BG64385B1 - Промотиран с молибден ванадиево-антимонов оксиден катализатор за селективна парафинова амоксидация - Google Patents

Промотиран с молибден ванадиево-антимонов оксиден катализатор за селективна парафинова амоксидация Download PDF

Info

Publication number: BG64385B1
Authority: BG; Bulgaria
Prior art keywords: catalyst; molybdenum; added; range; elements
Prior art date: 1998-03-26

Application number

BG103280A

Other languages

Bulgarian (bg)

English (en)

Other versions

BG103280A (en

Inventor

Mark Toft

Original Assignee

The Standard Oil Co.

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1998-03-26

Filing date

1999-03-25

Publication date

2004-12-30

1999-03-25 Application filed by The Standard Oil Co. filed Critical The Standard Oil Co.

2000-02-29 Publication of BG103280A publication Critical patent/BG103280A/xx

2004-12-30 Publication of BG64385B1 publication Critical patent/BG64385B1/bg

Links

239000003054 catalyst Substances 0.000 title claims abstract description 91
239000012188 paraffin wax Substances 0.000 title claims description 9
HBNLSMCCHISJHZ-UHFFFAOYSA-N [Sb]=O.[V] Chemical compound [Sb]=O.[V] HBNLSMCCHISJHZ-UHFFFAOYSA-N 0.000 title claims description 6
238000007254 oxidation reaction Methods 0.000 claims abstract description 11
230000003647 oxidation Effects 0.000 claims abstract description 10
229910052719 titanium Inorganic materials 0.000 claims abstract description 8
229910052742 iron Inorganic materials 0.000 claims abstract description 7
229910052718 tin Inorganic materials 0.000 claims abstract description 7
229910052785 arsenic Inorganic materials 0.000 claims abstract description 5
229910052796 boron Inorganic materials 0.000 claims abstract description 5
150000001768 cations Chemical class 0.000 claims abstract description 5
229910052804 chromium Inorganic materials 0.000 claims abstract description 5
229910052733 gallium Inorganic materials 0.000 claims abstract description 5
229910052738 indium Inorganic materials 0.000 claims abstract description 5
229910052759 nickel Inorganic materials 0.000 claims abstract description 5
229910052721 tungsten Inorganic materials 0.000 claims abstract description 5
229910052725 zinc Inorganic materials 0.000 claims abstract description 5
229910052726 zirconium Inorganic materials 0.000 claims abstract description 5
ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 claims description 26
238000000034 method Methods 0.000 claims description 20
238000006243 chemical reaction Methods 0.000 claims description 18
ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 17
NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 claims description 16
229910052750 molybdenum Inorganic materials 0.000 claims description 16
239000011733 molybdenum Substances 0.000 claims description 16
XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 15
239000000843 powder Substances 0.000 claims description 14
239000001294 propane Substances 0.000 claims description 13
239000001282 iso-butane Substances 0.000 claims description 8
238000001354 calcination Methods 0.000 claims description 7
239000010936 titanium Substances 0.000 claims description 7
239000011135 tin Substances 0.000 claims description 6
239000011651 chromium Substances 0.000 claims description 4
239000000463 material Substances 0.000 claims description 4
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 3
ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 2
YOZINWIFIXLBRV-UHFFFAOYSA-N [O].[V].[Sb].[Mo] Chemical compound [O].[V].[Sb].[Mo] YOZINWIFIXLBRV-UHFFFAOYSA-N 0.000 claims 1
APUPEJJSWDHEBO-UHFFFAOYSA-P ammonium molybdate Chemical compound [NH4+].[NH4+].[O-][Mo]([O-])(=O)=O APUPEJJSWDHEBO-UHFFFAOYSA-P 0.000 claims 1
229940010552 ammonium molybdate Drugs 0.000 claims 1
235000018660 ammonium molybdate Nutrition 0.000 claims 1
239000011609 ammonium molybdate Substances 0.000 claims 1
239000007864 aqueous solution Substances 0.000 claims 1
238000001035 drying Methods 0.000 claims 1
229910052748 manganese Inorganic materials 0.000 abstract 1
ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 description 56
239000000203 mixture Substances 0.000 description 23
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 15
229910006404 SnO 2 Inorganic materials 0.000 description 14
WGTYBPLFGIVFAS-UHFFFAOYSA-M tetramethylammonium hydroxide Chemical compound [OH-].C[N+](C)(C)C WGTYBPLFGIVFAS-UHFFFAOYSA-M 0.000 description 14
QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 12
239000011521 glass Substances 0.000 description 11
NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 8
GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 description 7
229910010413 TiO 2 Inorganic materials 0.000 description 7
239000002253 acid Substances 0.000 description 7
230000000052 comparative effect Effects 0.000 description 7
239000006185 dispersion Substances 0.000 description 7
239000002245 particle Substances 0.000 description 7
238000005406 washing Methods 0.000 description 7
229910021529 ammonia Inorganic materials 0.000 description 6
238000001704 evaporation Methods 0.000 description 6
230000008020 evaporation Effects 0.000 description 6
238000010438 heat treatment Methods 0.000 description 6
238000009736 wetting Methods 0.000 description 6
229910019614 (NH4)6 Mo7 O24.4H2 O Inorganic materials 0.000 description 5
VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical compound CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 description 5
FIXLYHHVMHXSCP-UHFFFAOYSA-H azane;dihydroxy(dioxo)molybdenum;trioxomolybdenum;tetrahydrate Chemical compound N.N.N.N.N.N.O.O.O.O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O[Mo](O)(=O)=O.O[Mo](O)(=O)=O.O[Mo](O)(=O)=O FIXLYHHVMHXSCP-UHFFFAOYSA-H 0.000 description 5
238000002360 preparation method Methods 0.000 description 5
QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 5
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 5
229910004298 SiO 2 Inorganic materials 0.000 description 4
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
230000015572 biosynthetic process Effects 0.000 description 4
230000003197 catalytic effect Effects 0.000 description 4
229910052760 oxygen Inorganic materials 0.000 description 4
239000001301 oxygen Substances 0.000 description 4
238000003756 stirring Methods 0.000 description 3
MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 2
150000001335 aliphatic alkanes Chemical class 0.000 description 2
238000006555 catalytic reaction Methods 0.000 description 2
229910001882 dioxygen Inorganic materials 0.000 description 2
239000007789 gas Substances 0.000 description 2
229910052736 halogen Inorganic materials 0.000 description 2
150000002367 halogens Chemical class 0.000 description 2
238000004519 manufacturing process Methods 0.000 description 2
150000005673 monoalkenes Chemical class 0.000 description 2
239000002994 raw material Substances 0.000 description 2
239000000376 reactant Substances 0.000 description 2
238000004064 recycling Methods 0.000 description 2
239000012808 vapor phase Substances 0.000 description 2
TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 1
NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
RJAAXVMENUVEAN-UHFFFAOYSA-N antimony vanadium Chemical compound [V].[Sb] RJAAXVMENUVEAN-UHFFFAOYSA-N 0.000 description 1
230000015271 coagulation Effects 0.000 description 1
238000005345 coagulation Methods 0.000 description 1
239000011362 coarse particle Substances 0.000 description 1
230000007717 exclusion Effects 0.000 description 1
239000000835 fiber Substances 0.000 description 1
150000002825 nitriles Chemical class 0.000 description 1
239000012071 phase Substances 0.000 description 1
229920003051 synthetic elastomer Polymers 0.000 description 1
229920003002 synthetic resin Polymers 0.000 description 1
239000000057 synthetic resin Substances 0.000 description 1
239000005061 synthetic rubber Substances 0.000 description 1
-1 vanadium-antimony propane Chemical compound 0.000 description 1
239000002699 waste material Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C253/00—Preparation of carboxylic acid nitriles
- C07C253/24—Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/002—Mixed oxides other than spinels, e.g. perovskite
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/24—Chromium, molybdenum or tungsten
- B01J23/28—Molybdenum
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/88—Molybdenum
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/88—Molybdenum
- B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/8876—Arsenic, antimony or bismuth
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/08—Heat treatment
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Chemical Kinetics & Catalysis (AREA)
Physics & Mathematics (AREA)
Thermal Sciences (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Catalysts (AREA)
Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

BG103280A 1998-03-26 1999-03-25 Промотиран с молибден ванадиево-антимонов оксиден катализатор за селективна парафинова амоксидация BG64385B1 (bg)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
US09/048,648 US6156920A (en)	1998-03-26	1998-03-26	Molybdenum promoted vanadium-antimony-oxide based catalyst for selective paraffin ammoxidation

Publications (2)

Publication Number	Publication Date
BG103280A BG103280A (en)	2000-02-29
BG64385B1 true BG64385B1 (bg)	2004-12-30

Family

ID=21955682

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
BG103280A BG64385B1 (bg)	1998-03-26	1999-03-25	Промотиран с молибден ванадиево-антимонов оксиден катализатор за селективна парафинова амоксидация

Country Status (16)

Country	Link
US (1)	US6156920A (ja)
EP (1)	EP0945432B1 (ja)
JP (1)	JPH11310562A (ja)
KR (1)	KR100586672B1 (ja)
CN (1)	CN1178903C (ja)
BG (1)	BG64385B1 (ja)
BR (1)	BR9901709A (ja)
DE (1)	DE69901645T2 (ja)
ES (1)	ES2178350T3 (ja)
MY (1)	MY129558A (ja)
RO (1)	RO116273B1 (ja)
RU (1)	RU2219164C2 (ja)
SG (1)	SG76602A1 (ja)
TR (1)	TR199900709A3 (ja)
TW (1)	TW487693B (ja)
ZA (1)	ZA992101B (ja)

Families Citing this family (26)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US6037304A (en) *	1999-01-11	2000-03-14	Saudi Basic Industries Corporation	Highly active and selective catalysts for the production of unsaturated nitriles, methods of making and using the same
US6043185A (en) *	1999-04-02	2000-03-28	The Standard Oil Company	Gallium promoted molybdenum vanadium-antimony-oxide based catalyst for selective paraffin ammoxidation
US6486091B1 (en)	2000-03-14	2002-11-26	Saudi Basic Industries Corporation	Process for making highly active and selective catalysts for the production of unsaturated nitriles
WO2001096016A1 (en) *	2000-06-15	2001-12-20	Asahi Kasei Kabushiki Kaisha	Catalyst for vapor-phase catalytic oxidation or vapor-phase catalytic ammoxidation of propane or isobutane
US20020038052A1 (en) *	2000-09-28	2002-03-28	Bogan, Leonard Edward	Calcination
JP4530595B2 (ja) *	2000-12-13	2010-08-25	旭化成ケミカルズ株式会社	酸化またはアンモ酸化用酸化物触媒
EP1346766B1 (en) *	2000-12-22	2009-02-11	Nippon Kayaku Kabushiki Kaisha	Process for producing oxygen-containing unsaturated compound
JP4647858B2 (ja) *	2001-09-06	2011-03-09	旭化成ケミカルズ株式会社	酸化またはアンモ酸化用酸化物触媒及びその製造方法
US6710011B2 (en)	2001-12-21	2004-03-23	Saudi Basic Industries Corporatioin	Catalyst compositions for the ammoxidation of alkanes and olefins, methods of making and of using same
US6887825B2 (en) *	2002-11-27	2005-05-03	The Standard Oil Company	Method for the preparation of vanadium-antimony-oxide based oxidation and ammoxidation catalysts using non-aqueous media
US6916763B2 (en) *	2002-11-27	2005-07-12	Solutia Inc.	Process for preparing a catalyst for the oxidation and ammoxidation of olefins
US6864384B2 (en) *	2002-11-27	2005-03-08	The Standard Oil Company	Preparation of vanadium antimony oxide based catalysts using nano-scale iron
US20040102318A1 (en) *	2002-11-27	2004-05-27	Brazdil James F.	Method for enhancing the productivity of vanadium antimony oxide catalysts
US7642214B2 (en)	2003-06-10	2010-01-05	Nippon Kayaku Kabushiki Kaisha	Catalyst for oxidation of alkane, process for preparing thereof and process for producing unsaturated oxygen-containing compound
US20080103326A1 (en) *	2006-10-31	2008-05-01	Bruce Irwin Rosen	Lithium containing mixed metal oxide catalysts for ammoxidation of propane and isobutane
US20080103325A1 (en) *	2006-10-31	2008-05-01	Claus Lugmair	Mixed metal oxide catalysts for the ammoxidation of propane and isobutane
US20080248947A1 (en) *	2007-04-03	2008-10-09	Zajac Gerry W	Mixed metal oxide catalysts and catalytic processes for conversions of lower alkane hydrocarbons
US8697596B2 (en) *	2007-04-03	2014-04-15	Ineos Usa Llc	Mixed metal oxide catalysts and catalytic conversions of lower alkane hydrocarbons
US20090005586A1 (en) *	2007-06-29	2009-01-01	Brazdil Jr James F	Mixed metal oxide catalysts for the ammoxidation of propane and isobutane
EP2310123A1 (en) *	2008-08-01	2011-04-20	Ineos USA, LLC	Method of making mixed metal oxide catalysts for ammoxidation and/or oxidation of lower alkane hydrocarbons
CN102458654B (zh) *	2009-06-11	2014-12-31	三菱瓦斯化学株式会社	氨氧化催化剂及使用该催化剂的腈化合物的制造方法
TWI520933B (zh) *	2011-01-13	2016-02-11	旭化成化學股份有限公司	Production method of unsaturated nitrile
CN103596909B (zh) *	2011-05-13	2015-08-26	艾菲纽技术公司	烷烃非均相催化气相氧化制备脂肪酮和/或其他含氧化合物
KR101471625B1 (ko) *	2013-04-09	2014-12-11	계명대학교 산학협력단	전이금속 촉매와 cvd를 이용한 탄소나노섬유 합성방법 및 이 방법으로 제조된 탄소나노섬유
CN108435223B (zh) *	2018-04-26	2020-03-20	厦门大学	一种磷改性的丙烷氨氧化催化剂及其制备方法和应用
CA3130719C (en)	2019-02-21	2023-09-26	Ascend Performance Materials Operations Llc	Processes for stabilizing antimony catalysts

Citations (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US5008427A (en) *	1988-12-23	1991-04-16	The Standard Oil Company	Ammoxidation of paraffins
EP0767164A1 (en) *	1995-10-05	1997-04-09	Mitsubishi Chemical Corporation	Method for producing a nitrile

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US5693587A (en) *	1995-06-06	1997-12-02	The Standard Oil Company	Method for preparing vanadium antimony oxide based oxidation and ammoxidation catalysts

1998
- 1998-03-26 US US09/048,648 patent/US6156920A/en not_active Expired - Fee Related
1999
- 1999-03-03 SG SG1999001526A patent/SG76602A1/en unknown
- 1999-03-16 ZA ZA9902101A patent/ZA992101B/xx unknown
- 1999-03-23 RO RO99-00313A patent/RO116273B1/ro unknown
- 1999-03-24 MY MYPI99001107A patent/MY129558A/en unknown
- 1999-03-24 BR BR9901709-1A patent/BR9901709A/pt not_active IP Right Cessation
- 1999-03-25 EP EP99302315A patent/EP0945432B1/en not_active Expired - Lifetime
- 1999-03-25 JP JP11082612A patent/JPH11310562A/ja active Pending
- 1999-03-25 RU RU99106152/04A patent/RU2219164C2/ru not_active IP Right Cessation
- 1999-03-25 BG BG103280A patent/BG64385B1/bg unknown
- 1999-03-25 TW TW088104716A patent/TW487693B/zh not_active IP Right Cessation
- 1999-03-25 CN CNB991055853A patent/CN1178903C/zh not_active Expired - Fee Related
- 1999-03-25 DE DE69901645T patent/DE69901645T2/de not_active Expired - Fee Related
- 1999-03-25 ES ES99302315T patent/ES2178350T3/es not_active Expired - Lifetime
- 1999-03-26 TR TR1999/00709A patent/TR199900709A3/tr unknown
- 1999-03-26 KR KR1019990010489A patent/KR100586672B1/ko not_active Expired - Fee Related

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US5008427A (en) *	1988-12-23	1991-04-16	The Standard Oil Company	Ammoxidation of paraffins
EP0767164A1 (en) *	1995-10-05	1997-04-09	Mitsubishi Chemical Corporation	Method for producing a nitrile

Also Published As

Publication number	Publication date
TR199900709A2 (xx)	1999-10-21
US6156920A (en)	2000-12-05
TR199900709A3 (tr)	1999-10-21
MY129558A (en)	2007-04-30
CN1231281A (zh)	1999-10-13
KR100586672B1 (ko)	2006-06-07
BR9901709A (pt)	2000-01-11
DE69901645D1 (de)	2002-07-11
EP0945432B1 (en)	2002-06-05
TW487693B (en)	2002-05-21
CN1178903C (zh)	2004-12-08
EP0945432A1 (en)	1999-09-29
ZA992101B (en)	1999-10-01
ES2178350T3 (es)	2002-12-16
RU2219164C2 (ru)	2003-12-20
JPH11310562A (ja)	1999-11-09
RO116273B1 (ro)	2000-12-29
SG76602A1 (en)	2000-11-21
DE69901645T2 (de)	2003-01-30
BG103280A (en)	2000-02-29
KR19990078301A (ko)	1999-10-25

Publication	Publication Date	Title
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