BE831954A - Procede de preparation des poly (n-alkyliminoalanes) par reaction de l'alulinium sur les amines primaires en presence d'hydrogene - Google Patents

Procede de preparation des poly (n-alkyliminoalanes) par reaction de l'alulinium sur les amines primaires en presence d'hydrogene

Info

Publication number: BE831954A
Authority: BE; Belgium
Prior art keywords: reaction; emi; aluminum; carried out; amine
Prior art date: 1974-08-02

Application number

BE158797A

Other languages

English (en)

French (fr)

Inventor

S Cucinella

A Mazzei

G Dozzi

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1974-08-02

Filing date

1975-07-31

Publication date

1975-11-17

1975-07-31 Application filed filed Critical

1975-11-17 Publication of BE831954A publication Critical patent/BE831954A/fr

Links

238000006243 chemical reaction Methods 0.000 title claims description 43
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical class [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title claims description 18
229910052739 hydrogen Inorganic materials 0.000 title claims description 18
239000001257 hydrogen Substances 0.000 title claims description 18
150000003141 primary amines Chemical class 0.000 title description 6
238000004519 manufacturing process Methods 0.000 title description 3
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 50
229910052782 aluminium Inorganic materials 0.000 claims description 49
238000000034 method Methods 0.000 claims description 21
239000000047 product Substances 0.000 claims description 16
150000001412 amines Chemical class 0.000 claims description 15
239000002904 solvent Substances 0.000 claims description 14
150000004678 hydrides Chemical class 0.000 claims description 9
229910052784 alkaline earth metal Inorganic materials 0.000 claims description 7
-1 aliphatic primary amine Chemical class 0.000 claims description 6
150000001342 alkaline earth metals Chemical class 0.000 claims description 4
239000002798 polar solvent Substances 0.000 claims description 4
239000003513 alkali Substances 0.000 claims description 3
239000007795 chemical reaction product Substances 0.000 claims description 3
229910052751 metal Inorganic materials 0.000 claims description 3
239000002184 metal Substances 0.000 claims description 3
150000001338 aliphatic hydrocarbons Chemical class 0.000 claims description 2
125000000217 alkyl group Chemical group 0.000 claims description 2
150000004982 aromatic amines Chemical class 0.000 claims description 2
125000004432 carbon atom Chemical group C* 0.000 claims description 2
238000000354 decomposition reaction Methods 0.000 claims description 2
125000000524 functional group Chemical group 0.000 claims description 2
125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 2
230000000737 periodic effect Effects 0.000 claims description 2
125000003118 aryl group Chemical group 0.000 claims 1
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 36
239000000243 solution Substances 0.000 description 27
239000000725 suspension Substances 0.000 description 13
IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 12
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 11
238000003756 stirring Methods 0.000 description 10
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 9
238000001914 filtration Methods 0.000 description 8
239000011541 reaction mixture Substances 0.000 description 8
150000001340 alkali metals Chemical class 0.000 description 7
238000004458 analytical method Methods 0.000 description 7
230000015572 biosynthetic process Effects 0.000 description 7
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 6
150000001875 compounds Chemical class 0.000 description 6
238000001819 mass spectrum Methods 0.000 description 6
239000000203 mixture Substances 0.000 description 6
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 6
229910052783 alkali metal Inorganic materials 0.000 description 5
150000002430 hydrocarbons Chemical class 0.000 description 5
JJWLVOIRVHMVIS-UHFFFAOYSA-N isopropylamine Chemical compound CC(C)N JJWLVOIRVHMVIS-UHFFFAOYSA-N 0.000 description 5
VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 5
238000005160 1H NMR spectroscopy Methods 0.000 description 4
239000004215 Carbon black (E152) Substances 0.000 description 4
229930195733 hydrocarbon Natural products 0.000 description 4
150000002500 ions Chemical class 0.000 description 4
238000002360 preparation method Methods 0.000 description 4
239000012265 solid product Substances 0.000 description 4
238000001228 spectrum Methods 0.000 description 4
229910001220 stainless steel Inorganic materials 0.000 description 4
239000010935 stainless steel Substances 0.000 description 4
239000006228 supernatant Substances 0.000 description 4
229910020828 NaAlH4 Inorganic materials 0.000 description 3
229910000831 Steel Inorganic materials 0.000 description 3
229910000086 alane Inorganic materials 0.000 description 3
229910001508 alkali metal halide Inorganic materials 0.000 description 3
150000002466 imines Chemical group 0.000 description 3
229910052757 nitrogen Inorganic materials 0.000 description 3
239000007787 solid Substances 0.000 description 3
239000010959 steel Substances 0.000 description 3
239000000126 substance Substances 0.000 description 3
238000003786 synthesis reaction Methods 0.000 description 3
229910001615 alkaline earth metal halide Inorganic materials 0.000 description 2
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
239000006227 byproduct Substances 0.000 description 2
238000002425 crystallisation Methods 0.000 description 2
230000008025 crystallization Effects 0.000 description 2
238000004949 mass spectrometry Methods 0.000 description 2
239000012299 nitrogen atmosphere Substances 0.000 description 2
229920000642 polymer Polymers 0.000 description 2
238000000926 separation method Methods 0.000 description 2
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
239000002879 Lewis base Substances 0.000 description 1
239000004698 Polyethylene Substances 0.000 description 1
241000786363 Rhampholeon spectrum Species 0.000 description 1
238000002083 X-ray spectrum Methods 0.000 description 1
150000008045 alkali metal halides Chemical class 0.000 description 1
229910000095 alkaline earth hydride Inorganic materials 0.000 description 1
125000005234 alkyl aluminium group Chemical group 0.000 description 1
150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
229910052799 carbon Inorganic materials 0.000 description 1
239000003153 chemical reaction reagent Substances 0.000 description 1
238000001816 cooling Methods 0.000 description 1
150000001993 dienes Chemical class 0.000 description 1
238000001704 evaporation Methods 0.000 description 1
230000008020 evaporation Effects 0.000 description 1
238000000227 grinding Methods 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
230000006698 induction Effects 0.000 description 1
238000002329 infrared spectrum Methods 0.000 description 1
239000013067 intermediate product Substances 0.000 description 1
150000007527 lewis bases Chemical class 0.000 description 1
239000007788 liquid Substances 0.000 description 1
239000007791 liquid phase Substances 0.000 description 1
238000005259 measurement Methods 0.000 description 1
229910001507 metal halide Inorganic materials 0.000 description 1
229910052987 metal hydride Inorganic materials 0.000 description 1
150000004681 metal hydrides Chemical class 0.000 description 1
239000002091 nanocage Substances 0.000 description 1
125000004433 nitrogen atom Chemical group N* 0.000 description 1
229920000573 polyethylene Polymers 0.000 description 1
239000002685 polymerization catalyst Substances 0.000 description 1
238000006116 polymerization reaction Methods 0.000 description 1
229920000098 polyolefin Polymers 0.000 description 1
239000000843 powder Substances 0.000 description 1
BHRZNVHARXXAHW-UHFFFAOYSA-N sec-butylamine Chemical compound CCC(C)N BHRZNVHARXXAHW-UHFFFAOYSA-N 0.000 description 1
239000002002 slurry Substances 0.000 description 1
229910052708 sodium Inorganic materials 0.000 description 1
239000011734 sodium Substances 0.000 description 1
239000010414 supernatant solution Substances 0.000 description 1
230000009466 transformation Effects 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G79/00—Macromolecular compounds obtained by reactions forming a linkage containing atoms other than silicon, sulfur, nitrogen, oxygen, and carbon with or without the latter elements in the main chain of the macromolecule
- C08G79/10—Macromolecular compounds obtained by reactions forming a linkage containing atoms other than silicon, sulfur, nitrogen, oxygen, and carbon with or without the latter elements in the main chain of the macromolecule a linkage containing aluminium
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
- C07F5/06—Aluminium compounds
- C07F5/069—Aluminium compounds without C-aluminium linkages
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)

BE158797A 1974-08-02 1975-07-31 Procede de preparation des poly (n-alkyliminoalanes) par reaction de l'alulinium sur les amines primaires en presence d'hydrogene BE831954A (fr)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
IT25941/74A IT1017876B (it)	1974-08-02	1974-08-02	Processo per la preparazione di poli n.alchil.imminualani

Publications (1)

Publication Number	Publication Date
BE831954A true BE831954A (fr)	1975-11-17

Family

ID=11218205

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
BE158797A BE831954A (fr)	1974-08-02	1975-07-31	Procede de preparation des poly (n-alkyliminoalanes) par reaction de l'alulinium sur les amines primaires en presence d'hydrogene

Country Status (5)

Country	Link
BE (1)	BE831954A (it)
IT (1)	IT1017876B (it)
MW (1)	MW4975A1 (it)
PH (1)	PH14629A (it)
ZA (1)	ZA754810B (it)

1974
- 1974-08-02 IT IT25941/74A patent/IT1017876B/it active
1975
- 1975-07-24 MW MW49/75A patent/MW4975A1/xx unknown
- 1975-07-25 ZA ZA00754810A patent/ZA754810B/xx unknown
- 1975-07-31 BE BE158797A patent/BE831954A/fr not_active IP Right Cessation
- 1975-07-31 PH PH17430A patent/PH14629A/en unknown

Also Published As

Publication number	Publication date
IT1017876B (it)	1977-08-10
MW4975A1 (en)	1976-10-13
ZA754810B (en)	1976-07-28
PH14629A (en)	1981-10-12

Legal Events

Date

Code

Title

Description

1988-01-31

RE

Patent lapsed

Owner name: SNAMPROGETTI S.P.A.

Effective date: 19870731

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