BG64351B1 - Метод за получаване на катализатори на базата на ванадиев антимонат,с използване на snо2хн2о - Google Patents

Метод за получаване на катализатори на базата на ванадиев антимонат,с използване на snо2хн2о Download PDF

Info

Publication number: BG64351B1
Authority: BG; Bulgaria
Prior art keywords: catalyst; mixture; tin; value; tetraalkylammonium hydroxide
Prior art date: 1997-01-17

Application number

BG102194A

Other languages

Bulgarian (bg)

English (en)

Other versions

BG102194A (en

Inventor

Jr. James Brazdil

Josef Bartek

Original Assignee

The Standard Oil Co.

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1997-01-17

Filing date

1998-01-16

Publication date

2004-11-30

1998-01-16 Application filed by The Standard Oil Co. filed Critical The Standard Oil Co.

1998-08-31 Publication of BG102194A publication Critical patent/BG102194A/xx

2004-11-30 Publication of BG64351B1 publication Critical patent/BG64351B1/bg

Links

239000003054 catalyst Substances 0.000 title claims abstract description 59
238000000034 method Methods 0.000 title claims abstract description 22
229910052720 vanadium Inorganic materials 0.000 title claims description 7
238000004519 manufacturing process Methods 0.000 title abstract description 3
LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 title description 5
239000000203 mixture Substances 0.000 claims abstract description 30
229910052718 tin Inorganic materials 0.000 claims abstract description 23
ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims abstract description 18
238000007254 oxidation reaction Methods 0.000 claims abstract description 12
238000002360 preparation method Methods 0.000 claims abstract description 12
230000003647 oxidation Effects 0.000 claims abstract description 11
150000005622 tetraalkylammonium hydroxides Chemical class 0.000 claims abstract description 10
150000001875 compounds Chemical class 0.000 claims abstract description 5
229910052749 magnesium Inorganic materials 0.000 claims abstract description 5
238000001035 drying Methods 0.000 claims abstract description 4
229910052726 zirconium Inorganic materials 0.000 claims abstract description 4
229910052782 aluminium Inorganic materials 0.000 claims abstract description 3
229910052785 arsenic Inorganic materials 0.000 claims abstract description 3
229910052796 boron Inorganic materials 0.000 claims abstract description 3
150000001768 cations Chemical class 0.000 claims abstract description 3
229910052804 chromium Inorganic materials 0.000 claims abstract description 3
229910052733 gallium Inorganic materials 0.000 claims abstract description 3
229910052738 indium Inorganic materials 0.000 claims abstract description 3
229910052742 iron Inorganic materials 0.000 claims abstract description 3
229910052750 molybdenum Inorganic materials 0.000 claims abstract description 3
229910052759 nickel Inorganic materials 0.000 claims abstract description 3
239000000725 suspension Substances 0.000 claims abstract description 3
229910052719 titanium Inorganic materials 0.000 claims abstract description 3
229910052721 tungsten Inorganic materials 0.000 claims abstract description 3
229910052725 zinc Inorganic materials 0.000 claims abstract description 3
238000001354 calcination Methods 0.000 claims description 10
229910006404 SnO 2 Inorganic materials 0.000 claims description 9
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical group O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 6
238000010438 heat treatment Methods 0.000 claims description 5
229910052787 antimony Inorganic materials 0.000 claims description 4
WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims description 3
238000002156 mixing Methods 0.000 claims description 3
239000000377 silicon dioxide Substances 0.000 claims description 3
TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 2
YAIQCYZCSGLAAN-UHFFFAOYSA-N [Si+4].[O-2].[Al+3] Chemical compound [Si+4].[O-2].[Al+3] YAIQCYZCSGLAAN-UHFFFAOYSA-N 0.000 claims 1
239000007788 liquid Substances 0.000 claims 1
RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 claims 1
GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 claims 1
229910001928 zirconium oxide Inorganic materials 0.000 claims 1
XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 abstract description 7
239000007900 aqueous suspension Substances 0.000 abstract description 3
239000000463 material Substances 0.000 abstract description 2
238000005496 tempering Methods 0.000 abstract 2
229910052748 manganese Inorganic materials 0.000 abstract 1
239000002994 raw material Substances 0.000 abstract 1
ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 description 26
ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 16
238000006243 chemical reaction Methods 0.000 description 15
QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 8
239000001294 propane Substances 0.000 description 8
CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical group CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 6
WGTYBPLFGIVFAS-UHFFFAOYSA-M tetramethylammonium hydroxide Chemical compound [OH-].C[N+](C)(C)C WGTYBPLFGIVFAS-UHFFFAOYSA-M 0.000 description 6
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 5
229910001887 tin oxide Inorganic materials 0.000 description 5
BSKHPKMHTQYZBB-UHFFFAOYSA-N 2-methylpyridine Chemical compound CC1=CC=CC=N1 BSKHPKMHTQYZBB-UHFFFAOYSA-N 0.000 description 4
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
229910021529 ammonia Inorganic materials 0.000 description 4
239000006185 dispersion Substances 0.000 description 4
NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 4
IVSZLXZYQVIEFR-UHFFFAOYSA-N m-xylene Chemical group CC1=CC=CC(C)=C1 IVSZLXZYQVIEFR-UHFFFAOYSA-N 0.000 description 4
239000012188 paraffin wax Substances 0.000 description 4
VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 description 3
LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 description 3
150000001336 alkenes Chemical class 0.000 description 3
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 description 3
230000003197 catalytic effect Effects 0.000 description 3
239000007789 gas Substances 0.000 description 3
239000011777 magnesium Substances 0.000 description 3
229940078552 o-xylene Drugs 0.000 description 3
229910052760 oxygen Inorganic materials 0.000 description 3
239000001301 oxygen Substances 0.000 description 3
239000002243 precursor Substances 0.000 description 3
239000007858 starting material Substances 0.000 description 3
238000003756 stirring Methods 0.000 description 3
FFNVQNRYTPFDDP-UHFFFAOYSA-N 2-cyanopyridine Chemical compound N#CC1=CC=CC=N1 FFNVQNRYTPFDDP-UHFFFAOYSA-N 0.000 description 2
-1 C 4 alkanes Chemical class 0.000 description 2
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 description 2
229910010413 TiO 2 Inorganic materials 0.000 description 2
ZAFJBYHGCSMBAY-UHFFFAOYSA-N [V][Sn][Sb] Chemical compound [V][Sn][Sb] ZAFJBYHGCSMBAY-UHFFFAOYSA-N 0.000 description 2
239000003153 chemical reaction reagent Substances 0.000 description 2
238000001704 evaporation Methods 0.000 description 2
230000008020 evaporation Effects 0.000 description 2
239000011521 glass Substances 0.000 description 2
239000001282 iso-butane Substances 0.000 description 2
LAQPNDIUHRHNCV-UHFFFAOYSA-N isophthalonitrile Chemical compound N#CC1=CC=CC(C#N)=C1 LAQPNDIUHRHNCV-UHFFFAOYSA-N 0.000 description 2
229910052757 nitrogen Inorganic materials 0.000 description 2
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 2
239000002245 particle Substances 0.000 description 2
239000000843 powder Substances 0.000 description 2
QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 2
238000005406 washing Methods 0.000 description 2
MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
HBNLSMCCHISJHZ-UHFFFAOYSA-N [Sb]=O.[V] Chemical compound [Sb]=O.[V] HBNLSMCCHISJHZ-UHFFFAOYSA-N 0.000 description 1
ZULRASGUWILXCS-UHFFFAOYSA-N [Sb]=O.[V].[Sn] Chemical compound [Sb]=O.[V].[Sn] ZULRASGUWILXCS-UHFFFAOYSA-N 0.000 description 1
150000008360 acrylonitriles Chemical class 0.000 description 1
239000012018 catalyst precursor Substances 0.000 description 1
239000003085 diluting agent Substances 0.000 description 1
229910001882 dioxygen Inorganic materials 0.000 description 1
238000010304 firing Methods 0.000 description 1
150000004679 hydroxides Chemical class 0.000 description 1
229910017604 nitric acid Inorganic materials 0.000 description 1
150000002902 organometallic compounds Chemical class 0.000 description 1
230000009257 reactivity Effects 0.000 description 1
150000003839 salts Chemical class 0.000 description 1
239000007787 solid Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D213/78—Carbon atoms having three bonds to hetero atoms, with at the most one bond to halogen, e.g. ester or nitrile radicals
- C07D213/84—Nitriles
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/18—Arsenic, antimony or bismuth
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/20—Vanadium, niobium or tantalum
- B01J23/22—Vanadium
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C253/00—Preparation of carboxylic acid nitriles
- C07C253/24—Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C253/00—Preparation of carboxylic acid nitriles
- C07C253/24—Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons
- C07C253/26—Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons containing carbon-to-carbon multiple bonds, e.g. unsaturated aldehydes
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Chemical Kinetics & Catalysis (AREA)
Catalysts (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

BG102194A 1997-01-17 1998-01-16 Метод за получаване на катализатори на базата на ванадиев антимонат,с използване на snо2хн2о BG64351B1 (bg)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
US08/785,543 US5854172A (en)	1997-01-17	1997-01-17	Preparation of vanadium antimonate based catalysts using SnO2 ·xH2 O

Publications (2)

Publication Number	Publication Date
BG102194A BG102194A (en)	1998-08-31
BG64351B1 true BG64351B1 (bg)	2004-11-30

Family

ID=25135844

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
BG102194A BG64351B1 (bg)	1997-01-17	1998-01-16	Метод за получаване на катализатори на базата на ванадиев антимонат,с използване на snо2хн2о

Country Status (17)

Country	Link
US (4)	US5854172A (es)
EP (1)	EP0853977B1 (es)
JP (1)	JP3974989B2 (es)
KR (1)	KR100519901B1 (es)
CN (2)	CN1104947C (es)
BG (1)	BG64351B1 (es)
BR (1)	BR9800349A (es)
DE (1)	DE69818718T2 (es)
ES (1)	ES2209062T3 (es)
MY (1)	MY117950A (es)
RO (1)	RO116253B1 (es)
RU (1)	RU2195999C2 (es)
SA (1)	SA98190054B1 (es)
SG (1)	SG77153A1 (es)
TR (1)	TR199800070A3 (es)
TW (1)	TW425304B (es)
ZA (1)	ZA98258B (es)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US5854172A (en) *	1997-01-17	1998-12-29	The Standard Oil Company	Preparation of vanadium antimonate based catalysts using SnO2 ·xH2 O
US5994259A (en) *	1998-07-29	1999-11-30	The Standard Oil Company	Catalysts for the ammoxidation of alkanes
US6162760A (en) *	1999-02-08	2000-12-19	The Standard Oil Company	Arsenic promoted vanadium-antimony-oxide based catalyst for selective paraffin ammoxidation
US6710011B2 (en)	2001-12-21	2004-03-23	Saudi Basic Industries Corporatioin	Catalyst compositions for the ammoxidation of alkanes and olefins, methods of making and of using same
US6887825B2 (en) *	2002-11-27	2005-05-03	The Standard Oil Company	Method for the preparation of vanadium-antimony-oxide based oxidation and ammoxidation catalysts using non-aqueous media
US20040102318A1 (en) *	2002-11-27	2004-05-27	Brazdil James F.	Method for enhancing the productivity of vanadium antimony oxide catalysts
US6864384B2 (en) *	2002-11-27	2005-03-08	The Standard Oil Company	Preparation of vanadium antimony oxide based catalysts using nano-scale iron
US20050054869A1 (en) *	2003-06-06	2005-03-10	Lugmair Claus G.	Mixed metal oxide catalysts for propane and isobutane oxidation and ammoxidation, and methods of preparing same
DE10344846A1 (de) *	2003-09-26	2005-04-14	Basf Ag	Gasphasenoxidationskatalysator mit definierter Vanadiumoxid-Teilchengrößenverteilung
BRPI0607717A2 (pt) *	2005-03-02	2009-10-06	Sued Chemie Ag	processo para a fabricação de um catalisador de multicamadas para a produção de anidrido de ácido ftálico
RU2370313C2 (ru) *	2005-05-22	2009-10-20	Зюд-Хеми Аг	Многослойный катализатор для получения ангидрида фталевой кислоты
US7766997B2 (en) *	2007-12-21	2010-08-03	Alstom Technology Ltd	Method of reducing an amount of mercury in a flue gas
US8623781B2 (en)	2011-06-28	2014-01-07	King Fahd University of Pretroleum and Minerals	Oxidative dehydrogenation of propane

Citations (7)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US3681421A (en) *	1967-04-18	1972-08-01	Bp Chem Int Ltd	Production of unsaturated aliphatic nitriles
GB1336135A (en) *	1969-11-25	1973-11-07	Power Gas Ltd	Catalytic ammoxidation of alkanes
GB1336136A (en) *	1970-03-24	1973-11-07	Power Gas Ltd	Catalytic ammoxidation of alkanes
US4788317A (en) *	1984-08-22	1988-11-29	Standard Oil Company	Ammoxidation of paraffins and catalysts therefor
US5008427A (en) *	1988-12-23	1991-04-16	The Standard Oil Company	Ammoxidation of paraffins
US5214016A (en) *	1992-04-02	1993-05-25	The Standard Oil Company	Method of making catalysts containing vanadium, antimony and tin
EP0691306A1 (fr) *	1994-06-23	1996-01-10	Rhone-Poulenc Chimie	Procédé de préparation de catalyseurs d'ammoxydation

Family Cites Families (50)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
CA718898A (en) *	1960-04-26	1965-09-28	B. Bream John	Oxidation catalysts
US3264225A (en) *	1962-10-15	1966-08-02	Standard Oil Co	Mixed antimony oxide-thorium oxide oxidation catalyst
US3625867A (en) *	1967-06-02	1971-12-07	Takachika Yoshino	Process for production of metal oxide-antimony oxide catalysts
US3890246A (en) *	1967-12-20	1975-06-17	Standard Oil Co	Catalysts for the oxidation of olefins to unsaturated aldehydes
US3544617A (en) *	1967-12-27	1970-12-01	Showa Denko Kk	Process for the manufacture of aromatic nitriles
BE741001A (es) *	1968-11-02	1970-04-01
US3873595A (en) *	1969-09-26	1975-03-25	Degussa	Production of o-phthalodinitrile
US3907975A (en) *	1970-02-09	1975-09-23	Azote & Prod Chim	Catalytic oxidation of ammonia
GB1280073A (en) *	1970-03-20	1972-07-05	Bp Chem Int Ltd	Improvements in or relating to catalysts
US3860534A (en) *	1971-03-24	1975-01-14	Power Gas Ltd	Method of making an antimony-vanadium catalyst
US3925447A (en) *	1971-05-26	1975-12-09	Lummus Co	Production of nitriles
GB1364587A (en) *	1972-03-17	1974-08-21	Bp Chem Int Ltd	Catalyst composition
GB1382733A (en) *	1972-10-05	1975-02-05	Bp Chem Int Ltd	Process for the production of acrylonitrile
US4139552A (en) *	1974-01-04	1979-02-13	The Standard Oil Company	Production of unsaturated nitriles
US3901933A (en) *	1973-06-20	1975-08-26	Sun Research Development	Production of nitriles by ammoxidation
US4388248A (en) *	1978-01-03	1983-06-14	Monsanto Company	Ammoxidation processes
US4162992A (en) *	1978-01-03	1979-07-31	Monsanto Company	Oxidation and ammoxidation catalysts
DE2814262A1 (de) *	1978-04-03	1979-10-18	Basf Ag	Schalenkatalysatoren und verfahren zu ihrer herstellung
US4408067A (en) *	1979-01-26	1983-10-04	Nitto Chemical Industries, Ltd.	Process for producing carboxylic acid esters from nitriles
US4257921A (en) *	1979-08-29	1981-03-24	Celanese Corporation	Catalyst for the oxidation of butene
JPS56139444A (en) *	1980-04-01	1981-10-30	Takeda Chem Ind Ltd	Production of aromatic nitrile
US4339598A (en) *	1980-12-31	1982-07-13	Sohio	Preparation of unsaturated acids and esters from saturated carboxylic acid derivatives and carbonyl compounds over catalysts containing V and Sb
GB8300554D0 (en) *	1983-01-10	1983-02-09	Atomic Energy Authority Uk	Catalyst preparation
DE3322940A1 (de) *	1983-06-25	1985-01-03	Basf Ag, 6700 Ludwigshafen	Verfahren zur herstellung eines katalysators fuer die oxidation von schwefeldioxid zu schwefeltrioxid
US4590011A (en) *	1983-11-23	1986-05-20	Monsanto Company	Ammoxidation process
US4746641A (en) *	1984-08-22	1988-05-24	Standard Oil Company	Ammoxidation of paraffins and catalysts therefor
US4788173A (en) *	1985-12-20	1988-11-29	The Standard Oil Company	Catalytic mixtures for ammoxidation of paraffins
US4783545A (en) *	1985-12-20	1988-11-08	The Standard Oil Company	Method for ammoxidation of paraffins and catalyst system therefor
US4767739A (en) *	1987-04-20	1988-08-30	The Standard Oil Company	Catalyst system for ammoxidation of paraffins
US4877764A (en) *	1987-04-20	1989-10-31	The Standard Oil Company	Catalyst system for ammoxidation of paraffins
US4801568A (en) *	1987-10-22	1989-01-31	The Standard Oil Company	Catalyst for ammoxidation of paraffins
US4784979A (en) *	1987-12-07	1988-11-15	The Standard Oil Company	Catalyst and catalyst precursor containing vanadium and antimony
US5179054A (en) *	1987-12-28	1993-01-12	Mobil Oil Corporation	Layered cracking catalyst and method of manufacture and use thereof
US4879264A (en) *	1988-11-14	1989-11-07	The Standard Oil Company	Method of making catalyst and catalyst precursor containing vanadium and antimony
CN1025551C (zh) *	1990-11-05	1994-08-03	中国石油化工总公司	保持丙烯腈流化床钼系催化剂活性稳定的补加催化剂
US5079207A (en) *	1990-12-03	1992-01-07	The Standard Oil Company	Catalyst for ammoxidation of paraffins
US5094989A (en) *	1990-12-21	1992-03-10	The Standard Oil Company	Process for activation of catalysts
US5229341A (en) *	1991-01-11	1993-07-20	Mobil Oil Corp.	Crystalline oxide material
FR2684989B1 (fr) *	1991-12-16	1994-02-04	Rhone Poulenc Chimie	Procede d'ammoxydation d'hydrocarbures satures.
US5258543A (en) *	1992-06-26	1993-11-02	The Standard Oil Company	Method for ammoxidation of olefins
US5354718A (en) *	1993-04-05	1994-10-11	Mobil Oil Corporation	Catalyst and process for isoparaffin-olefin alkylation
ES2141831T3 (es) *	1993-08-26	2000-04-01	Bp America	Metodo para mejorar catalizadores de oxidacion y amoxidacion.
US5432141A (en) *	1994-03-15	1995-07-11	The Standard Oil Company	Preparation of attrition resistant vanadium-antimony oxide catalysts
US5498588A (en) *	1994-09-09	1996-03-12	The Standard Oil Company	Surface modification and promotion of vanadium antimony oxide catalysts
DE19504283A1 (de) *	1995-02-09	1996-08-14	Degussa	Verfahren zur Herstellung von Cyanopyridinen und dafür geeignete Katalysatoren
US5576469A (en) *	1995-06-05	1996-11-19	The Standard Oil Co.	Paraffin ammoxidation using vanadium antimony oxide based catalysts with halide promoters
US5693587A (en) *	1995-06-06	1997-12-02	The Standard Oil Company	Method for preparing vanadium antimony oxide based oxidation and ammoxidation catalysts
GB2302291B (en) *	1995-06-15	1999-07-07	Basf Plc	Ammoxidation of propane and preparation of catalyst therefor
US5854172A (en) *	1997-01-17	1998-12-29	The Standard Oil Company	Preparation of vanadium antimonate based catalysts using SnO2 ·xH2 O
US5866502A (en) *	1997-03-27	1999-02-02	The Standard Oil Co.	Process for the preparation of antimonate catalysts for (AMM) oxidation of alkanes and alkenes

1997
- 1997-01-17 US US08/785,543 patent/US5854172A/en not_active Expired - Fee Related
1998
- 1998-01-06 SG SG1998000060A patent/SG77153A1/en unknown
- 1998-01-13 ZA ZA98258A patent/ZA98258B/xx unknown
- 1998-01-14 EP EP98300250A patent/EP0853977B1/en not_active Expired - Lifetime
- 1998-01-14 DE DE69818718T patent/DE69818718T2/de not_active Expired - Fee Related
- 1998-01-14 ES ES98300250T patent/ES2209062T3/es not_active Expired - Lifetime
- 1998-01-15 RO RO98-00065A patent/RO116253B1/ro unknown
- 1998-01-16 BR BR9800349A patent/BR9800349A/pt not_active IP Right Cessation
- 1998-01-16 TW TW087100547A patent/TW425304B/zh not_active IP Right Cessation
- 1998-01-16 TR TR1998/00070A patent/TR199800070A3/tr unknown
- 1998-01-16 BG BG102194A patent/BG64351B1/bg unknown
- 1998-01-16 KR KR10-1998-0001133A patent/KR100519901B1/ko not_active Expired - Fee Related
- 1998-01-16 JP JP00688398A patent/JP3974989B2/ja not_active Expired - Fee Related
- 1998-01-16 RU RU98101417/04A patent/RU2195999C2/ru not_active IP Right Cessation
- 1998-01-16 MY MYPI98000196A patent/MY117950A/en unknown
- 1998-01-17 CN CN98105606A patent/CN1104947C/zh not_active Expired - Fee Related
- 1998-05-10 SA SA98190054A patent/SA98190054B1/ar unknown
- 1998-11-09 US US09/151,463 patent/US5972833A/en not_active Expired - Fee Related
1999
- 1999-04-16 US US09/293,452 patent/US6087524A/en not_active Expired - Fee Related
2000
- 2000-05-09 US US09/567,674 patent/US6372908B1/en not_active Expired - Fee Related
2002
- 2002-04-12 CN CNB02105536XA patent/CN1196675C/zh not_active Expired - Fee Related

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US3681421A (en) *	1967-04-18	1972-08-01	Bp Chem Int Ltd	Production of unsaturated aliphatic nitriles
GB1336135A (en) *	1969-11-25	1973-11-07	Power Gas Ltd	Catalytic ammoxidation of alkanes
GB1336136A (en) *	1970-03-24	1973-11-07	Power Gas Ltd	Catalytic ammoxidation of alkanes
US4788317A (en) *	1984-08-22	1988-11-29	Standard Oil Company	Ammoxidation of paraffins and catalysts therefor
US5008427A (en) *	1988-12-23	1991-04-16	The Standard Oil Company	Ammoxidation of paraffins
US5214016A (en) *	1992-04-02	1993-05-25	The Standard Oil Company	Method of making catalysts containing vanadium, antimony and tin
EP0691306A1 (fr) *	1994-06-23	1996-01-10	Rhone-Poulenc Chimie	Procédé de préparation de catalyseurs d'ammoxydation

Also Published As

Publication number	Publication date
EP0853977A1 (en)	1998-07-22
EP0853977B1 (en)	2003-10-08
US5972833A (en)	1999-10-26
KR19980070558A (ko)	1998-10-26
CN1104947C (zh)	2003-04-09
SA98190054B1 (ar)	2006-04-22
RU2195999C2 (ru)	2003-01-10
CN1206627A (zh)	1999-02-03
KR100519901B1 (ko)	2005-11-25
TR199800070A2 (xx)	1999-10-21
US6087524A (en)	2000-07-11
TR199800070A3 (tr)	1999-10-21
ZA98258B (en)	1998-07-13
BR9800349A (pt)	1999-05-25
SG77153A1 (en)	2000-12-19
CN1196675C (zh)	2005-04-13
BG102194A (en)	1998-08-31
TW425304B (en)	2001-03-11
CN1389457A (zh)	2003-01-08
DE69818718T2 (de)	2004-09-23
MY117950A (en)	2004-08-30
RO116253B1 (ro)	2000-12-29
US6372908B1 (en)	2002-04-16
JPH10225634A (ja)	1998-08-25
JP3974989B2 (ja)	2007-09-12
DE69818718D1 (de)	2003-11-13
ES2209062T3 (es)	2004-06-16
US5854172A (en)	1998-12-29

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US4083804A (en)	1978-04-11	Catalyst for use in and process for preparing acrylonitrile
US5432141A (en)	1995-07-11	Preparation of attrition resistant vanadium-antimony oxide catalysts
JPS5950667B2 (ja)	1984-12-10	種々の金属を助触媒とした触媒を使う不飽和ニトリルの製造法
JP2000005603A (ja)	2000-01-11	不飽和ニトリル製造用触媒組成物
RU98101417A (ru)	1999-11-10	Способ получения катализаторов на основе антимоната ванадия с применением sno2x h2o
KR20010101956A (ko)	2001-11-15	선택적 파라핀 가암모니아 산화를 위한 비소 촉진된바나듐-안티몬-산화물 기재 촉매
WO2004050236A1 (en)	2004-06-17	Method for enhancing the productivity of vanadium antimony oxide catalysts
JP2520279B2 (ja)	1996-07-31	アクリロニトリルの製造方法
JPH05213848A (ja)	1993-08-24	α，β−不飽和ニトリルの製造方法
MXPA98000508A (es)	1999-02-24	Preparacion de catalizadores a base de antimonatode vanadio, usando sno2-xh20
KR0138499B1 (ko)	1998-05-01	올레핀의 암모산화 방법
JPH11309374A (ja)	1999-11-09	モリブデン含有酸化物触媒の製法
CN1046292A (zh)	1990-10-24	烷烃的氨氧化及其所用的催化剂
JPS6132302B2 (es)	1986-07-25