BE821433A - Procede de preparation de copolymeres styrene-acrylonitrile. - Google Patents
Procede de preparation de copolymeres styrene-acrylonitrile.Info
- Publication number
- BE821433A BE821433A BE149843A BE149843A BE821433A BE 821433 A BE821433 A BE 821433A BE 149843 A BE149843 A BE 149843A BE 149843 A BE149843 A BE 149843A BE 821433 A BE821433 A BE 821433A
- Authority
- BE
- Belgium
- Prior art keywords
- emi
- styrene
- acrylonitrile
- acrylonitrile copolymers
- preparing styrene
- Prior art date
Links
- 238000004519 manufacturing process Methods 0.000 title description 3
- 229920002285 poly(styrene-co-acrylonitrile) Polymers 0.000 title description 2
- 238000000034 method Methods 0.000 claims description 5
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 20
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 9
- 239000003795 chemical substances by application Substances 0.000 description 9
- 239000000178 monomer Substances 0.000 description 7
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 6
- 229920001577 copolymer Polymers 0.000 description 5
- 238000006116 polymerization reaction Methods 0.000 description 5
- 230000001105 regulatory effect Effects 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- 238000007334 copolymerization reaction Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- 229920000638 styrene acrylonitrile Polymers 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 2
- 239000012986 chain transfer agent Substances 0.000 description 2
- AFZSMODLJJCVPP-UHFFFAOYSA-N dibenzothiazol-2-yl disulfide Chemical compound C1=CC=C2SC(SSC=3SC4=CC=CC=C4N=3)=NC2=C1 AFZSMODLJJCVPP-UHFFFAOYSA-N 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- KTZVZZJJVJQZHV-UHFFFAOYSA-N 1-chloro-4-ethenylbenzene Chemical compound ClC1=CC=C(C=C)C=C1 KTZVZZJJVJQZHV-UHFFFAOYSA-N 0.000 description 1
- YAJYJWXEWKRTPO-UHFFFAOYSA-N 2,3,3,4,4,5-hexamethylhexane-2-thiol Chemical compound CC(C)C(C)(C)C(C)(C)C(C)(C)S YAJYJWXEWKRTPO-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 description 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 238000012719 thermal polymerization Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F279/00—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00
- C08F279/02—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00 on to polymers of conjugated dienes
- C08F279/04—Vinyl aromatic monomers and nitriles as the only monomers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
- C08F212/02—Monomers containing only one unsaturated aliphatic radical
- C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
- C08F212/06—Hydrocarbons
- C08F212/08—Styrene
- C08F212/10—Styrene with nitriles
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/42—Nitriles
- C08F220/44—Acrylonitrile
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polymerisation Methods In General (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Graft Or Block Polymers (AREA)
Priority Applications (13)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| BE149843A BE821433A (fr) | 1974-10-24 | 1974-10-24 | Procede de preparation de copolymeres styrene-acrylonitrile. |
| CS125375A CS188939B2 (en) | 1974-10-24 | 1975-02-25 | Process of copolymerisation of styrene and acrylonitrile |
| IT2062175A IT1033162B (it) | 1974-03-01 | 1975-02-25 | Procedimento di copolimerizzazione di stirold e di acrilonitrule e copolimeri ottenuti con tale procedimento |
| CA220,840A CA1033892A (en) | 1974-03-01 | 1975-02-26 | Process for copolymerizing styrene and acrylonitrile |
| GB827275A GB1475449A (en) | 1974-03-01 | 1975-02-27 | Process for copolymerizing styrene and acrylonitrile |
| JP2406675A JPS50124982A (cs) | 1974-03-01 | 1975-02-28 | |
| FR7506245A FR2262674B1 (cs) | 1974-03-01 | 1975-02-28 | |
| AT156375A AT334624B (de) | 1974-03-01 | 1975-02-28 | Verfahren zur copolymerisation von styrol und acrylnitril |
| ES435205A ES435205A1 (es) | 1974-03-01 | 1975-02-28 | Procedimiento de copolimerizacion de estireno y de acriloni-trilo. |
| NL7502394A NL7502394A (nl) | 1974-03-01 | 1975-02-28 | Werkwijze voor het copolymeriseren van styreen en acrylonitril en gevonden voortbrengselen, die geheel of ten dele bestaan uit de aldus bereide copolymeren. |
| AU78703/75A AU7870375A (en) | 1974-03-01 | 1975-02-28 | Copolymerization process |
| DE19752508996 DE2508996C2 (de) | 1974-03-01 | 1975-03-01 | Verfahren zur Herstellung von Copolymeren |
| SU752170161A SU663311A3 (ru) | 1974-10-24 | 1975-09-04 | Способ получени полимерных смол |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| BE149843A BE821433A (fr) | 1974-10-24 | 1974-10-24 | Procede de preparation de copolymeres styrene-acrylonitrile. |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| BE821433A true BE821433A (fr) | 1975-02-17 |
Family
ID=3842709
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BE149843A BE821433A (fr) | 1974-03-01 | 1974-10-24 | Procede de preparation de copolymeres styrene-acrylonitrile. |
Country Status (3)
| Country | Link |
|---|---|
| BE (1) | BE821433A (cs) |
| CS (1) | CS188939B2 (cs) |
| SU (1) | SU663311A3 (cs) |
-
1974
- 1974-10-24 BE BE149843A patent/BE821433A/fr not_active IP Right Cessation
-
1975
- 1975-02-25 CS CS125375A patent/CS188939B2/cs unknown
- 1975-09-04 SU SU752170161A patent/SU663311A3/ru active
Also Published As
| Publication number | Publication date |
|---|---|
| CS188939B2 (en) | 1979-03-30 |
| SU663311A3 (ru) | 1979-05-15 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| RE | Patent lapsed |
Owner name: LABOFINA S.A. Effective date: 19861031 |
|
| RR | Patent reestablished after lapse |
Free format text: 871026 *LABOFINA S.A. |
|
| RE20 | Patent expired |
Owner name: S.A. FINA RESEARCH Effective date: 19941024 |