BR0010688A - Ëxidos mistos modificados superficialmente contendo metal nobre e titânio para a oxidação seletiva de hidrocarbonetos - Google Patents
Ëxidos mistos modificados superficialmente contendo metal nobre e titânio para a oxidação seletiva de hidrocarbonetosInfo
- Publication number
- BR0010688A BR0010688A BR0010688-7A BR0010688A BR0010688A BR 0010688 A BR0010688 A BR 0010688A BR 0010688 A BR0010688 A BR 0010688A BR 0010688 A BR0010688 A BR 0010688A
- Authority
- BR
- Brazil
- Prior art keywords
- titanium
- mixed oxides
- oxides containing
- noble metal
- containing noble
- Prior art date
Links
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 title abstract 3
- 229930195733 hydrocarbon Natural products 0.000 title abstract 3
- 150000002430 hydrocarbons Chemical class 0.000 title abstract 3
- 230000003647 oxidation Effects 0.000 title abstract 3
- 238000007254 oxidation reaction Methods 0.000 title abstract 3
- 229910052719 titanium Inorganic materials 0.000 title abstract 3
- 239000010936 titanium Substances 0.000 title abstract 3
- 239000004215 Carbon black (E152) Substances 0.000 title 1
- 229910000510 noble metal Inorganic materials 0.000 title 1
- 239000000203 mixture Substances 0.000 abstract 4
- 238000000034 method Methods 0.000 abstract 3
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 125000003118 aryl group Chemical group 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- 239000003638 chemical reducing agent Substances 0.000 abstract 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 abstract 1
- 239000010931 gold Substances 0.000 abstract 1
- 229910052737 gold Inorganic materials 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- 239000002245 particle Substances 0.000 abstract 1
- 229910052710 silicon Inorganic materials 0.000 abstract 1
- 239000010703 silicon Substances 0.000 abstract 1
- 229910052709 silver Inorganic materials 0.000 abstract 1
- 239000004332 silver Substances 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0272—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing elements other than those covered by B01J31/0201 - B01J31/0255
- B01J31/0274—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing elements other than those covered by B01J31/0201 - B01J31/0255 containing silicon
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/48—Silver or gold
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/89—Silicates, aluminosilicates or borosilicates of titanium, zirconium or hafnium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
- B01J31/122—Metal aryl or alkyl compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D301/00—Preparation of oxiranes
- C07D301/02—Synthesis of the oxirane ring
- C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
- C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
- C07D301/08—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
- C07D301/10—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase with catalysts containing silver or gold
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
- C07D303/02—Compounds containing oxirane rings
- C07D303/04—Compounds containing oxirane rings containing only hydrogen and carbon atoms in addition to the ring oxygen atoms
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/70—Oxidation reactions, e.g. epoxidation, (di)hydroxylation, dehydrogenation and analogues
- B01J2231/72—Epoxidation
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Epoxy Compounds (AREA)
Abstract
Patente de Invenção: "óXIDOS MISTOS MODIFICADOS SUPERFICIALMENTE CONTENDO METAL NOBRE E TITâNIO PARA A OXIDAçãO SELETIVA DE HIDROCARBONETOS". A presente invenção refere-se a um processo para a preparação de uma composição contendo partículas de ouro e/ou prata, óxidos mistos contendo titânio e silício, os quais foram modificados superficialmente, de modo que a composição em sua superfície porta grupos escolhidos de grupos silício-alquila, alquila-fluorados ou grupos arila-fluorados, as composições preparáveis neste processo, bem como seu emprego em processos para a oxidação seletiva de hidrocarbonetos na presença de oxigênio e um agente de redução. As composições cataliticamente ativas mostram altas seletividades e produtividades invariáveis.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19918431A DE19918431A1 (de) | 1999-04-23 | 1999-04-23 | Verfahren zur Herstellung eines Katalysators zur selektiven Oxidation von Kohlenwasserstoffen |
| PCT/EP2000/003491 WO2000064582A1 (de) | 1999-04-23 | 2000-04-18 | Edelmetall- und titan-haltige oberflächenmodifizierte mischoxide zur selektiven oxidation von kohlenwasserstoffen |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| BR0010688A true BR0010688A (pt) | 2002-02-19 |
Family
ID=7905595
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BR0010688-7A BR0010688A (pt) | 1999-04-23 | 2000-04-18 | Ëxidos mistos modificados superficialmente contendo metal nobre e titânio para a oxidação seletiva de hidrocarbonetos |
Country Status (15)
| Country | Link |
|---|---|
| US (2) | US6734133B1 (pt) |
| EP (1) | EP1185365A1 (pt) |
| JP (1) | JP2002542031A (pt) |
| KR (1) | KR20020007381A (pt) |
| CN (1) | CN1347340A (pt) |
| AU (1) | AU4913100A (pt) |
| BR (1) | BR0010688A (pt) |
| CA (1) | CA2370796A1 (pt) |
| CZ (1) | CZ20013811A3 (pt) |
| DE (1) | DE19918431A1 (pt) |
| HU (1) | HUP0200811A2 (pt) |
| MX (1) | MXPA01010736A (pt) |
| PL (1) | PL351570A1 (pt) |
| TW (1) | TW539574B (pt) |
| WO (1) | WO2000064582A1 (pt) |
Families Citing this family (29)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19920753A1 (de) | 1999-04-23 | 2000-10-26 | Bayer Ag | Verfahren zur Herstellung von amorphen, edelmetallhaltigen Titan-Silizium-Mischoxiden |
| DE19959525A1 (de) * | 1999-12-09 | 2001-06-13 | Bayer Ag | Katalysatoren auf Basis Edelmetall- und Titan-haltiger, organisch-anorganisch Hybridmaterialien zur selektiven Oxidation von Kohlenwasserstoffen |
| JP4694712B2 (ja) * | 2001-01-15 | 2011-06-08 | 丸善石油化学株式会社 | チタン含有固体触媒及びこれを用いたエポキシ化合物の製造法 |
| AU2002317607A1 (en) * | 2001-08-01 | 2003-02-17 | Dow Global Technologies Inc. | Method of increasing the lifetime of a hydro-oxidation catalyst |
| EP1488853A4 (en) * | 2002-03-04 | 2011-11-02 | Sumitomo Chemical Co | PROCESS FOR IMPROVING CRYSTALLINE TITANICILICATE CATALYST WITH MWW STRUCTURE |
| US7435865B2 (en) * | 2003-08-18 | 2008-10-14 | Vrije Universiteit Brussel | Method for separating hydrocarbons and use of a zeolite therefor |
| US7348293B2 (en) * | 2003-12-05 | 2008-03-25 | Chevron U.S.A. Inc. | Homogeneous modified-alumina Fischer-Tropsch catalyst supports |
| US7329624B1 (en) * | 2004-08-16 | 2008-02-12 | Uop Llc | Regenerable adsorbents for the purification of silicone based solvents |
| US7713907B2 (en) * | 2006-03-06 | 2010-05-11 | Uchicago Argonne, Llc | Method of preparing size-selected metal clusters |
| JP5176426B2 (ja) * | 2007-03-16 | 2013-04-03 | 住友化学株式会社 | シクロアルカノール及び/又はシクロアルカノンの製造方法 |
| US7662476B2 (en) * | 2008-06-13 | 2010-02-16 | The Worthington Group of Tennessee, LLC | Metal surface-modified silica-titania composites and methods for forming the same |
| US9475998B2 (en) | 2008-10-09 | 2016-10-25 | Ceramatec, Inc. | Process for recovering alkali metals and sulfur from alkali metal sulfides and polysulfides |
| US9688920B2 (en) | 2009-11-02 | 2017-06-27 | Field Upgrading Limited | Process to separate alkali metal salts from alkali metal reacted hydrocarbons |
| US9441170B2 (en) | 2012-11-16 | 2016-09-13 | Field Upgrading Limited | Device and method for upgrading petroleum feedstocks and petroleum refinery streams using an alkali metal conductive membrane |
| US9546325B2 (en) | 2009-11-02 | 2017-01-17 | Field Upgrading Limited | Upgrading platform using alkali metals |
| ES2656073T3 (es) | 2009-11-02 | 2018-02-23 | Field Upgrading Limited | Mejoramiento de materias primas de petróleo que usan metales alcalinos e hidrocarburos |
| US9512368B2 (en) | 2009-11-02 | 2016-12-06 | Field Upgrading Limited | Method of preventing corrosion of oil pipelines, storage structures and piping |
| WO2011155407A1 (ja) * | 2010-06-07 | 2011-12-15 | セントラル硝子株式会社 | 保護膜形成用薬液 |
| US9228120B2 (en) | 2010-06-07 | 2016-01-05 | Central Glass Company, Limited | Liquid chemical for forming protecting film |
| CN102755907A (zh) * | 2011-04-28 | 2012-10-31 | 中国科学院大连化学物理研究所 | 一种烃类催化选择氧化的方法 |
| US20120304530A1 (en) * | 2011-06-03 | 2012-12-06 | Pallavi Chitta | Bio-Oil Upgrading Process |
| JP6062936B2 (ja) | 2011-07-15 | 2017-01-18 | フィールド アップグレーディング リミテッド | アルカリ金属を使用する石油原料の改質 |
| CN103030611B (zh) * | 2011-09-30 | 2015-02-11 | 中国石油化工股份有限公司 | 生产环氧丙烷的方法 |
| CA2878630A1 (en) | 2012-07-13 | 2014-01-16 | Ceramatec, Inc. | Integrated oil production and upgrading using a molten alkali metal |
| CN103627174B (zh) * | 2013-09-06 | 2015-10-28 | 杭州师范大学 | 一种尺寸可控的银钛纳米颗粒复合材料的制备方法与应用 |
| TWI594951B (zh) * | 2016-06-14 | 2017-08-11 | 東聯化學股份有限公司 | Preparation and Application of Titanium Oxide - containing Materials |
| US11123711B2 (en) | 2017-12-28 | 2021-09-21 | University Of Kentucky Research Foundation | System and method for alcohol oxidation reaction of lignins |
| KR102060081B1 (ko) * | 2019-04-29 | 2019-12-30 | 한국과학기술연구원 | 테트라알콕시실란의 연속 제조방법 |
| CN111054435B (zh) * | 2019-12-30 | 2023-01-24 | 苏州东杏表面技术有限公司 | 一种新型负载型Pt催化剂及其制备方法和在氢硅加成中的应用 |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3923843A (en) * | 1972-03-13 | 1975-12-02 | Shell Oil Co | Epoxidation process with improved heterogeneous catalyst |
| DE4110706C1 (pt) * | 1991-04-03 | 1992-12-17 | Degussa Ag, 6000 Frankfurt, De | |
| JP3658790B2 (ja) | 1995-03-30 | 2005-06-08 | 住友化学株式会社 | 触媒及びオキシラン化合物の製造方法 |
| DE19545042A1 (de) * | 1995-12-02 | 1997-06-05 | Studiengesellschaft Kohle Mbh | Amorphe mikroporöse Mischoxidkatalysatoren mit kontrollierter Oberflächenpolarität für die selektive heterogene Katalyse Adsorption und Stofftrennung |
| US5763630A (en) | 1996-03-18 | 1998-06-09 | Arco Chemical Technology, L.P. | Propylene oxide process using alkaline earth metal compound-supported silver catalysts |
| US5932750A (en) | 1996-03-21 | 1999-08-03 | Agency Of Industrial Science And Technology | Catalysts for partial oxidation of hydrocarbons and method of partial oxidation of hydrocarbons |
| JP2001505184A (ja) | 1996-07-01 | 2001-04-17 | ザ・ダウ・ケミカル・カンパニー | オレフィン類のオレフィンオキシド類への直接酸化方法 |
| US5760254A (en) | 1996-07-18 | 1998-06-02 | Arco Chemical Technology, L.P. | Production of oxirane compounds |
| US5703254A (en) | 1996-10-02 | 1997-12-30 | Arco Chemical Technology, L.P. | Propylene oxide process using mixed precious metal catalyst supported on alkaline earth metal carbonate |
| JP2001524475A (ja) | 1997-11-24 | 2001-12-04 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | 有機化合物の選択的酸化方法 |
| DE19804712A1 (de) | 1998-02-06 | 1999-08-12 | Bayer Ag | Verfahren zur Standzeitverlängerung von mit Goldteilen belegten Trägerkatalysatoren für die Oxidation ungesättigter Kohlenwasserstoffe |
| EP1005907A4 (en) | 1998-02-24 | 2000-12-27 | Agency Ind Science Techn | CATALYST FOR PARTIAL OXIDATION OF UNSATURATED HYDROCARBONS |
-
1999
- 1999-04-23 DE DE19918431A patent/DE19918431A1/de not_active Withdrawn
-
2000
- 2000-04-17 TW TW089107122A patent/TW539574B/zh active
- 2000-04-18 CA CA002370796A patent/CA2370796A1/en not_active Abandoned
- 2000-04-18 JP JP2000613566A patent/JP2002542031A/ja active Pending
- 2000-04-18 BR BR0010688-7A patent/BR0010688A/pt not_active IP Right Cessation
- 2000-04-18 US US09/980,603 patent/US6734133B1/en not_active Expired - Fee Related
- 2000-04-18 AU AU49131/00A patent/AU4913100A/en not_active Abandoned
- 2000-04-18 CZ CZ20013811A patent/CZ20013811A3/cs unknown
- 2000-04-18 EP EP00931062A patent/EP1185365A1/de not_active Withdrawn
- 2000-04-18 PL PL00351570A patent/PL351570A1/xx not_active Application Discontinuation
- 2000-04-18 CN CN00806486A patent/CN1347340A/zh active Pending
- 2000-04-18 MX MXPA01010736A patent/MXPA01010736A/es unknown
- 2000-04-18 WO PCT/EP2000/003491 patent/WO2000064582A1/de not_active Ceased
- 2000-04-18 HU HU0200811A patent/HUP0200811A2/hu unknown
- 2000-04-18 KR KR1020017013437A patent/KR20020007381A/ko not_active Withdrawn
-
2004
- 2004-03-22 US US10/806,010 patent/US20040176621A1/en not_active Abandoned
Also Published As
| Publication number | Publication date |
|---|---|
| US6734133B1 (en) | 2004-05-11 |
| KR20020007381A (ko) | 2002-01-26 |
| WO2000064582A1 (de) | 2000-11-02 |
| US20040176621A1 (en) | 2004-09-09 |
| JP2002542031A (ja) | 2002-12-10 |
| DE19918431A1 (de) | 2000-10-26 |
| TW539574B (en) | 2003-07-01 |
| HUP0200811A2 (en) | 2002-06-29 |
| MXPA01010736A (es) | 2002-06-04 |
| CA2370796A1 (en) | 2000-11-02 |
| AU4913100A (en) | 2000-11-10 |
| PL351570A1 (en) | 2003-05-05 |
| EP1185365A1 (de) | 2002-03-13 |
| CZ20013811A3 (cs) | 2002-06-12 |
| CN1347340A (zh) | 2002-05-01 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| B08F | Application dismissed because of non-payment of annual fees [chapter 8.6 patent gazette] |
Free format text: REFERENTE A 5A, 6A E 7A ANUIDADES. |
|
| B08K | Patent lapsed as no evidence of payment of the annual fee has been furnished to inpi [chapter 8.11 patent gazette] |
Free format text: REFERENTE AO DESPACHO 8.6 PUBLICADO NA RPI 1927 DE 11/12/2007. |