BE1006539A4 - Procede de synthese d'hydrocarbures a partir de gaz de synthese en presence d'un catalyseur a base de cobalt. - Google Patents

Procede de synthese d'hydrocarbures a partir de gaz de synthese en presence d'un catalyseur a base de cobalt. Download PDF

Info

Publication number: BE1006539A4
Authority: BE; Belgium
Prior art keywords: sep; catalyst; weight; cobalt; hydrocarbons
Prior art date: 1991-06-19

Application number

BE9200575A

Other languages

English (en)

French (fr)

Inventor

Patrick Chaumette

Catherine Verdon

Original Assignee

Inst Francais Du Petrole

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1991-06-19

Filing date

1992-06-19

Publication date

1994-10-11

1992-06-19 Application filed by Inst Francais Du Petrole filed Critical Inst Francais Du Petrole

1994-10-11 Application granted granted Critical

1994-10-11 Publication of BE1006539A4 publication Critical patent/BE1006539A4/fr

Links

239000003054 catalyst Substances 0.000 title claims abstract description 93
229910017052 cobalt Inorganic materials 0.000 title claims abstract description 46
239000010941 cobalt Substances 0.000 title claims abstract description 46
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 title claims abstract description 46
229930195733 hydrocarbon Natural products 0.000 title claims abstract description 45
150000002430 hydrocarbons Chemical class 0.000 title claims abstract description 44
238000000034 method Methods 0.000 title claims abstract description 35
230000008569 process Effects 0.000 title claims abstract description 14
230000015572 biosynthetic process Effects 0.000 title claims description 31
238000003786 synthesis reaction Methods 0.000 title claims description 31
239000000203 mixture Substances 0.000 claims abstract description 31
229910052750 molybdenum Inorganic materials 0.000 claims abstract description 23
ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims abstract description 22
239000011733 molybdenum Substances 0.000 claims abstract description 22
229910052739 hydrogen Inorganic materials 0.000 claims abstract description 13
239000001257 hydrogen Substances 0.000 claims abstract description 13
WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims abstract description 12
229910052721 tungsten Inorganic materials 0.000 claims abstract description 12
239000010937 tungsten Substances 0.000 claims abstract description 11
KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims abstract description 8
238000004519 manufacturing process Methods 0.000 claims abstract description 7
KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 claims abstract description 6
229910052707 ruthenium Inorganic materials 0.000 claims abstract description 6
229930195734 saturated hydrocarbon Natural products 0.000 claims abstract description 6
229910052770 Uranium Inorganic materials 0.000 claims abstract description 5
229910052763 palladium Inorganic materials 0.000 claims abstract description 4
229910052779 Neodymium Inorganic materials 0.000 claims abstract description 3
QEFYFXOXNSNQGX-UHFFFAOYSA-N neodymium atom Chemical compound [Nd] QEFYFXOXNSNQGX-UHFFFAOYSA-N 0.000 claims abstract description 3
239000007789 gas Substances 0.000 claims description 26
UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical class [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 11
229910002091 carbon monoxide Inorganic materials 0.000 claims description 10
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 8
125000004432 carbon atom Chemical group C* 0.000 claims description 7
150000001875 compounds Chemical class 0.000 claims description 7
238000001879 gelation Methods 0.000 claims description 7
239000007791 liquid phase Substances 0.000 claims description 7
239000004215 Carbon black (E152) Substances 0.000 claims description 5
230000009467 reduction Effects 0.000 claims description 5
150000002431 hydrogen Chemical class 0.000 claims description 4
239000011261 inert gas Substances 0.000 claims description 4
229910052726 zirconium Inorganic materials 0.000 claims description 4
229910052719 titanium Inorganic materials 0.000 claims description 3
229910052725 zinc Inorganic materials 0.000 claims description 3
229910052777 Praseodymium Inorganic materials 0.000 claims description 2
229910052782 aluminium Inorganic materials 0.000 claims description 2
238000001354 calcination Methods 0.000 claims description 2
229910002090 carbon oxide Inorganic materials 0.000 claims description 2
PUDIUYLPXJFUGB-UHFFFAOYSA-N praseodymium atom Chemical compound [Pr] PUDIUYLPXJFUGB-UHFFFAOYSA-N 0.000 claims description 2
229910052761 rare earth metal Inorganic materials 0.000 claims description 2
150000002910 rare earth metals Chemical class 0.000 claims description 2
229910052710 silicon Inorganic materials 0.000 claims description 2
229910052718 tin Inorganic materials 0.000 claims description 2
239000003638 chemical reducing agent Substances 0.000 claims 1
DNYWZCXLKNTFFI-UHFFFAOYSA-N uranium Chemical compound [U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U] DNYWZCXLKNTFFI-UHFFFAOYSA-N 0.000 claims 1
JFALSRSLKYAFGM-UHFFFAOYSA-N uranium(0) Chemical compound [U] JFALSRSLKYAFGM-UHFFFAOYSA-N 0.000 abstract description 4
229910052799 carbon Inorganic materials 0.000 abstract description 2
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 1
125000004435 hydrogen atom Chemical class [H]* 0.000 abstract 1
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 100
239000000377 silicon dioxide Substances 0.000 description 46
239000000243 solution Substances 0.000 description 42
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 28
238000005470 impregnation Methods 0.000 description 23
238000002360 preparation method Methods 0.000 description 23
UFMZWBIQTDUYBN-UHFFFAOYSA-N cobalt dinitrate Chemical compound [Co+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O UFMZWBIQTDUYBN-UHFFFAOYSA-N 0.000 description 17
229910001981 cobalt nitrate Inorganic materials 0.000 description 17
229910052757 nitrogen Inorganic materials 0.000 description 16
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 12
229910052700 potassium Inorganic materials 0.000 description 12
239000011591 potassium Substances 0.000 description 12
229910052681 coesite Inorganic materials 0.000 description 10
229910052906 cristobalite Inorganic materials 0.000 description 10
238000003756 stirring Methods 0.000 description 10
229910052682 stishovite Inorganic materials 0.000 description 10
229910052905 tridymite Inorganic materials 0.000 description 10
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
238000006243 chemical reaction Methods 0.000 description 9
239000000047 product Substances 0.000 description 9
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 8
FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 description 8
239000011734 sodium Substances 0.000 description 8
-1 zeolites Chemical compound 0.000 description 8
CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 6
239000007864 aqueous solution Substances 0.000 description 6
230000003197 catalytic effect Effects 0.000 description 6
230000000052 comparative effect Effects 0.000 description 6
150000003839 salts Chemical class 0.000 description 6
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 5
239000002253 acid Substances 0.000 description 5
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 5
238000001816 cooling Methods 0.000 description 5
229910052751 metal Inorganic materials 0.000 description 5
239000002184 metal Substances 0.000 description 5
239000011148 porous material Substances 0.000 description 5
239000000843 powder Substances 0.000 description 5
229910052708 sodium Inorganic materials 0.000 description 5
150000004685 tetrahydrates Chemical class 0.000 description 5
ZSLUVFAKFWKJRC-IGMARMGPSA-N 232Th Chemical compound [232Th] ZSLUVFAKFWKJRC-IGMARMGPSA-N 0.000 description 4
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 4
MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 4
229910052776 Thorium Inorganic materials 0.000 description 4
QGAVSDVURUSLQK-UHFFFAOYSA-N ammonium heptamolybdate Chemical compound N.N.N.N.N.N.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.[Mo].[Mo].[Mo].[Mo].[Mo].[Mo].[Mo] QGAVSDVURUSLQK-UHFFFAOYSA-N 0.000 description 4
238000009835 boiling Methods 0.000 description 4
QGUAJWGNOXCYJF-UHFFFAOYSA-N cobalt dinitrate hexahydrate Chemical compound O.O.O.O.O.O.[Co+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O QGUAJWGNOXCYJF-UHFFFAOYSA-N 0.000 description 4
239000010949 copper Substances 0.000 description 4
238000009826 distribution Methods 0.000 description 4
239000003350 kerosene Substances 0.000 description 4
238000002156 mixing Methods 0.000 description 4
235000010333 potassium nitrate Nutrition 0.000 description 4
239000004323 potassium nitrate Substances 0.000 description 4
239000002244 precipitate Substances 0.000 description 4
OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 4
229910052684 Cerium Inorganic materials 0.000 description 3
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 3
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 3
GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 description 3
KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
229910052802 copper Inorganic materials 0.000 description 3
239000012153 distilled water Substances 0.000 description 3
238000009472 formulation Methods 0.000 description 3
150000002739 metals Chemical class 0.000 description 3
JKQOBWVOAYFWKG-UHFFFAOYSA-N molybdenum trioxide Chemical compound O=[Mo](=O)=O JKQOBWVOAYFWKG-UHFFFAOYSA-N 0.000 description 3
239000000725 suspension Substances 0.000 description 3
101100007418 Caenorhabditis elegans cox-5A gene Proteins 0.000 description 2
VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 2
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 2
MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
125000005595 acetylacetonate group Chemical group 0.000 description 2
125000004429 atom Chemical group 0.000 description 2
238000004517 catalytic hydrocracking Methods 0.000 description 2
229910000422 cerium(IV) oxide Inorganic materials 0.000 description 2
229910052804 chromium Inorganic materials 0.000 description 2
239000011651 chromium Substances 0.000 description 2
238000000975 co-precipitation Methods 0.000 description 2
150000001868 cobalt Chemical class 0.000 description 2
FJDJVBXSSLDNJB-LNTINUHCSA-N cobalt;(z)-4-hydroxypent-3-en-2-one Chemical compound [Co].C\C(O)=C\C(C)=O.C\C(O)=C\C(C)=O.C\C(O)=C\C(C)=O FJDJVBXSSLDNJB-LNTINUHCSA-N 0.000 description 2
239000000446 fuel Substances 0.000 description 2
150000004820 halides Chemical class 0.000 description 2
238000011065 in-situ storage Methods 0.000 description 2
229910052742 iron Inorganic materials 0.000 description 2
239000007788 liquid Substances 0.000 description 2
229910052759 nickel Inorganic materials 0.000 description 2
QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 2
125000002524 organometallic group Chemical group 0.000 description 2
150000003891 oxalate salts Chemical class 0.000 description 2
239000012071 phase Substances 0.000 description 2
BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
230000005070 ripening Effects 0.000 description 2
235000012239 silicon dioxide Nutrition 0.000 description 2
239000007787 solid Substances 0.000 description 2
239000010936 titanium Substances 0.000 description 2
239000011701 zinc Substances 0.000 description 2
VEMKTZHHVJILDY-PMACEKPBSA-N (5-benzylfuran-3-yl)methyl (1r,3s)-2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropane-1-carboxylate Chemical compound CC1(C)[C@@H](C=C(C)C)[C@H]1C(=O)OCC1=COC(CC=2C=CC=CC=2)=C1 VEMKTZHHVJILDY-PMACEKPBSA-N 0.000 description 1
XIOUDVJTOYVRTB-UHFFFAOYSA-N 1-(1-adamantyl)-3-aminothiourea Chemical compound C1C(C2)CC3CC2CC1(NC(=S)NN)C3 XIOUDVJTOYVRTB-UHFFFAOYSA-N 0.000 description 1
QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 description 1
229910000013 Ammonium bicarbonate Inorganic materials 0.000 description 1
241000269350 Anura Species 0.000 description 1
BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 1
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 1
GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 description 1
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
229910002651 NO3 Inorganic materials 0.000 description 1
NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
101001012040 Pseudomonas aeruginosa (strain ATCC 15692 / DSM 22644 / CIP 104116 / JCM 14847 / LMG 12228 / 1C / PRS 101 / PAO1) Immunomodulating metalloprotease Proteins 0.000 description 1
BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 1
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
150000001242 acetic acid derivatives Chemical class 0.000 description 1
238000001994 activation Methods 0.000 description 1
230000004913 activation Effects 0.000 description 1
230000032683 aging Effects 0.000 description 1
230000001476 alcoholic effect Effects 0.000 description 1
150000001336 alkenes Chemical class 0.000 description 1
150000004703 alkoxides Chemical class 0.000 description 1
235000012538 ammonium bicarbonate Nutrition 0.000 description 1
239000001099 ammonium carbonate Substances 0.000 description 1
APUPEJJSWDHEBO-UHFFFAOYSA-P ammonium molybdate Chemical compound [NH4+].[NH4+].[O-][Mo]([O-])(=O)=O APUPEJJSWDHEBO-UHFFFAOYSA-P 0.000 description 1
239000011609 ammonium molybdate Substances 0.000 description 1
229940010552 ammonium molybdate Drugs 0.000 description 1
235000018660 ammonium molybdate Nutrition 0.000 description 1
REROKLPNVNAPBD-UHFFFAOYSA-N azane;tetrahydrate Chemical compound N.O.O.O.O REROKLPNVNAPBD-UHFFFAOYSA-N 0.000 description 1
229910052791 calcium Inorganic materials 0.000 description 1
239000011575 calcium Substances 0.000 description 1
238000005119 centrifugation Methods 0.000 description 1
CETPSERCERDGAM-UHFFFAOYSA-N ceric oxide Chemical compound O=[Ce]=O CETPSERCERDGAM-UHFFFAOYSA-N 0.000 description 1
229910000420 cerium oxide Inorganic materials 0.000 description 1
239000007795 chemical reaction product Substances 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
150000001860 citric acid derivatives Chemical class 0.000 description 1
238000005345 coagulation Methods 0.000 description 1
230000015271 coagulation Effects 0.000 description 1
239000011248 coating agent Substances 0.000 description 1
238000000576 coating method Methods 0.000 description 1
239000000470 constituent Substances 0.000 description 1
SXTLQDJHRPXDSB-UHFFFAOYSA-N copper;dinitrate;trihydrate Chemical compound O.O.O.[Cu+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O SXTLQDJHRPXDSB-UHFFFAOYSA-N 0.000 description 1
229910052593 corundum Inorganic materials 0.000 description 1
238000004821 distillation Methods 0.000 description 1
238000001035 drying Methods 0.000 description 1
238000001125 extrusion Methods 0.000 description 1
238000001914 filtration Methods 0.000 description 1
229910052733 gallium Inorganic materials 0.000 description 1
239000007792 gaseous phase Substances 0.000 description 1
238000000227 grinding Methods 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
229910052500 inorganic mineral Inorganic materials 0.000 description 1
238000005342 ion exchange Methods 0.000 description 1
150000002505 iron Chemical class 0.000 description 1
229910052746 lanthanum Inorganic materials 0.000 description 1
FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 description 1
GJKFIJKSBFYMQK-UHFFFAOYSA-N lanthanum(3+);trinitrate;hexahydrate Chemical compound O.O.O.O.O.O.[La+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O GJKFIJKSBFYMQK-UHFFFAOYSA-N 0.000 description 1
239000011777 magnesium Substances 0.000 description 1
229910052749 magnesium Inorganic materials 0.000 description 1
239000011707 mineral Substances 0.000 description 1
235000010755 mineral Nutrition 0.000 description 1
239000002808 molecular sieve Substances 0.000 description 1
MEFBJEMVZONFCJ-UHFFFAOYSA-N molybdate Chemical compound [O-][Mo]([O-])(=O)=O MEFBJEMVZONFCJ-UHFFFAOYSA-N 0.000 description 1
150000002751 molybdenum Chemical class 0.000 description 1
150000002823 nitrates Chemical class 0.000 description 1
229910017604 nitric acid Inorganic materials 0.000 description 1
239000003960 organic solvent Substances 0.000 description 1
150000002902 organometallic compounds Chemical class 0.000 description 1
235000006408 oxalic acid Nutrition 0.000 description 1
BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 description 1
239000002245 particle Substances 0.000 description 1
238000005453 pelletization Methods 0.000 description 1
229910052697 platinum Inorganic materials 0.000 description 1
239000002243 precursor Substances 0.000 description 1
239000013557 residual solvent Substances 0.000 description 1
229910052702 rhenium Inorganic materials 0.000 description 1
WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 description 1
238000007493 shaping process Methods 0.000 description 1
229910052709 silver Inorganic materials 0.000 description 1
239000004332 silver Substances 0.000 description 1
URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
239000002904 solvent Substances 0.000 description 1
230000006641 stabilisation Effects 0.000 description 1
238000011105 stabilization Methods 0.000 description 1
150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
239000011975 tartaric acid Substances 0.000 description 1
235000002906 tartaric acid Nutrition 0.000 description 1
150000003892 tartrate salts Chemical class 0.000 description 1
238000007725 thermal activation Methods 0.000 description 1
239000011135 tin Substances 0.000 description 1
230000009466 transformation Effects 0.000 description 1
229910052723 transition metal Inorganic materials 0.000 description 1
150000003624 transition metals Chemical class 0.000 description 1
229940077390 uranyl nitrate hexahydrate Drugs 0.000 description 1
238000005406 washing Methods 0.000 description 1
239000001993 wax Substances 0.000 description 1
229910001845 yogo sapphire Inorganic materials 0.000 description 1
239000010457 zeolite Substances 0.000 description 1

Classifications

- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
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Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Chemical Kinetics & Catalysis (AREA)
Engineering & Computer Science (AREA)
Oil, Petroleum & Natural Gas (AREA)
General Chemical & Material Sciences (AREA)
Materials Engineering (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Catalysts (AREA)
Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

BE9200575A 1991-06-19 1992-06-19 Procede de synthese d'hydrocarbures a partir de gaz de synthese en presence d'un catalyseur a base de cobalt. BE1006539A4 (fr)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
FR919107634A FR2677992B1 (fr)	1991-06-19	1991-06-19	Procede de synthese d'hydrocarbures a partir de gaz de synthese en presence d'un catalyseur a base de cobalt.

Publications (1)

Publication Number	Publication Date
BE1006539A4 true BE1006539A4 (fr)	1994-10-11

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ID=9414120

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Application Number	Title	Priority Date	Filing Date
BE9200575A BE1006539A4 (fr)	1991-06-19	1992-06-19	Procede de synthese d'hydrocarbures a partir de gaz de synthese en presence d'un catalyseur a base de cobalt.

Country Status (8)

Country	Link
BE (1)	BE1006539A4 (it)
DE (1)	DE4219690C2 (it)
FR (1)	FR2677992B1 (it)
GB (1)	GB2258414B (it)
IT (1)	IT1263193B (it)
MY (3)	MY113562A (it)
NL (1)	NL194864C (it)
ZA (1)	ZA924473B (it)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
WO1993015836A1 (en) *	1992-02-18	1993-08-19	The Broken Hill Proprietary Company Limited	Praseodymium containing cobalt catalysts for the fischer-tropsch process
DZ2013A1 (fr) *	1995-04-07	2002-10-23	Sastech Ltd	Catalyseurs.
FR2739038B1 (fr) *	1995-09-25	1997-11-21	Inst Francais Du Petrole	Procede de conversion du gaz de synthese en presence d'un catalyseur comprenant du cobalt et des elements additionnels
FR2741064B1 (fr)	1995-11-10	1997-12-12	Inst Francais Du Petrole	Procede de conversion de gaz de synthese en hydrocarbures
US6235677B1 (en)	1998-08-20	2001-05-22	Conoco Inc.	Fischer-Tropsch processes using xerogel and aerogel catalysts by destabilizing aqueous colloids
US20030050349A1 (en) *	2001-08-31	2003-03-13	Conoco Inc.	In-situ desulfurization of a feed stream in a catalytic reactor
US20160067682A1 (en) *	2014-09-10	2016-03-10	Chevron U.S.A. Inc.	Stable Support For Fischer-Tropsch Catalyst
CN116173959B (zh) *	2022-12-12	2024-10-22	陕西科技大学	一种反向ZrO2/Co催化剂及其催化CO2加氢合成C5+烷烃的应用

Citations (3)

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US4039302A (en) *	1976-01-05	1977-08-02	Battelle Development Corporation	Process and catalyst for synthesizing low boiling (C1 to C3) aliphatic hydrocarbons from carbon monoxide and hydrogen
WO1986000296A1 (en) *	1984-06-27	1986-01-16	Union Carbide Corporation	Enhanced catalyst and process for converting synthesis gas to liquid motor fuels
US4632941A (en) *	1984-06-27	1986-12-30	Union Carbide Corporation	Enhanced catalyst and process for converting synthesis gas to liquid motor fuels

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FR2082444A5 (it) *	1970-03-16	1971-12-10	Inst Francais Du Petrole

1991
- 1991-06-19 FR FR919107634A patent/FR2677992B1/fr not_active Expired - Lifetime
1992
- 1992-06-16 DE DE4219690A patent/DE4219690C2/de not_active Expired - Fee Related
- 1992-06-17 IT ITMI921478A patent/IT1263193B/it active IP Right Grant
- 1992-06-18 MY MYPI92001035A patent/MY113562A/en unknown
- 1992-06-18 MY MYPI98003188A patent/MY122270A/en unknown
- 1992-06-18 MY MYPI98003187A patent/MY122299A/en unknown
- 1992-06-18 GB GB9212921A patent/GB2258414B/en not_active Expired - Fee Related
- 1992-06-18 ZA ZA924473A patent/ZA924473B/xx unknown
- 1992-06-19 BE BE9200575A patent/BE1006539A4/fr not_active IP Right Cessation
- 1992-06-19 NL NL9201084A patent/NL194864C/nl not_active IP Right Cessation

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4039302A (en) *	1976-01-05	1977-08-02	Battelle Development Corporation	Process and catalyst for synthesizing low boiling (C1 to C3) aliphatic hydrocarbons from carbon monoxide and hydrogen
WO1986000296A1 (en) *	1984-06-27	1986-01-16	Union Carbide Corporation	Enhanced catalyst and process for converting synthesis gas to liquid motor fuels
US4632941A (en) *	1984-06-27	1986-12-30	Union Carbide Corporation	Enhanced catalyst and process for converting synthesis gas to liquid motor fuels

Also Published As

Publication number	Publication date
NL194864B (nl)	2003-01-06
MY122299A (en)	2006-04-29
ITMI921478A0 (it)	1992-06-17
MY113562A (en)	2002-04-30
DE4219690C2 (de)	2001-01-18
MY122270A (en)	2006-04-29
GB2258414A (en)	1993-02-10
ITMI921478A1 (it)	1993-12-17
DE4219690A1 (de)	1992-12-24
NL194864C (nl)	2003-05-06
IT1263193B (it)	1996-08-02
GB2258414B (en)	1996-02-14
NL9201084A (nl)	1993-01-18
GB9212921D0 (en)	1992-07-29
FR2677992B1 (fr)	1994-09-09
ZA924473B (en)	1993-12-20
FR2677992A1 (fr)	1992-12-24

Legal Events

Date	Code	Title	Description
2011-12-31	RE	Patent lapsed	Effective date: 20110630

Publication	Publication Date	Title
EP0581619B1 (fr)	1997-07-30	Procédé de conversion de gaz de synthèse en hydrocarbures avec un catalyseur à base de cobalt
EP0800864B1 (fr)	2001-09-26	Procédé de conversion du gaz de synthèse en présence d'un catalyseur a base de cobalt et de tinane
JP4225584B2 (ja)	2009-02-18	フィッシャー―トロプシュ法に適する触媒組成物
JP4210338B2 (ja)	2009-01-14	高活性触媒の調製方法ならびに該触媒およびその使用
RU2161067C2 (ru)	2000-12-27	Способ получения катализатора для конверсии синтез-газа, композиция, катализатор и способ синтеза газа
EP1126008A1 (fr)	2001-08-22	Procede de synthese d'hydrocarbures en présence d'un catalyseur comprenant un metal du groupe viii supporte sur silice-alumine
FR2782280A1 (fr)	2000-02-18	Catalyseurs supportes utilisables dans des reactions de transformation de composes organiques
WO2006067285A1 (fr)	2006-06-29	Catalyseur a base de cobalt pour la synthese fischer-tropsch
EP0764465B1 (fr)	1999-12-01	Procédé de conversion du gaz de synthèse en présence d'un catalyseur comprenant du cobalt et des éléments additionnels
BE1006539A4 (fr)	1994-10-11	Procede de synthese d'hydrocarbures a partir de gaz de synthese en presence d'un catalyseur a base de cobalt.
US20020151605A1 (en)	2002-10-17	Increased liquid sensitivity during Fischer-Tropsch synthesis by olefin incorporation
EP0987236B2 (fr)	2016-01-20	Procédé de conversion du gaz de synthèse en présence d'un catalyseur à base de métal du groupe VIII, les particules du métal étant réparties sour forme d'agrégats
RU2201801C2 (ru)	2003-04-10	Способ получения катализатора на основе кобальта и скандия
EP1702025B1 (fr)	2011-02-23	PROCEDE DE TRANSFORMATION D&rsquo;UN GAZ DE SYNTHESE EN HYDROCARBURES EN PRESENCE DE SIC BETA ET EFFLUENT DE CE PROCEDE
CA2280397C (fr)	2011-01-11	Procede de synthese fischer-tropsch en presence d'un catalyseur dont les particules metalliques ont une taille controlee
EP1436360B1 (fr)	2010-04-07	Procede de synthese d'hydrocarbures dans un reacteur triphasique en presence d'un catalyseur comprenant un metal du groupe viii supporte sur zircone ou sur oxyde mixte zircone-alumine
JPS60208929A (ja)	1985-10-21	炭化水素の製造方法
GB2291818A (en)	1996-02-07	Process for the synthesis of hydrocarbons from synthesis gases in the presence of a cobalt-based catalyst
WO2022130344A1 (en)	2022-06-23	Fischer-tropsch processes with modified product selectivity
FR3071749A1 (fr)	2019-04-05	Catalyseur comprenant un alliage ni4w et son utilisation en synthese fischer-tropsch