BG70207A - Метод за получаване на сребърни катализатори - Google Patents
Метод за получаване на сребърни катализаториInfo
- Publication number
- BG70207A BG70207A BG070207A BG7020785A BG70207A BG 70207 A BG70207 A BG 70207A BG 070207 A BG070207 A BG 070207A BG 7020785 A BG7020785 A BG 7020785A BG 70207 A BG70207 A BG 70207A
- Authority
- BG
- Bulgaria
- Prior art keywords
- catalysts
- silver catalysts
- obtaining silver
- ethylene
- acids
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title abstract 3
- 238000000034 method Methods 0.000 title abstract 2
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 title 1
- 229910052709 silver Inorganic materials 0.000 title 1
- 239000004332 silver Substances 0.000 title 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 2
- 239000004215 Carbon black (E152) Substances 0.000 abstract 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 abstract 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract 1
- 239000005977 Ethylene Substances 0.000 abstract 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 abstract 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 abstract 1
- 235000011054 acetic acid Nutrition 0.000 abstract 1
- 150000001243 acetic acids Chemical class 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 150000007513 acids Chemical class 0.000 abstract 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 1
- 229910000323 aluminium silicate Inorganic materials 0.000 abstract 1
- 229910052792 caesium Inorganic materials 0.000 abstract 1
- TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 abstract 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 abstract 1
- 229910001882 dioxygen Inorganic materials 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- 150000002430 hydrocarbons Chemical class 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 230000003647 oxidation Effects 0.000 abstract 1
- 238000007254 oxidation reaction Methods 0.000 abstract 1
- 229910052700 potassium Inorganic materials 0.000 abstract 1
- 239000011591 potassium Substances 0.000 abstract 1
- 229910052701 rubidium Inorganic materials 0.000 abstract 1
- IGLNJRXAVVLDKE-UHFFFAOYSA-N rubidium atom Chemical compound [Rb] IGLNJRXAVVLDKE-UHFFFAOYSA-N 0.000 abstract 1
- 235000012239 silicon dioxide Nutrition 0.000 abstract 1
- 239000000377 silicon dioxide Substances 0.000 abstract 1
- GGCZERPQGJTIQP-UHFFFAOYSA-N sodium;9,10-dioxoanthracene-2-sulfonic acid Chemical compound [Na+].C1=CC=C2C(=O)C3=CC(S(=O)(=O)O)=CC=C3C(=O)C2=C1 GGCZERPQGJTIQP-UHFFFAOYSA-N 0.000 abstract 1
- 239000012808 vapor phase Substances 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/48—Silver or gold
- B01J23/50—Silver
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/66—Silver or gold
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D301/00—Preparation of oxiranes
- C07D301/02—Synthesis of the oxirane ring
- C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
- C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
- C07D301/08—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
- C07D301/10—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase with catalysts containing silver or gold
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Epoxy Compounds (AREA)
Abstract
Катализаторите се използват при окисляване на етилен в парова фаза с молекулен кислород до етиленов окис. По метода се импрегнира носител с въглеводороден разтвор на сребърна сол на неокиселини, представляващи триалкилни оцетни киселини. Носителят е избран от групата на алуминиев окис, силициев двуокис, алумосилициев окис или техни смеси. Катализаторите могат в даден случай да бъдат промотирани с цезий, калий или рубидий. 16 претенции
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US06/610,229 US4555501A (en) | 1984-05-14 | 1984-05-14 | Process for preparing silver catalysts |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| BG70207A true BG70207A (bg) | 1993-12-24 |
| BG60611B1 BG60611B1 (bg) | 1995-10-31 |
Family
ID=24444215
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BG70207A BG60611B1 (bg) | 1984-05-14 | 1985-05-13 | Метод за получаване на сребърни катализатори |
Country Status (18)
| Country | Link |
|---|---|
| US (1) | US4555501A (bg) |
| EP (1) | EP0161930B1 (bg) |
| JP (1) | JPH0611398B2 (bg) |
| KR (1) | KR920005083B1 (bg) |
| AR (1) | AR240661A1 (bg) |
| AU (1) | AU570113B2 (bg) |
| BG (1) | BG60611B1 (bg) |
| BR (1) | BR8502254A (bg) |
| CA (1) | CA1250277A (bg) |
| DD (1) | DD233310A5 (bg) |
| DE (1) | DE3570664D1 (bg) |
| ES (1) | ES8606016A1 (bg) |
| IN (1) | IN169852B (bg) |
| MX (2) | MX167584B (bg) |
| RO (1) | RO92423B (bg) |
| SU (1) | SU1598856A3 (bg) |
| YU (2) | YU45717B (bg) |
| ZA (1) | ZA853653B (bg) |
Families Citing this family (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB8613818D0 (en) * | 1986-06-06 | 1986-07-09 | Ici Plc | Catalysts |
| DE3528313A1 (de) * | 1985-08-07 | 1987-02-12 | Basf Ag | Silberkatalysator, seine herstellung und verwendung |
| US4663303A (en) * | 1986-02-24 | 1987-05-05 | The Halcon Sd Group, Inc. | Process for preparing silver catalysts |
| US4897376A (en) * | 1988-06-27 | 1990-01-30 | Scientific Design Company, Inc. | Process for preparing a catalyst for oxidation of ethylene to ethylene oxide |
| US5008413A (en) * | 1989-10-23 | 1991-04-16 | Scientific Design Company, Inc. | Catalyst for oxidation of ethylene to ethylene oxide |
| US6184175B1 (en) * | 1993-03-01 | 2001-02-06 | Scientic Design Company, Inc. | Process for preparing silver catalyst |
| US5525740A (en) * | 1993-03-01 | 1996-06-11 | Scientific Design Company, Inc. | Process for preparing silver catalyst and process of using same to produce ethylene oxide |
| DE69433270T2 (de) * | 1994-08-04 | 2004-08-12 | Scientific Design Co. Inc. | Verfahren zur herstellung eines silberkatalysators |
| AU7558394A (en) * | 1994-08-09 | 1996-03-07 | Scientific Design Company, Inc. | Process for preparing silver catalyst |
| US5602070A (en) * | 1995-01-09 | 1997-02-11 | Scientific Design Company, Inc. | Process for preparing silver catalyst |
| US6455713B1 (en) | 1998-09-14 | 2002-09-24 | Eastman Chemical Company | Reactivation of Cs-promoted, Ag catalysts for the selective epoxidation of butadiene to 3,4-epoxy-1-butene |
| DE69928073T2 (de) * | 1999-02-19 | 2006-07-20 | Nippon Shokubai Co., Ltd. | Verfahren zur Herstellung von Acrylsäure und Verfahren zur Herstellung vom Katalysator |
| DE60109704D1 (de) | 2000-10-25 | 2005-05-04 | Mitsubishi Chem Corp | Verfahren zur Oxidation von Olefinen unter Verwendung eines Silber und Alkalimetall(e) enthaltenden Katalysator |
| KR100980123B1 (ko) * | 2002-06-28 | 2010-09-03 | 셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이 | 촉매 선택성을 향상시키는 방법 및 올레핀 에폭시화 방법 |
| US8148555B2 (en) * | 2003-06-26 | 2012-04-03 | Shell Oil Company | Method for improving the selectivity of a catalyst and a process for the epoxidation of an olefin |
| JP2009525848A (ja) * | 2006-02-03 | 2009-07-16 | シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー | 触媒の処理方法、触媒、および触媒の使用 |
| AR066468A1 (es) | 2007-05-09 | 2009-08-19 | Shell Int Research | Un catalizador de epoxidacion, un proceso para preparar el mismo, y un proceso para producir un oxido de olefina , un 1,2- diol, un 1,2 - diol eter, un 1,2- carbonato, o una alcanolamina |
| US20090148600A1 (en) * | 2007-12-05 | 2009-06-11 | Xerox Corporation | Metal Nanoparticles Stabilized With a Carboxylic Acid-Organoamine Complex |
| KR101629037B1 (ko) * | 2008-05-07 | 2016-06-09 | 셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이 | 에폭시화 방법의 스타트업 방법, 산화에틸렌, 1,2-디올, 1,2-디올 에테르, 1,2-카보네이트 또는 알칸올아민의 생산방법 |
| KR101629038B1 (ko) * | 2008-05-07 | 2016-06-09 | 셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이 | 산화올레핀, 1,2-디올, 1,2-디올 에테르, 1,2-카보네이트 또는 알칸올아민의 생산방법 |
| BR112019011162B1 (pt) | 2016-12-02 | 2022-08-16 | Shell Internationale Research Maatschappij B.V. | Método para o condicionamento de um catalisador de epoxidação de etileno e método para melhorar a seletividade do referido catalisador em um processo de epoxidação de etileno |
Family Cites Families (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US424235A (en) * | 1890-03-25 | Gearing for spring vehicles | ||
| US2391842A (en) * | 1942-10-16 | 1945-12-25 | Cities Service Oil Co | Lubricating greases |
| US2807553A (en) * | 1955-07-18 | 1957-09-24 | Heyden Newport Chemical Corp | Stabilized metal soap compositions |
| US2955949A (en) * | 1958-09-17 | 1960-10-11 | Exxon Research Engineering Co | Paint driers |
| US3255222A (en) * | 1961-10-23 | 1966-06-07 | Yardney International Corp | Silver salt complexes of fatty acids and method of making same |
| US3255223A (en) * | 1962-10-29 | 1966-06-07 | Yardney International Corp | Method of preparing stable silvercontaining compositions |
| US3702259A (en) * | 1970-12-02 | 1972-11-07 | Shell Oil Co | Chemical production of metallic silver deposits |
| US3962136A (en) * | 1972-01-07 | 1976-06-08 | Shell Oil Company | Catalyst for production of ethylene oxide |
| US4065442A (en) * | 1974-10-31 | 1977-12-27 | Standard Oil Company | Pyrolysis compositions from silver salts of polycarboxylic acids |
| US4005049A (en) * | 1975-05-23 | 1977-01-25 | Standard Oil Company (Indiana) | Silver catalysts |
| US4102820A (en) * | 1975-12-29 | 1978-07-25 | Texaco Development Corp. | Silver catalyst for ethylene epoxidation |
| US4066575A (en) * | 1976-07-26 | 1978-01-03 | Halcon International, Inc. | Process for the preparation of a supported silver catalyst |
| US4097414A (en) * | 1976-08-30 | 1978-06-27 | Texaco Development Corp. | Modified ethylene oxide catalyst and a process for its preparation |
| FR2412538A1 (fr) * | 1977-12-22 | 1979-07-20 | Ugine Kuhlmann | Catalyseurs a base d'argent pour la production d'oxyde d'ethylene |
| JPS54125603A (en) * | 1978-03-16 | 1979-09-29 | Kao Corp | Preparation of aliphatic amine |
| US4262040A (en) * | 1978-08-30 | 1981-04-14 | Engelhard Minerals & Chemicals Corporation | Decoration for ceramics having the appearance of gold |
| DE2904919A1 (de) * | 1979-02-09 | 1980-08-21 | Basf Ag | Verfahren zur herstellung und regenerierung von traegerkatalysatoren sowie deren verwendung fuer die herstellung von aethylenoxid |
| CA1162181A (en) * | 1979-03-20 | 1984-02-14 | Paul C. Ellgen | Catalyst composition and process for oxidation of ethylene to ethylene oxide |
| US4342667A (en) * | 1979-03-26 | 1982-08-03 | The Halcon Sd Group, Inc. | Process for preparing a silver catalyst |
| DE2925625C2 (de) * | 1979-06-26 | 1981-10-01 | Chemische Werke Hüls AG, 4370 Marl | Verfahren zur Steigerung der Aktivität und zur Verlängerung der Standzeit bei hoher Selektivität von Silber-Träger-Katalysatoren für den Einsatz zur Ethylenoxid-Synthese |
| DE3014091A1 (de) * | 1980-04-12 | 1981-10-15 | EC Erdölchemie GmbH, 5000 Köln | Silberhaltige traegerkatalysatoren und katalysator-zwischenprodukte, verfahren zu ihrer herstellung und ihre verwendung |
| FR2495958A1 (fr) * | 1980-12-12 | 1982-06-18 | Gau Georges | Catalyseurs a l'argent pour la synthese de l'oxyde d'ethylene et de l'oxyde de propylene par un procede regeneratif |
| US4368144A (en) * | 1980-12-22 | 1983-01-11 | Nippon Shokubai Kagaku Kogyo Co., Ltd. | Silver catalyst for production of ethylene oxide |
| JPS57107240A (en) * | 1980-12-26 | 1982-07-03 | Nippon Shokubai Kagaku Kogyo Co Ltd | Production of silver catalyst for producing ethylene oxide |
| US4419276A (en) * | 1981-09-30 | 1983-12-06 | Union Carbide Corporation | Silver catalyst for the manufacture of ethylene oxide and a process for preparing the catalyst |
-
1984
- 1984-05-14 US US06/610,229 patent/US4555501A/en not_active Expired - Lifetime
-
1985
- 1985-04-23 IN IN347/DEL/85A patent/IN169852B/en unknown
- 1985-04-29 CA CA000480269A patent/CA1250277A/en not_active Expired
- 1985-05-10 AU AU42282/85A patent/AU570113B2/en not_active Expired
- 1985-05-13 DE DE8585303359T patent/DE3570664D1/de not_active Expired
- 1985-05-13 BR BR8502254A patent/BR8502254A/pt not_active IP Right Cessation
- 1985-05-13 ES ES543098A patent/ES8606016A1/es not_active Expired
- 1985-05-13 JP JP60101181A patent/JPH0611398B2/ja not_active Expired - Lifetime
- 1985-05-13 YU YU79485A patent/YU45717B/sh unknown
- 1985-05-13 KR KR1019850003234A patent/KR920005083B1/ko not_active Expired
- 1985-05-13 EP EP85303359A patent/EP0161930B1/en not_active Expired
- 1985-05-13 BG BG70207A patent/BG60611B1/bg unknown
- 1985-05-13 RO RO118717A patent/RO92423B/ro unknown
- 1985-05-13 SU SU853898659A patent/SU1598856A3/ru active
- 1985-05-14 MX MX205289A patent/MX167584B/es unknown
- 1985-05-14 AR AR30036985A patent/AR240661A1/es active
- 1985-05-14 DD DD85276322A patent/DD233310A5/de unknown
- 1985-05-14 ZA ZA853653A patent/ZA853653B/xx unknown
-
1990
- 1990-08-20 YU YU158990A patent/YU47370B/sh unknown
-
1992
- 1992-12-24 MX MX9207577A patent/MX9207577A/es unknown
Also Published As
| Publication number | Publication date |
|---|---|
| CA1250277A (en) | 1989-02-21 |
| BG60611B1 (bg) | 1995-10-31 |
| YU47370B (sh) | 1995-01-31 |
| DD233310A5 (de) | 1986-02-26 |
| YU45717B (sh) | 1992-07-20 |
| JPS60244338A (ja) | 1985-12-04 |
| YU79485A (en) | 1987-10-31 |
| AU570113B2 (en) | 1988-03-03 |
| AU4228285A (en) | 1985-11-21 |
| JPH0611398B2 (ja) | 1994-02-16 |
| MX9207577A (es) | 1994-06-30 |
| DE3570664D1 (en) | 1989-07-06 |
| SU1598856A3 (ru) | 1990-10-07 |
| AR240661A1 (es) | 1990-08-31 |
| YU158990A (sh) | 1992-12-21 |
| ES8606016A1 (es) | 1986-04-01 |
| IN169852B (bg) | 1992-01-04 |
| ZA853653B (en) | 1986-12-30 |
| KR920005083B1 (ko) | 1992-06-26 |
| RO92423B (ro) | 1987-10-01 |
| US4555501A (en) | 1985-11-26 |
| ES543098A0 (es) | 1986-04-01 |
| MX167584B (es) | 1993-03-30 |
| BR8502254A (pt) | 1986-01-14 |
| KR850008630A (ko) | 1985-12-21 |
| EP0161930A2 (en) | 1985-11-21 |
| RO92423A (ro) | 1987-09-30 |
| EP0161930B1 (en) | 1989-05-31 |
| EP0161930A3 (en) | 1986-04-16 |
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