amphoteric surfactant Substances 0.000 description 1
125000000129 anionic group Chemical group 0.000 description 1
239000003945 anionic surfactant Substances 0.000 description 1
239000002216 antistatic agent Substances 0.000 description 1
229940116226 behenic acid Drugs 0.000 description 1
150000001642 boronic acid derivatives Chemical class 0.000 description 1
229910052791 calcium Inorganic materials 0.000 description 1
239000011575 calcium Substances 0.000 description 1
239000003093 cationic surfactant Substances 0.000 description 1
239000011248 coating agent Substances 0.000 description 1
238000000576 coating method Methods 0.000 description 1
239000000470 constituent Substances 0.000 description 1
229910052802 copper Inorganic materials 0.000 description 1
239000010949 copper Substances 0.000 description 1
YRIUSKIDOIARQF-UHFFFAOYSA-N dodecyl benzenesulfonate Chemical compound CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 YRIUSKIDOIARQF-UHFFFAOYSA-N 0.000 description 1
229940071161 dodecylbenzenesulfonate Drugs 0.000 description 1
CQLRGDLBSOUXNO-UHFFFAOYSA-N ethane-1,2-diol;tetradecane Chemical compound OCCO.CCCCCCCCCCCCCC CQLRGDLBSOUXNO-UHFFFAOYSA-N 0.000 description 1
RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
229940071106 ethylenediaminetetraacetate Drugs 0.000 description 1
238000000605 extraction Methods 0.000 description 1
239000006260 foam Substances 0.000 description 1
238000005469 granulation Methods 0.000 description 1
230000003179 granulation Effects 0.000 description 1
238000000227 grinding Methods 0.000 description 1
150000002484 inorganic compounds Chemical class 0.000 description 1
229910052744 lithium Inorganic materials 0.000 description 1
229910052749 magnesium Inorganic materials 0.000 description 1
229910052748 manganese Chemical class 0.000 description 1
239000011572 manganese Chemical class 0.000 description 1
238000005259 measurement Methods 0.000 description 1
MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 description 1
239000002736 nonionic surfactant Substances 0.000 description 1
150000002894 organic compounds Chemical class 0.000 description 1
239000002304 perfume Substances 0.000 description 1
239000000049 pigment Substances 0.000 description 1
229920005646 polycarboxylate Polymers 0.000 description 1
229920005996 polystyrene-poly(ethylene-butylene)-polystyrene Polymers 0.000 description 1
229910052700 potassium Inorganic materials 0.000 description 1
239000011591 potassium Substances 0.000 description 1
239000010453 quartz Substances 0.000 description 1
VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
239000002002 slurry Substances 0.000 description 1
229910052708 sodium Inorganic materials 0.000 description 1
229910052938 sodium sulfate Inorganic materials 0.000 description 1
235000011152 sodium sulphate Nutrition 0.000 description 1
239000000243 solution Substances 0.000 description 1
239000002904 solvent Substances 0.000 description 1
238000002943 spectrophotometric absorbance Methods 0.000 description 1
238000001694 spray drying Methods 0.000 description 1
239000012086 standard solution Substances 0.000 description 1
239000000375 suspending agent Substances 0.000 description 1
229920002994 synthetic fiber Polymers 0.000 description 1
239000003760 tallow Substances 0.000 description 1
QEMXHQIAXOOASZ-UHFFFAOYSA-N tetramethylammonium Chemical compound C[N+](C)(C)C QEMXHQIAXOOASZ-UHFFFAOYSA-N 0.000 description 1
GSEJCLTVZPLZKY-UHFFFAOYSA-O triethanolammonium Chemical compound OCC[NH+](CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-O 0.000 description 1
GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 description 1
239000010457 zeolite Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/40—Dyes ; Pigments
- C11D3/42—Brightening agents ; Blueing agents
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3942—Inorganic per-compounds
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3945—Organic per-compounds

Landscapes

Chemical & Material Sciences (AREA)
Life Sciences & Earth Sciences (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
Oil, Petroleum & Natural Gas (AREA)
Wood Science & Technology (AREA)
Organic Chemistry (AREA)
Inorganic Chemistry (AREA)
Detergent Compositions (AREA)

AU25932/88A 1987-12-23 1988-11-25 Stable detergents containing fluorescent whitening agents Ceased AU624094B2 (en)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
CH5027/87		1987-11-23
CH502787		1987-12-23

Publications (2)

Publication Number	Publication Date
AU2593288A AU2593288A (en)	1989-07-06
AU624094B2 true AU624094B2 (en)	1992-06-04

Family

ID=4286688

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
AU25932/88A Ceased AU624094B2 (en)	1987-12-23	1988-11-25	Stable detergents containing fluorescent whitening agents

Country Status (8)

Country	Link
EP (1)	EP0321715B1 (fr)
JP (1)	JPH02138398A (fr)
AU (1)	AU624094B2 (fr)
BR (1)	BR8806216A (fr)
DE (1)	DE3850232D1 (fr)
ES (1)	ES2054775T3 (fr)
MX (1)	MX169371B (fr)
ZA (1)	ZA888794B (fr)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
EP0317978B1 (fr) *	1987-11-26	1994-12-07	Ciba-Geigy Ag	Détergents stables contenant des azurants optiques
GB8824108D0 (en) *	1988-10-14	1988-11-23	Unilever Plc	Bleaching & detergent compositions
US4970019A (en) *	1988-10-27	1990-11-13	Fmc Corporation	Particulate composition containing bleach and optical brightener and process for its manufacture
ES2085296T3 (es) *	1989-04-28	1996-06-01	Ciba Geigy Ag	Detergentes liquidos.
US5279772A (en) *	1989-04-28	1994-01-18	Ciba-Geigy Corporation	Liquid detergents containing specifically disulfonated dibenzofuranyl-biphenyls as flourescent whitening agents
MX9207050A (es) *	1991-12-19	1993-06-01	Ciba Geigy Ag	Dispersion de blanqueador estable durante el almacenamiento

Citations (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4002423A (en) *	1971-08-13	1977-01-11	Hoechst Aktiengesellschaft	Benzofuran derivatives process for their preparation and their use as optical brighteners
AU2593388A (en) *	1987-11-26	1989-06-01	Ciba Specialty Chemicals Holding Inc.	Stable detergents containing fluorescent whitening agents
AU4279689A (en) *	1988-10-14	1990-04-26	Unilever Plc	Bleaching and detergent compositions

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPS529270B2 (fr) *	1973-06-14	1977-03-15
ES2001074A6 (es) *	1985-08-21	1988-04-16	Clorox Co	Perfeccionamientos en la fabricacion de productos blanqueantes secos basados en diperacidos.

1988
- 1988-11-23 ES ES88119487T patent/ES2054775T3/es not_active Expired - Lifetime
- 1988-11-23 DE DE3850232T patent/DE3850232D1/de not_active Expired - Fee Related
- 1988-11-23 EP EP88119487A patent/EP0321715B1/fr not_active Expired - Lifetime
- 1988-11-24 MX MX013913A patent/MX169371B/es unknown
- 1988-11-24 JP JP63294820A patent/JPH02138398A/ja active Pending
- 1988-11-24 ZA ZA888794A patent/ZA888794B/xx unknown
- 1988-11-25 BR BR888806216A patent/BR8806216A/pt unknown
- 1988-11-25 AU AU25932/88A patent/AU624094B2/en not_active Ceased

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4002423A (en) *	1971-08-13	1977-01-11	Hoechst Aktiengesellschaft	Benzofuran derivatives process for their preparation and their use as optical brighteners
AU2593388A (en) *	1987-11-26	1989-06-01	Ciba Specialty Chemicals Holding Inc.	Stable detergents containing fluorescent whitening agents
AU4279689A (en) *	1988-10-14	1990-04-26	Unilever Plc	Bleaching and detergent compositions

Also Published As

Publication number	Publication date
EP0321715B1 (fr)	1994-06-15
JPH02138398A (ja)	1990-05-28
EP0321715A2 (fr)	1989-06-28
ZA888794B (en)	1989-08-30
ES2054775T3 (es)	1994-08-16
DE3850232D1 (de)	1994-07-21
EP0321715A3 (en)	1989-08-09
BR8806216A (pt)	1989-08-15
AU2593288A (en)	1989-07-06
MX169371B (es)	1993-06-30

Publication	Publication Date	Title
US4064062A (en)	1977-12-20	Stabilized activated percompound bleaching compositions and methods for manufacture thereof
CA1241156A (fr)	1988-08-30	Agent de blanchiment
US5057236A (en)	1991-10-15	Surfactant ion pair fluorescent whitener compositions
US4199466A (en)	1980-04-22	Activated bleaching process and compositions therefor
CN100519719C (zh)	2009-07-29	液体洗涤剂和清洁剂组合物
NO172901B (no)	1993-06-14	Vaskemiddel med lagringsstabilisert blekesystem
US4055505A (en)	1977-10-25	Activated percompound bleaching compositions
US4146496A (en)	1979-03-27	Peroxy bleach system suitable for colored laundry
GB2076011A (en)	1981-11-25	Coated white diphenyl and stilbene fabric brighteners
AU624587B2 (en)	1992-06-18	Stable detergents containing fluorescent whitening agents
AU624094B2 (en)	1992-06-04	Stable detergents containing fluorescent whitening agents
US5035825A (en)	1991-07-30	Stable bleaching detergents containing stilbene fluorescent whitening agents
CA2101289A1 (fr)	1994-02-08	Compositions pour detersif a rendement eleve, reduisant le transfert de la teinture
AU624343B2 (en)	1992-06-11	Stable detergents containing fluorescent whitening agents
AU623869B2 (en)	1992-05-28	Stable detergents containing fluorescent whitening agents
SK281006B6 (sk)	2000-10-09	Časticová detergentná, bieliaca alebo čistiaca zmes
US5230820A (en)	1993-07-27	Storage-stable bleaching detergents containing bis-benzofuranyl fluoescent whitening agents
US4559158A (en)	1985-12-17	Organic cyanamide compounds as activators for inorganic per compounds
US4618445A (en)	1986-10-21	Peroxide bleach and compositions comprising said bleach
US6274664B1 (en)	2001-08-14	Dye-transfer-inhibiting compositions and particulate detergent compositions containing them
CA1090505A (fr)	1980-12-02	Agent de blanchiment
NZ235965A (en)	1992-05-26	Liquid detergent composition containing a fluorescent whitener
US6773625B2 (en)	2004-08-10	Dry bleach compositions
KR100464891B1 (ko)	2005-02-28	개질된알루미노실리케이트
GB2274849A (en)	1994-08-10	Detergent bars containing enzymes.