BE515534A - - Google Patents
Info
- Publication number
- BE515534A BE515534A BE515534DA BE515534A BE 515534 A BE515534 A BE 515534A BE 515534D A BE515534D A BE 515534DA BE 515534 A BE515534 A BE 515534A
- Authority
- BE
- Belgium
- Prior art keywords
- casting
- iron
- titanium
- silicon
- aluminum
- Prior art date
Links
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 12
- 238000005266 casting Methods 0.000 claims description 9
- 229910000831 Steel Inorganic materials 0.000 claims description 7
- 239000010959 steel Substances 0.000 claims description 7
- 229910045601 alloy Inorganic materials 0.000 claims description 6
- 239000000956 alloy Substances 0.000 claims description 6
- 229910052742 iron Inorganic materials 0.000 claims description 6
- 239000000126 substance Substances 0.000 claims description 6
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 4
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 4
- 229910052782 aluminium Inorganic materials 0.000 claims description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 4
- 239000011575 calcium Substances 0.000 claims description 4
- 229910052791 calcium Inorganic materials 0.000 claims description 4
- 239000010936 titanium Substances 0.000 claims description 4
- 229910052719 titanium Inorganic materials 0.000 claims description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 3
- WMOHXRDWCVHXGS-UHFFFAOYSA-N [La].[Ce] Chemical compound [La].[Ce] WMOHXRDWCVHXGS-UHFFFAOYSA-N 0.000 claims description 3
- 229910052799 carbon Inorganic materials 0.000 claims description 3
- 238000002844 melting Methods 0.000 claims description 3
- 230000008018 melting Effects 0.000 claims description 3
- 238000000034 method Methods 0.000 claims description 3
- 229910052710 silicon Inorganic materials 0.000 claims description 3
- 239000010703 silicon Substances 0.000 claims description 3
- 239000012159 carrier gas Substances 0.000 claims description 2
- VNNRSPGTAMTISX-UHFFFAOYSA-N chromium nickel Chemical compound [Cr].[Ni] VNNRSPGTAMTISX-UHFFFAOYSA-N 0.000 claims description 2
- 230000001603 reducing effect Effects 0.000 claims 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims 1
- 239000012535 impurity Substances 0.000 claims 1
- 238000005058 metal casting Methods 0.000 claims 1
- 229910052751 metal Inorganic materials 0.000 description 7
- 239000002184 metal Substances 0.000 description 7
- 239000000843 powder Substances 0.000 description 3
- 238000007792 addition Methods 0.000 description 2
- 238000007664 blowing Methods 0.000 description 2
- 238000011081 inoculation Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- ZSLUVFAKFWKJRC-IGMARMGPSA-N 232Th Chemical compound [232Th] ZSLUVFAKFWKJRC-IGMARMGPSA-N 0.000 description 1
- 229910000851 Alloy steel Inorganic materials 0.000 description 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- 229910052684 Cerium Inorganic materials 0.000 description 1
- 229910052776 Thorium Inorganic materials 0.000 description 1
- 229910001069 Ti alloy Inorganic materials 0.000 description 1
- 229910000756 V alloy Inorganic materials 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- 229910001093 Zr alloy Inorganic materials 0.000 description 1
- ATBAMAFKBVZNFJ-UHFFFAOYSA-N beryllium atom Chemical compound [Be] ATBAMAFKBVZNFJ-UHFFFAOYSA-N 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- OSMSIOKMMFKNIL-UHFFFAOYSA-N calcium;silicon Chemical compound [Ca]=[Si] OSMSIOKMMFKNIL-UHFFFAOYSA-N 0.000 description 1
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 229910052746 lanthanum Inorganic materials 0.000 description 1
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 150000001247 metal acetylides Chemical class 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 229910052712 strontium Inorganic materials 0.000 description 1
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 description 1
- 238000002604 ultrasonography Methods 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21C—PROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
- C21C7/00—Treating molten ferrous alloys, e.g. steel, not covered by groups C21C1/00 - C21C5/00
- C21C7/0068—Treating molten ferrous alloys, e.g. steel, not covered by groups C21C1/00 - C21C5/00 by introducing material into a current of streaming metal
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Multimedia (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Refinement Of Pig-Iron, Manufacture Of Cast Iron, And Steel Manufacture Other Than In Revolving Furnaces (AREA)
Description
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PROCEDE POUR OBTENIR UNE DIMINUTION DU GRAIN DANS LA COULEE EN COQUILLE DE
METAUX A POINT DE FUSION ELEVE TELS QUE LE FER ET L'ACIERo
Dans la coulée à la barre de métaux à point de fusion élevé, par exemple de fer, d'acier ou d'aciers alliés en coquilles métalliques re- froidies par liquide, on peut obtenir des textures de métal diverses. Cer- tains aciers font prise avec une texture à grains relativement fins, d'au- tres sous forme transcristpll ine. Ce sont également ces phénomènes, qui se produisent dans la coulée sous forme de blocs, normale, en coquilles métal- liques. Si la texture transcristalline est fortement marquée, il peut en ré- sulter des difficultés lors du travail à chaud du métal coulé.
On est donc conduit à chercher par des moyens particuliers à obtenir une texture du mé- tal coulé qui soit le plus possible à grains fins. Pour y parvenir on a fait quantité de propositions, par exemple celle qui consiste à faire agir des vibrations sonores ou ultra-sonores ; a également proposé d'assurer l'ob- tention de grains fins par inoculation. On a proposé de disposer dans la co- quille ou d'introduire pendant la coulée des éléments relativement gros, par exemple sous forme d'un paquet de fils, d'un corps de même analyse, qui, du fait qu'il ne se dissout pas complètement, inocule le métal lors de la prise. La proportion de corps a introduire sous forme solide est dans ce pro- cédé de quelques pourcents du volume à couler, toujours de plus de 1%.
Or l'expérience a montré que ces effets d'inoculation peuvent être obtenus d'une façon spécialement avantageuse si l'on utilise plus par- ticulièrement des substances agissant comme des réducteurs, en très petite quantité et de façon très répartie. L'introduction de ces substances exis- tant à l'état de poudre doit, suivant l'invention, être assurée par souffla- ge dans le jet de coulée ou bien par soufflage sur la surface du bain dans la coquille. On a constaté l'efficacité de substances telles que l'aluminium, le titane ou les alliages de titane, le zirconium ou les alliages de zirco- nium, le calcium, le calcium-silicium, le vanadium ou les alliages de vana-
<Desc/Clms Page number 2>
dium, ainsi également que les alliages des éléments énumérés ci-dessus en- tre eux avec éventuellement une teneur additionnelle en fer.
Ces alliages peuvent au surplus contenir de petites quantités de bore, de glucinium, de strontium, de terres rares comme le cérium ou le lanthane ainsi que l'haf- nium ou le thorium. De plus ces alliages peuvent contenir encore du carbone, si bien qu'ils peuvent aussi être utilisés sous forme de carbures, soit en totalité, soit en partie. La grosseur de grains des poudres employées doit être inférieure à 1 mm, de préférence inférieure à 0,3 mm. Ces poudres son± alors soufflées par le moyen connu d'un courant de gaz porteur et de manière connue en soi sur le jet de coulée ou sur la surface du bain dans la coquil- le. L'importance de l'effet de telles additions est surprenante.
On indiquera par exemple qu'un alliage de 15% de calcium, 30% de silicium, 10% d'aluminium, 10% de titane, 3% de cérium-lanthane, le reste de fer, carbone et additions usuelles, utilisé dans la proportion de 0,25% de la matière coulée et comportant une grosseur de grain inférieure à 0,15 mm, a déterminé une diminution surprenante du grain de la matière coulée dans des alliages d'acier au chrome-nickel, qui ont particulièrement tendan- ce à avoir une texture grossière. Rapporté aux mêmes, volumes le nombre de grains cristallins pour un bloc traité suivant l'invention était 30 fois plus grand que pour le bloc de comparaison. Ces moyens sont particulière- ment avantageux dans la coulée d'acier à la barre.
<Desc / Clms Page number 1>
PROCESS FOR OBTAINING A DECREASE OF THE GRAIN IN THE SHELL CAST
HIGH MELTING POINT METALS SUCH AS IRON AND STEEL
In the bar casting of high melting point metals, for example iron, steel or alloy steels in liquid cooled metal shells, various metal textures can be obtained. Some steels set with a relatively fine-grained texture, others in a trans-crystalline form. It is also these phenomena, which occur in the casting in the form of blocks, normal, in metallic shells. If the transcrystalline texture is strongly marked, it may result in difficulty in hot working the cast metal.
We are therefore led to seek by particular means to obtain a texture of the cast metal which is as fine-grained as possible. To achieve this, a number of proposals have been made, for example that which consists in making sound or ultra-sound vibrations act; has also proposed to ensure that fine grains are obtained by inoculation. It has been proposed to place in the shell or to introduce during the casting relatively large elements, for example in the form of a bundle of threads, of a body of the same analysis, which, because it does not not completely dissolve, inoculates the metal upon setting. The proportion of substance to be introduced in solid form is in this process a few percent of the volume to be poured, always more than 1%.
However, experience has shown that these inoculation effects can be obtained in a particularly advantageous manner if substances which act as reducing agents are used more particularly in very small quantities and in a very distributed manner. The introduction of these substances existing in the powder state must, according to the invention, be ensured by blowing in the casting jet or else by blowing on the surface of the bath in the shell. Substances such as aluminum, titanium or titanium alloys, zirconium or zirconium alloys, calcium, calcium-silicon, vanadium or vanadium alloys have been found to be effective.
<Desc / Clms Page number 2>
dium, as well as the alloys of the elements enumerated above together with possibly an additional iron content.
These alloys may additionally contain small amounts of boron, glucinium, strontium, rare earths such as cerium or lanthanum as well as hafinium or thorium. In addition, these alloys can still contain carbon, so that they can also be used in the form of carbides, either in whole or in part. The grain size of the powders used should be less than 1 mm, preferably less than 0.3 mm. These powders are then blown by the known means of a stream of carrier gas and in a manner known per se onto the casting jet or onto the surface of the bath in the shell. The magnitude of the effect of such additions is surprising.
It will be indicated for example that an alloy of 15% calcium, 30% silicon, 10% aluminum, 10% titanium, 3% cerium-lanthanum, the rest of iron, carbon and usual additions, used in the proportion of 0.25% of the cast material and having a grain size of less than 0.15 mm, determined a surprising decrease in the grain of the cast material in chromium-nickel steel alloys, which have a particular tendency. this to have a coarse texture. Compared to the same volumes, the number of crystal grains for a block treated according to the invention was 30 times greater than for the comparison block. These means are particularly advantageous in bar steel casting.
Claims (1)
Publications (1)
| Publication Number | Publication Date |
|---|---|
| BE515534A true BE515534A (en) |
Family
ID=153007
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BE515534D BE515534A (en) |
Country Status (1)
| Country | Link |
|---|---|
| BE (1) | BE515534A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1220617B (en) * | 1958-02-03 | 1966-07-07 | Res Inst Iron Steel | Master alloy for the production of fine-grained steels |
| DE1289660B (en) * | 1958-09-18 | 1969-02-20 | Res Inst Iron Steel | Iron-calcium additive alloy |
-
0
- BE BE515534D patent/BE515534A/fr unknown
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1220617B (en) * | 1958-02-03 | 1966-07-07 | Res Inst Iron Steel | Master alloy for the production of fine-grained steels |
| DE1289660B (en) * | 1958-09-18 | 1969-02-20 | Res Inst Iron Steel | Iron-calcium additive alloy |
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