BG108046A - Метод за едновременно отстраняване на азотни окиси и райски газ от газов поток, съдържащ азотни окиси и райски газ - Google Patents
Метод за едновременно отстраняване на азотни окиси и райски газ от газов поток, съдържащ азотни окиси и райски газ Download PDFInfo
- Publication number
- BG108046A BG108046A BG108046A BG10804603A BG108046A BG 108046 A BG108046 A BG 108046A BG 108046 A BG108046 A BG 108046A BG 10804603 A BG10804603 A BG 10804603A BG 108046 A BG108046 A BG 108046A
- Authority
- BG
- Bulgaria
- Prior art keywords
- catalyst
- gas
- nitrogen oxides
- carrier
- paradise
- Prior art date
Links
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 title claims abstract description 88
- 239000007789 gas Substances 0.000 title claims abstract description 72
- 238000000034 method Methods 0.000 title claims abstract description 21
- GQPLMRYTRLFLPF-UHFFFAOYSA-N Nitrous Oxide Chemical compound [O-][N+]#N GQPLMRYTRLFLPF-UHFFFAOYSA-N 0.000 title abstract description 12
- 235000013842 nitrous oxide Nutrition 0.000 title abstract 5
- 239000003054 catalyst Substances 0.000 claims abstract description 130
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 27
- 229910017052 cobalt Inorganic materials 0.000 claims abstract description 16
- 239000010941 cobalt Substances 0.000 claims abstract description 16
- 229910044991 metal oxide Inorganic materials 0.000 claims abstract description 15
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims abstract description 14
- 229910052742 iron Inorganic materials 0.000 claims abstract description 14
- 150000004706 metal oxides Chemical class 0.000 claims abstract description 14
- 229930195734 saturated hydrocarbon Natural products 0.000 claims abstract description 9
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims abstract description 5
- 229910017604 nitric acid Inorganic materials 0.000 claims abstract description 5
- 239000010457 zeolite Substances 0.000 claims description 26
- 229910021536 Zeolite Inorganic materials 0.000 claims description 24
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical group O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 23
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 20
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 claims description 16
- 239000001294 propane Substances 0.000 claims description 8
- 229910052763 palladium Inorganic materials 0.000 claims description 5
- 229910052697 platinum Inorganic materials 0.000 claims description 4
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 3
- 229910052782 aluminium Inorganic materials 0.000 claims description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 3
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 claims description 3
- 229920001296 polysiloxane Polymers 0.000 claims description 3
- 239000003345 natural gas Substances 0.000 claims description 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims 1
- 239000003546 flue gas Substances 0.000 claims 1
- 238000006243 chemical reaction Methods 0.000 description 53
- 239000000203 mixture Substances 0.000 description 20
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 11
- QQONPFPTGQHPMA-UHFFFAOYSA-N Propene Chemical compound CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 10
- 229910052760 oxygen Inorganic materials 0.000 description 7
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Substances [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 6
- 229910052757 nitrogen Inorganic materials 0.000 description 6
- 239000001301 oxygen Substances 0.000 description 6
- 230000000694 effects Effects 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 230000008901 benefit Effects 0.000 description 4
- 239000003638 chemical reducing agent Substances 0.000 description 4
- -1 paradise gas (see Chemical class 0.000 description 4
- 230000009467 reduction Effects 0.000 description 4
- 238000006722 reduction reaction Methods 0.000 description 4
- 230000002411 adverse Effects 0.000 description 3
- 238000010531 catalytic reduction reaction Methods 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 229910052680 mordenite Inorganic materials 0.000 description 3
- 239000010948 rhodium Substances 0.000 description 3
- 229910052703 rhodium Inorganic materials 0.000 description 3
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 229910019931 (NH4)2Fe(SO4)2 Inorganic materials 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- QGUAJWGNOXCYJF-UHFFFAOYSA-N cobalt dinitrate hexahydrate Chemical compound O.O.O.O.O.O.[Co+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O QGUAJWGNOXCYJF-UHFFFAOYSA-N 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 230000000737 periodic effect Effects 0.000 description 2
- 239000010970 precious metal Substances 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 239000007858 starting material Substances 0.000 description 2
- 230000009466 transformation Effects 0.000 description 2
- 238000000844 transformation Methods 0.000 description 2
- 239000002912 waste gas Substances 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- 238000005033 Fourier transform infrared spectroscopy Methods 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 239000003426 co-catalyst Substances 0.000 description 1
- 150000001868 cobalt Chemical class 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 238000004868 gas analysis Methods 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 229910052741 iridium Inorganic materials 0.000 description 1
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- VUZPPFZMUPKLLV-UHFFFAOYSA-N methane;hydrate Chemical compound C.O VUZPPFZMUPKLLV-UHFFFAOYSA-N 0.000 description 1
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 239000001272 nitrous oxide Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000012694 precious metal precursor Substances 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
- B01D53/8621—Removing nitrogen compounds
- B01D53/8625—Nitrogen oxides
- B01D53/8628—Processes characterised by a specific catalyst
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/40—Nitrogen compounds
- B01D2257/402—Dinitrogen oxide
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
- Y02C20/00—Capture or disposal of greenhouse gases
- Y02C20/10—Capture or disposal of greenhouse gases of nitrous oxide (N2O)
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Biomedical Technology (AREA)
- Analytical Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Catalysts (AREA)
- Exhaust Gas Treatment By Means Of Catalyst (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Treating Waste Gases (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NL1017245A NL1017245C2 (nl) | 2001-01-31 | 2001-01-31 | Werkwijze voor het gelijktijdig verwijderen van stikstofoxiden en lachgas uit een stikstofoxiden en lachgas bevattende gasstroom. |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| BG108046A true BG108046A (bg) | 2005-04-30 |
Family
ID=19772822
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BG108046A BG108046A (bg) | 2001-01-31 | 2003-07-31 | Метод за едновременно отстраняване на азотни окиси и райски газ от газов поток, съдържащ азотни окиси и райски газ |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US7011801B2 (pl) |
| EP (1) | EP1355725B1 (pl) |
| AT (1) | ATE280631T1 (pl) |
| BG (1) | BG108046A (pl) |
| DE (1) | DE60201730T2 (pl) |
| ES (1) | ES2231665T3 (pl) |
| NL (1) | NL1017245C2 (pl) |
| NO (1) | NO20033231L (pl) |
| PL (1) | PL363860A1 (pl) |
| PT (1) | PT1355725E (pl) |
| WO (1) | WO2002060563A1 (pl) |
Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2002068117A1 (en) * | 2001-02-28 | 2002-09-06 | Showa Denko K. K. | Decomposition catalyst for nitrous oxide, process for producing the same and process for decomposing nitrous oxide |
| US20040247498A1 (en) * | 2003-06-04 | 2004-12-09 | Jonathan Phillips | Catalytic reactor system |
| DE102004024026A1 (de) * | 2004-03-11 | 2005-09-29 | W.C. Heraeus Gmbh | Katalysator zur N2O-Zersetzung beim Ostwaldprozess |
| EP1640434A1 (en) * | 2004-09-22 | 2006-03-29 | Indian Oil Corporation Limited | Hydrocracking process and catalyst composition |
| EP1819422B1 (en) * | 2004-11-30 | 2014-07-30 | Showa Denko K.K. | Treatment method and treatment apparatus for gas containing nitrous oxide |
| DE102007003155A1 (de) | 2007-01-22 | 2008-07-24 | Süd-Chemie AG | Katalysatorzusammensetzung zur Reduktion von Stickoxiden |
| DE102007034284A1 (de) * | 2007-07-20 | 2009-01-22 | Leibniz-Institut Für Katalyse E.V. An Der Universität Rostock | Verfahren zur katalytischen N2O-Reduktion mit gleichzeitiger Gewinnung von Wasserstoff und leichten Alkenen |
| DE102011121188A1 (de) * | 2011-12-16 | 2013-06-20 | Thyssen Krupp Uhde Gmbh | Vorrichtung und Verfahren zur Beseitigung von NOx und N20 |
| US8858907B2 (en) | 2012-08-09 | 2014-10-14 | Exxonmobil Research And Engineering Company | Catalytic reduction of NOx with high activity catalysts with NH3 reductant |
| US8815195B2 (en) | 2012-08-09 | 2014-08-26 | Exxonmobil Research And Engineering Company | Catalytic reduction of NOx with high activity catalysts with propylene reductant |
| US8795621B2 (en) | 2012-08-09 | 2014-08-05 | Exxonmobil Research And Engineering | Catalytic reduction of NOx with high activity catalysts with acetaldehyde reductant |
| US8834823B2 (en) | 2012-08-09 | 2014-09-16 | Exxonmobil Research And Engineering Company | Catalytic reduction of NOx with high activity catalysts |
| WO2018077554A1 (en) | 2016-10-28 | 2018-05-03 | Casale Sa | A method for removing nitrogen oxides from a gas using an iron exchanged zeolite catalyst |
| EP3162427A1 (en) | 2015-10-28 | 2017-05-03 | Casale SA | A method and apparatus for removing nox and n2o from a gas |
| CN111108063B (zh) | 2017-11-30 | 2024-01-16 | 卡萨乐有限公司 | 三级减排n2o和nox生产硝酸的方法 |
| CN113198525B (zh) * | 2021-05-08 | 2023-05-09 | 北京工业大学 | 一种低温条件下笑气分解和NOx催化还原协同净化的催化剂及其制备方法 |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4003976A (en) * | 1973-04-03 | 1977-01-18 | Kabushiki Kaisha Toyota Chuo Kenkyusho | Converter for the purification of exhaust gases |
| GB2162830B (en) * | 1984-08-10 | 1988-08-10 | Babcock Hitachi Kk | Ammonia reduction-denitration process and apparatus therefor |
| JPH04243525A (ja) * | 1991-01-22 | 1992-08-31 | Toyota Motor Corp | 内燃機関の排気浄化装置 |
| US5149512A (en) * | 1991-08-01 | 1992-09-22 | Air Products And Chemicals, Inc. | Catalytic reduction of NOx using methane in the presence of oxygen |
| US5171553A (en) * | 1991-11-08 | 1992-12-15 | Air Products And Chemicals, Inc. | Catalytic decomposition of N2 O |
| EP0664147B1 (en) * | 1994-01-20 | 1998-07-22 | Toyota Jidosha Kabushiki Kaisha | Catalyst for purifying exhaust gases |
| EP0935055B1 (en) * | 1998-02-05 | 2006-01-11 | Nissan Motor Company, Limited | Method for purifying oxygen rich exhaust gas |
| NL1008746C2 (nl) * | 1998-03-30 | 1999-10-01 | Stichting Energie | Werkwijze voor het omzetten van distikstofoxide. |
| NL1013862C2 (nl) * | 1999-09-06 | 2001-03-08 | Stichting Energie | Reductie van N#2O emissies. |
| WO2001074475A1 (de) | 2000-04-03 | 2001-10-11 | Basf Aktiengesellschaft | Katalysatorsystem zur zersetzung von n2o |
-
2001
- 2001-01-31 NL NL1017245A patent/NL1017245C2/nl not_active IP Right Cessation
-
2002
- 2002-01-31 EP EP20020700886 patent/EP1355725B1/en not_active Expired - Lifetime
- 2002-01-31 ES ES02700886T patent/ES2231665T3/es not_active Expired - Lifetime
- 2002-01-31 AT AT02700886T patent/ATE280631T1/de active
- 2002-01-31 DE DE60201730T patent/DE60201730T2/de not_active Expired - Lifetime
- 2002-01-31 PT PT02700886T patent/PT1355725E/pt unknown
- 2002-01-31 US US10/470,756 patent/US7011801B2/en not_active Expired - Fee Related
- 2002-01-31 WO PCT/NL2002/000075 patent/WO2002060563A1/en not_active Ceased
- 2002-01-31 PL PL02363860A patent/PL363860A1/pl unknown
-
2003
- 2003-07-17 NO NO20033231A patent/NO20033231L/no not_active Application Discontinuation
- 2003-07-31 BG BG108046A patent/BG108046A/bg unknown
Also Published As
| Publication number | Publication date |
|---|---|
| ATE280631T1 (de) | 2004-11-15 |
| US20040109804A1 (en) | 2004-06-10 |
| PL363860A1 (pl) | 2004-11-29 |
| DE60201730T2 (de) | 2005-03-10 |
| ES2231665T3 (es) | 2005-05-16 |
| EP1355725A1 (en) | 2003-10-29 |
| US7011801B2 (en) | 2006-03-14 |
| DE60201730D1 (de) | 2004-12-02 |
| NL1017245C2 (nl) | 2002-08-01 |
| EP1355725B1 (en) | 2004-10-27 |
| NO20033231L (no) | 2003-09-25 |
| WO2002060563A1 (en) | 2002-08-08 |
| NO20033231D0 (no) | 2003-07-17 |
| PT1355725E (pt) | 2005-01-31 |
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