BG64217B1 - Използване на катализатори за получаване на пенополиуретан, метод за получаване и композиция - Google Patents

Използване на катализатори за получаване на пенополиуретан, метод за получаване и композиция Download PDF

Info

Publication number: BG64217B1
Authority: BG; Bulgaria
Prior art keywords: catalyst; water; foam; isocyanate; acid
Prior art date: 1996-11-08

Application number

BG103422A

Other languages

Bulgarian (bg)

English (en)

Other versions

BG103422A (en

Inventor

Berend Eling

Original Assignee

Huntsman International Llc

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1996-11-08

Filing date

1999-05-20

Publication date

2004-05-31

1999-05-20 Application filed by Huntsman International Llc filed Critical Huntsman International Llc

2000-01-31 Publication of BG103422A publication Critical patent/BG103422A/xx

2004-05-31 Publication of BG64217B1 publication Critical patent/BG64217B1/bg

Links

238000000034 method Methods 0.000 title claims abstract description 31
229920002635 polyurethane Polymers 0.000 title claims abstract description 10
239000004814 polyurethane Substances 0.000 title claims abstract description 10
239000003054 catalyst Substances 0.000 title claims description 105
239000000203 mixture Substances 0.000 title claims description 55
238000002360 preparation method Methods 0.000 title claims description 25
239000006260 foam Substances 0.000 claims abstract description 109
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 60
239000002253 acid Substances 0.000 claims abstract description 35
125000004435 hydrogen atom Chemical group [H]* 0.000 claims abstract description 19
150000003839 salts Chemical class 0.000 claims abstract description 14
150000003077 polyols Chemical class 0.000 claims description 119
229920005862 polyol Polymers 0.000 claims description 102
229920001228 polyisocyanate Polymers 0.000 claims description 59
239000005056 polyisocyanate Substances 0.000 claims description 59
229920005830 Polyurethane Foam Polymers 0.000 claims description 44
239000011496 polyurethane foam Substances 0.000 claims description 44
150000001875 compounds Chemical class 0.000 claims description 36
239000012948 isocyanate Substances 0.000 claims description 34
125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 31
150000002513 isocyanates Chemical class 0.000 claims description 31
238000006243 chemical reaction Methods 0.000 claims description 24
239000004615 ingredient Substances 0.000 claims description 13
239000011734 sodium Substances 0.000 claims description 13
239000000126 substance Substances 0.000 claims description 11
238000005187 foaming Methods 0.000 claims description 10
239000007787 solid Substances 0.000 claims description 10
230000002378 acidificating effect Effects 0.000 claims description 9
150000007513 acids Chemical class 0.000 claims description 9
150000001412 amines Chemical class 0.000 claims description 9
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 8
DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 claims description 8
238000004519 manufacturing process Methods 0.000 claims description 7
125000004432 carbon atom Chemical group C* 0.000 claims description 6
ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical class [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 5
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230000009477 glass transition Effects 0.000 claims description 4
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229920000867 polyelectrolyte Polymers 0.000 claims description 4
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229910052791 calcium Inorganic materials 0.000 claims description 3
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229910052744 lithium Inorganic materials 0.000 claims description 3
229910052749 magnesium Inorganic materials 0.000 claims description 3
239000011777 magnesium Substances 0.000 claims description 3
229910052700 potassium Inorganic materials 0.000 claims description 3
229910052701 rubidium Inorganic materials 0.000 claims description 3
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 2
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239000011591 potassium Substances 0.000 claims description 2
239000000376 reactant Substances 0.000 claims description 2
IGLNJRXAVVLDKE-UHFFFAOYSA-N rubidium atom Chemical compound [Rb] IGLNJRXAVVLDKE-UHFFFAOYSA-N 0.000 claims description 2
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XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 claims 1
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IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 description 8
150000001414 amino alcohols Chemical class 0.000 description 7
239000008259 solid foam Substances 0.000 description 7
XSQUKJJJFZCRTK-UHFFFAOYSA-N urea group Chemical group NC(=O)N XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 7
QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 6
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125000003118 aryl group Chemical group 0.000 description 6
238000007906 compression Methods 0.000 description 6
230000006835 compression Effects 0.000 description 6
239000011975 tartaric acid Substances 0.000 description 6
235000002906 tartaric acid Nutrition 0.000 description 6
PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 5
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 5
230000015572 biosynthetic process Effects 0.000 description 5
CDQSJQSWAWPGKG-UHFFFAOYSA-N butane-1,1-diol Chemical compound CCCC(O)O CDQSJQSWAWPGKG-UHFFFAOYSA-N 0.000 description 5
150000001718 carbodiimides Chemical class 0.000 description 5
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ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 5
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238000007046 ethoxylation reaction Methods 0.000 description 5
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125000004433 nitrogen atom Chemical group N* 0.000 description 5
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238000012360 testing method Methods 0.000 description 5
239000012974 tin catalyst Substances 0.000 description 5
BOZRCGLDOHDZBP-UHFFFAOYSA-N 2-ethylhexanoic acid;tin Chemical compound [Sn].CCCCC(CC)C(O)=O BOZRCGLDOHDZBP-UHFFFAOYSA-N 0.000 description 4
UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 description 4
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125000006353 oxyethylene group Chemical group 0.000 description 4
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JOYRKODLDBILNP-UHFFFAOYSA-N urethane group Chemical group NC(=O)OCC JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 4
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URDCARMUOSMFFI-UHFFFAOYSA-N 2-[2-[bis(carboxymethyl)amino]ethyl-(2-hydroxyethyl)amino]acetic acid Chemical compound OCCN(CC(O)=O)CCN(CC(O)=O)CC(O)=O URDCARMUOSMFFI-UHFFFAOYSA-N 0.000 description 3
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229910019142 PO4 Inorganic materials 0.000 description 1
239000002202 Polyethylene glycol Substances 0.000 description 1
OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
101100163890 Rattus norvegicus Ascl2 gene Proteins 0.000 description 1
FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 1
239000012963 UV stabilizer Substances 0.000 description 1
UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 description 1
150000001243 acetic acids Chemical class 0.000 description 1
230000000996 additive effect Effects 0.000 description 1
239000002671 adjuvant Substances 0.000 description 1
150000007933 aliphatic carboxylic acids Chemical class 0.000 description 1
239000003513 alkali Substances 0.000 description 1
150000004703 alkoxides Chemical class 0.000 description 1
230000000843 anti-fungal effect Effects 0.000 description 1
230000000845 anti-microbial effect Effects 0.000 description 1
229940121375 antifungal agent Drugs 0.000 description 1
230000003078 antioxidant effect Effects 0.000 description 1
239000002216 antistatic agent Substances 0.000 description 1
150000004945 aromatic hydrocarbons Chemical group 0.000 description 1
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Inorganic materials [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 1
VJRITMATACIYAF-UHFFFAOYSA-N benzenesulfonohydrazide Chemical compound NNS(=O)(=O)C1=CC=CC=C1 VJRITMATACIYAF-UHFFFAOYSA-N 0.000 description 1
229920001400 block copolymer Polymers 0.000 description 1
STIAPHVBRDNOAJ-UHFFFAOYSA-N carbamimidoylazanium;carbonate Chemical compound NC(N)=N.NC(N)=N.OC(O)=O STIAPHVBRDNOAJ-UHFFFAOYSA-N 0.000 description 1
239000001569 carbon dioxide Substances 0.000 description 1
229910002092 carbon dioxide Inorganic materials 0.000 description 1
230000001413 cellular effect Effects 0.000 description 1
239000007795 chemical reaction product Substances 0.000 description 1
238000000576 coating method Methods 0.000 description 1
239000003086 colorant Substances 0.000 description 1
239000000470 constituent Substances 0.000 description 1
238000010276 construction Methods 0.000 description 1
238000005520 cutting process Methods 0.000 description 1
XHMWGEWUBYMZDB-UHFFFAOYSA-N cyclooctane-1,1-diamine Chemical compound NC1(N)CCCCCCC1 XHMWGEWUBYMZDB-UHFFFAOYSA-N 0.000 description 1
230000006866 deterioration Effects 0.000 description 1
239000012975 dibutyltin dilaurate Substances 0.000 description 1
239000002526 disodium citrate Substances 0.000 description 1
235000019262 disodium citrate Nutrition 0.000 description 1
238000010494 dissociation reaction Methods 0.000 description 1
230000005593 dissociations Effects 0.000 description 1
230000000694 effects Effects 0.000 description 1
239000000839 emulsion Substances 0.000 description 1
238000005516 engineering process Methods 0.000 description 1
239000000835 fiber Substances 0.000 description 1
239000004872 foam stabilizing agent Substances 0.000 description 1
239000003365 glass fiber Substances 0.000 description 1
239000010440 gypsum Substances 0.000 description 1
229910052602 gypsum Inorganic materials 0.000 description 1
230000003301 hydrolyzing effect Effects 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
229910052500 inorganic mineral Inorganic materials 0.000 description 1
239000011810 insulating material Substances 0.000 description 1
238000010030 laminating Methods 0.000 description 1
239000004816 latex Substances 0.000 description 1
229920000126 latex Polymers 0.000 description 1
150000002611 lead compounds Chemical class 0.000 description 1
VQPKAMAVKYTPLB-UHFFFAOYSA-N lead;octanoic acid Chemical compound [Pb].CCCCCCCC(O)=O VQPKAMAVKYTPLB-UHFFFAOYSA-N 0.000 description 1
VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
239000011976 maleic acid Substances 0.000 description 1
238000005259 measurement Methods 0.000 description 1
JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 1
229910000000 metal hydroxide Inorganic materials 0.000 description 1
150000004692 metal hydroxides Chemical class 0.000 description 1
239000000401 methanolic extract Substances 0.000 description 1
239000011707 mineral Substances 0.000 description 1
150000007522 mineralic acids Chemical class 0.000 description 1
150000002763 monocarboxylic acids Chemical class 0.000 description 1
239000000178 monomer Substances 0.000 description 1
238000000465 moulding Methods 0.000 description 1
238000006386 neutralization reaction Methods 0.000 description 1
239000001301 oxygen Substances 0.000 description 1
229910052760 oxygen Inorganic materials 0.000 description 1
238000004806 packaging method and process Methods 0.000 description 1
239000002245 particle Substances 0.000 description 1
239000011049 pearl Substances 0.000 description 1
235000021317 phosphate Nutrition 0.000 description 1
230000000704 physical effect Effects 0.000 description 1
229920003023 plastic Polymers 0.000 description 1
239000004033 plastic Substances 0.000 description 1
229920000771 poly (alkylcyanoacrylate) Polymers 0.000 description 1
229920000162 poly(ureaurethane) Polymers 0.000 description 1
239000004584 polyacrylic acid Substances 0.000 description 1
229920001223 polyethylene glycol Polymers 0.000 description 1
229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 description 1
FRMWBRPWYBNAFB-UHFFFAOYSA-M potassium salicylate Chemical compound [K+].OC1=CC=CC=C1C([O-])=O FRMWBRPWYBNAFB-UHFFFAOYSA-M 0.000 description 1
229960003629 potassium salicylate Drugs 0.000 description 1
230000002028 premature Effects 0.000 description 1
235000019260 propionic acid Nutrition 0.000 description 1
IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
150000004760 silicates Chemical class 0.000 description 1
239000011780 sodium chloride Substances 0.000 description 1
239000001509 sodium citrate Substances 0.000 description 1
239000002904 solvent Substances 0.000 description 1
239000011493 spray foam Substances 0.000 description 1
239000003381 stabilizer Substances 0.000 description 1
238000003860 storage Methods 0.000 description 1
229910052712 strontium Inorganic materials 0.000 description 1
229940014800 succinic anhydride Drugs 0.000 description 1
239000004094 surface-active agent Substances 0.000 description 1
150000003512 tertiary amines Chemical class 0.000 description 1
238000002076 thermal analysis method Methods 0.000 description 1
238000004448 titration Methods 0.000 description 1
VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
230000007704 transition Effects 0.000 description 1
CYRMSUTZVYGINF-UHFFFAOYSA-N trichlorofluoromethane Chemical compound FC(Cl)(Cl)Cl CYRMSUTZVYGINF-UHFFFAOYSA-N 0.000 description 1
150000004072 triols Chemical group 0.000 description 1
229940038773 trisodium citrate Drugs 0.000 description 1
239000006200 vaporizer Substances 0.000 description 1
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
229920002554 vinyl polymer Polymers 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/16—Catalysts
- C08G18/22—Catalysts containing metal compounds
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0008—Foam properties flexible
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0025—Foam properties rigid
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0083—Foam properties prepared using water as the sole blowing agent

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Polyurethanes Or Polyureas (AREA)
Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)

BG103422A 1996-11-08 1999-05-20 Използване на катализатори за получаване на пенополиуретан, метод за получаване и композиция BG64217B1 (bg)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
EP96203133		1996-11-08
PCT/EP1997/005507 WO1998021254A1 (fr)	1996-11-08	1997-10-07	Procede de preparation de mousses rigides ou souples de polyurethane

Publications (2)

Publication Number	Publication Date
BG103422A BG103422A (en)	2000-01-31
BG64217B1 true BG64217B1 (bg)	2004-05-31

Family

ID=8224567

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
BG103422A BG64217B1 (bg)	1996-11-08	1999-05-20	Използване на катализатори за получаване на пенополиуретан, метод за получаване и композиция

Country Status (27)

Country	Link
US (2)	US6100311A (fr)
EP (1)	EP0937109B1 (fr)
JP (2)	JP4021939B2 (fr)
KR (1)	KR100544935B1 (fr)
AR (3)	AR010278A1 (fr)
AT (1)	ATE234334T1 (fr)
AU (1)	AU731094B2 (fr)
BG (1)	BG64217B1 (fr)
BR (1)	BR9712924A (fr)
CA (1)	CA2268178C (fr)
CO (1)	CO4870781A1 (fr)
CZ (1)	CZ298818B6 (fr)
DE (1)	DE69719779T2 (fr)
ES (1)	ES2194189T3 (fr)
HU (1)	HU223492B1 (fr)
MY (1)	MY123094A (fr)
NO (1)	NO327485B1 (fr)
NZ (1)	NZ335217A (fr)
PL (1)	PL192479B1 (fr)
PT (1)	PT937109E (fr)
RU (1)	RU2201941C2 (fr)
SI (1)	SI0937109T1 (fr)
TR (1)	TR199900994T2 (fr)
TW (1)	TW448194B (fr)
UA (1)	UA61089C2 (fr)
WO (1)	WO1998021254A1 (fr)
ZA (1)	ZA979380B (fr)

Families Citing this family (20)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
UA61089C2 (uk) *	1996-11-08	2003-11-17	Хантсмен Ай Сі Ай Кемікалз, Ллс	Спосіб одержання жорстких та еластичних пінополіуретанових матеріалів
GB0120200D0 (en) *	2001-08-18	2001-10-10	Beatty Simon P M	An acoustically absorbant foam with elastic properties
GB0307330D0 (en) *	2003-03-29	2003-05-07	Dow Corning Ltd	Improvements in and relating to composite materials and structures
DE502007000788D1 (de) *	2006-01-27	2009-07-09	Basf Se	Verfahren zur herstellung von offenzelligen viskoelastischen polyurethan-weichschaumstoffen
KR100774634B1 (ko) *	2006-03-23	2007-11-08	현대자동차주식회사	장섬유 사출성형 공법용 발포 폼 조성물
MX2010005069A (es) *	2009-05-27	2010-11-26	Bayer Materialscience Ag	Procedimiento para la fabricacion de espumas blandas de poliuretano con emision reducida.
DE102009033710A1 (de)	2009-07-18	2011-01-20	Evonik Goldschmidt Gmbh	Verwendung von Metallsalzen einer Carbonsäure bei der Herstellung von Polyurethansystemen
EP2461022A1 (fr) *	2010-12-01	2012-06-06	Basf Se	Mousse à noyau en polyuréthane pour la fabrication de pales, notamment pour éoliennes
PL2663584T3 (pl) *	2011-01-13	2015-07-31	Huntsman Int Llc	Sposób wytwarzania cząstek polimocznikowych
EP2503040A1 (fr)	2011-03-23	2012-09-26	Autoneum Management AG	Garniture multicouches moulée
EP2502788B1 (fr)	2011-03-23	2014-03-12	Autoneum Management AG	Procédé de production pour revêtement multicouche moulé
JP6617269B2 (ja) *	2015-06-02	2019-12-11	パナソニックＩｐマネジメント株式会社	超音波振動子およびそれを用いた超音波流量計
EP3196007A1 (fr)	2016-01-21	2017-07-26	Autoneum Management AG	Élément de garnissage moulé pour un véhicule
CN121046162A (zh) *	2016-07-27	2025-12-02	弗门尼舍有限公司	制备微胶囊的方法
US10233278B1 (en)	2017-09-14	2019-03-19	Fxi, Inc.	Cesium and rubidium derivatives as catalysts for polyurethane foams
MY204154A (en) *	2018-08-21	2024-08-09	Huntsman Int Llc	Catalyst for pir/pur foam production
SG11202109011QA (en)	2019-03-25	2021-09-29	Greiner Aerospace Gmbh	Cushion for a plane seat, having antimicrobial effect
ES2988758T3 (es) *	2019-10-08	2024-11-21	Evonik Operations Gmbh	Preparación de espuma rígida de poliuretano
KR102270004B1 (ko) *	2020-02-13	2021-06-29	서울시립대학교 산학협력단	연질 폴리우레탄 조성물, 쿠션재용 연질 폴리우레탄 폼 및 이를 포함하는 차량용 시트
WO2022137951A1 (fr) *	2020-12-25	2022-06-30	富士フイルム株式会社	Ensemble de feuilles pour mesure de pression, feuille pour mesure de pression, microcapsules, dispersion, procédé de production d'ensemble de feuilles pour mesure de pression, procédé de production de feuille pour mesure de pression

Family Cites Families (18)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4107069A (en) *	1975-07-02	1978-08-15	M&T Chemicals Inc.	Storage-stable precursors for rigid polyurethane foams
US4173691A (en) *	1978-02-21	1979-11-06	M&T Chemicals Inc.	Catalyst composition for flexible polyurethane foams
DE2825569A1 (de)	1978-06-10	1979-12-20	Basf Ag	Verfahren zur herstellung von lichtbestaendigen polyurethan-integralschaumstoffen
GB2028348A (en) *	1978-08-21	1980-03-05	Incas Srl	Improved urethanic polymerisation by use of chelating agent is used as catalyst or cocatalysts
US4237235A (en) *	1978-08-21	1980-12-02	Rosalba Mazzucco	Urethanic polymerization by chelating agents acting as catalysts or cocatalysts
SU1647006A1 (ru) *	1988-04-04	1991-05-07	Научно-производственное объединение "Полимерсинтез"	Способ получени эластичного формованного пенополиуретана
EP0358282B1 (fr) *	1989-11-08	1993-10-13	Shell Internationale Researchmaatschappij B.V.	Mousses souples de polyuréthane flexible, leur procédé de préparation et composition de polyol utilisable dans ce procédé
JP2517426B2 (ja) *	1990-02-14	1996-07-24	大日精化工業株式会社	ウレタンフォ―ムの製造方法
DE4029081C1 (fr) *	1990-09-13	1991-06-06	Th. Goldschmidt Ag, 4300 Essen, De
US5084486A (en) *	1990-12-20	1992-01-28	Union Carbide Chemicals & Plastics Technology Corporation	Reactive feed stream to replace inert blowing agent feed stream in a polyurethane foam process
DE4111098A1 (de) *	1991-04-05	1992-10-08	Beiersdorf Ag	Hydrophile schaeume und verfahren zu deren herstellung
US5324754A (en) *	1992-12-14	1994-06-28	Basf Corporation	Lithium-based salts in flexible foams
EP0622388B2 (fr) *	1993-04-26	2001-04-11	Takeda Chemical Industries, Ltd.	Procédé de préparation de mousse rigide de polyuréthanes à pores ouvertes
DE4318962A1 (de) *	1993-06-08	1994-12-15	Basf Ag	Verfahren zur Herstellung von Polyurethan-Hartschaumstoffen
US5489618A (en) *	1993-11-29	1996-02-06	Osi Specialties, Inc.	Process for preparing polyurethane foam
DE19502969A1 (de) *	1995-01-31	1996-08-01	Elastogran Gmbh	Verfahren zur Herstellung von Polyurethan-Hartschaumstoffen
JP3060095B2 (ja) *	1995-05-31	2000-07-04	三洋化成工業株式会社	ウレタン樹脂組成物、吸水材および吸放湿材
UA61089C2 (uk) *	1996-11-08	2003-11-17	Хантсмен Ай Сі Ай Кемікалз, Ллс	Спосіб одержання жорстких та еластичних пінополіуретанових матеріалів

1997
- 1997-07-10 UA UA99063117A patent/UA61089C2/uk unknown
- 1997-10-07 TR TR1999/00994T patent/TR199900994T2/xx unknown
- 1997-10-07 NZ NZ335217A patent/NZ335217A/xx unknown
- 1997-10-07 SI SI9730531T patent/SI0937109T1/xx unknown
- 1997-10-07 ES ES97912131T patent/ES2194189T3/es not_active Expired - Lifetime
- 1997-10-07 JP JP52207898A patent/JP4021939B2/ja not_active Expired - Fee Related
- 1997-10-07 AU AU49445/97A patent/AU731094B2/en not_active Ceased
- 1997-10-07 PL PL333135A patent/PL192479B1/pl not_active IP Right Cessation
- 1997-10-07 PT PT97912131T patent/PT937109E/pt unknown
- 1997-10-07 KR KR1019997004044A patent/KR100544935B1/ko not_active Expired - Fee Related
- 1997-10-07 WO PCT/EP1997/005507 patent/WO1998021254A1/fr not_active Ceased
- 1997-10-07 HU HU9904117A patent/HU223492B1/hu not_active IP Right Cessation
- 1997-10-07 RU RU99112130/04A patent/RU2201941C2/ru not_active IP Right Cessation
- 1997-10-07 DE DE69719779T patent/DE69719779T2/de not_active Expired - Lifetime
- 1997-10-07 EP EP97912131A patent/EP0937109B1/fr not_active Expired - Lifetime
- 1997-10-07 CZ CZ0163199A patent/CZ298818B6/cs not_active IP Right Cessation
- 1997-10-07 BR BR9712924-0A patent/BR9712924A/pt not_active IP Right Cessation
- 1997-10-07 CA CA002268178A patent/CA2268178C/fr not_active Expired - Fee Related
- 1997-10-07 AT AT97912131T patent/ATE234334T1/de not_active IP Right Cessation
- 1997-10-15 TW TW086115161A patent/TW448194B/zh not_active IP Right Cessation
- 1997-10-20 ZA ZA979380A patent/ZA979380B/xx unknown
- 1997-11-04 AR ARP970105131A patent/AR010278A1/es active IP Right Grant
- 1997-11-04 US US08/963,753 patent/US6100311A/en not_active Expired - Lifetime
- 1997-11-06 MY MYPI97005261A patent/MY123094A/en unknown
- 1997-11-06 CO CO97065176A patent/CO4870781A1/es unknown
1999
- 1999-05-07 NO NO19992235A patent/NO327485B1/no not_active IP Right Cessation
- 1999-05-20 BG BG103422A patent/BG64217B1/bg unknown
2000
- 2000-02-25 US US09/513,823 patent/US6211258B1/en not_active Expired - Lifetime
2005
- 2005-09-26 AR ARP050103989A patent/AR051298A2/es active IP Right Grant
- 2005-09-26 AR ARP050103990A patent/AR051299A2/es active IP Right Grant
2007
- 2007-02-05 JP JP2007025133A patent/JP4699398B2/ja not_active Expired - Fee Related

Also Published As

Publication number	Publication date
PL192479B1 (pl)	2006-10-31
CA2268178C (fr)	2009-01-06
KR100544935B1 (ko)	2006-01-24
UA61089C2 (uk)	2003-11-17
DE69719779D1 (de)	2003-04-17
JP2001503468A (ja)	2001-03-13
HUP9904117A3 (en)	2000-05-29
CA2268178A1 (fr)	1998-05-22
BG103422A (en)	2000-01-31
NO992235D0 (no)	1999-05-07
MY123094A (en)	2006-05-31
NZ335217A (en)	2000-12-22
EP0937109B1 (fr)	2003-03-12
HUP9904117A2 (hu)	2000-04-28
ATE234334T1 (de)	2003-03-15
CZ163199A3 (cs)	1999-08-11
EP0937109A1 (fr)	1999-08-25
JP2007146179A (ja)	2007-06-14
JP4699398B2 (ja)	2011-06-08
JP4021939B2 (ja)	2007-12-12
US6100311A (en)	2000-08-08
BR9712924A (pt)	1999-12-07
AU731094B2 (en)	2001-03-22
AU4944597A (en)	1998-06-03
RU2201941C2 (ru)	2003-04-10
NO992235L (no)	1999-05-07
US6211258B1 (en)	2001-04-03
CZ298818B6 (cs)	2008-02-13
PT937109E (pt)	2003-07-31
HU223492B1 (hu)	2004-07-28
WO1998021254A1 (fr)	1998-05-22
AR010278A1 (es)	2000-06-07
DE69719779T2 (de)	2003-10-23
ES2194189T3 (es)	2003-11-16
AR051299A2 (es)	2007-01-03
ZA979380B (en)	1998-07-01
SI0937109T1 (en)	2003-10-31
CO4870781A1 (es)	1999-12-27
TR199900994T2 (en)	1999-07-21
TW448194B (en)	2001-08-01
PL333135A1 (en)	1999-11-22
KR20000053119A (ko)	2000-08-25
NO327485B1 (no)	2009-07-13
AR051298A2 (es)	2007-01-03

Publication	Publication Date	Title
JP4699398B2 (ja)	2011-06-08	硬質及び軟質ポリウレタンフォームの製造方法
EP1230297B1 (fr)	2004-10-20	Procede servant a preparer des mousses de polyurethanne rigides et flexibles contenant un agent ignifuge
AU731092B2 (en)	2001-03-22	Process for preparing rigid and flexible polyurethane foams
JP2005232465A (ja)	2005-09-02	新規な軟質ポリウレタンフォーム
US6288134B1 (en)	2001-09-11	Flexible polyurethane foams
AU728594B2 (en)	2001-01-11	Process for making rigid and flexible polyurethane foams
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