BG99508A - Метод за получаване на моно-олефини - Google Patents

Метод за получаване на моно-олефини Download PDF

Info

Publication number: BG99508A
Authority: BG; Bulgaria
Prior art keywords: reaction chamber; oxygen; gas; hydrocarbon; feedstock
Prior art date: 1992-08-20

Application number

BG99508A

Other languages

Bulgarian (bg)

English (en)

Inventor

Christopher Astbury

David Griffiths

Ian Reid

Original Assignee

D.S.I. Josef Breitwisch & Co.Gmbh

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1992-08-20

Filing date

1995-03-20

Publication date

1996-01-31

1995-03-20 Application filed by D.S.I. Josef Breitwisch & Co.Gmbh filed Critical D.S.I. Josef Breitwisch & Co.Gmbh

1996-01-31 Publication of BG99508A publication Critical patent/BG99508A/bg

Links

238000000034 method Methods 0.000 title claims abstract description 55
150000005673 monoalkenes Chemical class 0.000 title claims abstract description 11
238000004519 manufacturing process Methods 0.000 title description 7
229930195733 hydrocarbon Natural products 0.000 claims abstract description 65
150000002430 hydrocarbons Chemical class 0.000 claims abstract description 65
238000006243 chemical reaction Methods 0.000 claims abstract description 61
239000007789 gas Substances 0.000 claims abstract description 48
239000004215 Carbon black (E152) Substances 0.000 claims abstract description 38
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 37
239000001301 oxygen Substances 0.000 claims abstract description 37
229910052760 oxygen Inorganic materials 0.000 claims abstract description 37
239000003054 catalyst Substances 0.000 claims abstract description 32
238000002485 combustion reaction Methods 0.000 claims abstract description 21
239000000203 mixture Substances 0.000 claims abstract description 21
239000002994 raw material Substances 0.000 claims abstract description 18
125000004432 carbon atom Chemical group C* 0.000 claims abstract description 3
239000007788 liquid Substances 0.000 claims description 36
BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical group [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 15
KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 13
CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 12
238000005292 vacuum distillation Methods 0.000 claims description 8
229910052763 palladium Inorganic materials 0.000 claims description 7
239000003208 petroleum Substances 0.000 claims description 7
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 7
229910002092 carbon dioxide Inorganic materials 0.000 claims description 6
239000001569 carbon dioxide Substances 0.000 claims description 6
229910052697 platinum Inorganic materials 0.000 claims description 6
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 5
238000002360 preparation method Methods 0.000 claims description 4
229910052751 metal Inorganic materials 0.000 claims description 3
239000002184 metal Substances 0.000 claims description 3
VUZPPFZMUPKLLV-UHFFFAOYSA-N methane;hydrate Chemical compound C.O VUZPPFZMUPKLLV-UHFFFAOYSA-N 0.000 claims description 3
239000010779 crude oil Substances 0.000 claims description 2
238000004821 distillation Methods 0.000 claims 1
239000012188 paraffin wax Substances 0.000 abstract description 6
239000000463 material Substances 0.000 abstract description 3
238000010304 firing Methods 0.000 abstract 1
230000003197 catalytic effect Effects 0.000 description 19
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 16
OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 13
239000000047 product Substances 0.000 description 13
238000005336 cracking Methods 0.000 description 11
150000001336 alkenes Chemical class 0.000 description 10
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 8
229910052799 carbon Inorganic materials 0.000 description 8
239000001257 hydrogen Substances 0.000 description 8
229910052739 hydrogen Inorganic materials 0.000 description 8
229910052757 nitrogen Inorganic materials 0.000 description 8
239000003921 oil Substances 0.000 description 8
ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 6
239000003153 chemical reaction reagent Substances 0.000 description 6
238000001704 evaporation Methods 0.000 description 6
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 6
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 5
UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical class [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 5
230000008020 evaporation Effects 0.000 description 5
239000000446 fuel Substances 0.000 description 5
230000008901 benefit Effects 0.000 description 4
230000015572 biosynthetic process Effects 0.000 description 4
239000007795 chemical reaction product Substances 0.000 description 4
239000012809 cooling fluid Substances 0.000 description 4
239000012530 fluid Substances 0.000 description 4
VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 4
238000004458 analytical method Methods 0.000 description 3
229910002091 carbon monoxide Inorganic materials 0.000 description 3
239000000919 ceramic Substances 0.000 description 3
238000001816 cooling Methods 0.000 description 3
238000002156 mixing Methods 0.000 description 3
239000001294 propane Substances 0.000 description 3
QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 3
-1 propylene olefins Chemical class 0.000 description 3
150000003464 sulfur compounds Chemical class 0.000 description 3
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
239000001273 butane Substances 0.000 description 2
229910002090 carbon oxide Inorganic materials 0.000 description 2
238000004587 chromatography analysis Methods 0.000 description 2
230000000694 effects Effects 0.000 description 2
238000010438 heat treatment Methods 0.000 description 2
IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 2
OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 2
230000003647 oxidation Effects 0.000 description 2
238000007254 oxidation reaction Methods 0.000 description 2
239000002574 poison Substances 0.000 description 2
231100000614 poison Toxicity 0.000 description 2
239000007921 spray Substances 0.000 description 2
238000012546 transfer Methods 0.000 description 2
239000012808 vapor phase Substances 0.000 description 2
VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 1
KSSJBGNOJJETTC-UHFFFAOYSA-N COC1=C(C=CC=C1)N(C1=CC=2C3(C4=CC(=CC=C4C=2C=C1)N(C1=CC=C(C=C1)OC)C1=C(C=CC=C1)OC)C1=CC(=CC=C1C=1C=CC(=CC=13)N(C1=CC=C(C=C1)OC)C1=C(C=CC=C1)OC)N(C1=CC=C(C=C1)OC)C1=C(C=CC=C1)OC)C1=CC=C(C=C1)OC Chemical compound COC1=C(C=CC=C1)N(C1=CC=2C3(C4=CC(=CC=C4C=2C=C1)N(C1=CC=C(C=C1)OC)C1=C(C=CC=C1)OC)C1=CC(=CC=C1C=1C=CC(=CC=13)N(C1=CC=C(C=C1)OC)C1=C(C=CC=C1)OC)N(C1=CC=C(C=C1)OC)C1=C(C=CC=C1)OC)C1=CC=C(C=C1)OC KSSJBGNOJJETTC-UHFFFAOYSA-N 0.000 description 1
MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
239000005977 Ethylene Substances 0.000 description 1
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
JFBZPFYRPYOZCQ-UHFFFAOYSA-N [Li].[Al] Chemical compound [Li].[Al] JFBZPFYRPYOZCQ-UHFFFAOYSA-N 0.000 description 1
YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 description 1
HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 description 1
OUFSPJHSJZZGCE-UHFFFAOYSA-N aluminum lithium silicate Chemical compound [Li+].[Al+3].[O-][Si]([O-])([O-])[O-] OUFSPJHSJZZGCE-UHFFFAOYSA-N 0.000 description 1
150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 1
239000000969 carrier Substances 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
150000003841 chloride salts Chemical class 0.000 description 1
230000000052 comparative effect Effects 0.000 description 1
150000001875 compounds Chemical class 0.000 description 1
238000007796 conventional method Methods 0.000 description 1
229920001577 copolymer Polymers 0.000 description 1
230000018044 dehydration Effects 0.000 description 1
238000006297 dehydration reaction Methods 0.000 description 1
238000013461 design Methods 0.000 description 1
238000011161 development Methods 0.000 description 1
229910001882 dioxygen Inorganic materials 0.000 description 1
238000005516 engineering process Methods 0.000 description 1
125000002534 ethynyl group Chemical group [H]C#C* 0.000 description 1
238000002474 experimental method Methods 0.000 description 1
150000002431 hydrogen Chemical class 0.000 description 1
238000005470 impregnation Methods 0.000 description 1
239000011261 inert gas Substances 0.000 description 1
239000003915 liquefied petroleum gas Substances 0.000 description 1
229940057995 liquid paraffin Drugs 0.000 description 1
229910001510 metal chloride Inorganic materials 0.000 description 1
YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 1
239000007858 starting material Substances 0.000 description 1
239000000126 substance Substances 0.000 description 1
229910052717 sulfur Inorganic materials 0.000 description 1
239000011593 sulfur Substances 0.000 description 1
230000000153 supplemental effect Effects 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/42—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor
- C07C5/48—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor with oxygen as an acceptor
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
- C10G11/20—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils by direct contact with inert heated gases or vapours
- C10G11/22—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils by direct contact with inert heated gases or vapours produced by partial combustion of the material to be cracked
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
- C10G2400/20—C2-C4 olefins

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Engineering & Computer Science (AREA)
Oil, Petroleum & Natural Gas (AREA)
Combustion & Propulsion (AREA)
Chemical Kinetics & Catalysis (AREA)
General Chemical & Material Sciences (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Crystals, And After-Treatments Of Crystals (AREA)
Saccharide Compounds (AREA)

BG99508A 1992-08-20 1995-03-20 Метод за получаване на моно-олефини BG99508A (bg)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
GB929217685A GB9217685D0 (en)	1992-08-20	1992-08-20	Process for the production of mono-olefins
PCT/GB1993/001741 WO1994004632A1 (en)	1992-08-20	1993-08-17	Process for the production of mono-olefins

Publications (1)

Publication Number	Publication Date
BG99508A true BG99508A (bg)	1996-01-31

Family

ID=10720652

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
BG99508A BG99508A (bg)	1992-08-20	1995-03-20	Метод за получаване на моно-олефини

Country Status (19)

Country	Link
US (1)	US5625111A (de)
EP (1)	EP0656044B1 (de)
CN (1)	CN1090566A (de)
AT (1)	ATE148914T1 (de)
AU (1)	AU4727193A (de)
BG (1)	BG99508A (de)
BR (1)	BR9306931A (de)
CZ (1)	CZ37395A3 (de)
DE (1)	DE69308145T2 (de)
GB (1)	GB9217685D0 (de)
HR (1)	HRP931121B1 (de)
HU (1)	HU213941B (de)
PL (1)	PL174161B1 (de)
RO (1)	RO116907B1 (de)
RU (1)	RU2115692C1 (de)
SI (1)	SI9300441A (de)
SK (1)	SK23195A3 (de)
WO (1)	WO1994004632A1 (de)
ZA (1)	ZA936019B (de)

Families Citing this family (34)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
GB9421734D0 (en) *	1994-10-28	1994-12-14	Bp Chem Int Ltd	Hydrocarbon conversion process
US5905180A (en)	1996-01-22	1999-05-18	Regents Of The University Of Minnesota	Catalytic oxidative dehydrogenation process and catalyst
US6254807B1 (en)	1998-01-12	2001-07-03	Regents Of The University Of Minnesota	Control of H2 and CO produced in partial oxidation process
ES2183610T3 (es)	1998-09-03	2003-03-16	Dow Global Technologies Inc	Sintesis y regeneracion en linea de un catalizador usado en oxidacion autotermica.
DE69909490T2 (de)	1998-09-03	2004-05-27	Dow Global Technologies, Inc., Midland	Autothermisches verfahren zur herstellung von olefinen
GB9819603D0 (en) *	1998-09-08	1998-11-04	Bp Chem Int Ltd	Process for the production of olefins
GB9828337D0 (en) *	1998-12-22	1999-02-17	Bp Chem Int Ltd	Process for the production of olefins
CA2395380C (en)	1999-12-23	2008-10-14	Bp Chemicals Limited	Process for the production of olefins
WO2001047842A1 (en) *	1999-12-23	2001-07-05	Bp Chemicals Limited	Process for the production of olefins
GB0010693D0 (en) *	2000-05-03	2000-06-28	Bp Chem Int Ltd	Process for the production of olefins
GB0017075D0 (en)	2000-07-11	2000-08-30	Bp Chem Int Ltd	Process for the production of olefins
GB0025081D0 (en) *	2000-10-13	2000-11-29	Bp Chem Int Ltd	Process for monitoring loss of reaction
CA2443139A1 (en) *	2001-04-06	2002-10-17	The Lubrizol Corporation	Atomized polysulfide used in ethylene steam cracker
GB0204140D0 (en)	2002-02-22	2002-04-10	Bp Chem Int Ltd	Production of olefins
US7145051B2 (en) *	2002-03-22	2006-12-05	Exxonmobil Chemical Patents Inc.	Combined oxydehydrogenation and cracking catalyst for production of olefins
US20040068148A1 (en) *	2002-10-08	2004-04-08	Conoco Inc.	Oxidative dehydrogenation of hydrocarbons using catalysts with trace promoter metal loading
US20040068153A1 (en) *	2002-10-08	2004-04-08	Conoco Inc.	Rare earth metals as oxidative dehydrogenation catalysts
ITMI20022710A1 (it) *	2002-12-20	2004-06-21	Enitecnologie Spa	Procedimento e reattore per la produzione di olefine leggere mediante reazione di steam cracking di cariche idrocarburiche liquide in presenza di catalizzatore
US7125817B2 (en) *	2003-02-20	2006-10-24	Exxonmobil Chemical Patents Inc.	Combined cracking and selective hydrogen combustion for catalytic cracking
US7122493B2 (en) *	2003-02-05	2006-10-17	Exxonmobil Chemical Patents Inc.	Combined cracking and selective hydrogen combustion for catalytic cracking
US7122495B2 (en) *	2003-02-05	2006-10-17	Exxonmobil Chemical Patents Inc.	Combined cracking and selective hydrogen combustion for catalytic cracking
US7122492B2 (en) *	2003-02-05	2006-10-17	Exxonmobil Chemical Patents Inc.	Combined cracking and selective hydrogen combustion for catalytic cracking
US7122494B2 (en) *	2003-02-05	2006-10-17	Exxonmobil Chemical Patents Inc.	Combined cracking and selective hydrogen combustion for catalytic cracking
AU2004226137A1 (en) *	2003-04-03	2004-10-14	Ineos Europe Limited	Autothermal cracking process
GB0312093D0 (en) *	2003-05-27	2003-07-02	Bp Chem Int Ltd	Process for the production of olefins
US7074977B2 (en) *	2003-12-09	2006-07-11	Conocophillips Company	Reactor and process for converting alkanes to alkenes
GB0423427D0 (en) *	2004-10-21	2004-11-24	Bp Chem Int Ltd	Olefins shipping
GB0501255D0 (en) *	2005-01-21	2005-03-02	Bp Chem Int Ltd	Process for the production of olefins
GB0501253D0 (en) *	2005-01-21	2005-03-02	Bp Chem Int Ltd	Process for the production of olefins
GB0613676D0 (en) *	2006-07-10	2006-08-16	Ineos Europe Ltd	Process
US7999144B2 (en) *	2006-09-01	2011-08-16	Velocys	Microchannel apparatus and methods of conducting catalyzed oxidative dehydrogenation
RU2415702C1 (ru) *	2009-12-22	2011-04-10	Юрий Павлович Скакунов	Установка для обработки углеводородосодержащих жидких сред и способ ее работы
FR3092117B1 (fr) *	2019-01-25	2021-01-29	Pierre Dumons	Procédé et dispositif de production de produits énergétiques par craquage catalytique d’un matériau solide hydrocarboné sans formation de coke
JP2023103558A (ja) *	2022-01-14	2023-07-27	株式会社日立製作所	メタネーション反応器

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Publication number	Priority date	Publication date	Assignee	Title
FR1113102A (fr) *	1954-08-30	1956-03-23		Procédé et four de traitement et de transformation thermique physique et chimique
DE1093948B (de) *	1960-06-02	1960-12-01	Carl Mertens	Katalytische Umformungsanlage zur kontinuierlichen Erzeugung von Gasen aller Art aus Kohlenwasserstoffen
DE1680261C3 (de) *	1967-09-15	1979-09-20	Keiper Automobiltechnik & Co, 5630 Remscheid	Gelenkbeschlag für Sitze, insbesondere Kraftfahrzeugsitze
US3765851A (en) *	1970-12-14	1973-10-16	Chervon Res Co	Gas production
DE2723685A1 (de) *	1977-05-25	1978-11-30	Siemens Ag	Spaltgasgenerator zur katalytischen umsetzung von fluessigem brennstoff mit einem sauerstoffhaltigen gas
US4760210A (en) *	1981-01-27	1988-07-26	Sweeney Maxwell P	Partial oxidation system
JPS6247232A (ja) *	1985-08-24	1987-02-28	Fujitsu Ltd	回線切替方式
FR2624115B1 (fr) *	1987-12-03	1990-04-13	Gaz De France	Procede et appareil pour la conversion des hydrocarbures
GB8805447D0 (en) *	1988-03-08	1988-04-07	British Petroleum Co Plc	Chemical process
FR2660305A1 (fr) *	1990-03-27	1991-10-04	Come Guy Marie	Procede de conversion d'hydrocarbures satures.

1992
- 1992-08-20 GB GB929217685A patent/GB9217685D0/en active Pending
1993
- 1993-08-17 RO RO95-00315A patent/RO116907B1/ro unknown
- 1993-08-17 AT AT93918038T patent/ATE148914T1/de not_active IP Right Cessation
- 1993-08-17 DE DE69308145T patent/DE69308145T2/de not_active Expired - Fee Related
- 1993-08-17 SK SK231-95A patent/SK23195A3/sk unknown
- 1993-08-17 PL PL93307559A patent/PL174161B1/pl unknown
- 1993-08-17 AU AU47271/93A patent/AU4727193A/en not_active Abandoned
- 1993-08-17 ZA ZA936019A patent/ZA936019B/xx unknown
- 1993-08-17 RU RU95108257A patent/RU2115692C1/ru not_active IP Right Cessation
- 1993-08-17 CZ CZ95373A patent/CZ37395A3/cs unknown
- 1993-08-17 WO PCT/GB1993/001741 patent/WO1994004632A1/en not_active Ceased
- 1993-08-17 BR BR9306931A patent/BR9306931A/pt not_active Application Discontinuation
- 1993-08-17 HU HU9500489A patent/HU213941B/hu not_active IP Right Cessation
- 1993-08-17 EP EP93918038A patent/EP0656044B1/de not_active Expired - Lifetime
- 1993-08-19 HR HR9217685.8A patent/HRP931121B1/xx not_active IP Right Cessation
- 1993-08-20 SI SI9300441A patent/SI9300441A/sl unknown
- 1993-08-20 CN CN93118265A patent/CN1090566A/zh active Pending
1995
- 1995-01-04 US US08/368,720 patent/US5625111A/en not_active Expired - Fee Related
- 1995-03-20 BG BG99508A patent/BG99508A/bg unknown

Also Published As

Publication number	Publication date
SI9300441A (en)	1994-03-31
DE69308145D1 (de)	1997-03-27
HU213941B (en)	1997-11-28
HU9500489D0 (en)	1995-04-28
EP0656044B1 (de)	1997-02-12
HUT71164A (en)	1995-11-28
HRP931121B1 (en)	1998-12-31
RU95108257A (ru)	1997-01-10
PL307559A1 (en)	1995-05-29
CN1090566A (zh)	1994-08-10
PL174161B1 (pl)	1998-06-30
ZA936019B (en)	1995-02-17
SK23195A3 (en)	1995-07-11
AU4727193A (en)	1994-03-15
DE69308145T2 (de)	1997-05-28
US5625111A (en)	1997-04-29
RU2115692C1 (ru)	1998-07-20
RO116907B1 (ro)	2001-07-30
EP0656044A1 (de)	1995-06-07
ATE148914T1 (de)	1997-02-15
GB9217685D0 (en)	1992-09-30
CZ37395A3 (en)	1995-10-18
HRP931121A2 (en)	1994-12-31
WO1994004632A1 (en)	1994-03-03
BR9306931A (pt)	1999-01-12

Publication	Publication Date	Title
RU2115692C1 (ru)	1998-07-20	Способ получения моноолефинов
KR100199684B1 (ko)	1999-06-15	모노올레핀류의 제조방법
CA1316946C (en)	1993-04-27	Process for the production of mono-olefins by the catalytic oxidative dehydrogenation of gaseous paraffinic hydrocarbons having two or more carbon atoms
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